BRPI0417591A - método para produção de ácido (met)acrìlico ou (met)acroleìna - Google Patents

método para produção de ácido (met)acrìlico ou (met)acroleìna

Info

Publication number
BRPI0417591A
BRPI0417591A BRPI0417591-3A BRPI0417591A BRPI0417591A BR PI0417591 A BRPI0417591 A BR PI0417591A BR PI0417591 A BRPI0417591 A BR PI0417591A BR PI0417591 A BRPI0417591 A BR PI0417591A
Authority
BR
Brazil
Prior art keywords
meth
production
temperature
acrolein
reaction
Prior art date
Application number
BRPI0417591-3A
Other languages
English (en)
Inventor
Shuhei Yada
Yasushi Ogawa
Yoshiro Suzuki
Kimikatsu Jinno
Original Assignee
Mitsubishi Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34697001&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI0417591(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Mitsubishi Chem Corp filed Critical Mitsubishi Chem Corp
Publication of BRPI0417591A publication Critical patent/BRPI0417591A/pt
Publication of BRPI0417591B1 publication Critical patent/BRPI0417591B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

"MéTODO PARA PRODUçãO DE áCIDO (MET) ACRìLICO OU (MET) ACROLEìNA". é provido um método para a produção de ácido (met) acrílico ou (met) acroleína, no qual uma reação de oxidação catalítica de fase gasosa de um material a ser oxidado, tal como, propileno, propano, isobutileno e (met) acroleína com oxigênio molecular ou gás que contém oxigênio molecular é realizada pelo emprego de um reator multi-tubular possuindo uma ou mais camadas catalíticas na direção do eixo geométrico do tubo. Onde a elevação escalonada na temperatura da reação e suprimida e assim o catalisador é impedido de ser desativado e a produção pode ser realizada de modo estável, mesmo após a troca da condição de reação para aumentar a razão de produção, o que causa aumento da temperatura. Método que compreende a realização da troca de uma condição de reação que causa elevação da temperatura através da alteração da temperatura em uma entrada de um meio de aquecimento para ajustar a temperatura de reação sendo provida no reator multi-tubular acima, onde (1) a alteração da temperatura em uma entrada do meio de aquecimento é realizada dentro de cerca de 2<198>C ou menos por uma operação de troca, e (2) quando são realizadas sucessivas operações de troca, elas são praticadas com um intervalo de tempo de 10 minutos ou mais.
BRPI0417591-3A 2003-12-15 2004-10-27 processo para a produção de ácido acrílico ou acroleína BRPI0417591B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2003-416718 2003-12-15
JP2003416718A JP4867129B2 (ja) 2003-12-15 2003-12-15 （メタ）アクリル酸または（メタ）アクロレインの製造方法
PCT/JP2004/016287 WO2005058785A1 (ja) 2003-12-15 2004-10-27 （メタ）アクリル酸または（メタ）アクロレインの製造方法

Publications (2)

Publication Number Publication Date
BRPI0417591A true BRPI0417591A (pt) 2007-03-20
BRPI0417591B1 BRPI0417591B1 (pt) 2020-12-01

Family

ID=34697001

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0417591-3A BRPI0417591B1 (pt) 2003-12-15 2004-10-27 processo para a produção de ácido acrílico ou acroleína

Country Status (10)

Country Link
US (1) US20070043238A1 (pt)
EP (1) EP1695954B1 (pt)
JP (1) JP4867129B2 (pt)
CN (1) CN100335455C (pt)
AU (1) AU2004299367A1 (pt)
BR (1) BRPI0417591B1 (pt)
ES (1) ES2429440T3 (pt)
RU (1) RU2370483C2 (pt)
WO (1) WO2005058785A1 (pt)
ZA (1) ZA200604662B (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2059334A1 (de) * 2006-11-15 2009-05-20 Basf Se Verfahren zum betreiben einer exothermen heterogen katalysierten partiellen gasphasenoxidation einer organischen ausgangsverbindung zu einer organischen zielverbindung
DE102007014603A1 (de) 2007-03-23 2008-09-25 Basf Se Verfahren des Transports einer aus einem Lagerbehälter entnommenen flüssigen Monomerenphase im Tank eines Tankwagens oder eines Tankschiffs
DE102007014606A1 (de) 2007-03-23 2008-09-25 Basf Se Verfahren zur Lagerung einer unter den Bedingungen der Lagerung flüssigen Monomerenphase
DE102007019597A1 (de) 2007-04-24 2008-05-15 Basf Ag Verfahren der Inbetriebnahme einer heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure oder von Methacrolein zu Methacrylsäure
DE102007025869A1 (de) 2007-06-01 2008-07-03 Basf Se Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett
DE102007028333A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors
JP5107084B2 (ja) * 2008-02-12 2012-12-26 三菱レイヨン株式会社 メタクリル酸の製造方法
JP5479803B2 (ja) * 2009-07-29 2014-04-23 三菱レイヨン株式会社 （メタ）アクロレインまたは（メタ）アクリル酸の製造方法
JP5852134B2 (ja) * 2010-12-29 2016-02-03 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ プロパン酸化のための反応器及び方法
CN103347845B (zh) * 2011-02-02 2015-04-01 日本化药株式会社 制造不饱和醛和/或不饱和羧酸的方法
JP2014019675A (ja) * 2012-07-20 2014-02-03 Nippon Kayaku Co Ltd 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JP2016106082A (ja) * 2015-11-24 2016-06-16 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
SG11201809019YA (en) * 2016-04-21 2018-11-29 Rohm & Haas Methods for using macroporous inert materials in monomer production
KR102084768B1 (ko) * 2016-11-01 2020-03-04 주식회사 엘지화학 불포화 알데하이드 및 불포화 카르복실산의 제조 방법
CN107388036A (zh) * 2017-08-30 2017-11-24 湖南申鑫能源科技有限公司 基于压缩天然气的节能系统及其应用方法
EP3892367A1 (en) * 2020-04-09 2021-10-13 Röhm GmbH A tube bundle reactor and method for the production of methacrylic acid through the partial oxidation of methacrolein
KR102931966B1 (ko) * 2021-01-29 2026-02-26 미츠비시 파워 가부시키가이샤 열교환기
CN117396457A (zh) * 2021-05-25 2024-01-12 三菱化学株式会社 （甲基）丙烯醛和（甲基）丙烯酸中的一者或两者的制造方法
CN114225884A (zh) * 2021-12-29 2022-03-25 江苏吉华化工有限公司 一种连续硝化反应装置

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2056614C3 (de) 1970-11-18 1981-04-16 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure aus Propylen
IN142430B (pt) 1975-04-21 1977-07-09 Standard Oil Co
JPH0638918B2 (ja) 1986-02-27 1994-05-25 三菱油化株式会社 複合酸化物触媒の製造法
JPH0613096B2 (ja) 1986-08-23 1994-02-23 三菱油化株式会社 複合酸化物触媒の製造法
JPH0613097B2 (ja) 1986-08-23 1994-02-23 三菱油化株式会社 複合酸化物触媒の製造法
JPH0294239A (ja) 1988-09-30 1990-04-05 Toshiba Corp 走査型電子顕微鏡
JP3287066B2 (ja) 1993-06-28 2002-05-27 住友化学工業株式会社 アクリル酸の製造方法
DE4431957A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein
DE4431949A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure
JP3559456B2 (ja) * 1998-09-18 2004-09-02 株式会社日本触媒 接触気相酸化方法及び多管式反応器
US6384274B1 (en) * 1998-09-27 2002-05-07 Rohm And Haas Company Single reactor process for preparing acrylic acid from propylene having improved capacity
JP2003252820A (ja) * 2001-12-27 2003-09-10 Mitsubishi Chemicals Corp （メタ）アクロレイン又は（メタ）アクリル酸の製造方法
JP4163021B2 (ja) * 2002-02-14 2008-10-08 三菱化学株式会社 多管式熱交換器型反応器を用いた気相接触酸化方法
JP4325146B2 (ja) * 2002-03-11 2009-09-02 三菱化学株式会社 （メタ）アクリル酸類の製造方法
ES2527452T3 (es) * 2002-03-11 2015-01-23 Mitsubishi Chemical Corporation Procedimiento para oxidación catalítica en fase de vapor
JP4163895B2 (ja) * 2002-04-30 2008-10-08 三菱化学株式会社 （メタ）アクロレイン及び（メタ）アクリル酸の製造方法
JP5330688B2 (ja) * 2005-05-12 2013-10-30 三井化学株式会社 乳酸系ポリマー組成物、該組成物からなる成形品およびその製造方法

