CA1307085C - Stranded insulated wire - Google Patents
Stranded insulated wireInfo
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- CA1307085C CA1307085C CA000561259A CA561259A CA1307085C CA 1307085 C CA1307085 C CA 1307085C CA 000561259 A CA000561259 A CA 000561259A CA 561259 A CA561259 A CA 561259A CA 1307085 C CA1307085 C CA 1307085C
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Abstract
Abstract of the Disclosure A stranded insulated wire and a method of producing the same. The stranded insulated wire is produced by applying a coating material containing polyvinyl butyral and a stabilized polyisocyanate to an enameled strands assembly and then by baking the assembly. The coating material contains about 1 to about 1000 parts by weight of the stabilized polyisocyanate per 100 parts by weight of the polyvinyl butyral.
Description
~30708~
STRANDED INSULATED WIRE
The present invention relates to a stranded insulated wire in which an assembling layer is formed ~
coating a resin over an enameled strands stranded assembly.
When such a kind of stranded insulated wire is to be `soldered at its one terminal, it is necessary to remove the assembling layer from there to separate enameled strands from each other.
Removal of the assembling layer of the stranded insulated wire is conducted by a method in which a terminal portion of the stranded insulated wire is dipped in an alcoholic solvent to dissolve therein a resin constituting the assembling layer or a method in which the assembling layer is mechanically removed. The method of dipping a terminal portion of a stranded insulated wire in an alcoholic solvent is predominantly employed from the viewpoint of working eficiency and prevention of damage to the insulating làyers of enameled strands.
As a resin constituting an assembling layer of a stranded insulated wire, there is used, for example, polyvinyl butyral; a crosslinked resin such as an epoxy resin, polyester, or polyurethane; or polyamide (nylon).
13~7~5 As assembling layer made of polyvinyl butyral is readily soluble in an alcoholic solvent. Thus, strands at the terminal of a stranded insulated wire can be easily separated from each other.
However, the assembling layer i5 swellable or soluble in an alcohol-Freon cleaning solvent, which is used in the cleaning step after incorporating, for example, as a coil in a magnetic head of a disk drive, and hence loses its function.
An assembling layer made of a crosslinked resin such as an epoxy resin is neither swellable nor soluble in an alcohol-Freon cleaning solvent, and is insoluble in an alcoholic solvent, either.
Therefore, the method of mechanically removing the assembling layer must be employed, thus presenting a problem of workability.
An assembling layer made of a polyamide such as nylon 12 is neither swellable nor soluble in an alcohol-Freon cleaning solvent, and is insoluble in an alcoholic solvent, either. It can be dissolved in and removed by a phenolic compound such as phenol or cresol. However, a difficulty is encountered in handling the phenolic compound because of its toxicity.
* TRADE-MARK
~',,~;
, ~.3e)7085 According to one aspect of the invention there is provided a stranded insulated wire, comprising: (a) an assembly of a plurality of enameled strands, each comprising an annealed copper wire or tin-plated annealed copper wire having thereon an insulating coating made of polyvinyl formal, polyester, polyurethane, silicone, epoxy, nylon, phenoxy, polyimide, polyester-imide, polyester-amide-imide, polyhydantoin or polyhydantoin-ester-imide;
and (b) an assembling layer coating over said assembly of enameled strands, said assembling layer being produced by applying a coating material, consisting essentially of about 100 parts by weight of polyvinyl butyral, and about 1 to 1,000 parts by weight of a stabilized polyisocyanate, to the assembly and then baking said coating material to e~fect crosslinking.
According to another aspect of the invention there is provided a method o~ producing a stranded insulated wire having (a) an assembly o~ a plurality o~ enameled strands, each comprising an annealed copper wire or tin-plated annealed copper wire having thereon an insulating coating made o~ polyvinyl ~ormal, polyester, polyurethane, silicone, epoxy, nylon, phenoxy, polyimide, polyester-imide, polyester-amide-imide, polyhydantoin or polyhydantoin-ester-imide; and ~b) an assembling layer coating over said assembly of enameled strands, said assembling layer being produced by applying a coating material, consisting essentially o~ about 100 parts by weight o~ polyvinyl butyral, and about 1 to 1,000 parts by .,,,t~.-, ~i - 3a -weight of a stabilized polyisocyanate, to the assembly and then baking said coating material to effect crosslinking, said method comprising the steps of: (i) stranding a plurality of enameled strands for forming an assembly; (ii) applying a coating material over the assem~ly, the coating material containing loo parts by weight of polyvinyl butyral and about 1 to about 1000 parts by weight of a stabilized polyisocyanate; and (iii) baking the applied coating material to effect crosslinking to form an assembling layer.
The assembling layer is well soluble in an alcoholic solvent and hence separation of the strands from each other can be easily and quickly effected. It is not swellable in an alcohol-Freon during cleaning of the stranded insulated wire after incorporating thereof into an electronic appliance, and hence the cleaning is possible as usual.
In the drawings:
FIG. 1 is a diagrammatic cross-sectional view of a stranded insulated wire according to the present invention;
and FIG. 2 is a diagrammatic cross-sectional view of a modi~ied ~orm of the stranded insulated wire in FIG. 1.
Referring to FIG. 1, the stranded insulated wire lA is produced by bundling three enameled strands 2 in parallel with each other and in a row to ~orm an assembly 3 and covering the latter with an assembling layer 4.
,,~, , The above-mentioned enameled strand 2 is each produced by coating the surface of a conductor 5 such as an annealed copper wire or a tin-plated annealed copper wire usually having a diameter of about 0.01 to 1 mm with an insulating coating made of polyvinyl formal, polyester, polyurethane, silicone, epoxy, nylon, phenoxy, polyimide, polyester-imide, polyester-amide-imide, polyhydantoin, or polyhydantoin-ester-imide, and baking the coating to form an insulating layer 6 having a thickness of about 0.5 to 10 ~m.
The above-mentioned assembling layer 4 is formed by coating the assembly 3 with a coating material containing polyvinyl butyral and a stabilized polyisocyanate and baking the same.
Polyvinyl butyral is obtained by condensation of polyvinyl alcohol with butyraldehyde as follows:
CH-OH CH - O
I
CH-OH CH - O
' Commsrcially available polyvinyl 'outyral having a degree of polymerization of about 300 to about 3,000 and a degree of butyralization of about 70 to about 90 mol%
may be used in the present invention although it is not ~3~7~8S
limited within such ranges. Preferably, the polyvinyl butyral has a sufficient amount of hydroxyl groups in a molecular chain which can react with isocyanate groups of a stabilized polyisocyanate as described later.
The stabilized polyisocyanate is a polyisocyanate whose isocyanate groups are temporarily masked with a protective agent such as phenol or an amide to inactivate the same and are regenerated by removing the protective group with the aid o~ heat or a catalyst according to need. There can be used, for example, a type of compound which is prepared by adding tolylene diisocyana~e to trimethylolpropane as a polyhydric alcohol to form a polyisocyanate and , ,~,....
protecting the polyisocyanate with phenol. Such a stabilized polyisocyanate is sold under the registered trademark "Desmodur AP Stable" by Bayer, West Germany, or trade-mark "Coronate AP Stable" by Nippon Polyurethane Industry Co., Japan (hereinafter N.P.I.).
The followlng stabilized polyisocyanate which is blocked with phenol and i8 sold under the trade~rk "Coronate CT
Stable" by N.P.I may be also used in the present invention:
~c~N,~ NCO
~ \N/ ~
~CO
~307~85 Alternative stabilized polyisocyanate which may be used in the present invention is the following which is obtained by blocking OCN~CH~NCO
with cresol:
CH34~ O-C- N ~3 CH2~N- C- ~ CH3 OH H O
Such a stabilized polyisocyanate is sold under the trade -",..; . ,.
mark "Millionate MS-50" by N~P.I. The stabilized polyisocyanate used in the present invention is not limited to those named above.
In the present invention, the stabilized polyisocyanate is generally used in an amount from about 1 to absut 1000 parts by weight, preferably from about to about 300 parts by weight per 100 parts by weight of polyvinyl butyral. When the amount of the stabilized polyisocyanate is less than about 1 parts by weight, the assembllng layer is unfavorably swollen in an alcohol-Freon cleaning solvent due to insufficient density of crosslinkage thereof. With more than about 1000 parts by weight of the stabilized polyisocyanate, a difficulty is encountered in dissolving the assembling layer 4 in an alcoholic solvent due to its rather high crosslinking density. Within the preerable range from about 10 to about 300 parts by weight of stabilized polyisocyanate, excellent results in both resistance to the alcohol-freon cleaning solvent and solubility in an alcoholic solvent are achieved.
~ , ~ ,, ~".
