BR9907267A - Processo de copolimerização de etileno - Google Patents

Processo de copolimerização de etileno

Info

Publication number
BR9907267A
BR9907267A BR9907267-0A BR9907267A BR9907267A BR 9907267 A BR9907267 A BR 9907267A BR 9907267 A BR9907267 A BR 9907267A BR 9907267 A BR9907267 A BR 9907267A
Authority
BR
Brazil
Prior art keywords
ethylene
propylene
cyclopentadienyl
catalyst
diene
Prior art date
Application number
BR9907267-0A
Other languages
English (en)
Inventor
Rinaldo S Schiffino
Donna J Crowther
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of BR9907267A publication Critical patent/BR9907267A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Patente de Invenção: <B>"PROCESSO DE COPOLIMERIZAçãO DE ETILENO"<D>. Esta invenção é um processo em solução para preparação de copolímeros etileno-<244>-olefina-diolefina compreendendo o contato de etileno, um ou mais monómeros <244>- olefínicos, um ou mais monómeros dieno cíclicos, com uma composição de catalisador compreendendo um composto bis(ciclopentadienil) zircónio ligado em ponte tendo um ligante ciclopentadienila não substituído, um ligante ciclopentadienila multiplamente substituído, os referidos ligantes ligados em ponte por um grupo ponte covalente contendo um ou mais elementos do Grupo14, e dois ligantes reativos de ativação uninegativos e um composto ativador de catalisador. O processo da invenção exibe alta atividade catalisadora, alta incorporação de comonómero e altas taxas de conversão de monómero dieno, e é particularmente adequado para a preparação de elastómeros de monómeros etileno-propileno ou etileno-propileno-dieno elastoméricos.
BR9907267-0A 1998-02-17 1999-02-17 Processo de copolimerização de etileno BR9907267A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US7481498P 1998-02-17 1998-02-17
PCT/US1999/003264 WO1999041294A1 (en) 1998-02-17 1999-02-17 Ethylene copolymerization process

Publications (1)

Publication Number Publication Date
BR9907267A true BR9907267A (pt) 2000-11-14

Family

ID=22121842

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9907267-0A BR9907267A (pt) 1998-02-17 1999-02-17 Processo de copolimerização de etileno

Country Status (10)

Country Link
US (2) US6486278B1 (pt)
EP (1) EP1056792B1 (pt)
JP (1) JP2002503736A (pt)
KR (1) KR100564506B1 (pt)
CN (1) CN1124296C (pt)
BR (1) BR9907267A (pt)
CA (1) CA2319008A1 (pt)
DE (1) DE69909757T2 (pt)
ES (1) ES2203074T3 (pt)
WO (1) WO1999041294A1 (pt)

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US20020115639A1 (en) 2001-02-16 2002-08-22 Weiyu Fan Glucosamine and method of making glucosamine from microbial blomass
US8222232B2 (en) 2001-02-16 2012-07-17 Cargill, Incorporated Glucosamine and N-acetylglucosamine compositions and methods of making the same fungal biomass
US7816514B2 (en) 2001-02-16 2010-10-19 Cargill, Incorporated Glucosamine and method of making glucosamine from microbial biomass
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JP2018522099A (ja) 2015-06-15 2018-08-09 エクソンモービル・ケミカル・パテンツ・インク 連続溶液重合プロセス
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JP7216184B2 (ja) 2018-07-23 2023-01-31 エクソンモービル・ケミカル・パテンツ・インク バイモーダルゴム、熱可塑性加硫物の調製およびそれから作られた物品
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EP4176005A1 (en) 2020-07-02 2023-05-10 Celanese International Corporation Thermoplastic vulcanizate compositions containing metallocene multimodal copolymer rubber and processes for making same
CN116419941A (zh) 2020-11-10 2023-07-11 陶氏环球技术有限责任公司 用于增加聚乙烯的表面能的聚烯烃-聚丙烯酸酯嵌段共聚物添加剂的制备
JP7824290B2 (ja) 2020-11-10 2026-03-04 ダウ グローバル テクノロジーズ エルエルシー ビニル末端ポリオレフィンを介した非極性－極性ブロックコポリマーの調製
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Also Published As

Publication number Publication date
EP1056792A1 (en) 2000-12-06
CN1291206A (zh) 2001-04-11
KR20010040983A (ko) 2001-05-15
WO1999041294A1 (en) 1999-08-19
US6713574B2 (en) 2004-03-30
US20030060578A1 (en) 2003-03-27
KR100564506B1 (ko) 2006-03-29
WO1999041294B1 (en) 1999-09-23
DE69909757D1 (de) 2003-08-28
DE69909757T2 (de) 2004-04-15
ES2203074T3 (es) 2004-04-01
CA2319008A1 (en) 1999-08-19
EP1056792B1 (en) 2003-07-23
JP2002503736A (ja) 2002-02-05
CN1124296C (zh) 2003-10-15
US6486278B1 (en) 2002-11-26

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B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B11B Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements