CN1328817A - 固体油包水型乳剂化妆品组合物 - Google Patents
固体油包水型乳剂化妆品组合物 Download PDFInfo
- Publication number
- CN1328817A CN1328817A CN01122178A CN01122178A CN1328817A CN 1328817 A CN1328817 A CN 1328817A CN 01122178 A CN01122178 A CN 01122178A CN 01122178 A CN01122178 A CN 01122178A CN 1328817 A CN1328817 A CN 1328817A
- Authority
- CN
- China
- Prior art keywords
- composition
- cometics
- oil
- water
- oil emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 239000007787 solid Substances 0.000 title claims abstract description 27
- 239000007762 w/o emulsion Substances 0.000 title claims description 23
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 26
- 229940119170 jojoba wax Drugs 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- -1 polysiloxanes Polymers 0.000 claims description 48
- 238000012986 modification Methods 0.000 claims description 17
- 230000004048 modification Effects 0.000 claims description 17
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 claims description 6
- 229960005215 dichloroacetic acid Drugs 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000002537 cosmetic Substances 0.000 abstract description 16
- 206010016322 Feeling abnormal Diseases 0.000 abstract description 5
- 239000000839 emulsion Substances 0.000 abstract description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 27
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
- 239000000194 fatty acid Substances 0.000 description 16
- 229930195729 fatty acid Natural products 0.000 description 16
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 12
- 239000001993 wax Substances 0.000 description 11
- 239000000049 pigment Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 230000035807 sensation Effects 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 7
- 238000005342 ion exchange Methods 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 235000013599 spices Nutrition 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 230000002421 anti-septic effect Effects 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000001835 salubrious effect Effects 0.000 description 5
- 235000015424 sodium Nutrition 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- 241001597008 Nomeidae Species 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 229940024606 amino acid Drugs 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- QLSANCGSHSPSDS-FJSYBICCSA-N (2s)-2-(octadecanoylamino)pentanedioic acid;sodium Chemical compound [Na].[Na].CCCCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O QLSANCGSHSPSDS-FJSYBICCSA-N 0.000 description 1
