CA1255603A - Hair brightener - Google Patents
Hair brightenerInfo
- Publication number
- CA1255603A CA1255603A CA000493903A CA493903A CA1255603A CA 1255603 A CA1255603 A CA 1255603A CA 000493903 A CA000493903 A CA 000493903A CA 493903 A CA493903 A CA 493903A CA 1255603 A CA1255603 A CA 1255603A
- Authority
- CA
- Canada
- Prior art keywords
- hair
- composition according
- liquid vehicle
- compound
- formulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 48
- 239000000203 mixture Substances 0.000 claims abstract description 35
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 238000009472 formulation Methods 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims abstract description 4
- -1 for example Chemical class 0.000 claims abstract description 3
- AFYCEAFSNDLKSX-UHFFFAOYSA-N coumarin 460 Chemical compound CC1=CC(=O)OC2=CC(N(CC)CC)=CC=C21 AFYCEAFSNDLKSX-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000007850 fluorescent dye Substances 0.000 claims abstract 2
- 239000007788 liquid Substances 0.000 claims description 10
- 239000000758 substrate Substances 0.000 claims description 7
- 238000004040 coloring Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 238000005282 brightening Methods 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 239000000284 extract Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- CFNMUZCFSDMZPQ-GHXNOFRVSA-N 7-[(z)-3-methyl-4-(4-methyl-5-oxo-2h-furan-2-yl)but-2-enoxy]chromen-2-one Chemical compound C=1C=C2C=CC(=O)OC2=CC=1OC/C=C(/C)CC1OC(=O)C(C)=C1 CFNMUZCFSDMZPQ-GHXNOFRVSA-N 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 3
- 230000003750 conditioning effect Effects 0.000 claims 1
- 150000002334 glycols Chemical class 0.000 claims 1
- 239000012676 herbal extract Substances 0.000 claims 1
- 239000002304 perfume Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 239000001993 wax Substances 0.000 claims 1
- 150000004775 coumarins Chemical class 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- VIIIJFZJKFXOGG-UHFFFAOYSA-N 3-methylchromen-2-one Chemical compound C1=CC=C2OC(=O)C(C)=CC2=C1 VIIIJFZJKFXOGG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004150 EU approved colour Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
- A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/434—Luminescent, Fluorescent; Optical brighteners; Photosensitizers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
ABSTRACT
Fluorescent compounds, for example, coumarin deriva-tives are employed to impart a fluorescent or bright quality to hair; the compounds may be employed as ingredients in con-ventional hair treatment compositions, for example, hair washing formulations; an especially preferred fluorescent compound is 7-diethylamino-4-methylcoumarin
Fluorescent compounds, for example, coumarin deriva-tives are employed to impart a fluorescent or bright quality to hair; the compounds may be employed as ingredients in con-ventional hair treatment compositions, for example, hair washing formulations; an especially preferred fluorescent compound is 7-diethylamino-4-methylcoumarin
Description
'I'his in~lention rela-tes -to nair treatmerlt com~osi'cions and me-thods o-F trea-ting hair.
Fluorescen-t r~Jhitenirlg agents also ]~no-"n as optical brighteners have been ernployed by detergen-t.,1anuLacturers to increase the whi-telless or brightness of clothing ~7nich has been i7ashed ~.7ith such detergents.
Such fluorescent ~Jhitening agen-ts have also been ern-plo-yed in paint com?osi'._ions to increase -the ~,7hiteness or T,7hite pigments such as titaniurn dioxide ~Chelnical Abstrac-ts Vol. 74, 1971, 143399a).
These agents are, in particular, ~luorescent organic cornpounds ~f~hich absorb radiation or light at one waveleng-th or region and emit it a-~- a different wavelength or region. In par-ticular, the absorbed radiation or light excites khe agent to a higher electronic state and then ernits visible radiation in passing to a lower electronic state.
