CA2003693A1 - Silica/alumina cogel catalysts - Google Patents

Silica/alumina cogel catalysts

Info

Publication number: CA2003693A1
Authority: CA; Canada
Prior art keywords: composition; silica; catalyst; cogel; slurry
Prior art date: 1988-11-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2003693

Other languages

English (en)

French (fr)

Inventor

Theresa A. Pecoraro

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Chevron USA Inc

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-11-23

Filing date

1989-11-23

Publication date

1990-05-23

1989-11-23 Application filed by Individual filed Critical Individual

1990-05-23 Publication of CA2003693A1 publication Critical patent/CA2003693A1/en

Status Abandoned legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 54
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 35
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 44
239000000377 silicon dioxide Substances 0.000 title claims description 22
238000000034 method Methods 0.000 claims abstract description 30
238000006243 chemical reaction Methods 0.000 claims abstract description 27
239000011159 matrix material Substances 0.000 claims abstract description 12
239000000203 mixture Substances 0.000 claims description 46
239000011148 porous material Substances 0.000 claims description 26
239000000243 solution Substances 0.000 claims description 20
230000008569 process Effects 0.000 claims description 17
230000000694 effects Effects 0.000 claims description 16
239000002002 slurry Substances 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 11
238000005336 cracking Methods 0.000 claims description 10
238000002156 mixing Methods 0.000 claims description 10
239000002245 particle Substances 0.000 claims description 8
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 8
230000032683 aging Effects 0.000 claims description 7
238000001694 spray drying Methods 0.000 claims description 7
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 6
238000005406 washing Methods 0.000 claims description 6
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 5
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 5
239000000908 ammonium hydroxide Substances 0.000 claims description 5
239000000084 colloidal system Substances 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 4
239000002184 metal Substances 0.000 claims description 4
229910052761 rare earth metal Inorganic materials 0.000 claims description 4
239000012266 salt solution Substances 0.000 claims description 4
150000002739 metals Chemical class 0.000 claims description 3
-1 rare earth ions Chemical class 0.000 claims description 3
239000007864 aqueous solution Substances 0.000 claims description 2
239000012798 spherical particle Substances 0.000 claims description 2
150000002500 ions Chemical class 0.000 claims 2
230000000717 retained effect Effects 0.000 claims 1
238000003756 stirring Methods 0.000 claims 1
229930195733 hydrocarbon Natural products 0.000 abstract description 11
150000002430 hydrocarbons Chemical class 0.000 abstract description 11
239000004215 Carbon black (E152) Substances 0.000 abstract description 10
238000002360 preparation method Methods 0.000 abstract description 10
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract description 8
230000003247 decreasing effect Effects 0.000 abstract 1
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 21
239000000017 hydrogel Substances 0.000 description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
239000000463 material Substances 0.000 description 12
239000000499 gel Substances 0.000 description 10
239000010457 zeolite Substances 0.000 description 8
229910017974 NH40H Inorganic materials 0.000 description 7
238000009826 distribution Methods 0.000 description 7
238000004519 manufacturing process Methods 0.000 description 7
229910001868 water Inorganic materials 0.000 description 7
239000008367 deionised water Substances 0.000 description 6
229910021641 deionized water Inorganic materials 0.000 description 6
239000000047 product Substances 0.000 description 6
239000007921 spray Substances 0.000 description 6
229910021536 Zeolite Inorganic materials 0.000 description 5
150000001336 alkenes Chemical class 0.000 description 5
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 5
239000004927 clay Substances 0.000 description 5
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
230000002378 acidificating effect Effects 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
238000001035 drying Methods 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000003921 oil Substances 0.000 description 4
230000008707 rearrangement Effects 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000011959 amorphous silica alumina Substances 0.000 description 3
239000002585 base Substances 0.000 description 3
238000009835 boiling Methods 0.000 description 3
238000001354 calcination Methods 0.000 description 3
229910052809 inorganic oxide Inorganic materials 0.000 description 3
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
239000000126 substance Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 2
239000005695 Ammonium acetate Substances 0.000 description 2
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
239000004115 Sodium Silicate Substances 0.000 description 2
229940043376 ammonium acetate Drugs 0.000 description 2
235000019257 ammonium acetate Nutrition 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
239000000571 coke Substances 0.000 description 2
238000001246 colloidal dispersion Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
239000002131 composite material Substances 0.000 description 2
238000006317 isomerization reaction Methods 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
230000001376 precipitating effect Effects 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
150000002910 rare earth metals Chemical class 0.000 description 2
238000009877 rendering Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052911 sodium silicate Inorganic materials 0.000 description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
238000010025 steaming Methods 0.000 description 2
239000000725 suspension Substances 0.000 description 2
JQMFQLVAJGZSQS-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-N-(2-oxo-3H-1,3-benzoxazol-6-yl)acetamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)NC1=CC2=C(NC(O2)=O)C=C1 JQMFQLVAJGZSQS-UHFFFAOYSA-N 0.000 description 1
229910017119 AlPO Inorganic materials 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
241000269350 Anura Species 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
239000000654 additive Substances 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
229940037003 alum Drugs 0.000 description 1
150000004645 aluminates Chemical class 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
238000004380 ashing Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
230000008859 change Effects 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000006482 condensation reaction Methods 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000007324 demetalation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
239000012013 faujasite Substances 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000004231 fluid catalytic cracking Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
230000003278 mimic effect Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000001935 peptisation Methods 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
229910001845 yogo sapphire Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Materials Engineering (AREA)
General Chemical & Material Sciences (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA 2003693 1988-11-23 1989-11-23 Silica/alumina cogel catalysts Abandoned CA2003693A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US27547088A	1988-11-23	1988-11-23
US275,470		1988-11-23

Publications (1)