- WCDDVEOXEIYWFB-VXORFPGASA-N (2s,3s,4r,5r,6r)-3-[(2s,3r,5s,6r)-3-acetamido-5-hydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,5,6-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@@H]1C[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](C(O)=O)O[C@@H](O)[C@H](O)[C@H]1O WCDDVEOXEIYWFB-VXORFPGASA-N 0.000 description 1
- XIIAYQZJNBULGD-UHFFFAOYSA-N (5alpha)-cholestane Natural products C1CC2CCCCC2(C)C2C1C1CCC(C(C)CCCC(C)C)C1(C)CC2 XIIAYQZJNBULGD-UHFFFAOYSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- IFBDFMPSOCGRKA-UHFFFAOYSA-N 1-octadecoxyoctadecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC IFBDFMPSOCGRKA-UHFFFAOYSA-N 0.000 description 1
- QQXJNLYVPPBERR-UHFFFAOYSA-N 1-phenyldecan-1-one Chemical compound CCCCCCCCCC(=O)C1=CC=CC=C1 QQXJNLYVPPBERR-UHFFFAOYSA-N 0.000 description 1
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 1
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- DHHFDKNIEVKVKS-FMOSSLLZSA-N Betanin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)O)=CC(C[C@H]2C([O-])=O)=C1[N+]2=C\C=C\1C=C(C(O)=O)N[C@H](C(O)=O)C/1 DHHFDKNIEVKVKS-FMOSSLLZSA-N 0.000 description 1
- DHHFDKNIEVKVKS-MVUYWVKGSA-N Betanin Natural products O=C(O)[C@@H]1NC(C(=O)O)=C/C(=C\C=[N+]/2\[C@@H](C(=O)[O-])Cc3c\2cc(O)c(O[C@H]2[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O2)c3)/C1 DHHFDKNIEVKVKS-MVUYWVKGSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 206010009691 Clubbing Diseases 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 241000221095 Simmondsia Species 0.000 description 1
- 235000004433 Simmondsia californica Nutrition 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 229920002359 Tetronic® Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- BLJNPOIVYYWHMA-UHFFFAOYSA-N alumane;cobalt Chemical compound [AlH3].[Co] BLJNPOIVYYWHMA-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000001654 beetroot red Substances 0.000 description 1
- 235000012677 beetroot red Nutrition 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- 229960001950 benzethonium chloride Drugs 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 235000002185 betanin Nutrition 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000007766 cera flava Substances 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- XIIAYQZJNBULGD-LDHZKLTISA-N cholestane Chemical compound C1CC2CCCC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 XIIAYQZJNBULGD-LDHZKLTISA-N 0.000 description 1