Also Published As

Publication number Publication date
EP1695954A1 (en) 2006-08-30
AU2004299367A1 (en) 2005-06-30
ZA200604662B (en) 2007-10-31
CN1697813A (zh) 2005-11-16
BRPI0417591B1 (pt) 2020-12-01
US20070043238A1 (en) 2007-02-22
JP2005170909A (ja) 2005-06-30
EP1695954B1 (en) 2013-09-18
RU2006121130A (ru) 2007-12-27
CN100335455C (zh) 2007-09-05
EP1695954A4 (en) 2007-10-10
RU2370483C2 (ru) 2009-10-20
WO2005058785A1 (ja) 2005-06-30
ES2429440T3 (es) 2013-11-14
JP4867129B2 (ja) 2012-02-01

Similar Documents

Publication Publication Date Title
BRPI0417591A (pt) método para produção de ácido (met)acrìlico ou (met)acroleìna
TW581758B (en) High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids
TW579421B (en) Flow reactors for chemical conversions with heterogeneous catalysts
Darvishi et al. Modeling-based optimization of a fixed-bed industrial reactor for oxidative dehydrogenation of propane
WO2005073160A1 (ja) アクリル酸の製造方法
TW200740745A (en) Oxidation system with sidedraw secondary reactor
MXPA99001856A (es) Proceso,de un solo reactor,que tiene capacidad mejorada,para preparar acido acrilico a partir del propileno.
EP0900774A4 (en) METHOD FOR PRODUCING ACROLEIN AND ACRYLIC ACID
SA03240312B1 (ar) تحضير منتج واحد على الأقل من البروبيلين من التأكسد الجزئي و/ أو الأمينة والتأكسد
BR0202414A (pt) Reator preenchido com partìculas sólidas e oxidação catalìtica de fase gasosa com o reator
MY121141A (en) Method for the catalytic gas-phase oxidation of propene into acrolein
KR960010603A (ko) 아크롤레인으로의 프로펜의 촉매적 기체-상 산화 방법
BR0003856A (pt) Reator para oxidação catalìtica de fase gasosa
KR970061848A (ko) 방향족 카르복실산의 제조 방법
BRPI0408539B8 (pt) processo para a oxidação parcial de acroleína para ácido acrílico em fase gasosa
CN101379017A (zh) 丙烯醛的制备方法
EA200400604A1 (ru) Способ газофазного каталитического окисления и способ получения (мет)акролеина или (мет)акриловой кислоты
BRPI0408554B1 (pt) processo para a oxidaÇço parcial de propeno a Ácido acrÍlico em fase gasosa
BRPI0418699A (pt) processo para a produção de ácido (met) acrìlico ou (met) acroleìna
EP1987877A3 (en) Oxide catalyst, process for producing acrolein or acrylic acid and process for producing water-absorbent resin
MY141738A (en) Thermal treatment of the precursor material of a catalytically active material
BR0300752A (pt) Processo produtivo para aldeìdo insaturado
WO2009060704A1 (ja) メタクロレイン及び／又はメタクリル酸の製造方法
BRPI0405643A (pt) processo para a produção de ácido (met) acrìlico e ésteres (met) acrìlicos
KR101278795B1 (ko) 프로판으로부터 아크롤레인 또는 아크릴산 또는 그의혼합물을 수득하기 위한 안정한 연속 제조 방법

Legal Events

Date Code Title Description
B07A Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O E 13 DA LPI.

B12B Appeal: appeal against refusal
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL.

B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: ANULADA A PUBLICACAO DA MANUTENCAO DO INDEFERIMENTO POR TER SIDO INDEVIDA.

B25A Requested transfer of rights approved

Owner name: MITSUBISHI RAYON CO., LTD. (JP)

B25D Requested change of name of applicant approved

Owner name: MITSUBISHI CHEMICAL CORPORATION (JP)

B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 01/12/2020, OBSERVADAS AS CONDICOES LEGAIS.