CH134832A - Process for the preparation of an arylaminonaphthalene derivative. - Google Patents
Process for the preparation of an arylaminonaphthalene derivative.Info
- Publication number
- CH134832A CH134832A CH134832DA CH134832A CH 134832 A CH134832 A CH 134832A CH 134832D A CH134832D A CH 134832DA CH 134832 A CH134832 A CH 134832A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- derivative
- arylaminonaphthalene
- aminonaphthalene
- diaminobenzene
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title claims description 4
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- -1 aryl aminonaphthalene derivative Chemical class 0.000 claims 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Darstellung eines ArylaminonaphtaUnderivates. Im Hauptpatent ist ein Verfahren zur Darstellung eines Arylaminonaphtalinderiva- tes beschrieben., welches dadurch gekenn zeichnet ist, dass man 2-Ogynaphtalin mit 1 . 2-Diaminobenzol in Gegenwart von Bi- sulfitlauge bei höheren Temperaturen mit oder ohne Anwendung von, Druck konden siert.
Wie nun weiter gefunden wurde, er hält man das gleiche Produkt, nämlich das 2'-Aminophenyl-2-aminonaphtalin, wenn man an Stelle des 2-Oxynaphtalins 2-Aminonaph- ta-lin dieser Kondensation unterwirft.
Beispiel 144 Teile 2-Aminonaphtalin, <B>150</B> Teile 1. 2-Diaminobenzol und 4000 Teile Natrium- bisulfitlösung von<B>19'</B> B6 werden in einem geschlossenen emaillierten Kessel zirka 40 Stunden bei 115 bis 120' C gerührt. Die Aufarbeitung erfolgt, wie im Beispiel des Hauptpatentes angegeben. Das Reaktions produkt, ist identisch mit dem des Haupt patentes.
Process for the preparation of an arylaminonaphtha derivative. The main patent describes a process for the preparation of an arylaminonaphthalene derivative, which is characterized in that 2-ogynaphthalene is 1. 2-Diaminobenzene condensed in the presence of bisulfite liquor at higher temperatures with or without the use of pressure.
As has now been found, the same product is obtained, namely 2'-aminophenyl-2-aminonaphthalene, if 2-aminonaphthalene is subjected to this condensation instead of 2-oxynaphthalene.
Example 144 parts of 2-aminonaphthalene, 150 parts of 1. 2-diaminobenzene and 4000 parts of sodium bisulfite solution of 19 'B6 are heated in a closed enamelled kettle at 115 to Stirred at 120 ° C. The work-up takes place as indicated in the example of the main patent. The reaction product is identical to that of the main patent.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE134832X | 1926-12-13 | ||
| CH132030T | 1927-12-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH134832A true CH134832A (en) | 1929-08-15 |
Family
ID=25711741
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH134832D CH134832A (en) | 1926-12-13 | 1927-12-03 | Process for the preparation of an arylaminonaphthalene derivative. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH134832A (en) |
-
1927
- 1927-12-03 CH CH134832D patent/CH134832A/en unknown
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