- KXKPYJOVDUMHGS-OSRGNVMNSA-N chondroitin sulfate Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](OS(O)(=O)=O)[C@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](C(O)=O)O1 KXKPYJOVDUMHGS-OSRGNVMNSA-N 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- LXMQZGGLHVSEBA-UHFFFAOYSA-N chromium;trihydrate Chemical compound O.O.O.[Cr] LXMQZGGLHVSEBA-UHFFFAOYSA-N 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 229940071160 cocoate Drugs 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 229940049906 glutamate Drugs 0.000 description 1
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 229940014041 hyaluronate Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- QGKLPGKXAVVPOJ-UHFFFAOYSA-N pyrrolidin-3-one Chemical compound O=C1CCNC1 QGKLPGKXAVVPOJ-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229940080237 sodium caseinate Drugs 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
一种具有良好稳定性的棒状固体油包水型乳剂化妆品组合物,涂敷于皮肤上时有一种清新和用后清爽、尤其是柔软的感觉,其含有(a)0.5－40.0wt%的氢化霍霍巴油、(b)0.1－10.0wt%的表面活性剂,由聚氧化烯改性的聚硅氧烷或烷基－和聚氧化烯改性的聚硅氧烷组成,和(c)5.0－50.0wt%的水。
Description
本发明涉及棒状固体油包水型乳剂化妆品组合物。具体地说，本发明涉及一种具有优异稳定性、涂敷于皮肤上时，尽管呈固体形式，仍具有一种清新和用后清爽感觉且尤其是在涂敷时可提供柔软感的新型棒状固体油包水型乳剂化妆品组合物。
近年来，市场上已出现了具有良好稳定性的固体油包水型乳剂化妆品组合物。特别是这种类型的化妆品组合物给出了乳剂型处理，即使是固体形式，且因此其对皮肤的效果也较高。另外，由于加入了水，使用后可获得如清新和湿润的新感觉。
然而，大多数情况下，主要采用具有高固化能力的烃基蜡作为主要固化成分的固体润滑油，这不能满足所谓的“皮肤的柔软感”。
本发明的一个目的是提供新颖的棒状固体油包水型乳剂化妆品组合物，所述组合物可解决现有技术中存在的上述问题，并能在涂敷于皮肤上时有一种清新和用后清爽感觉、尤其是柔软感。
本发明将提供一种含有下述(a)-(c)组分的棒状固体油包水型乳剂化妆品组合物：
(a)0.5-40.0wt％的氢化霍霍巴油；
(b)0.1-10.0wt％的表面活性剂，由聚氧化烯改性的聚硅氧烷或烷基-和聚氧化烯改性的聚硅氧烷组成；和
(c)5.0-50.0wt％的水。
下面将对本发明详细说明。除非另有说明，说明书和权利要求书中的单数形式的不定冠词“a”、“an”和定冠词“the”均包括复数。
为解决存在的问题，本发明人进行了深入的研究，结果发现：本发明含有氢化霍霍巴油作为固体润滑油的棒状固体油包水型乳剂化妆品组合物可解决上述问题，由此完成了本发明。
由于所采用的蜡具有适当低的熔点，本发明棒状固体油包水型乳剂化妆品组合物在皮肤上易于融化，并且由于涂敷时的屈服值较小而能光滑地涂敷在皮肤上。另外，由于是乳剂基质，可以掺入保湿成分而且可用于冬天时粗糙的皮肤。
本发明的棒状固体油包水型乳剂化妆品组合物是指装入棒状容器中的组合物，该化妆品组合物一般呈固态，也包括糊状，在如0-50℃下使用时不流动。在棒状油包水型乳剂化妆品组合物中，优选可以在使用时释放出其内含物的组合物。本发明中所用的“棒状容器”典型地为柱状或圆柱或椭圆柱，直径为5-40mm、尤其对粉底优选8-25mm，高3-15cm、从实用性考虑对粉底而言高度为7cm或更高。
本发明采用的氢化霍霍巴油主要为一种通过氢化霍霍巴油得到的化合物，所述霍霍巴油主要由一价高级不饱和脂肪酸和一价高级不饱和醇的酯组成，该酯具有下述化学结构：其中m为16、18或20，n为18、20或22，总碳数为38-44。用作示例的市售产品是，例如：部分氢化的霍霍巴油如Floraesters20、Floraesters30和Floraesters60(均由Floratech制造)和Jobacream M-40(由KoeiKogyosha制造)完全氢化的霍霍巴油如Floraesters70和Floraesters70HG(均由Floratech制造)以及极度氢化的霍霍巴(Extreme HydrogenatedJojoba)(由Koei Kosansha制造)等。优选不饱和键均被氢化的完全氢化霍霍巴油。
在整个化妆品组合物中氢化霍霍巴油的用量为0.5-40wt％、特别优选2.0-20.0wt％。
可用下述式(I)表示聚氧化烯改性的聚硅氧烷或烷基-和聚氧化烯改性的聚硅氧烷：其中a为1-5的整数，b为7-100的整数，c为0-100的整数，m为10-500的整数，n为0-150的整数， o为1-50的整数，R1为C1-C26烷基，R2为H或C1-C5烷基。
使用聚氧化烯改性的聚硅氧烷以及烷基-和聚氧化烯改性的聚硅氧烷的理由为，例如：易于填充到容器中，尤其是高温性能，适用性，特别是没有粘腻感，制得的乳剂稳定。
本发明化妆品组合物中表面活性剂的用量取决于乳化含水相的量，优选占化妆品组合物总重量的0.1-10.0wt％，更优选1.0-8.0wt％。
本发明化妆品组合物中水的量占总化妆品组合物重量的5.0-50.0％，优选10.0-25.0wt％。若水量少于5.0wt％，使用时不能产生清新的感觉。具体地讲，要在使用时获得非常高的清新感觉，优选水量至少占总化妆品组合物重量的10.0％。而且，水的含量越高，润滑的倾向就越大。因此，优选水的含量不超过25.0wt％。
在本发明中，蜡组分除了氢化霍霍巴油外还优选包含烃蜡。烃蜡的例子是地蜡、石蜡、微晶蜡、Fisher-Tropsh蜡、SASOL蜡等。这些蜡中，从填充到容器中固化的均匀角度优选地蜡。例如，在只含聚氧乙烯蜡的情况下由于相对高的熔点，填充性能不如人意。
氢化霍霍巴油对烃蜡的比率(重量比)为烃蜡/氢化霍霍巴油＝0.05-15，优选0.1-7.5。其中，优选烃蜡的含量不超过15wt％。并且，优选化妆品组合物总重量中蜡组分的量为3-22wt％。如果氢化霍霍巴油与烃蜡联用，稳定性会更高。
优选本发明固体油包水型乳剂化妆品组合物的硬度为4-70(通过卡式张力仪测定，37℃，负重200g和1.5φ)。尤其是从皮肤感觉的角度，7-40的硬度为最佳。
此外，在本发明中，除了氢化霍霍巴油、表面活性剂和水等上述提到的必要组分外，还可选用颜料粉末。在这种情况下，只要求颜料粉末可常规用于化妆品组合物而无其它特别限定。可选用的颜料粉末为无机颜料、有机颜料或金属颜料。无机颜料粉末的例子是滑石、高岭土、碳酸钙、锌白、二氧化钛、三氧化二铁、氧化铁黄、氧化铁黑、佛青、钛包衣云母、氯氧化铋、Bengara、烧结颜料、Gunjo Pink、氢氧化铬、氧化钛包衣云母、氧化铬、氧化铝钴、普鲁士蓝、碳黑、无水硅酸、硅酸镁、膨润土、云母、氧化锆、氧化镁、氧化锌、氧化钛、轻质碳酸钙、重质碳酸钙、轻质碳酸镁、重质碳酸镁、水锌矿等。其中，尤其优选经处理成具有疏水性的颜料粉末。疏水性处理的方法可以包括用高粘度聚硅氧烷进行表面处理，用有机硅树脂与烷基氢聚硅氧烷反应进行表面涂层，然后用链烯烃处理，用一种或几种阳离子活性剂、阴离子活性剂和非离子活性剂处理，用蜡进行表面包衣等。应使表面呈疏水性。其方法没有特别限制。另外，优选颜料粉末的用量不超过化妆品组合物总重的50％。
此外，只要不影响本发明的效果，本发明的棒状固态油包水型乳剂组合物可以包含化妆品组合物常用的成分。例如，可将化妆品组合物常用的其它表面活性剂和上述的表面活性剂一起使用，可不考虑其离子性质。
阴离子表面活性剂的实例是：肥皂原材料；脂肪酸皂如月桂酸钠；高级烷基硫酸酯盐如十二烷基硫酸钠；烷基醚硫酸酯盐如聚氧乙烯(即“POE”)十二烷基硫酸盐三乙醇胺；N-酰基肌氨酸如月桂酰肌氨酸钠；高级脂肪酸酰胺磺酸盐如N-椰油基-N-甲基牛磺酸钠；磷酸酯盐如POE硬脂基醚磷酸盐；磺基丁二酸酯如磺基丁二酸二-2-乙基己基酯钠；烷基苯磺酸盐如十二烷基苯磺酸钠；N-酰基谷氨酸盐如N-硬脂酰谷氨酸二钠；高级脂肪酸酯硫酸酯盐如氢化椰油酸甘油基酯(cocoate)硫酸钠；硫酸化油如土耳其红油；POE烷基醚羧酸；POE烷基芳基醚羧酸盐；α-烯烃硫酸盐；高级脂肪酸酯磺酸盐；仲醇硫酸酯盐；高级脂肪酸烷醇酰胺硫酸酯盐；月桂酰单乙醇酰胺琥珀酸钠；N-棕榈酰基天冬酰胺盐双三乙醇胺；酪蛋白酸钠。
阳离子表面活性剂的实例是：烷基三甲基铵盐如硬脂基三甲基氯化铵；二烷基二甲基铵盐如二硬脂基二甲基氯化铵；烷基吡啶鎓盐如十六烷基氯化吡啶鎓；烷基季铵盐、烷基二甲基苄基铵盐、烷基异喹啉鎓盐；二烷基吗啉鎓盐(morphonium)；POE烷基胺；烷基胺盐；多元胺脂肪酸衍生物；戊基醇脂肪酸衍生物；苯扎氯铵；苯索氯铵等。
两性表面活性剂的实例是：咪唑啉类两性表面活性剂如2-十一烷基-N，N，N-(羟乙基羧基甲基)-2-咪唑啉钠；甜菜碱类表面活性剂如月桂基二甲基-氨基乙酸甜菜碱。
非离子亲液表面活性剂的实例是：脱水山梨糖醇脂肪酸酯如脱水山梨糖醇单异硬脂酸酯和脱水山梨糖醇倍半油酸酯；甘油基聚甘油脂肪酸酯如单硬脂酸甘油基酯；丙二醇脂肪酸酯如丙二醇单硬脂酸酯；氢化蓖麻油衍生物；甘油基烷基醚；聚氧化烯改性的聚硅氧烷或烷基-和聚氧化烯改性的聚硅氧烷等。
非离子亲水表面活性剂的实例是：POE脱水山梨醇脂肪酸酯如POE脱水山梨醇单油酸酯；POE山梨糖醇脂肪酸酯如POE脱水山梨醇单油酸酯；POE甘油基脂肪酸酯如POE甘油基单异硬脂酸酯；POE烷基醚如POE硬脂基醚和POE胆甾烷醇醚；POE烷基苯基醚如POE壬基苯基醚；pluaronics如普卢诺尼克；POE-POP烷基醚如POE·聚氧丙烯(即“POP”)十六烷基醚，四-POE·四-POP乙二胺缩合产物如Tetronic；POE蓖麻油，POE蓖麻油氢化蓖麻油衍生物如POE氢化蓖麻油POE蜂蜡羊毛脂衍生物；烷醇酰胺；POE丙二醇脂肪酸酯；POE烷基胺；POE脂肪酸酰胺；蔗糖脂肪酸酯；POE壬基苯基甲醛缩合产物；烷基乙氧基二甲基胺氧化物；三油酰基磷酸等。但是，请注意本发明不仅限于使用上述的表面活性剂。
此外，这些表面活性剂可以单独或任意联合应用于本发明的棒状固体油包水型乳剂化妆品组合物中。
本发明固体油包水型乳剂化妆品组合物可选用的其它成分包括：水相成分、多羟基醇、粘糖类(透明质酸钠等)、有机酸和有机盐(氨基酸、氨基酸盐、羟基酸盐)和其它保温剂，醇如乙醇，油相成分如凡士林，固态和半固态油如羊毛脂、聚硅氧烷蜡、氟代蜡、有机硅树脂、硅橡胶、高级脂肪酸、高级醇；液态油如角鲨烯、液体石蜡、酯油、甘油三酯、挥发性烃油、碳氟化合物、药物如维生素E、维生素E醋酸酯、收敛剂、抗氧剂、防腐剂、香料、磷酸钠(II)和其它pH调节剂、粘土矿物质、增稠剂、UV遮蔽剂等。
本发明的棒状固体油包水型乳剂化妆品组合物可用手指或垫片(puff)涂敷于皮肤，或直接用棒剂抹在皮肤上。该棒状固体油包水型乳剂化妆品组合物较至今为止可能的化妆品具有更好的肌肤感觉。
实施例
将在下列实施例中对本发明作更详细的说明，但不作任何限定，除非另外注明，否则所有量均为重量百分比。
实施例1-3和比较实施例1-3
按下表I所示处方配制棒状油包水型乳剂化妆品组合物，并且通过上文所述方法评估其可用性和硬度，结果见表II。
1)可用性的评估
棒状油包水型乳剂化妆品组合物的样品评估小组由20人组成，将棒状容器中的棒状油包水型乳剂化妆品组合物直接涂敷于皮肤上，评估使用的感受(例如肌肤柔软度、清新感、用后清爽感、润滑的光泽度)。评估标准G(好)：至少15人反应为“好”F(一般)：7-14人反应为“好”P(差)：不超过6人反应为“好”
2)硬度