1~07~85 Polyvinyl butyral and the stabilized polyisocyanate are mixed at the above-mentioned mixing ratio, and may be dissolved in a-solvent such as ethanol, butanol, xylene, or cyclohexanone, or a mixed solvent of two or more kinds of them to form a coating material. The resin content of the coating material is typically about S to about 40 wt.% but may be outside this range.
This coating material is applied to the assembly 3 and baked to form the assembling layer 4.
Application and baki'n*g are conducted by using a common apparatus for application and baking of an enamel coating; In the present in~vention, the baking may be preferably made at a temperature of the baking furnace of about 200 to about 300C and with a baking time of about 2 to about 30 sec but it may be carried out outside these ranges.
The density of crosslinkage of the assembling layer 4 thus formed is preferably about 30 to about 80% in terms of a gel fraction or gel content although it is not limited to this range.
Although the coating thickness of the assembling layer 4 varies depending on the position in the embodiment in FIG. 1, the thickness of the thinnest part thereof is preferably in a range of about 0.1 to 10 ~um for excellent assembling performance and solubility in an alcoholic solvent thereof.
1307(~85 Since the assembling layer 4 of the stranded insulated wire 1 is obtained by applying a coating material containin~ polyvinyl butyral and a stabilized polyisocyanate to an assembly of enameled strands and baking the same, hydroxyl groups of the polyvinyl butyral react with isocyanate groups of the stabilized polyisocyanate to form a crosslinked structure. Since the density of crosslinkage is in an adequate range, the assembling layer 4 is soluble in an alcoholic solvent. Thus r the assembling layer 4 can be removed by dipping a terminal portion of the stranded insulated wire lA
in the alcoholic solvent to thereby effect separation of enameled strands 2-- from each other. Since the assembling layer 4 is insoluble in an alcohol-Freon cleaning solvent, it will be neither swollen nor dissolved during normal cleaning operation with the al¢ohol-Freon cleaning solvent.
FIG. 2 shows a modified form of the stranded insulated wire in FIG. 1. This modified wire 1B is obtained by assembling a plurality of enameled strands 2... (seven enameled strands in this case) by concentric laying, bunch stranding, rope lay stranding, or the like to form an assembly 3 and forming an assembling layer 4 on the assembly 3 in the 7~85 same manner as that of the foregoing e~bodiment.
The function and effect of the present invention will now be clarified with reference to Examples thereof.
In the following Examples and Comparative ~" Example , polyurethane copper wires having a diameter of a conductor of 0.05 mm and a thickness of a polyurethane insulating layer of lO ~m were used as the enameled strands. Assemblies consisting of three enameled strands arranged in a row were respectively coated with coating materials having various compositions.
Baking was conducted under conditions involving a baking furnace temperature of 220C, a furnace ; length of 10 m, and a linear velocity of lO m~in form an assembling layer having a thickness of 4 ~m. Thus, stranded insulated wires were produced.
Each of the obtained wires was dipped in ethanol (alcoholic solvent) at room temperature to determine the time taken to separate it into three strands.
It was dipped also in Freon TMS (an alcohol-Freon cleaning solvent) and washed with the aid of supersonic waves for 3 minutes. The appearance of the assembling layer was observed to examine the resistance to the alcohol-Freon cleaning solvent.
The results are given in Tables 1A to 1D.
* TRADE-MARK
~3~7~85 Example 1 The coating material was prepared by dissolving 100 parts by weight of polyvinyl butyral (Denka Butyral 6000C sold by Denki Ragaku Xogyo K.K, Japan) and 80 parts by weight of a stabilized polyisocyanate (Coronate *
,~AP Stable) in 2,000 parts by weight of a 1:1 mixed solvent of ethanol and xylene.
Example 2 Another stranded insulated wire was prepared.on the same conditions as in Example 1 except that Millonate MS-S0* was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 3 ;The stranded insulated wire of this example was prepared on the same conditions as in Example 1 except that trifunctional MDI was used as the stab~lized polyisocyanate lnstead of Coronate AP Stable.
Example 4 Another stranded insulated wire was prepared on the same conditions as in Example 1 except that Coronate CT
Stable was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 5 The coating material in this example was prepared * TRADE-MARK
~,., , *~f;
: ' .,.,.,,,".. , ,~ , ~3~7~8S
by dissolving both 100 parts by weight of poly~inyL
butyral (Denka Butyral 2000L sold by Denki Kagaku Kogyo K.K, Japan) and 60 parts by weight of a stabilized polyisocyanate (Coronate AP Stable) in 1,000 parts by weight of a 1:1 mixed solvent of n-butanol and xylene.
