CN1274706A - 螯合型施肥素及其配制方法 - Google Patents
螯合型施肥素及其配制方法 Download PDFInfo
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- CN1274706A CN1274706A CN 99112233 CN99112233A CN1274706A CN 1274706 A CN1274706 A CN 1274706A CN 99112233 CN99112233 CN 99112233 CN 99112233 A CN99112233 A CN 99112233A CN 1274706 A CN1274706 A CN 1274706A
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- Prior art keywords
- sulfate
- fertilizer
- chelating
- calcium chloride
- added
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims description 9
- 238000013329 compounding Methods 0.000 title 1
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 14
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000001110 calcium chloride Substances 0.000 claims abstract description 7
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 7
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 7
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 7
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 7
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims abstract description 7
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims abstract description 7
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims abstract description 6
- 229910021538 borax Inorganic materials 0.000 claims abstract description 6
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000006012 monoammonium phosphate Substances 0.000 claims abstract description 6
- 235000019837 monoammonium phosphate Nutrition 0.000 claims abstract description 6
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 6
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 6
- 239000011734 sodium Substances 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 6
- 208000006558 Dental Calculus Diseases 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 2
- 238000010668 complexation reaction Methods 0.000 abstract 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 abstract 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract 1
- 235000019341 magnesium sulphate Nutrition 0.000 abstract 1
- 229940099596 manganese sulfate Drugs 0.000 abstract 1
- 239000011702 manganese sulphate Substances 0.000 abstract 1
- 235000007079 manganese sulphate Nutrition 0.000 abstract 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 abstract 1
- 229910052939 potassium sulfate Inorganic materials 0.000 abstract 1
- 235000011151 potassium sulphates Nutrition 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 230000000536 complexating effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 235000015097 nutrients Nutrition 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- CFQZKFWQLAHGSL-FNTYJUCDSA-N (3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e)-octadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoic acid Chemical compound OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C CFQZKFWQLAHGSL-FNTYJUCDSA-N 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 235000021050 feed intake Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- -1 weedicide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
螯合型施肥素及其配制方法,是用螯合载体三聚磷酸钠加硫酸钾、硫酸亚铁、硫酸锰、硫酸铜、无水氯化钙、硫酸锌、硫酸镁、硼砂、磷酸一铵组成。首先将螯合载体三聚磷酸钠放入反应罐,加入自来水,再将氯化钙放入反应罐,再加入硫酸钾、硫酸亚铁、硫酸锰、硫酸锌、硫酸铜、硫酸镁、硼砂、磷酸一铵的均匀混合物,充分络合后,引入离心机分离,卸料后送入回转干燥器干燥后即为成品。
Description
本发明属于一种肥料的配制方法。
在本发明以前的肥料，大致有二类：第一大类为腐植质型肥料，有原始的桔杆、人和动物排泄物发酵后的肥料，及各种腐植酸及腐植酸盐，其肥料的特点为缓效肥料，肥效长，见效慢。第二大类为离子型肥料，有如碳酸氢铵、磷二铵、氯化钾、硫酸锰、硫酸亚铁、尿素等等数量众多。其肥料特点为速效肥料，肥效短，见效快。近年来，高新农业科技进步很快，但本发明螯合型肥料一直没有进展，现在人们一直在期待着一种新的肥料的出现，既能全面充分利用一、二类肥料的养分，又能有速效、长效的特点。
本发明的任务是：提供一种速效，长效持久且养分齐全的新型肥料。
本发明的解决方法是：用螯合载体三聚磷酸钠或六聚磷酸钠加硫酸钾、硫酸亚铁、硫酸锰、硫酸铜、无水氯化钙、硫酸锌、硫酸镁、硼砂、磷酸一铵加工合成，变成一种新型肥料。这种发明的配制方法，首先将螯合载体三聚磷酸钠放入搪玻璃K型反应罐，加入自来水，再将氯化钙放入反应罐，在产生热量的同时使罐内物质充分溶解，再放入硫酸钾、硫酸亚铁、硫酸锰、硫酸锌、硫酸铜、硫酸镁、硼砂、磷酸一铵的均匀混合物，充分络合后，经蛇形管引入，WG型离心机，进行离心分离，卸料后将湿料再送入回转干燥器干燥后即为成品。
本发明肥料的投料比为(质量百分比)
1、螯合载体三聚酸钠(8～12)％
2、硫酸锰(7～12)％
3、硫酸亚铁(7～12)％
4、硫酸锌(7～12)％
5、氯化钙(12～17)％
6、硫酸镁(12～17)％
7、硼砂(7～12)％
8、硫酸钾(7～12)％
9、磷酸一铵(7～12)％
10、硫酸铜(3～7)％
注自来水的用量为肥料所有投料总重的5倍。
上述肥料就是利用三聚磷酸钠或六聚磷酸钠的络合作用，将无机盐中的金属离子组成一个网状有机整体，在作物有吸收能力的时候，迅速从网状整体上获取自己所需营养成分，不能被吸收的仍被螯合载体所络合，螯合物络合力能使它足以很长时间的保持稳定，以达到长效性。
这种肥料易于保存，溶解速度快，既适合作基肥，又可做为最好的追肥肥料，包括冲施、叶面喷施，无污染、无毒，特别是速效、长效、养分全的特点，使它足可以被农民欢迎，大量使用，它可以与任何酸性和中性的其他农药、植物生长调节剂、除草剂、肥料混合使用，且有增效作用。
实施例：
首先将三聚磷酸钠或六聚磷酸钠50Kg放入搪玻璃K型反应罐，加入250Kg自来水，启动反应罐浆轮，使混合物尽量溶解，同时放入7.5Kg无水氯化钙，搅动5～10分钟，将已被粉碎成粉状的硫酸锰、硫酸亚铁、硼砂、硫酸锌、硫酸镁、硫酸钾、磷酸一铵各4.5Kg放入反应罐，不断搅动再加入粉碎后的硫酸铜2.5Kg放入反应罐，不断搅动，持续一段时间后，调节酸碱度，调至PH值4.5～5.0之间，即可将螯合物送入WG型离心机，经离心分离，将半成品送入回转干燥器干燥，干燥后即成成品。
采用这种方法生产的肥料，突出表现在长效、速效、养分全，原料充足，易于生产，成本低，质量稳定，方便、安全贮存和运输，特别是市场需求量大，市场发展潜力广阔，便于推广应用，深受欢迎和支持。
Claims (3)
1、螯合型施肥素及其配制方法，用螯合载体三聚磷酸钠或六聚磷酸钠加硫酸钾、硫酸亚铁、硫酸锰、硫酸铜、无水氯化钙、硫酸锌、硫酸镁、硼砂、磷酸一铵加工合成，变成一种新型肥料，其特征在于配方中加入了三聚磷酸钠8～12％。
2、根据权利要求1所述的螯合型施肥素及其配制方法，其特征在于配方中加入了无水氯化钙12～17％。
3、根据权利要求1所述的螯合型施肥素及其配制方法，其特征在于配方中加入了硫酸镁12～17％。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99112233 CN1274706A (zh) | 1999-05-19 | 1999-05-19 | 螯合型施肥素及其配制方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99112233 CN1274706A (zh) | 1999-05-19 | 1999-05-19 | 螯合型施肥素及其配制方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1274706A true CN1274706A (zh) | 2000-11-29 |
Family
ID=5275559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99112233 Pending CN1274706A (zh) | 1999-05-19 | 1999-05-19 | 螯合型施肥素及其配制方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1274706A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014056688A1 (fr) | 2012-10-10 | 2014-04-17 | Prayon | Composition nutritive a base de fer |
-
1999
- 1999-05-19 CN CN 99112233 patent/CN1274706A/zh active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014056688A1 (fr) | 2012-10-10 | 2014-04-17 | Prayon | Composition nutritive a base de fer |
| BE1021212B1 (fr) * | 2012-10-10 | 2015-08-11 | Prayon | Composition nutritive |
| EP3009005A1 (fr) | 2012-10-10 | 2016-04-20 | Prayon | Composition nutritive à base de fer |
| US9902658B2 (en) | 2012-10-10 | 2018-02-27 | Prayon | Iron-based nutritive composition |
| US20180118630A1 (en) * | 2012-10-10 | 2018-05-03 | Prayon | Iron-based nutritive composition |
| EA031880B1 (ru) * | 2012-10-10 | 2019-03-29 | Прейон | Состав водорастворимой твердой неорганической питательной композиции на основе железа, способ ее получения и ее применение |
| US10577288B2 (en) | 2012-10-10 | 2020-03-03 | Prayon | Iron-based nutritive composition |
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