BR0308921A - Resinatos de ácidos graxos de monÈmero - Google Patents
Resinatos de ácidos graxos de monÈmeroInfo
- Publication number
- BR0308921A BR0308921A BR0308921-5A BR0308921A BR0308921A BR 0308921 A BR0308921 A BR 0308921A BR 0308921 A BR0308921 A BR 0308921A BR 0308921 A BR0308921 A BR 0308921A
- Authority
- BR
- Brazil
- Prior art keywords
- fatty acid
- resin
- acid resins
- monomer fatty
- rosin
- Prior art date
Links
- 235000014113 dietary fatty acids Nutrition 0.000 title abstract 2
- 229930195729 fatty acid Natural products 0.000 title abstract 2
- 239000000194 fatty acid Substances 0.000 title abstract 2
- 150000004665 fatty acids Chemical class 0.000 title 1
- 239000000178 monomer Substances 0.000 title 1
- 229920005989 resin Polymers 0.000 title 1
- 239000011347 resin Substances 0.000 title 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 2
- 239000000976 ink Substances 0.000 abstract 2
- 239000011342 resin composition Substances 0.000 abstract 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 125000005313 fatty acid group Chemical group 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 238000001459 lithography Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
- C08G8/34—Chemically modified polycondensates by natural resins or resin acids, e.g. rosin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyesters Or Polycarbonates (AREA)
- Fats And Perfumes (AREA)
Abstract
"RESINATOS DE áCIDOS GRAXOS DE MONÈMERO". Composições de rosina reduzida de tintas de impressão e os aglutinantes de resinato inclusos, e os processos de preparação destes, são descritos. Nas referidas composições, uma porção da rosina normalmente empregada na técnica é substituída por Monómero, e é também reagida com um composto carboxílico <244>, <225>-insaturado, sal de metal alcalino, e solvente para produzir o produto aglutinante de resinato. O referido aglutinante de resinato pode então ser formulado com um corante para produzir uma tinta, preferivelmente para emprego em fotogravura de publicação.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36910602P | 2002-03-28 | 2002-03-28 | |
| PCT/US2003/009660 WO2003082984A1 (en) | 2002-03-28 | 2003-03-28 | Resinates from monomer fatty acids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0308921A true BR0308921A (pt) | 2005-01-04 |
| BR0308921B1 BR0308921B1 (pt) | 2013-11-19 |
Family
ID=28675566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0308921-5B1A BR0308921B1 (pt) | 2002-03-28 | 2003-03-28 | Composição de resinato de monômero de ácido graxo, seu processo de preparação, tinta de impressão e verniz de tinta de impressão |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6875842B2 (pt) |
| EP (2) | EP1490438B1 (pt) |
| AT (1) | ATE434645T1 (pt) |
| AU (1) | AU2003226126A1 (pt) |
| BR (1) | BR0308921B1 (pt) |
| CA (1) | CA2480640C (pt) |
| DE (1) | DE60328088D1 (pt) |
| MX (1) | MXPA04009446A (pt) |
| WO (1) | WO2003082984A1 (pt) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040176559A1 (en) | 2003-03-05 | 2004-09-09 | Fontana Thomas A. | Rosin phenolic resins for printing inks |
| BRPI0408070A (pt) * | 2003-03-05 | 2006-02-14 | Arizona Chem | resinas fenólicas de resina colofÈnia e usos relacionados a estas |
| US7256162B2 (en) * | 2003-09-26 | 2007-08-14 | Arizona Chemical Company | Fatty acid esters and uses thereof |
| US20060111502A1 (en) * | 2004-10-18 | 2006-05-25 | Groeneveld Daan Y | Teak deck caulking |
| WO2006105306A2 (en) * | 2005-03-29 | 2006-10-05 | Arizona Chemical Company | Compostions containing fatty acids and/or derivatives thereof and a low temperature stabilizer |