The present invention is rnore especially concerned T.7itn fluorescent organic cornpounds ~17hich absorb inc.ident light in the ~ e rg ~/
.~ ultraviolet region and emit part oE the absorbed ~ as .~
visible li~ht, especiall~ in the blue region o~ the visible spectrum.
In accordance -i7ith the present invention i-t has no~.,7 been found that certain fluorescent organic cornpounds can be employed to impart a fluorescent or "bright" quality to :the hair.
Particular fluorescent compounds emplo~ed in acco.dance .~i-th the invention have a subs-tantivit~ for the ]~eratinaceous substrate o~ hair and -.~ill thus bincl-to -the hair.
The fluorescent organic compounds rna~ be employed in a 3~ variet~ of hair -trea-cment com2ositions including hair washing compositions or shampoos, hair conditiol1ing co~positions, nair setting cornpositions, hair colouring compositiolls and hair 3i9~
~S~3 rinsincJ colnposi-tiorls, in ;~hich case other ac'cive inyrediencs will also be present in tne composition. The ~luorescent or-yanic cornpounds may also be ernployed as the sole active in~Jre-dient in a new class oL hair trea-t.nent compositions eM~loycd solely to iinparc a fluorescent cluality 'co hair.
The invention thus provides hair treatrnen-t composi'cions comprisinc; an accep-table amount o-~ a -;luorescen'c orcJanic com-pound havinc3 a substan-tivity for tne l~era-tinaceous subs'crate or the hair in association with an aeceptable earrier or vehicle.
The invention also provides a method of brightening hair or impartiny a briyhteniny e~feet to hair whieh eomprises applyiny a brighteninc3 amount o~ a fluorescen-t compound or tne invention to hair.
It will be understood that an acce?table amoun-t o~ the compound in the composition is one such thak trea-trnent of the hair ~ith the composition ~ill result in binding of an amount (herein referred to as a briyhtening amount) of the compound to the hair, eE~eetive to aehieve a diseernible and desired fluor-eseent effeet visible to the human eye.
If the eoneentration of the fluorescent eompound is too lo~J, either no discernible effeet will be produeed, or repeated use o-f the eomposi-tion a plurality of times may be required in order to aehieve a discernible eEfeet.
Ir the concentration o~ the fluorescen-t compound is too high the presence of~h~com~ound in the hair may be noticeable and an unsic~htly, unelean appearanee may resul-ti in addition in-ereasing the eoneentration beyond what is required~ inereases the eost unneeessarily.
Generally it is found that a eoncentration o~ about 0.0001% to about 2o~ by ~7eiyht, of fluorescent eom~ound, based on tne JJeiyht of che COlll~OSiCiOII, provides sa-tis~actory results.
preferably the concentra-tion is abouto 005 ^~ to about o 05 ~o~
'~25~6~3 by weight.
It l~Jill be understood.tnat an acceptablc carri2r or vehicle is one ~7hicn is relatively inert, ~7hich -7ill not deleteriously interfere ~7itn the binding of 'che compound 'co 'cne hair and ~i7hich ~7il 1 no-t affect the hair or scalp such chat i-ts applica-tion to a head of hair 70u.1d be harmIul.
Liquid vehicles employed in e,~isting hair treatrnent composi-tions are sui.table for use in ~he compositions OL -the invention. Thus suitable liquid vehicles include hair ~Jashing formulations, hair condit:ioning formulations, hair se-tting formulations, hair colouring formulations and hair rinsing formulations~
It ~ill be understood that ~.7hen the hair treatment composi-tion has a function other than to impart a fluorescent quality to the hair, it will contain othQr ingredients necessary for its function, for e~ample, washing or colouring agents.
A particularly useful class of fluorescent compounds for use in the composition of -the invention are coumarin deri-vatives of formula (r) ~ (I~
~;7rlerein R1, ~2 and R3, ~Ihich may be the same or different are selected from the group consisting of s-traight or branched chain al};yl and nydro~yal,~yl groups of 1 to 6 carbon a-toms.