Example 6 The coating material in this example was prepared on the same conditions as in Example 5 except that Millonate MS-50 was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example ~
The coating material of this example was prepared on the same conditions as in Example 5 except that trifunctional MDI was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 8 The coating material in this example was prepared on the same conditions as in Example 5 except that Coronate CT Stable was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 9 The coating material in this example was prepared by dissolving both 100 parts by weight of polyvinyl butyral (Denka Butyral 3000K sold by Denki Kagaku Kogyo : - . .~. . .;
- ~3C17~85 K.K, Japan) and 100 parts by weight of a stabilized polyisocyanate (Coronate AP Stable) in 1,000 parts by weight of a 1:1 mixed solvent of cyclohexanone and xylene.
Example 10 The coating material in this example was prepared on the same conditions as in Example 9 except that Millonate MS-50 was used as the stabilized polyisocyànate instead of Coronate AP Stable.
Example 11 The coating material in this example was prepared on the same conditions as in Example 9 except that trlfunctional MDI was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 12 The coating material in this example was prepared on the same conditions as in Example 9 except that Coronate CT Stable was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Comparative Example The coatlng material was prepared on the same conditions as in Example 1 except that no stabilized polyisocyanate was used.
13C)7~85 As indicated in the Tables, it was confirmed that the assembling layers of wires of Examples 1 to 12 little swelled nor dissolved in the alcohol-Freon solvent.
1.3C~7085 Table 1A
Example 1 2 3 4 Separation time (sec) 90 60 90 90 Appearance after cleaning with Freon TMS good good ~ good good -Table 1B
Example 5 6 7 8 Separation time (~ec) 50 40 50 50 Appearance after cleaning with Freon TMSgood good good good -Table 1C
Example 9 10 11 12 Separation time (~ec) 60 50 60 60 Appearance after cleaning with Freon TMSgood good good good 13~7~985 Table 1D
Comparative Example Separation time (sec) 30 Appearance after cleaning with Freon TMS swollen -
STRANDED INSULATED WIRE
The present invention relates to a stranded insulated wire in which an assembling layer is formed ~
coating a resin over an enameled strands stranded assembly.
When such a kind of stranded insulated wire is to be `soldered at its one terminal, it is necessary to remove the assembling layer from there to separate enameled strands from each other.
Removal of the assembling layer of the stranded insulated wire is conducted by a method in which a terminal portion of the stranded insulated wire is dipped in an alcoholic solvent to dissolve therein a resin constituting the assembling layer or a method in which the assembling layer is mechanically removed. The method of dipping a terminal portion of a stranded insulated wire in an alcoholic solvent is predominantly employed from the viewpoint of working eficiency and prevention of damage to the insulating làyers of enameled strands.
As a resin constituting an assembling layer of a stranded insulated wire, there is used, for example, polyvinyl butyral; a crosslinked resin such as an epoxy resin, polyester, or polyurethane; or polyamide (nylon).
13~7~5 As assembling layer made of polyvinyl butyral is readily soluble in an alcoholic solvent. Thus, strands at the terminal of a stranded insulated wire can be easily separated from each other.
However, the assembling layer i5 swellable or soluble in an alcohol-Freon cleaning solvent, which is used in the cleaning step after incorporating, for example, as a coil in a magnetic head of a disk drive, and hence loses its function.
An assembling layer made of a crosslinked resin such as an epoxy resin is neither swellable nor soluble in an alcohol-Freon cleaning solvent, and is insoluble in an alcoholic solvent, either.
Therefore, the method of mechanically removing the assembling layer must be employed, thus presenting a problem of workability.
An assembling layer made of a polyamide such as nylon 12 is neither swellable nor soluble in an alcohol-Freon cleaning solvent, and is insoluble in an alcoholic solvent, either. It can be dissolved in and removed by a phenolic compound such as phenol or cresol. However, a difficulty is encountered in handling the phenolic compound because of its toxicity.
* TRADE-MARK
~',,~;
, ~.3e)7085 According to one aspect of the invention there is provided a stranded insulated wire, comprising: (a) an assembly of a plurality of enameled strands, each comprising an annealed copper wire or tin-plated annealed copper wire having thereon an insulating coating made of polyvinyl formal, polyester, polyurethane, silicone, epoxy, nylon, phenoxy, polyimide, polyester-imide, polyester-amide-imide, polyhydantoin or polyhydantoin-ester-imide;
and (b) an assembling layer coating over said assembly of enameled strands, said assembling layer being produced by applying a coating material, consisting essentially of about 100 parts by weight of polyvinyl butyral, and about 1 to 1,000 parts by weight of a stabilized polyisocyanate, to the assembly and then baking said coating material to e~fect crosslinking.
