CH90849A - Process for the preparation of a chromable o-oxydisazo dye. - Google Patents
Process for the preparation of a chromable o-oxydisazo dye.Info
- Publication number
- CH90849A CH90849A CH90849DA CH90849A CH 90849 A CH90849 A CH 90849A CH 90849D A CH90849D A CH 90849DA CH 90849 A CH90849 A CH 90849A
- Authority
- CH
- Switzerland
- Prior art keywords
- dye
- oxydisazo
- preparation
- chromable
- sulfonic acid
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title claims description 4
- 239000013067 intermediate product Substances 0.000 claims description 3
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012670 alkaline solution Substances 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- RHPXYZMDLOJTFF-UHFFFAOYSA-N 3-amino-4-hydroxy-5-nitrobenzenesulfonic acid Chemical compound NC1=CC(S(O)(=O)=O)=CC([N+]([O-])=O)=C1O RHPXYZMDLOJTFF-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- AACMNEWXGKOJJK-UHFFFAOYSA-N 2-amino-6-nitrophenol Chemical compound NC1=CC=CC([N+]([O-])=O)=C1O AACMNEWXGKOJJK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Coloring (AREA)
Description
Verfahren zur Darstellung eines chromierbar en o-Oxydisazofär bstoffes. Im Hauptpatent wurde ein Verfahren zur Darstellung eines chromierbaren o-Oxydisazo- farbstoffes beschrieben, darin bestehend, dass man dianotiertes 4-Nitrö-2-aminopheiiol in alkalischer Lösung mit 2-Amino-5-naphtol- 7-sulfosäure kuppelt, das Zwischenprodukt weiter dianotiert und mit Aethylbenzylanilin- 4'-sulfosäure vereinigt.
In diesem Verfahren lässt sich die Anfangs komponente durch 6-Nitro-2-aminophenol-4- 8ulfosäure ersetzen, wobei man einen ähnlichen Farbstoff erhält, dessen Färbung auf Wolle nachchromiert schwarz ist und sich durch vorzügliche Licht-, Wasch- und Wallechtheit auszeichnet.
<I>Beispiel:</I> Die aus 23,4 Teilen 6-Nitro-2-aminophenol-
EMI0001.0018
,QMure <SEP> bereitete <SEP> Diazoverhindung <SEP> wird
<tb> . <SEP> -."ä\@illra.lischer <SEP> Lösung <SEP> mit <SEP> 24 <SEP> Teilen 2-Aminö-5-näphtöl-7-sulfösäuregekuppelt. Das Zwischenprodukt wird mit Salzsäure bis zur sauren Reaktion auf Congo versetzt und nach weiterer Zugabe von 30 Teilen Salzsäure von 120 Bö mit -7 Teilen -Natriumnitrit bei etwa 0 innerhalb 3 Stunden dianotiert. Darnach erfolgt die Kupplung.
mit 33 Teilen Aethyl- benzylaniliii-4'-sülfosäure mit 35 Teilen Wasser y freiem Natriumkarbonat in 600 Teilen Wasser gelöst. Der Farbstoff wird ausgesalzen und in üblicher Weise isoliert.
Process for the preparation of a chromizable o-oxydisazo dye. In the main patent, a process for the preparation of a chromable o-oxydisazo dye was described, consisting in coupling dianotated 4-nitro-2-aminopheiiol in alkaline solution with 2-amino-5-naphthol-7-sulfonic acid and dianotating the intermediate product further and combined with ethylbenzylaniline-4'-sulfonic acid.
In this process, the initial component can be replaced by 6-nitro-2-aminophenol-4-8ulfonic acid, whereby a similar dye is obtained, the color of which on wool is chromed black and is characterized by excellent light, wash and whiteness.
<I> Example: </I> The 6-nitro-2-aminophenol from 23.4 parts
EMI0001.0018
, QMure <SEP> prepared <SEP> diazo prevention <SEP>
<tb>. <SEP> -. "Ä \ @ Illra.lischer <SEP> solution <SEP> with <SEP> 24 <SEP> parts of 2-amino-5-naphthol-7-sulfoic acid. The intermediate product is diluted with hydrochloric acid until it reacts acidic Congo is added and, after further addition of 30 parts of hydrochloric acid of 120 Bo, dianotized with -7 parts of sodium nitrite at about 0 within 3 hours.
with 33 parts of ethyl benzylaniliii-4'-sulphonic acid with 35 parts of water and free sodium carbonate dissolved in 600 parts of water. The dye is salted out and isolated in the usual way.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE74077X | 1915-07-28 | ||
| CH88563T | 1920-06-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH90849A true CH90849A (en) | 1921-10-01 |
Family
ID=25703857
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH90849D CH90849A (en) | 1915-07-28 | 1920-06-18 | Process for the preparation of a chromable o-oxydisazo dye. |
| CH90848D CH90848A (en) | 1915-07-28 | 1920-06-18 | Process for the preparation of a chromable o-oxydisazo dye. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH90848D CH90848A (en) | 1915-07-28 | 1920-06-18 | Process for the preparation of a chromable o-oxydisazo dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (2) | CH90849A (en) |
-
1920
- 1920-06-18 CH CH90849D patent/CH90849A/en unknown
- 1920-06-18 CH CH90848D patent/CH90848A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH90848A (en) | 1921-10-01 |
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