用卡式张力仪在37℃、负重200g和1.5φ条件下测量硬度。
表I
| 实施例 | 比较实施例 | |||||
| 1 | 2 | 3 | 1 | 2 | 3 | |
| 十甲基环五硅氧烷聚氧化烯改性的有机聚硅氧烷*1含长链烷基的聚氧化烯改性的有机聚硅氧烷*2地蜡氢化霍霍巴油*3微晶蜡巴西棕榈蜡聚硅氧烷处理的滑石粉聚硅氧烷处理的二氧化钛聚硅氧烷处理的氧化铁(黄)聚硅氧烷处理的氧化铁(红)聚硅氧烷处理的氧化铁(黑)聚甲基丙烯酸甲酯离子交换水二丙二醇防腐剂香料 | 26.05.0-2.08.0--16.010.02.91.00.14.020.05.0适量适量 | 26.0-5.0-7.01.02.016.010.02.91.00.14.020.05.0适量适量 | 21.05.0-5.05.0--16.010.02.91.00.14.030.0-适量适量 | 26.05.0-10.0---16.010.02.91.00.14.020.05.0适量适量 | 26.0-5.05.0-5.0-16.010.02.91.00.14.020.05.0适量适量 | 51.05.0-8.0--2.016.010.02.91.00.14.0--适量适量 |
*1：具有上述通式(I)的化合物，其中a＝3，b＝8-10，c＝0，m＝50-60，n＝0，o＝2-5，R2＝H，分子量＝约6000，聚醚改性率＝约20wt％。
*2：具有上述通式(I)的化合物，其中a＝3，b＝50，c＝60，m＝100，n＝50，o＝15，R1＝C16H33，R2＝H，分子量＝约15000。
*3：Floraester70(Floratech制造)
表II
| 实施例 | 比较实施例 | |||||
| 1 | 2 | 3 | 1 | 2 | 3 | |
| 皮肤柔软感清新感用后清爽感光滑硬度 | GGGG18 | GGGG25 | GGGF20 | PGGG15 | PGPG8 | PPGG28 |
下列实施例的生产方法是将油相成分加热到80℃以使其熔融，然后将粉末分散其中，乳化并且分散预先加热的水相成分，将所得混合物在流体状态填充到容器中。接着，冷却而获得所需产品。在所有的例子中，产品的稳定性良好，具有清新感觉，肌肤的光滑度极佳。分子量＝约6000，聚醚改性率＝约20wt％疏水处理的颜料粉末 20.0离子交换水 10.0甘油基 15.01，3-丁二醇 2.0防腐剂 适量香料 适量
实施例4：棒状乳剂粉底
十甲基环五硅氧烷 35.0wt％
聚氧化烯改性的有机聚硅氧烷(具有上述通式(I) 2.0
中的化合物，其中a＝3，b＝50，c＝60，m＝100，
n＝50，o＝15，R1＝C16H33，R2＝H，分子量＝约15000)
脱水山梨醇倍半异硬脂酸酯 2.0地蜡 2.0氢化霍霍巴油 7.0疏水处理的颜料粉末 15.0聚丙烯酸烷基酯 12.0二丙二醇 5.0离子交换水 20.0防腐剂 适量抗氧剂 适量
实施例5：含尿素的固态化妆品组合物三甲基甲硅烷氧基硅酸盐 3.0wt％二甲基聚硅氧烷 10.0十甲基环五硅氧烷 20.0氢化霍霍巴油 8.0地蜡 2.0聚氧化烯改性的有机聚硅氧烷(具有上述通式(I)中的 2.0化合物，其中a＝3，b＝24，c＝24，m＝400，n＝0，o＝10，R2＝H，分子量＝约55000)离子交换水 46.0尿素 3.0甘油基 3.0双甘油基 2.0丙二醇 1.0防腐剂 适量
实施例6：口红二甲基聚硅氧烷(1.5厘沲) 20.0wt％十甲基环五硅氧烷 10.0异辛酸十六烷基酯 15.0聚氧化烯改性的有机聚硅氧烷(具有上述通式(I)的 3.0化合物，其中a＝3，b＝8-10，c＝0，m＝50-60，n＝0，o＝2-5，R2＝H，分子量＝约6000，聚醚改性率＝约20wt％)氢化霍霍巴油 10.0烃蜡 2.0香料 适量疏水处理的颜料粉末 30.0离子交换水 6.9透明质酸钠 0.1硫酸软骨素钠 1.5聚乙二醇 1.5防腐剂 适量
实施例7：唇膏八甲基环四硅氧烷 10.0wt％二甲基聚硅氧烷(6厘沲) 23.0巴西棕榈蜡 2.8氢化霍霍巴油 8.0聚氧化烯改性的有机聚硅氧烷(具有上述通式(I)的 5.0化合物，其中a＝3，b＝50，c＝60，m＝100，n＝50，o＝15，R1＝C16H33，R2＝H，分子量＝约15,000)氧化铁红 0.3氧化铁黄 1.0色淀红CBA(红No.204) 0.7二丁基羟基甲苯 适量香料 适量离子交换水 48.4水溶性胶原溶液 0.3吡咯烷酮羧酸钠 0.5
实施例8：唇部处理角鲨烷 10.0wt％羊毛脂 2.0八甲基环四硅氧烷 27.69
异链烷烃(沸点1553) 10.0
三甲基甲硅烷氧基硅酸盐 3.0
氢化霍霍巴油 8.0
聚氧化烯改性的有机硅氧烷(具有上述通式(I)的化 3.0
合物，其中a＝3，b＝24，c＝24，m＝400，n＝0，
o＝10，R2＝H，分子量＝约55000)
离子交换水 30.0
甘油基 5.0
乳酸钠 0.3
L-谷氨酸钠 0.3
透明质酸钠 0.1
山梨醇 0.5
立索玉红BCA(红No.202) 0.01
薄荷醇 0.1
香料 适量
如上所述，本发明的棒状固体油包水型乳剂化妆品组合物具有良好的稳定性，当涂抹于皮肤上时，尽管是固体形式但仍感觉清新和清爽，特别是给予肌肤柔软的感觉。
Claims (3)
1.棒状固体油包水型乳剂化妆品组合物，含有下述(a)-(c)组分：
(a)0.5-40.0wt％的氢化霍霍巴油；
(b)0.1-10.0wt％的表面活性剂，由至少一种式(I)的聚氧化烯改性的聚硅氧烷或烷基-和聚氧化烯改性的聚硅氧烷组成：
其中a为1-5的整数，b为7-100的整数，c为0-100的整数，m为10-500的整数，n为0-150的整数，o为1-50的整数，R1为C1-C26烷基，R2为H或C1-C5烷基；和
(c)5.0-50.0wt％的水。
2.如权利要求1的棒状固体油包水型乳剂化妆品组合物，还包括一种烃蜡，其中烃蜡与氢化霍霍巴油的重量比为0.05-15。
3.如权利要求2的棒状固体油包水型乳剂化妆品组合物，其中烃蜡为地蜡。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000161867 | 2000-05-31 | ||
| JP161867/2000 | 2000-05-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1328817A true CN1328817A (zh) | 2002-01-02 |
| CN1232243C CN1232243C (zh) | 2005-12-21 |
Family
ID=18665821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB01122178XA Expired - Fee Related CN1232243C (zh) | 2000-05-31 | 2001-05-31 | 固体油包水型乳剂化妆品组合物 |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US20020009471A1 (zh) |
| EP (1) | EP1159954A3 (zh) |
| KR (1) | KR20010110123A (zh) |
| CN (1) | CN1232243C (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332647C (zh) * | 2002-08-31 | 2007-08-22 | 狮王-狮达比罗化妆品股份有限公司 | 含脂质制品的化妆品 |
| EP2123257A2 (en) | 2008-05-20 | 2009-11-25 | Evonik Goldschmidt GmbH | Stable high Vitamin C content polyol-in-oil emulsified system and its preparation |
| EP2135597A1 (en) | 2008-06-20 | 2009-12-23 | Evonik Goldschmidt GmbH | A high water content lip stick and its preparation |
| CN106456510A (zh) * | 2014-05-14 | 2017-02-22 | 株式会社资生堂 | 补水保湿用棒状化妆品 |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030207971A1 (en) * | 2001-11-27 | 2003-11-06 | React Of Delafield Llc | Emollient gel |
| DE10300506A1 (de) * | 2003-01-08 | 2004-07-22 | Cognis Deutschland Gmbh & Co. Kg | Wachsdispersionen |
| US20040166083A1 (en) * | 2003-02-26 | 2004-08-26 | The Andrew Jergens Company | Personal care water-in-oil emulsion products |
| US20040175347A1 (en) * | 2003-03-04 | 2004-09-09 | The Procter & Gamble Company | Regulation of mammalian keratinous tissue using hexamidine compositions |
| US20040265346A1 (en) * | 2003-04-28 | 2004-12-30 | Aurore Verloo | Water-in-oil emulsions for use in cosmetics |
| US8246970B2 (en) * | 2003-04-30 | 2012-08-21 | L'oreal | Water-in-oil solid emulsion-type cosmetic compositions |
| US20060013792A1 (en) * | 2004-07-16 | 2006-01-19 | Jacqueline Fontaine | Solid water-in-oil cosmetic emulsion |
| US20060013793A1 (en) * | 2004-07-16 | 2006-01-19 | Agnes Themens | Solid water-in-oil cosmetic emulsion |
| FR2873019B1 (fr) * | 2004-07-16 | 2008-02-15 | Oreal | Emulsion cosmetique eau-dans-huile solide |
| US20070128137A1 (en) * | 2005-12-02 | 2007-06-07 | Naohisa Yoshimi | Water in oil emulsion compositions containing siloxane elastomers |
| US7674781B2 (en) * | 2006-04-28 | 2010-03-09 | Heather Sheardown | Hyaluronic acid-retaining polymers |
| US20070274932A1 (en) * | 2006-05-15 | 2007-11-29 | The Procter & Gamble Company | Water in oil emulsion compositions containing sunscreen actives and siloxane elastomers |
| US20070264210A1 (en) * | 2006-05-15 | 2007-11-15 | The Procter & Gamble Company | Method of enhancing penetration of water-soluble actives |
| US20080038360A1 (en) * | 2006-08-11 | 2008-02-14 | Joseph Michael Zukowski | Personal care composition |
| KR101054884B1 (ko) * | 2007-04-02 | 2011-08-05 | 주식회사 엘지생활건강 | 고형상의 자외선 차단 화장료 조성물 |
| US20090011035A1 (en) * | 2007-07-03 | 2009-01-08 | Joseph Michael Zukowski | Personal care composition |
| US8623386B2 (en) * | 2008-04-11 | 2014-01-07 | Kobo Products, Inc. | Natural ester, wax or oil treated pigment, process for production thereof, and cosmetic made therewith |
| NL1035426C2 (nl) * | 2008-05-15 | 2009-11-17 | Atp Marketing & Promotion Ag | Farmaceutische samenstellingen voor de behandeling van wratten. |
| GB0911488D0 (en) * | 2009-07-02 | 2009-08-12 | Dow Corning | Personal care emulsions comprising waxy materials and organopolysiloxanes |
| CA2968075A1 (en) | 2014-12-05 | 2016-06-09 | Western Michigan University Research Foundation | Colored special effect inks |
| US20210077378A1 (en) * | 2017-09-01 | 2021-03-18 | Shiseido Company, Ltd. | Water-in-oil type emulsion cosmetic |
| US20200138681A1 (en) * | 2018-11-06 | 2020-05-07 | L'oreal | Mineral sunscreen compositions |
| FR3144915A1 (fr) | 2023-01-18 | 2024-07-19 | ABC Texture | Composition galénique sous forme d’émulsion solide contenant pigments, particules solides et colorants. |
| WO2025127159A1 (en) * | 2023-12-15 | 2025-06-19 | L'oreal | Process for preparing w/o type cosmetic composition |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4360327A (en) * | 1980-04-23 | 1982-11-23 | Wang Liang Chih | Multipurpose, synchronous, three angle-cross compressor |
| US4532132A (en) * | 1983-04-11 | 1985-07-30 | Dow Corning Corporation | Skin care formulations comprising a water-in-mineral oil emulsion and siloxane compositions therefor |
| JP2691729B2 (ja) * | 1987-06-23 | 1997-12-17 | 株式会社資生堂 | 固型状油中水型乳化化粧料 |
| FR2740678B1 (fr) * | 1995-11-06 | 1999-05-14 | Oreal | Utilisation en cosmetique d'une composition solide ayant une matrice gelifiee et compositions cosmetiques ou dermatologiques mises en oeuvre |
| FR2776183B1 (fr) * | 1998-03-17 | 2004-05-28 | Oreal | Utilisation d'un tensio-actif silicone du type alkyldimethicone copolyol pour la preparation d'emulsions cosmetiques solides eau-dans-huile et emulsions solides eau-dans-huile ainsi obtenues |
| US6045783A (en) * | 1998-05-22 | 2000-04-04 | Coty B.V. | Cosmetic formulation with a swelling effect |
| US6042815A (en) * | 1998-10-21 | 2000-03-28 | Revlon Consumer Products Corporation | Water and oil emulsion solid cosmetic composition |
-
2001
- 2001-05-29 EP EP01401398A patent/EP1159954A3/en not_active Withdrawn