According to another aspect of the invention there is provided a method o~ producing a stranded insulated wire having (a) an assembly o~ a plurality o~ enameled strands, each comprising an annealed copper wire or tin-plated annealed copper wire having thereon an insulating coating made o~ polyvinyl ~ormal, polyester, polyurethane, silicone, epoxy, nylon, phenoxy, polyimide, polyester-imide, polyester-amide-imide, polyhydantoin or polyhydantoin-ester-imide; and ~b) an assembling layer coating over said assembly of enameled strands, said assembling layer being produced by applying a coating material, consisting essentially o~ about 100 parts by weight o~ polyvinyl butyral, and about 1 to 1,000 parts by .,,,t~.-, ~i - 3a -weight of a stabilized polyisocyanate, to the assembly and then baking said coating material to effect crosslinking, said method comprising the steps of: (i) stranding a plurality of enameled strands for forming an assembly; (ii) applying a coating material over the assem~ly, the coating material containing loo parts by weight of polyvinyl butyral and about 1 to about 1000 parts by weight of a stabilized polyisocyanate; and (iii) baking the applied coating material to effect crosslinking to form an assembling layer.
The assembling layer is well soluble in an alcoholic solvent and hence separation of the strands from each other can be easily and quickly effected. It is not swellable in an alcohol-Freon during cleaning of the stranded insulated wire after incorporating thereof into an electronic appliance, and hence the cleaning is possible as usual.
In the drawings:
FIG. 1 is a diagrammatic cross-sectional view of a stranded insulated wire according to the present invention;
and FIG. 2 is a diagrammatic cross-sectional view of a modi~ied ~orm of the stranded insulated wire in FIG. 1.
Referring to FIG. 1, the stranded insulated wire lA is produced by bundling three enameled strands 2 in parallel with each other and in a row to ~orm an assembly 3 and covering the latter with an assembling layer 4.
,,~, , The above-mentioned enameled strand 2 is each produced by coating the surface of a conductor 5 such as an annealed copper wire or a tin-plated annealed copper wire usually having a diameter of about 0.01 to 1 mm with an insulating coating made of polyvinyl formal, polyester, polyurethane, silicone, epoxy, nylon, phenoxy, polyimide, polyester-imide, polyester-amide-imide, polyhydantoin, or polyhydantoin-ester-imide, and baking the coating to form an insulating layer 6 having a thickness of about 0.5 to 10 ~m.
The above-mentioned assembling layer 4 is formed by coating the assembly 3 with a coating material containing polyvinyl butyral and a stabilized polyisocyanate and baking the same.
Polyvinyl butyral is obtained by condensation of polyvinyl alcohol with butyraldehyde as follows:
CH-OH CH - O
I
CH-OH CH - O
' Commsrcially available polyvinyl 'outyral having a degree of polymerization of about 300 to about 3,000 and a degree of butyralization of about 70 to about 90 mol%
may be used in the present invention although it is not ~3~7~8S
limited within such ranges. Preferably, the polyvinyl butyral has a sufficient amount of hydroxyl groups in a molecular chain which can react with isocyanate groups of a stabilized polyisocyanate as described later.
The stabilized polyisocyanate is a polyisocyanate whose isocyanate groups are temporarily masked with a protective agent such as phenol or an amide to inactivate the same and are regenerated by removing the protective group with the aid o~ heat or a catalyst according to need. There can be used, for example, a type of compound which is prepared by adding tolylene diisocyana~e to trimethylolpropane as a polyhydric alcohol to form a polyisocyanate and , ,~,....
protecting the polyisocyanate with phenol. Such a stabilized polyisocyanate is sold under the registered trademark "Desmodur AP Stable" by Bayer, West Germany, or trade-mark "Coronate AP Stable" by Nippon Polyurethane Industry Co., Japan (hereinafter N.P.I.).
The followlng stabilized polyisocyanate which is blocked with phenol and i8 sold under the trade~rk "Coronate CT
Stable" by N.P.I may be also used in the present invention:
~c~N,~ NCO
~ \N/ ~
~CO
~307~85 Alternative stabilized polyisocyanate which may be used in the present invention is the following which is obtained by blocking OCN~CH~NCO
with cresol:
CH34~ O-C- N ~3 CH2~N- C- ~ CH3 OH H O
Such a stabilized polyisocyanate is sold under the trade -",..; . ,.
mark "Millionate MS-50" by N~P.I. The stabilized polyisocyanate used in the present invention is not limited to those named above.