Publication Number	Publication Date
CA2003693A1 true CA2003693A1 (en)	1990-05-23

Family

ID=23052430

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2003693 Abandoned CA2003693A1 (en)	1988-11-23	1989-11-23	Silica/alumina cogel catalysts

Country Status (5)

Country	Link
EP (1)	EP0404908A4 (pt)
JP (1)	JPH03503742A (pt)
BR (1)	BR8907200A (pt)
CA (1)	CA2003693A1 (pt)
WO (1)	WO1990005702A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5399535A (en) *	1993-08-17	1995-03-21	Rohm And Haas Company	Reticulated ceramic products
US6872685B2 (en) *	2002-11-08	2005-03-29	Chevron U.S.A. Inc.	Method for preparing a highly homogeneous amorphous silica-alumina composition
US6995112B2 (en) *	2002-11-08	2006-02-07	Chevron U.S.A. Inc.	Highly homogeneous amorphous silica-alumina catalyst composition

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
USRE23438E (en) *		1951-12-04		Preparation of silica-alumina
US2166970A (en) *	1938-07-27	1939-07-25	Rudolph I Schonitzer	Combined door-checking and doorholding device
US2908635A (en) *	1953-08-24	1959-10-13	Exxon Research Engineering Co	Method of making co-precipitated silica-alumina catalyst
US3210293A (en) *	1962-07-25	1965-10-05	Universal Oil Prod Co	Hydrorefining catalyst base prepared by high ph precipitation
US3496116A (en) *	1967-02-13	1970-02-17	Universal Oil Prod Co	Catalyst manufacture
GB1355214A (en) *	1971-09-15	1974-06-05	Engelhard Min & Chem	Preparation of silica-alumina composites
JPS5335705A (en) *	1976-09-14	1978-04-03	Toa Nenryo Kogyo Kk	Hydrogenation and purification of petroleum wax
US4310441A (en) *	1977-02-16	1982-01-12	Filtrol Corporation	Large pore silica-alumina gels and method of producing the same
US4289653A (en) *	1978-12-11	1981-09-15	Chevron Research Company	Comulled silica-alumina base denitrification catalyst
US4226743A (en) *	1979-03-12	1980-10-07	W. R. Grace & Co.	Silica-alumina hydrogel catalyst
CA1211428A (en) *	1982-09-30	1986-09-16	Joseph F. Porinchak	Alumina-silica cogel

1989
- 1989-11-22 BR BR898907200A patent/BR8907200A/pt not_active Application Discontinuation
- 1989-11-22 JP JP2500876A patent/JPH03503742A/ja active Pending
- 1989-11-22 WO PCT/US1989/005298 patent/WO1990005702A1/en not_active Ceased
- 1989-11-22 EP EP19900900622 patent/EP0404908A4/en not_active Withdrawn
- 1989-11-23 CA CA 2003693 patent/CA2003693A1/en not_active Abandoned

Also Published As

Publication number	Publication date
EP0404908A4 (en)	1991-04-03
EP0404908A1 (en)	1991-01-02
BR8907200A (pt)	1991-03-05
JPH03503742A (ja)	1991-08-22
WO1990005702A1 (en)	1990-05-31

Legal Events

Date	Code	Title	Description
1994-05-23	FZDE	Dead

Publication	Publication Date	Title
US4988659A (en)	1991-01-29	Silica/alumina cogel catalysts
US4458023A (en)	1984-07-03	Catalyst manufacture
RU2435643C2 (ru)	2011-12-10	Катализатор гидрокрекинга, который включает образованный in situ y-фожазит, и процесс гидрокрекинга
US3210267A (en)	1965-10-05	Catalytic cracking of hydrocarbons with the use of a crystalline zeolite catalyst containing rare earths and a porous matrix
US6114267A (en)	2000-09-05	Process for the preparation of fluidized catalytic cracking (FCC) catalyst
US3459680A (en)	1969-08-05	Crystalline zeolite composite for catalytic hydrocarbon conversion
US5001097A (en)	1991-03-19	Hydrocarbon conversion with octane-enhancing catalysts
US20030136707A1 (en)	2003-07-24	FCC catalysts for feeds containing nickel and vanadium
CA2524548C (en)	2012-07-17	Fcc catalysts prepared by in-situ crystallization of zeolite
US4332699A (en)	1982-06-01	Catalyst preparation
US5168086A (en)	1992-12-01	Catalytic cracking catalysis
JP3949778B2 (ja)	2007-07-25	接触分解触媒
US3436357A (en)	1969-04-01	Catalyst and conversion of organic compounds in the presence thereof
CA1171054A (en)	1984-07-17	Hydrocarbon conversion catalysts and processes utilizing the same
US4843052A (en)	1989-06-27	Acid-reacted metakaolin catalyst and catalyst support compositions
US5071806A (en)	1991-12-10	Vanadium tolerant cracking catalyst
US3352796A (en)	1967-11-14	Catalyst for hydrocarbon conversions
JPH11564A5 (pt)	2005-03-10
NL8001598A (nl)	1980-09-25	Werkwijze ter bereiding van een koolwaterstofomzet- tingskatalysator.
US4376039A (en)	1983-03-08	Hydrocarbon conversion catalysts and processes utilizing the same
US6528447B1 (en)	2003-03-04	Process for the preparation of a catalyst composite
US3391075A (en)	1968-07-02	Catalytic conversion of hydrocarbons with the use of a steam treated y type of crystalline aluminosilicate
US5160601A (en)	1992-11-03	Hydrocarbon conversion with octane-enhancing catalysts
US5135641A (en)	1992-08-04	Catalytic cracking process employing silica/alumina cogel catalysts
US4940531A (en)	1990-07-10	Catalytic cracking process employing an acid-reacted metakaolin catalyst