An especially preferred compound (I) is 7 diethylamino-~-^metllylcoumarin (~ is ~e-thyl, R2 and R3 are ethyl) .7hich e~-hibits the iollo~7ing cnarac-teristics:
~;5~
Ionic Cllarac-Ler: wea;~ly cationic Absori~-tion ma.~imum 375 nn (in et.lanol) Fluorescence ma~imum~ 0 n.n (on wool~
The com30sitions o~ -~he invention may additionall~ con-~ain one o.r more conventional addi-tives selected 7ror.l sur-ace active agents, perIume, colouring substances, inorganic sal'cs, oxidizing agents, reducing agents~ oils, al]~anols, gl~cols, waYes, pol~mers, he.rbal extracts, animal e,~tracts and silicones.
The invention is further illustrated by relerence to the accompanying drawings in which:
FicJ. 1 illustrates graphically the reflectance/emission curve of 7-diethylalnino-4~methylcoumarin on a subs-trate of polyamide fibres.
Fiy. 2 illustrates graphically the increase in the brightness e'-~ect achieved employing a composition in accordance wi-th -the invention, appliecl to a wool substrate.
The invencion is further illustrated b~ rererence to the rollowing Eramples.
EX~lPL~ 1 7-Diethylar.~ino 4 .nethylcoumarin -was added to a wash liquid suitable for wool, in a concentration of 0.0002r'6, by weight. A woollen substrate was washed successively 1 to 15 times in the wash liquid a'c a temperature or about ~0C., each wash being Eor a period of about 15 minutes. Tne brightness oF
the substrate was rated on a scale or 1 to 15 after each wasn.
The brightness scale employed i5 an arbitrary scale quantified .Jith the use of a suitable spectrophotometer.
The results aro shown graphically in Fig. 2, ~Jhic}l SLIOWS a steady increase in brightness during ~he 7irst seven waslles with a less significant increase in brightness being achieved with subse¢uent wasnes.
Fluorescen-t r~Jhitenirlg agents also ]~no-"n as optical brighteners have been ernployed by detergen-t.,1anuLacturers to increase the whi-telless or brightness of clothing ~7nich has been i7ashed ~.7ith such detergents.
Such fluorescent ~Jhitening agen-ts have also been ern-plo-yed in paint com?osi'._ions to increase -the ~,7hiteness or T,7hite pigments such as titaniurn dioxide ~Chelnical Abstrac-ts Vol. 74, 1971, 143399a).
These agents are, in particular, ~luorescent organic cornpounds ~f~hich absorb radiation or light at one waveleng-th or region and emit it a-~- a different wavelength or region. In par-ticular, the absorbed radiation or light excites khe agent to a higher electronic state and then ernits visible radiation in passing to a lower electronic state.
The present invention is rnore especially concerned T.7itn fluorescent organic cornpounds ~17hich absorb inc.ident light in the ~ e rg ~/
.~ ultraviolet region and emit part oE the absorbed ~ as .~
visible li~ht, especiall~ in the blue region o~ the visible spectrum.
In accordance -i7ith the present invention i-t has no~.,7 been found that certain fluorescent organic cornpounds can be employed to impart a fluorescent or "bright" quality to :the hair.
Particular fluorescent compounds emplo~ed in acco.dance .~i-th the invention have a subs-tantivit~ for the ]~eratinaceous substrate o~ hair and -.~ill thus bincl-to -the hair.
The fluorescent organic compounds rna~ be employed in a 3~ variet~ of hair -trea-cment com2ositions including hair washing compositions or shampoos, hair conditiol1ing co~positions, nair setting cornpositions, hair colouring compositiolls and hair 3i9~
~S~3 rinsincJ colnposi-tiorls, in ;~hich case other ac'cive inyrediencs will also be present in tne composition. The ~luorescent or-yanic cornpounds may also be ernployed as the sole active in~Jre-dient in a new class oL hair trea-t.nent compositions eM~loycd solely to iinparc a fluorescent cluality 'co hair.