- 2001-05-30 KR KR1020010029926A patent/KR20010110123A/ko not_active Withdrawn
- 2001-05-31 CN CNB01122178XA patent/CN1232243C/zh not_active Expired - Fee Related
- 2001-05-31 US US09/867,441 patent/US20020009471A1/en not_active Abandoned
-
2002
- 2002-12-16 US US10/319,479 patent/US20030161801A1/en not_active Abandoned
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332647C (zh) * | 2002-08-31 | 2007-08-22 | 狮王-狮达比罗化妆品股份有限公司 | 含脂质制品的化妆品 |
| EP2123257A2 (en) | 2008-05-20 | 2009-11-25 | Evonik Goldschmidt GmbH | Stable high Vitamin C content polyol-in-oil emulsified system and its preparation |
| EP2135597A1 (en) | 2008-06-20 | 2009-12-23 | Evonik Goldschmidt GmbH | A high water content lip stick and its preparation |
| CN106456510A (zh) * | 2014-05-14 | 2017-02-22 | 株式会社资生堂 | 补水保湿用棒状化妆品 |
| CN106456510B (zh) * | 2014-05-14 | 2018-01-16 | 株式会社资生堂 | 补水保湿用棒状化妆品 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1159954A3 (en) | 2003-01-02 |
| CN1232243C (zh) | 2005-12-21 |
| EP1159954A2 (en) | 2001-12-05 |
| KR20010110123A (ko) | 2001-12-12 |
| US20030161801A1 (en) | 2003-08-28 |
| US20020009471A1 (en) | 2002-01-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1328817A (zh) | 固体油包水型乳剂化妆品组合物 | |
| CN102046142B (zh) | 水包油型皮肤外用剂 | |
| CN104546512B (zh) | 硅橡胶颗粒的水分散液、硅橡胶颗粒、以及化妆品 | |
| CN102470085B (zh) | 皮肤外用剂 | |
| KR101815024B1 (ko) | 수분 보급용 스틱형상 화장료 | |
| TW555567B (en) | External-use composition | |
| CN104095772A (zh) | 水包油型防晒化妆料 | |
| JPWO2001015658A1 (ja) | 化粧料 | |
| TW201141528A (en) | Silicone composite particle and method for manufacturing the same, and cosmetic material | |
| CN102712759A (zh) | 用于油类材料的增稠剂或胶凝剂、包含该增稠剂或胶凝剂的凝胶组合物及制备化妆品材料或局部剂的方法 | |
| CN109153790A (zh) | 有机硅颗粒、配伍有其的化妆品、涂料及树脂 | |
| CN102695758B (zh) | 包含苯基的有机聚硅氧烷组合物、粗制化妆品材料及有光泽的化妆品材料 | |
| CN104321044A (zh) | 用于施用于皮肤的包含倍半硅氧烷树脂蜡和固体颗粒的组合物 | |
| JP2010507671A (ja) | ポリアルキルシルセスキオキサン粉末エマルションを含んだ水系スキンケア組成物およびその作製方法 | |
| EP3327064A1 (en) | Cured silicone particles and cosmetic incorporating same therein | |
| RU2577305C2 (ru) | Косметическая композиция в виде эмульсии вода-в-масле | |
| CN1237407A (zh) | 含有醋己氨酸的护唇组合物及其应用 | |
| JP5339740B2 (ja) | スティック状の口唇用化粧料 | |
| JPH036182B2 (zh) | ||
| JP5774338B2 (ja) | 無機粒子内包型ポリオルガノシルセスキオキサン粒子の製造方法および該粒子を配合した化粧料 | |
| KR20220094711A (ko) | 오일 겔화제를 포함하는 수중유형 화장료 조성물 및 이의 제조방법 | |
| CN1678279A (zh) | 含水量高的防水睫毛膏组合物 | |
| JPH10245317A (ja) | 油中水型乳化組成物 | |
| JP2002053425A (ja) | 固型状油中水型乳化化粧料 | |
| KR101780709B1 (ko) | 수용성 실리콘 화합물을 함유하는 입술용 화장료 조성물 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20051221 Termination date: 20130531 |