| KR100698699B1 (ko) * | 2005-08-01 | 2007-03-23 | 삼성에스디아이 주식회사 | 데이터 구동회로와 이를 이용한 발광 표시장치 및 그의구동방법 |
| EP2940072B1 (en) | 2005-08-09 | 2020-05-27 | Kraton Chemical, LLC | Rubber compositions containing improved tackifiers |
| EP2016147B1 (en) | 2006-05-09 | 2017-07-26 | Arizona Chemical Company | Water-soluble rosin acid esters |
| US8444758B2 (en) * | 2006-10-19 | 2013-05-21 | Eastman Chemical Company | Low voc additives for extending the wet edge and open time of aqueous coatings |
| US20080092776A1 (en) * | 2006-10-19 | 2008-04-24 | Rebecca Reid Stockl | Low-VOC additives for extending wet edge and open times of coatings |
| AR065015A1 (es) * | 2007-01-26 | 2009-05-13 | Smithkline Beecham Corp | Derivados de antranilamida, composiciones farmaceuticas que los contienen, y usos para el tratamiento del cancer |
| PT106499B (pt) * | 2012-08-13 | 2014-11-12 | Euro Yser Produtos Químicos S A | Processo de produção de resina de colofónia, produto obtido pelo referido processo, e sua utilização |
| US10462151B2 (en) * | 2015-11-17 | 2019-10-29 | Avaya Inc. | Temporary access of a user profile |
| EP3378908A1 (en) * | 2017-03-23 | 2018-09-26 | Siegwerk Druckfarben AG & Co. KGaA | Gravure printing ink |
| WO2018226728A1 (en) * | 2017-06-06 | 2018-12-13 | Ingevity South Carolina, Llc | Tall oil pitch based binders, methods of producing the same, and uses thereof |
| EP3668933B1 (en) * | 2017-08-17 | 2022-02-23 | Sun Chemical Corporation | Water-based inks with high renewable content |
| JP7139193B2 (ja) * | 2018-08-28 | 2022-09-20 | サカタインクス株式会社 | プラズマ硬化用インキ組成物 |
| CN121039223A (zh) | 2023-05-30 | 2025-11-28 | 陶氏环球技术有限责任公司 | 粘合剂组合物 |
| WO2025050086A1 (en) | 2023-08-31 | 2025-03-06 | Dow Global Technologies Llc | Adhesive composition with compatibilizer |
Family Cites Families (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB417845A (en) * | 1933-01-14 | 1934-10-15 | Henleys Telegraph Works Co Ltd | Improvements in the manufacture of hard or highly viscous materials |
| US2369125A (en) * | 1941-06-28 | 1945-02-13 | Hercules Powder Co Ltd | Rosin esters and method of producing |
| US2478490A (en) * | 1946-08-12 | 1949-08-09 | Krumbhaar William | Rosin modified phenol formaldehyde resins of enlarged molecular size |
| US2590910A (en) * | 1947-05-08 | 1952-04-01 | Gen Mills Inc | Rosin acid esters |
| US2572086A (en) * | 1947-05-08 | 1951-10-23 | Gen Mills Inc | Rosin acid esters |
| US3468829A (en) * | 1964-10-31 | 1969-09-23 | Arakawa Rinsan Kagaku Kogyo Kk | Gravure ink for paper |
| US3880788A (en) * | 1971-10-08 | 1975-04-29 | Hoechst Ag | Modified natural resin binder and process for preparation |
| US3969233A (en) * | 1971-10-12 | 1976-07-13 | Lucas William J | Biodegradable internal combustion engine lubricants and motor fuel compositions |
| US3997487A (en) * | 1973-10-12 | 1976-12-14 | E. I. Du Pont De Nemours And Company | Thermoplastic elastomer |
| US4079102A (en) | 1973-11-10 | 1978-03-14 | Hoechst Aktiengesellschaft | Printing ink binder |
| JPS5228402B2 (pt) * | 1974-06-25 | 1977-07-26 | ||
| US4175979A (en) * | 1974-08-21 | 1979-11-27 | Ciba-Geigy Corporation | Process for the manufacture of a pigment composition in bead form |
| DK152371C (da) * | 1975-01-08 | 1988-07-25 | Ciba Geigy Ag | Organisk pigmentpraeparat |
| JPS5219754A (en) * | 1975-08-06 | 1977-02-15 | Osaka Soda Co Ltd | Preparation of crosslinked epihalohydrin polymer composition |
| US4041227A (en) * | 1975-11-25 | 1977-08-09 | Phillips Petroleum Company | Cleavable branching agents in emulsion polymerization systems |
| JPS5332015A (en) * | 1976-09-07 | 1978-03-25 | Fuji Photo Film Co Ltd | Thermodevelopable photosensitive material |
| JPS53103986A (en) * | 1977-02-24 | 1978-09-09 | Agency Of Ind Science & Technol | Manufacture of coagulating agent for flowed-out oil |
| DE2755825C3 (de) * | 1977-12-15 | 1982-03-25 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von teilveresterten und teilversalzten Umsetzungsprodukten von Naturharzsäuren und Formaldehyd |
| DE2802702A1 (de) * | 1978-01-23 | 1979-07-26 | Hoechst Ag | Verfahren zur herstellung von teilveresterten und teilversalzten umsetzungsprodukten von harzsaeuren und dicarbonsaeureeinheiten |
| US4244866A (en) * | 1978-09-29 | 1981-01-13 | Inmont Corporation | Calcium resinates and inks |
| JPS5950191B2 (ja) * | 1978-11-14 | 1984-12-06 | 三井化学株式会社 | ホツトメルト型粘着剤組成物 |
| ES8104932A1 (es) * | 1979-04-06 | 1981-05-16 | Johnson Matthey Co Ltd | Procedimiento para la obtencion de una composicion para sol-dar. |
| AU532173B2 (en) * | 1979-06-13 | 1983-09-22 | Mitsui Toatsu Chemicals Inc. | Electrophotographic toner |
| US4301055A (en) * | 1979-08-10 | 1981-11-17 | Inmont Corporation | Printing inks containing novel limed resinates |
| US4250066A (en) * | 1980-01-07 | 1981-02-10 | Inmont Corporation | Modified phenolic resinates and inks |
| JPS572319A (en) * | 1980-06-05 | 1982-01-07 | Dainippon Ink & Chem Inc | Preparation of rosin phenolic resin for printing ink modified with oil |
| JPS58199355A (ja) * | 1982-05-17 | 1983-11-19 | Toray Ind Inc | 二成分系現像剤 |
| US4690712A (en) * | 1985-04-01 | 1987-09-01 | Sun Chemical Corporation | Polyamide-modified metal resinates and their use in publication gravure printing inks |
| US4644026A (en) * | 1985-07-18 | 1987-02-17 | Dennison Manufacturing Company | Readhering and removable adhesive |
| JPS63113073A (ja) * | 1986-05-19 | 1988-05-18 | Harima Chem Inc | 電子回路部材を接着し且つその端子間に選択的に電気的導通を得る方法 |
| KR960003723B1 (ko) * | 1986-05-19 | 1996-03-21 | 하라마 카세이 고오교오 가부시끼가이샤 | 기판 금속의 표면상에 금속 필름을 형성하는 방법 |
| US4857624A (en) * | 1988-05-27 | 1989-08-15 | Basf Corporation | Phenolic-modified rosin ester printing inks |
| JP2784045B2 (ja) * | 1989-06-15 | 1998-08-06 | 東芝シリコーン株式会社 | 室温硬化性シリコーンゴム組成物 |
| US5217812A (en) * | 1990-06-25 | 1993-06-08 | E. I. Du Pont De Nemours And Company | Extrudable and primerless adhesives and products therefrom |
| US5082497A (en) * | 1990-09-24 | 1992-01-21 | Westvaco Corporation | Solution rosin resinate for publication gravure inks |
| US5166256A (en) * | 1991-02-19 | 1992-11-24 | Westvaco Corporation | Modified rosin esters and their use in printing inks |
| US5166262A (en) * | 1991-02-19 | 1992-11-24 | Westvaco Corporation | Modified rosin esters and their use in printing inks |
| US5166258A (en) * | 1991-02-19 | 1992-11-24 | Westvaco Corporation | Modified rosin esters and their use in printing inks |
| US5166257A (en) * | 1991-02-19 | 1992-11-24 | Westvaco Corporation | Modified rosin esters and their use in printing inks |
| US5164446A (en) * | 1991-02-19 | 1992-11-17 | Westvaco Corporation | Modified rosin esters and their use in printing inks |
| US5180774A (en) * | 1991-02-19 | 1993-01-19 | Westvaco Corporation | Modified rosin esters and their use in printing inks |
| US5306342A (en) * | 1991-06-06 | 1994-04-26 | Ciba-Geigy Corporation | Production of pigments |
| GB2257154B (en) * | 1991-06-26 | 1995-09-06 | Yung Chi Paint & Varnish Mfg C | Antifouling coating composition comprising a polymerisable metal soap |
| US5137569A (en) * | 1991-10-10 | 1992-08-11 | Olin Corporation | Process for stabilizing zinc pyrithione plus cuprous oxide in paint |
| DE4206697A1 (de) * | 1992-03-04 | 1993-09-09 | Hoechst Ag | Verfahren zur herstellung von modifizierten phenolharzen |
| DE4308109A1 (de) * | 1993-03-15 | 1994-09-22 | Hoechst Ag | Mit Phenolharz modifizierte Naturharzsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung in Druckfarben |
| US5512622A (en) * | 1994-11-17 | 1996-04-30 | Hercules Incorporated | Dilution-enhancing additives for publication gravure vehicles |
| DE19509647A1 (de) * | 1995-03-17 | 1996-09-19 | Hoechst Ag | Naturharz-Montanharz-Copolymere, Verfahren zu deren Herstellung und deren Verwendung |
| US5699668A (en) | 1995-03-30 | 1997-12-23 | Boreaus Technical Limited | Multiple electrostatic gas phase heat pump and method |
| DE19520530A1 (de) * | 1995-06-03 | 1996-12-05 | Hoechst Ag | Modifizierte Naturharzsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung als Bindemittelharze in Druckfarben |
| DE19538161A1 (de) * | 1995-10-13 | 1997-04-17 | Hoechst Ag | Modifizierte Naturharzsäure-Aldehyd-Addukte |
| US5763373A (en) * | 1996-06-20 | 1998-06-09 | High Point Chemical Corp. | Method of preparing an alkaline earth metal tallate |
| EP0964029B1 (en) * | 1997-02-04 | 2003-10-15 | New Japan Chemical Co.,Ltd. | Particulate diacetal composition, process for producing the same, and polyolefin resin composition and molding |
| US5886128A (en) * | 1997-06-17 | 1999-03-23 | Union Camp Corporation | Modified phenolic resin and uses related thereto |
| GB9721188D0 (en) * | 1997-10-08 | 1997-12-03 | Raisio Chemicals Uk Limited | Rosin emulsion |
| US5969071A (en) * | 1998-05-08 | 1999-10-19 | Westvaco Corporation | Method for preparing phenolic rosin resins |
| JP3571233B2 (ja) * | 1998-10-19 | 2004-09-29 | 理想科学工業株式会社 | 孔版印刷用エマルションインキ |
| US6469125B1 (en) * | 2001-08-27 | 2002-10-22 | Arizona Chemical Company | Tall oil pitch-modified phenolic resin and methods related thereto |
-
2003
- 2003-03-28 MX MXPA04009446A patent/MXPA04009446A/es active IP Right Grant
- 2003-03-28 EP EP03745658A patent/EP1490438B1/en not_active Expired - Lifetime
- 2003-03-28 AT AT03745658T patent/ATE434645T1/de not_active IP Right Cessation
- 2003-03-28 BR BRPI0308921-5B1A patent/BR0308921B1/pt not_active IP Right Cessation
- 2003-03-28 EP EP09163412A patent/EP2098572A1/en not_active Withdrawn
- 2003-03-28 CA CA2480640A patent/CA2480640C/en not_active Expired - Fee Related
- 2003-03-28 WO PCT/US2003/009660 patent/WO2003082984A1/en not_active Ceased
- 2003-03-28 AU AU2003226126A patent/AU2003226126A1/en not_active Abandoned
- 2003-03-28 US US10/402,348 patent/US6875842B2/en not_active Expired - Lifetime
- 2003-03-28 DE DE60328088T patent/DE60328088D1/de not_active Expired - Lifetime
-
2005
- 2005-04-04 US US11/099,438 patent/US7291697B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6875842B2 (en) | 2005-04-05 |
| MXPA04009446A (es) | 2005-07-05 |
| AU2003226126A1 (en) | 2003-10-13 |
| DE60328088D1 (de) | 2009-08-06 |
| CA2480640C (en) | 2010-09-21 |
| EP1490438B1 (en) | 2009-06-24 |
| US7291697B2 (en) | 2007-11-06 |
| WO2003082984A1 (en) | 2003-10-09 |
| ATE434645T1 (de) | 2009-07-15 |
| EP2098572A1 (en) | 2009-09-09 |
| CA2480640A1 (en) | 2003-10-09 |
| EP1490438A1 (en) | 2004-12-29 |
| US20060009543A1 (en) | 2006-01-12 |
| BR0308921B1 (pt) | 2013-11-19 |
| US20040024088A1 (en) | 2004-02-05 |
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