The invention thus provides hair treatrnen-t composi'cions comprisinc; an accep-table amount o-~ a -;luorescen'c orcJanic com-pound havinc3 a substan-tivity for tne l~era-tinaceous subs'crate or the hair in association with an aeceptable earrier or vehicle.
The invention also provides a method of brightening hair or impartiny a briyhteniny e~feet to hair whieh eomprises applyiny a brighteninc3 amount o~ a fluorescen-t compound or tne invention to hair.
It will be understood that an acce?table amoun-t o~ the compound in the composition is one such thak trea-trnent of the hair ~ith the composition ~ill result in binding of an amount (herein referred to as a briyhtening amount) of the compound to the hair, eE~eetive to aehieve a diseernible and desired fluor-eseent effeet visible to the human eye.
If the eoneentration of the fluorescent eompound is too lo~J, either no discernible effeet will be produeed, or repeated use o-f the eomposi-tion a plurality of times may be required in order to aehieve a discernible eEfeet.
Ir the concentration o~ the fluorescen-t compound is too high the presence of~h~com~ound in the hair may be noticeable and an unsic~htly, unelean appearanee may resul-ti in addition in-ereasing the eoneentration beyond what is required~ inereases the eost unneeessarily.
Generally it is found that a eoncentration o~ about 0.0001% to about 2o~ by ~7eiyht, of fluorescent eom~ound, based on tne JJeiyht of che COlll~OSiCiOII, provides sa-tis~actory results.
preferably the concentra-tion is abouto 005 ^~ to about o 05 ~o~
'~25~6~3 by weight.
It l~Jill be understood.tnat an acceptablc carri2r or vehicle is one ~7hicn is relatively inert, ~7hich -7ill not deleteriously interfere ~7itn the binding of 'che compound 'co 'cne hair and ~i7hich ~7il 1 no-t affect the hair or scalp such chat i-ts applica-tion to a head of hair 70u.1d be harmIul.
Liquid vehicles employed in e,~isting hair treatrnent composi-tions are sui.table for use in ~he compositions OL -the invention. Thus suitable liquid vehicles include hair ~Jashing formulations, hair condit:ioning formulations, hair se-tting formulations, hair colouring formulations and hair rinsing formulations~
It ~ill be understood that ~.7hen the hair treatment composi-tion has a function other than to impart a fluorescent quality to the hair, it will contain othQr ingredients necessary for its function, for e~ample, washing or colouring agents.
A particularly useful class of fluorescent compounds for use in the composition of -the invention are coumarin deri-vatives of formula (r) ~ (I~
~;7rlerein R1, ~2 and R3, ~Ihich may be the same or different are selected from the group consisting of s-traight or branched chain al};yl and nydro~yal,~yl groups of 1 to 6 carbon a-toms.
An especially preferred compound (I) is 7 diethylamino-~-^metllylcoumarin (~ is ~e-thyl, R2 and R3 are ethyl) .7hich e~-hibits the iollo~7ing cnarac-teristics:
~;5~
Ionic Cllarac-Ler: wea;~ly cationic Absori~-tion ma.~imum 375 nn (in et.lanol) Fluorescence ma~imum~ 0 n.n (on wool~
The com30sitions o~ -~he invention may additionall~ con-~ain one o.r more conventional addi-tives selected 7ror.l sur-ace active agents, perIume, colouring substances, inorganic sal'cs, oxidizing agents, reducing agents~ oils, al]~anols, gl~cols, waYes, pol~mers, he.rbal extracts, animal e,~tracts and silicones.
The invention is further illustrated by relerence to the accompanying drawings in which:
FicJ. 1 illustrates graphically the reflectance/emission curve of 7-diethylalnino-4~methylcoumarin on a subs-trate of polyamide fibres.
Fiy. 2 illustrates graphically the increase in the brightness e'-~ect achieved employing a composition in accordance wi-th -the invention, appliecl to a wool substrate.
The invencion is further illustrated b~ rererence to the rollowing Eramples.