In the present invention, the stabilized polyisocyanate is generally used in an amount from about 1 to absut 1000 parts by weight, preferably from about to about 300 parts by weight per 100 parts by weight of polyvinyl butyral. When the amount of the stabilized polyisocyanate is less than about 1 parts by weight, the assembllng layer is unfavorably swollen in an alcohol-Freon cleaning solvent due to insufficient density of crosslinkage thereof. With more than about 1000 parts by weight of the stabilized polyisocyanate, a difficulty is encountered in dissolving the assembling layer 4 in an alcoholic solvent due to its rather high crosslinking density. Within the preerable range from about 10 to about 300 parts by weight of stabilized polyisocyanate, excellent results in both resistance to the alcohol-freon cleaning solvent and solubility in an alcoholic solvent are achieved.
~ , ~ ,, ~".
1~07~85 Polyvinyl butyral and the stabilized polyisocyanate are mixed at the above-mentioned mixing ratio, and may be dissolved in a-solvent such as ethanol, butanol, xylene, or cyclohexanone, or a mixed solvent of two or more kinds of them to form a coating material. The resin content of the coating material is typically about S to about 40 wt.% but may be outside this range.
This coating material is applied to the assembly 3 and baked to form the assembling layer 4.
Application and baki'n*g are conducted by using a common apparatus for application and baking of an enamel coating; In the present in~vention, the baking may be preferably made at a temperature of the baking furnace of about 200 to about 300C and with a baking time of about 2 to about 30 sec but it may be carried out outside these ranges.
The density of crosslinkage of the assembling layer 4 thus formed is preferably about 30 to about 80% in terms of a gel fraction or gel content although it is not limited to this range.
Although the coating thickness of the assembling layer 4 varies depending on the position in the embodiment in FIG. 1, the thickness of the thinnest part thereof is preferably in a range of about 0.1 to 10 ~um for excellent assembling performance and solubility in an alcoholic solvent thereof.
1307(~85 Since the assembling layer 4 of the stranded insulated wire 1 is obtained by applying a coating material containin~ polyvinyl butyral and a stabilized polyisocyanate to an assembly of enameled strands and baking the same, hydroxyl groups of the polyvinyl butyral react with isocyanate groups of the stabilized polyisocyanate to form a crosslinked structure. Since the density of crosslinkage is in an adequate range, the assembling layer 4 is soluble in an alcoholic solvent. Thus r the assembling layer 4 can be removed by dipping a terminal portion of the stranded insulated wire lA
in the alcoholic solvent to thereby effect separation of enameled strands 2-- from each other. Since the assembling layer 4 is insoluble in an alcohol-Freon cleaning solvent, it will be neither swollen nor dissolved during normal cleaning operation with the al¢ohol-Freon cleaning solvent.
FIG. 2 shows a modified form of the stranded insulated wire in FIG. 1. This modified wire 1B is obtained by assembling a plurality of enameled strands 2... (seven enameled strands in this case) by concentric laying, bunch stranding, rope lay stranding, or the like to form an assembly 3 and forming an assembling layer 4 on the assembly 3 in the 7~85 same manner as that of the foregoing e~bodiment.
The function and effect of the present invention will now be clarified with reference to Examples thereof.
In the following Examples and Comparative ~" Example , polyurethane copper wires having a diameter of a conductor of 0.05 mm and a thickness of a polyurethane insulating layer of lO ~m were used as the enameled strands. Assemblies consisting of three enameled strands arranged in a row were respectively coated with coating materials having various compositions.
Baking was conducted under conditions involving a baking furnace temperature of 220C, a furnace ; length of 10 m, and a linear velocity of lO m~in form an assembling layer having a thickness of 4 ~m. Thus, stranded insulated wires were produced.
Each of the obtained wires was dipped in ethanol (alcoholic solvent) at room temperature to determine the time taken to separate it into three strands.
It was dipped also in Freon TMS (an alcohol-Freon cleaning solvent) and washed with the aid of supersonic waves for 3 minutes. The appearance of the assembling layer was observed to examine the resistance to the alcohol-Freon cleaning solvent.
The results are given in Tables 1A to 1D.
