CH93492A - Process for the preparation of a dye of the phenyldinaphtylmethane series. - Google Patents

Process for the preparation of a dye of the phenyldinaphtylmethane series.

Info

Publication number
CH93492A
CH93492A CH93492DA CH93492A CH 93492 A CH93492 A CH 93492A CH 93492D A CH93492D A CH 93492DA CH 93492 A CH93492 A CH 93492A
Authority
CH
Switzerland
Prior art keywords
dye
acid
preparation
phenyldinaphtylmethane
series
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH93492A publication Critical patent/CH93492A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B11/00—Diaryl- or thriarylmethane dyes
    • C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
    • C09B11/06—Hydroxy derivatives of triarylmethanes in which at least one OH group is bound to an aryl nucleus and their ethers or esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Description

  

  Verfahren zur Herstellung eines     Farbstoffe-s    der     Plienyldinahhtylnietlianreihe.       Es wurde-     gefunden,        dass,        wenn    man     a12'          1-Naphtol-2-e,rbonsäiire        4-Clilorbenzoltri-          chlorid    in     (-T'e"enwart    eines     säurebindenden     Mittels.

       vorzugsweise        unter        Zugabe    eines       Katalysators,        einwirken    lässt, ein neuer     Farb-          toff        erhalten    wird. Dieser Farbstoff gibt  s<B>s</B>  auf Wolle, aus     saurein    Bade gefärbt eine  graue Färbung, welche     beine        Nachchroniieren     in ein reines.     N-        orzüglicli    echtes Grün über  geht.

           Beispiel:     752 Teile     1-Naphtol-2-carlionsäure        -,ver-          den    - in 1900 Teilen     Natronlauge        von    30       Gew.    und 500 Teilen     -\Vasser    gelöst. Hier  auf gibt     inan    ! 34 Teile     4-Clilorbenzotrichlorid     und 0,5 Teile Kupfer     hinzu    und rührt so  lange, bis alles     Benzotriclilorid        verschwunden     ist.

   Das     Natriumsalz    des gebildeten Farb  stoffes wird     durch        Aussalzen    aus dein mit  Wasser verdünnten Reaktionsgemisch abge  schieden.



  Process for the preparation of a dye of the Plienyldinahhtylnietlian reason. It has been found that if one converts a12 '1-naphthol-2-e, carbonic acid 4-chlorobenzene trichloride into (-T'e "in the presence of an acid-binding agent.

       preferably with the addition of a catalyst, a new dye is obtained. This dye gives s <B> s </B> on wool, dyed from acidic bath a gray color, which is followed by post-chronizing into a pure. N- orzüglicli real green goes over.

           Example: 752 parts of 1-naphthol-2-carlionic acid - dissolved in 1900 parts of 30% by weight sodium hydroxide solution and 500 parts of water. Give up here! Add 34 parts of 4-chlorobenzotrichloride and 0.5 part of copper and stir until all the benzotricliloride has disappeared.

   The sodium salt of the dye formed is separated out by salting out the reaction mixture diluted with water.

Claims (1)

PATENTANSPRUCH Verfahren zur Herstellung eine Farb stoffes der Plie -\-ldinaphtylmetlianreilie, da- cIurcli 1-Veliennzeiclinet, dass 1-Naph'tol-2-car- l@onsäiire mit 4-Clilorbeiizotrichlorid in Ge- gen%vart eines säurebindenden Mittels behan delt wird. Dieser Farbstoff gibt auf Wolle, aus saurem Bade gefärbt, eine graue Fär bung, PATENT CLAIM A process for the production of a dye of the Plie - \ - ldinaphtylmetlianreilie, da- cIurcli 1-Veliennzeiclinet that 1-Naph'tol-2-carl @ onsäiire treated with 4-Clilorbeiizotrichlorid in the opposite of an acid binding agent becomes. This dye gives wool, dyed from an acid bath, a gray color, welche beim Nachcliromieren in ein reines, vorzüglich echtes Grün übergeht. UNTERAN SPRMIE 1. Verfahren nach Patentanspruch, dadurch gel@ennzeicli.net, dass Natronlauge <I>als</I> säurebindendes 3Iittel verwendet wird. 2. Verfahren naeh Patentanspruch, dadurch gekennzeichnet, dar die Peaktion in Ge genwart von Kupfer dureligeführt wird. which turns into a pure, exquisitely real green when re-cloning. UNDER AN SPRMIE 1. Process according to patent claim, characterized in that caustic soda <I> is used as </I> acid-binding agent. 2. Method according to claim, characterized in that the reaction is carried out in the presence of copper.
CH93492D 1921-01-18 1921-01-18 Process for the preparation of a dye of the phenyldinaphtylmethane series. CH93492A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH93492T 1921-01-18
CH92406T 1921-01-18

Publications (1)

Publication Number Publication Date
CH93492A true CH93492A (en) 1922-03-01

Family

ID=25704488

Family Applications (1)

Application Number Title Priority Date Filing Date
CH93492D CH93492A (en) 1921-01-18 1921-01-18 Process for the preparation of a dye of the phenyldinaphtylmethane series.

Country Status (1)

Country Link
CH (1) CH93492A (en)

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