EX~lPL~ 1 7-Diethylar.~ino 4 .nethylcoumarin -was added to a wash liquid suitable for wool, in a concentration of 0.0002r'6, by weight. A woollen substrate was washed successively 1 to 15 times in the wash liquid a'c a temperature or about ~0C., each wash being Eor a period of about 15 minutes. Tne brightness oF
the substrate was rated on a scale or 1 to 15 after each wasn.
The brightness scale employed i5 an arbitrary scale quantified .Jith the use of a suitable spectrophotometer.
The results aro shown graphically in Fig. 2, ~Jhic}l SLIOWS a steady increase in brightness during ~he 7irst seven waslles with a less significant increase in brightness being achieved with subse¢uent wasnes.
Claims (16)
1. A hair treatment composition comprising a fluorescent orga-nic compound having a substantivity for the keratinaceous sub-strate of hair, in an amount effective to impart a briyhtening amount to hair, in association with an acceptable carrier or vehicle.
2. A hair treatment composition according to claim 1, wherein said compound is a coumarin derivative of formula (I) (I) wherein R1, R2 and R3, which may be the same or different are selected from the group consisting of straight or branched chain alkyl and hydroxyalkyl groups of 1 to 6 carbon atoms.
3. A hair treatment composition according to claim 1, wherein said compound is 7-diethylamino-4-methylcoumarin.
4. A hair treatment composition comprising about 0.0001.% to about 2%, by weight, of a coumarin derivative of formula (I):
(I) wherein R1, R2 and R3, which may be the same or different are selected from the group consisting of straight or branched chain alkyl and hydroxyalkyl groups of 1 to 6 carbon atoms, in association with an acceptable liquid vehicle.
(I) wherein R1, R2 and R3, which may be the same or different are selected from the group consisting of straight or branched chain alkyl and hydroxyalkyl groups of 1 to 6 carbon atoms, in association with an acceptable liquid vehicle.
5. A composition according to claim 4, wherein said liquid vehicle comprises a hair washing formulation.
6. A composition according to claim 4, wherein said liquid vehicle comprises a hair conditioning formulation.
7. A composition according to claim 4, wherein said liquid vehicle comprises a hair setting formulation.
8. A composition according to claim 4, wherein said liquid vehicle comprises a hair colouring formulation.
9. A composition according to claim 4, wherein said liquid vehicle comprises a hair rinsing formulation.
10. A composition according to claim 5, 6 or 7, wherein said coumarin derivative is 7-diethylamino-4-methyl coumarin.
11. A composition according to claim 8 or 9, wherein said coumarin derivative is 7-diethylamino-4-methyl coumarin.
12. A composition according to claim 1, 2 or 4, further in-eluding at least one additive selected from the group consisting of surface active agents, perfume, colouring substances, inor-ganic salts, oxidizing agents, reducing agents, oils, alkanols, glycols, waxes, polymers, herbal extracts, animal extracts and silicones.
13. A Method of brightening hair which comprises applying to said hair a brightening amount of a fluorescent organic compound having a substantivity for the keratinaceous substrate of hair.
14. A method according to claim 13, wherein said com-pound is a coumarin derivative of formula (I):
(I) wherein R1, R2 and R3, which may be the same or different are selected from the group consisting of straight or branched chain alkyl and hydroxyalkyl groups of 1 to 6 carbon atoms.
(I) wherein R1, R2 and R3, which may be the same or different are selected from the group consisting of straight or branched chain alkyl and hydroxyalkyl groups of 1 to 6 carbon atoms.