* TRADE-MARK
~3~7~85 Example 1 The coating material was prepared by dissolving 100 parts by weight of polyvinyl butyral (Denka Butyral 6000C sold by Denki Ragaku Xogyo K.K, Japan) and 80 parts by weight of a stabilized polyisocyanate (Coronate *
,~AP Stable) in 2,000 parts by weight of a 1:1 mixed solvent of ethanol and xylene.
Example 2 Another stranded insulated wire was prepared.on the same conditions as in Example 1 except that Millonate MS-S0* was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 3 ;The stranded insulated wire of this example was prepared on the same conditions as in Example 1 except that trifunctional MDI was used as the stab~lized polyisocyanate lnstead of Coronate AP Stable.
Example 4 Another stranded insulated wire was prepared on the same conditions as in Example 1 except that Coronate CT
Stable was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 5 The coating material in this example was prepared * TRADE-MARK
~,., , *~f;
: ' .,.,.,,,".. , ,~ , ~3~7~8S
by dissolving both 100 parts by weight of poly~inyL
butyral (Denka Butyral 2000L sold by Denki Kagaku Kogyo K.K, Japan) and 60 parts by weight of a stabilized polyisocyanate (Coronate AP Stable) in 1,000 parts by weight of a 1:1 mixed solvent of n-butanol and xylene.
Example 6 The coating material in this example was prepared on the same conditions as in Example 5 except that Millonate MS-50 was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example ~
The coating material of this example was prepared on the same conditions as in Example 5 except that trifunctional MDI was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 8 The coating material in this example was prepared on the same conditions as in Example 5 except that Coronate CT Stable was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 9 The coating material in this example was prepared by dissolving both 100 parts by weight of polyvinyl butyral (Denka Butyral 3000K sold by Denki Kagaku Kogyo : - . .~. . .;
- ~3C17~85 K.K, Japan) and 100 parts by weight of a stabilized polyisocyanate (Coronate AP Stable) in 1,000 parts by weight of a 1:1 mixed solvent of cyclohexanone and xylene.
Example 10 The coating material in this example was prepared on the same conditions as in Example 9 except that Millonate MS-50 was used as the stabilized polyisocyànate instead of Coronate AP Stable.
Example 11 The coating material in this example was prepared on the same conditions as in Example 9 except that trlfunctional MDI was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Example 12 The coating material in this example was prepared on the same conditions as in Example 9 except that Coronate CT Stable was used as the stabilized polyisocyanate instead of Coronate AP Stable.
Comparative Example The coatlng material was prepared on the same conditions as in Example 1 except that no stabilized polyisocyanate was used.
13C)7~85 As indicated in the Tables, it was confirmed that the assembling layers of wires of Examples 1 to 12 little swelled nor dissolved in the alcohol-Freon solvent.
1.3C~7085 Table 1A
Example 1 2 3 4 Separation time (sec) 90 60 90 90 Appearance after cleaning with Freon TMS good good ~ good good -Table 1B
Example 5 6 7 8 Separation time (~ec) 50 40 50 50 Appearance after cleaning with Freon TMSgood good good good -Table 1C
Example 9 10 11 12 Separation time (~ec) 60 50 60 60 Appearance after cleaning with Freon TMSgood good good good 13~7~985 Table 1D
Comparative Example Separation time (sec) 30 Appearance after cleaning with Freon TMS swollen -
Claims (10)
1. A stranded insulated wire, comprising:
(a) an assembly of a plurality of enameled strands, each comprising an annealed copper wire or tin-plated annealed copper wire having thereon an insulating coating made of polyvinyl formal, polyester, polyurethane, silicone, epoxy, nylon, phenoxy, polyimide, polyester-imide, polyester-amide-imide, polyhydantoin or polyhydantoin-ester-imide;
and (b) an assembling layer coating over said assembly of enameled strands, said assembling layer being produced by applying a coating material, consisting essentially of about 100 parts by weight of polyvinyl butyral, and about 1 to 1,000 parts by weight of a stabilized polyisocyanate, to the assembly and then baking said coating material to effect crosslinking.
(a) an assembly of a plurality of enameled strands, each comprising an annealed copper wire or tin-plated annealed copper wire having thereon an insulating coating made of polyvinyl formal, polyester, polyurethane, silicone, epoxy, nylon, phenoxy, polyimide, polyester-imide, polyester-amide-imide, polyhydantoin or polyhydantoin-ester-imide;
and (b) an assembling layer coating over said assembly of enameled strands, said assembling layer being produced by applying a coating material, consisting essentially of about 100 parts by weight of polyvinyl butyral, and about 1 to 1,000 parts by weight of a stabilized polyisocyanate, to the assembly and then baking said coating material to effect crosslinking.
2. The stranded insulated wire as recited in claim 1, wherein about 10 to 300 parts by weight of stabilized polyisocyanate is used per 100 parts by weight of the polyvinyl butyral.
3. The stranded insulated wire as recited in claim 1, wherein the assembling layer has a density of crosslinkage of about 30 to about 80% in terms of a gel fraction.
4. The stranded insulated wire as recited in claim 3, wherein the coating material contains a solvent selected from the group consisting of ethanol, butanol, xylene, cyclohexanone, and a mixture thereof and contains about 5 to about 40 weight % of both the polyvinyl butyral and stabilized polyisocyanate.
5. The stranded insulated wire as recited in claim 4, wherein the polyvinyl butyral has a degree of polymerization of about 300 to about 3000 and a degree of butyralization of about 70 to about so mol%.
6. The stranded insulated wire as recited in claim 5, wherein the thinnest part of assembling layer has a thickness of about 0.1 to about 10 µm.
7. A method of producing a stranded insulated wire having (a) an assembly of a plurality of enameled strands, each comprising an annealed copper wire or tin-plated annealed copper wire having thereon an insulating coating made of polyvinyl formal, polyester, polyurethane, silicone, epoxy, nylon, phenoxy, polyimide, polyester-imide, polyester-amide-imide, polyhydantoin or polyhydantoin-ester-imide;
and (b) an assembling layer coating over said assembly of enameled strands, said assembling layer being produced by applying a coating material, consisting essentially of about 100 parts by weight of polyvinyl butyral, and about 1 to 1,000 parts by weight of a stabilized polyisocyanate, to the assembly and then baking said coating material to effect crosslinking, said method comprising the steps of:
(i) stranding a plurality of enameled strands for forming an assembly;
(ii) applying a coating material over the assembly, the coating material containing 100 parts by weight of polyvinyl butyral and about 1 to about 1000 parts by weight of a stabilized polyisocyanate; and (iii) baking the applied coating material to effect crosslinking to form an assembling layer.
and (b) an assembling layer coating over said assembly of enameled strands, said assembling layer being produced by applying a coating material, consisting essentially of about 100 parts by weight of polyvinyl butyral, and about 1 to 1,000 parts by weight of a stabilized polyisocyanate, to the assembly and then baking said coating material to effect crosslinking, said method comprising the steps of:
(i) stranding a plurality of enameled strands for forming an assembly;
(ii) applying a coating material over the assembly, the coating material containing 100 parts by weight of polyvinyl butyral and about 1 to about 1000 parts by weight of a stabilized polyisocyanate; and (iii) baking the applied coating material to effect crosslinking to form an assembling layer.
8. A method as recited in claim 7, wherein the coating material contains about 10 to about 300 parts by weight of the stabilized polyisocyanate per 100 parts by weight of the polyvinyl butyral.
9. A method as recited in claim 7, wherein the baking is carried out at about 200C for about 2 to about 30 sec.
10. A method as recited in claim 7, wherein the coating material contains a solvent selected from the group consisting of ethanol, butanol, xylene, cyclohexanone, and a mixture thereof and contains about 5 to 40 weight % of both the polyvinyl butyral and stabilized polyisocyanate.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3852879T DE3852879T2 (en) | 1988-03-07 | 1988-03-07 | Insulated stranded wire and method for its production. |
| CA000561259A CA1307085C (en) | 1988-03-07 | 1988-03-11 | Stranded insulated wire |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP88301951A EP0331823B1 (en) | 1986-09-06 | 1988-03-07 | A stranded insulated wire and a method of producing the same |
| CA000561259A CA1307085C (en) | 1988-03-07 | 1988-03-11 | Stranded insulated wire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1307085C true CA1307085C (en) | 1992-09-08 |
Family
ID=25671767
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000561259A Expired - Lifetime CA1307085C (en) | 1988-03-07 | 1988-03-11 | Stranded insulated wire |
Country Status (2)
| Country | Link |
|---|---|
| CA (1) | CA1307085C (en) |
| DE (1) | DE3852879T2 (en) |
-
1988
- 1988-03-07 DE DE3852879T patent/DE3852879T2/en not_active Expired - Fee Related
- 1988-03-11 CA CA000561259A patent/CA1307085C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE3852879D1 (en) | 1995-03-09 |
| DE3852879T2 (en) | 1995-08-03 |
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