15. A method according to claim 13, wherein said com-pound is 7-diethylamino-4-methylcoumarin.
16. A composition according to claim 1 or 3, wherein said fluorescent compound is present in an amount of about 0.0001% to about 2%, by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000493903A CA1255603A (en) | 1985-10-25 | 1985-10-25 | Hair brightener |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000493903A CA1255603A (en) | 1985-10-25 | 1985-10-25 | Hair brightener |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1255603A true CA1255603A (en) | 1989-06-13 |
Family
ID=4131719
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000493903A Expired CA1255603A (en) | 1985-10-25 | 1985-10-25 | Hair brightener |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1255603A (en) |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2741261A1 (en) * | 1995-11-17 | 1997-05-23 | Gen Electric | METHOD FOR INCREASING HAIR STATUS OR COLOR INTENSITY OF A COSMETIC PRODUCT USING A FLUORESCENT FLAVORING AGENT AND COMPOSITIONS USED THEREIN |
| WO1999013844A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners which provide uv protection |
| WO1999013841A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair styling compositions comprising nonionic and amphoteric optical brighteners |
| WO1999013848A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners and polymeric suspending agents |
| WO1999013834A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners and perfume compounds |
| WO1999013832A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners and water-insoluble high molecular weight oily compounds |
| WO1999013843A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair styling compositions comprising anionic optical brighteners |
| WO1999013845A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners which alter hair colors |
| WO1999013842A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair styling compositions comprising cationic optical brighteners |
| WO1999013833A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners and cationic compounds |
| WO1999013823A3 (en) * | 1997-09-17 | 1999-08-12 | Procter & Gamble | Hair care compositions comprising optical brighteners and hair conditioning agents |
| EP1464320A1 (en) * | 2003-04-01 | 2004-10-06 | L'oreal | Brightening composition comprising a fluorescent dye and a non-associative polymer thickener for human keratinaceous matter |
| EP1464323A1 (en) * | 2003-04-01 | 2004-10-06 | L'oreal | Fluorescent dye composition for human keratin fibres |
| EP1464319A1 (en) * | 2003-04-01 | 2004-10-06 | L'oreal | Dye for human keratin matter comprising a fluorescent colourant and cationic polymer, and methods for its preparation and use |
| US7147673B2 (en) | 2003-04-01 | 2006-12-12 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, process therefor and use thereof |
| US7150764B2 (en) | 2003-04-01 | 2006-12-19 | L'oreal S.A. | Composition for dyeing a human keratin material, comprising at least one fluorescent dye and at least one insoluble conditioning agent, process thereof, use thereof, and devices thereof |
| US7186278B2 (en) | 2003-04-01 | 2007-03-06 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor |
| US7192454B2 (en) | 2003-04-01 | 2007-03-20 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof |
| US7195650B2 (en) | 2003-04-01 | 2007-03-27 | L'oreal S.A. | Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye |
| US7195651B2 (en) | 2003-04-01 | 2007-03-27 | L'oreal S.A. | Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor |
| US7198650B2 (en) | 2003-04-01 | 2007-04-03 | L'oreal S.A. | Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor |
| US7204860B2 (en) | 2003-04-01 | 2007-04-17 | L'oreal | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof |
| US7208018B2 (en) | 2003-04-01 | 2007-04-24 | L'oreal | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof |
| US7217296B2 (en) | 2001-09-28 | 2007-05-15 | L'oreal S.A. | Dyeing composition with a lightening effect for human keratin materials comprising at least one fluorescent dye |
| US7250064B2 (en) | 2003-04-01 | 2007-07-31 | L'oreal S.A. | Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof |
| US7261744B2 (en) | 2002-12-24 | 2007-08-28 | L'oreal S.A. | Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener |
| US7303589B2 (en) | 2003-04-01 | 2007-12-04 | L'oreal S.A. | Process for dyeing human keratin fibers, having a lightening effect, comprising at least one fluorescent compound and compositions of the same |
| US7306809B2 (en) * | 2002-09-13 | 2007-12-11 | Lipo Chemicals, Inc. | Optically activated particles for use in cosmetic compositions |
| US7736631B2 (en) | 2003-04-01 | 2010-06-15 | L'oreal S.A. | Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing |
-
1985
- 1985-10-25 CA CA000493903A patent/CA1255603A/en not_active Expired
Cited By (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2307639B (en) * | 1995-11-17 | 1999-07-28 | Gen Electric | Fluorescent brightening of cosmetic compositions |
| GB2307639A (en) * | 1995-11-17 | 1997-06-04 | Gen Electric | Fluorescent brightening of cosmetic compositions |
| FR2741261A1 (en) * | 1995-11-17 | 1997-05-23 | Gen Electric | METHOD FOR INCREASING HAIR STATUS OR COLOR INTENSITY OF A COSMETIC PRODUCT USING A FLUORESCENT FLAVORING AGENT AND COMPOSITIONS USED THEREIN |
| WO1999013848A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners and polymeric suspending agents |
| WO1999013842A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair styling compositions comprising cationic optical brighteners |
| WO1999013834A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners and perfume compounds |
| WO1999013832A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners and water-insoluble high molecular weight oily compounds |
| WO1999013843A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair styling compositions comprising anionic optical brighteners |
| WO1999013822A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners and polymeric suspending agents |
| WO1999013845A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners which alter hair colors |
| WO1999013844A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners which provide uv protection |
| WO1999013833A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair care compositions comprising optical brighteners and cationic compounds |
| WO1999013841A1 (en) * | 1997-09-17 | 1999-03-25 | The Procter & Gamble Company | Hair styling compositions comprising nonionic and amphoteric optical brighteners |
| WO1999013823A3 (en) * | 1997-09-17 | 1999-08-12 | Procter & Gamble | Hair care compositions comprising optical brighteners and hair conditioning agents |
| US7217296B2 (en) | 2001-09-28 | 2007-05-15 | L'oreal S.A. | Dyeing composition with a lightening effect for human keratin materials comprising at least one fluorescent dye |
| US7306809B2 (en) * | 2002-09-13 | 2007-12-11 | Lipo Chemicals, Inc. | Optically activated particles for use in cosmetic compositions |
| US7261744B2 (en) | 2002-12-24 | 2007-08-28 | L'oreal S.A. | Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener |
| EP1464319A1 (en) * | 2003-04-01 | 2004-10-06 | L'oreal | Dye for human keratin matter comprising a fluorescent colourant and cationic polymer, and methods for its preparation and use |
| US7198650B2 (en) | 2003-04-01 | 2007-04-03 | L'oreal S.A. | Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor |
| FR2853232A1 (en) * | 2003-04-01 | 2004-10-08 | Oreal | COLORING COMPOSITION FOR HUMAN KERATINIC MATERIALS COMPRISING A FLUORESCENT COLORANT AND A CATIONIC POLYMER, METHOD AND USE |
| US7147673B2 (en) | 2003-04-01 | 2006-12-12 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, process therefor and use thereof |
| US7150764B2 (en) | 2003-04-01 | 2006-12-19 | L'oreal S.A. | Composition for dyeing a human keratin material, comprising at least one fluorescent dye and at least one insoluble conditioning agent, process thereof, use thereof, and devices thereof |
| US7186278B2 (en) | 2003-04-01 | 2007-03-06 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor |
| US7192454B2 (en) | 2003-04-01 | 2007-03-20 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof |
| US7195650B2 (en) | 2003-04-01 | 2007-03-27 | L'oreal S.A. | Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye |
| US7195651B2 (en) | 2003-04-01 | 2007-03-27 | L'oreal S.A. | Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor |
| FR2853234A1 (en) * | 2003-04-01 | 2004-10-08 | Oreal | COLORING COMPOSITION COMPRISING A FLUORESCENT COLORANT AND A NON-ASSOCIATIVE THICKENING POLYMER FOR HUMAN KERATINIC MATERIALS, METHOD AND USE |
| US7204860B2 (en) | 2003-04-01 | 2007-04-17 | L'oreal | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof |
| US7208018B2 (en) | 2003-04-01 | 2007-04-24 | L'oreal | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof |
| FR2853230A1 (en) * | 2003-04-01 | 2004-10-08 | Oreal | COLORING COMPOSITION FOR HUMAN KERATINIC MATERIALS COMPRISING A SELF-OXIDABLE COLOR, PROCESS AND USE |
| US7250064B2 (en) | 2003-04-01 | 2007-07-31 | L'oreal S.A. | Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof |
| EP1464323A1 (en) * | 2003-04-01 | 2004-10-06 | L'oreal | Fluorescent dye composition for human keratin fibres |
| US7303589B2 (en) | 2003-04-01 | 2007-12-04 | L'oreal S.A. | Process for dyeing human keratin fibers, having a lightening effect, comprising at least one fluorescent compound and compositions of the same |
| EP1464320A1 (en) * | 2003-04-01 | 2004-10-06 | L'oreal | Brightening composition comprising a fluorescent dye and a non-associative polymer thickener for human keratinaceous matter |
| US7736631B2 (en) | 2003-04-01 | 2010-06-15 | L'oreal S.A. | Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1255603A (en) | Hair brightener | |
| RU2186560C2 (en) | Composition for oxidizing coloring of keratin fibers, method of their coloring, set for oxidizing coloring of keratin fibers | |
| US5651960A (en) | Method and composition for removing semi-permanent color from human hair | |
| JP5006664B2 (en) | A composition for lightening and coloring the hair using a stable acidic and basic pigment as a depigmenting agent | |
| DE69925570T2 (en) | Coloring agent for keratin fibers containing a cationic dye and a silicone compound | |
| US6440177B1 (en) | One-step bleach and coloring composition for hair and method of using same | |
| ATE344090T1 (en) | A DYE COMPOSITION CONTAINING DICATIONIC DIAZO DYE FOR DYEING KERATIN FIBERS | |
| MXPA01008125A (en) | Composition for the oxidation dyeing of keratinous fibers comprising at least one oxidation dye and at least one cationic amphiphilic polymer, and dyeing methods. | |
| EA199700152A1 (en) | COMPOSITION FOR LIGHTENING COLORING KERATIN FIBERS CONTAINING DIRECT DYE | |
| US20020074003A1 (en) | Photochromatic tattoo | |
| BR0204935A (en) | Human keratin fiber dye composition comprising a direct or oxidizing dye and a particular amine silicone, 2 and 3-compartment process and devices or kit for the dyeing of human keratin fibers | |
| WO2002074266A3 (en) | Method and composition for the gradual permanent coloring of hair | |
| WO1980000303A1 (en) | Preparation for hair coloration | |
| EP0951900A3 (en) | Hair dyeing compositions containing 2-chloro- and 2,6-dichloro-4-aminophenol & phenylpyrazolones | |
| PT96958A (en) | PAINT PROCESS OF 6-OR 7-MONO-HYDROXY-INDOLE, PH PHARMACEUTICAL AND PREPARATION OF COMPOSITION USED | |
| ATE68704T1 (en) | NIFEDIPIN CONCENTRATE STABILIZED AGAINST LIGHT EFFECTS AND PROCESS FOR ITS PRODUCTION. | |
| BR9906441A (en) | Agent and process for obtaining temporary dyes on keratin fibers | |
| ATE134867T1 (en) | METHOD FOR OXIDATIVE DYEING OR DYEING HUMAN HAIR | |
| DE69612487D1 (en) | LIPOSOMOGENIC UV ABSORBERS | |
| DE69700686D1 (en) | Preparation for coloring human hair | |
| BR9204544A (en) | SINGLE STAGE PROCESS, COMPOSITION AND KIT FOR DYING KERATIN FIBERS IN INTENSE COLORS | |
| DE60222682D1 (en) | COSMETIC COMPOSITION WITH SULFUR ACID DERIVATIVES | |
| BR9907694A (en) | Fiber dyeing agent | |
| NL8003960A (en) | HAIR PAINT PREPARATION BASED ON P-PHENYLENE DIAMINES. | |
| BR9711649A (en) | Process and agent for permanent modeling of keratin fibers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |