DE2265612C2 - Verfahren zur Herstellung von wäßrigen Dispersionen von Polytetrafluoräthylen - Google Patents

Verfahren zur Herstellung von wäßrigen Dispersionen von Polytetrafluoräthylen

Info

Publication number: DE2265612C2
Authority: DE; Germany
Prior art keywords: polymerization; polytetrafluoroethylene; tetrafluoroethylene; preparation; stabilizer
Prior art date: 1971-01-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

DE19722265612

Other languages

German (de)

English (en)

Inventor

Edouard Oullins Grimaud

Claude Saint-Genis Laval Tournut

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Pechiney SA

Original Assignee

Pechiney Ugine Kuhlmann SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1971-01-28

Filing date

1972-01-26

Publication date

1983-01-13

1972-01-26 Application filed by Pechiney Ugine Kuhlmann SA filed Critical Pechiney Ugine Kuhlmann SA

1983-01-13 Application granted granted Critical

1983-01-13 Publication of DE2265612C2 publication Critical patent/DE2265612C2/de

Status Expired legal-status Critical Current

Links

239000006185 dispersion Substances 0.000 title claims description 20
238000000034 method Methods 0.000 title claims description 14
-1 polytetrafluoroethylene Polymers 0.000 title claims description 14
229920001343 polytetrafluoroethylene Polymers 0.000 title claims description 12
239000004810 polytetrafluoroethylene Substances 0.000 title claims description 12
238000006116 polymerization reaction Methods 0.000 claims description 20
239000003381 stabilizer Substances 0.000 claims description 18
229930195733 hydrocarbon Natural products 0.000 claims description 8
150000002430 hydrocarbons Chemical class 0.000 claims description 8
239000003995 emulsifying agent Substances 0.000 claims description 6
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 6
238000007720 emulsion polymerization reaction Methods 0.000 claims description 5
239000003513 alkali Substances 0.000 claims description 4
239000000203 mixture Substances 0.000 claims description 4
239000012736 aqueous medium Substances 0.000 claims description 3
239000003999 initiator Substances 0.000 claims description 3
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 2
239000003638 chemical reducing agent Substances 0.000 claims description 2
150000002978 peroxides Chemical class 0.000 claims description 2
239000000126 substance Substances 0.000 claims description 2
VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 claims 1
229910001870 ammonium persulfate Inorganic materials 0.000 claims 1
YMEPHRXFRJPMOW-UHFFFAOYSA-N chloro carbonofluoridate Chemical compound FC(=O)OCl YMEPHRXFRJPMOW-UHFFFAOYSA-N 0.000 claims 1
150000003839 salts Chemical class 0.000 claims 1
229920006395 saturated elastomer Polymers 0.000 claims 1
238000004519 manufacturing process Methods 0.000 description 7
239000004215 Carbon black (E152) Substances 0.000 description 5
125000004432 carbon atom Chemical group C* 0.000 description 3
230000015271 coagulation Effects 0.000 description 3
238000005345 coagulation Methods 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
239000000047 product Substances 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
239000004744 fabric Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000000178 monomer Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
229930195734 saturated hydrocarbon Natural products 0.000 description 2
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
238000003756 stirring Methods 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000004160 Ammonium persulphate Substances 0.000 description 1
239000004254 Ammonium phosphate Substances 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
235000019395 ammonium persulphate Nutrition 0.000 description 1
229910000148 ammonium phosphate Inorganic materials 0.000 description 1
235000019289 ammonium phosphates Nutrition 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 1
ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical class OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000011888 foil Substances 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
239000004922 lacquer Substances 0.000 description 1
238000011031 large-scale manufacturing process Methods 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
229910001961 silver nitrate Inorganic materials 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
230000001960 triggered effect Effects 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/26—Tetrafluoroethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Compositions Of Macromolecular Compounds (AREA)

DE19722265612 1971-01-28 1972-01-26 Verfahren zur Herstellung von wäßrigen Dispersionen von Polytetrafluoräthylen Expired DE2265612C2 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR7102800A FR2123703A5 (2)	1971-01-28	1971-01-28

Publications (1)

Publication Number	Publication Date
DE2265612C2 true DE2265612C2 (de)	1983-01-13

Family

ID=9071019

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
DE19722203465 Expired DE2203465C2 (de)	1971-01-28	1972-01-26	Verfahren zur Herstellung von wäßrigen Dispersionen von Polytetrafluoräthylen
DE19722265612 Expired DE2265612C2 (de)	1971-01-28	1972-01-26	Verfahren zur Herstellung von wäßrigen Dispersionen von Polytetrafluoräthylen

Family Applications Before (1)

Application Number	Title	Priority Date	Filing Date
DE19722203465 Expired DE2203465C2 (de)	1971-01-28	1972-01-26	Verfahren zur Herstellung von wäßrigen Dispersionen von Polytetrafluoräthylen

Country Status (8)

Country	Link
JP (1)	JPS5125076B1 (2)
BE (1)	BE777815A (2)
DE (2)	DE2203465C2 (2)
FR (1)	FR2123703A5 (2)
GB (1)	GB1372966A (2)
IT (1)	IT948939B (2)
LU (1)	LU64665A1 (2)
NL (1)	NL165473C (2)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU2002228671A1 (en) *	2000-11-30	2002-06-11	3M Innovative Properties Company	Explosion-free process for the production of polytetrafluoroethylene
US6911515B2 (en)	2001-03-23	2005-06-28	University Of Pennsylvania	Aqueous room temperature living radical polymerization of vinyl halides
US7345127B2 (en)	2001-03-23	2008-03-18	University Of Pennsylvania	Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom
WO2003002621A1 (en) *	2001-06-27	2003-01-09	University Of Pennsylvania	Radical polymerization of vinyl halide

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1178170A (en) *	1967-07-05	1970-01-21	Ici Ltd	Polymers of Tetrafluoroethylene

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3345317A (en) *	1963-04-04	1967-10-03	Thiokol Chemical Corp	Emulsion polymerization of tetrafluoroethylene using trifluorotrichloroethane as emulsion stabilizer

1971
- 1971-01-28 FR FR7102800A patent/FR2123703A5/fr not_active Expired
1972
- 1972-01-07 BE BE777815A patent/BE777815A/xx unknown
- 1972-01-26 DE DE19722203465 patent/DE2203465C2/de not_active Expired
- 1972-01-26 LU LU64665D patent/LU64665A1/xx unknown
- 1972-01-26 DE DE19722265612 patent/DE2265612C2/de not_active Expired
- 1972-01-26 IT IT6722872A patent/IT948939B/it active
- 1972-01-27 NL NL7201105A patent/NL165473C/xx not_active IP Right Cessation
- 1972-01-28 GB GB418572A patent/GB1372966A/en not_active Expired
- 1972-01-28 JP JP47009962A patent/JPS5125076B1/ja active Pending

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1178170A (en) *	1967-07-05	1970-01-21	Ici Ltd	Polymers of Tetrafluoroethylene

Also Published As

Publication number	Publication date
NL165473B (nl)	1980-11-17
NL165473C (nl)	1981-04-15
LU64665A1 (2)	1972-06-26
IT948939B (it)	1973-06-11
FR2123703A5 (2)	1972-09-15
BE777815A (fr)	1972-05-02
DE2203465C2 (de)	1983-02-10
NL7201105A (2)	1972-08-01
DE2203465A1 (de)	1972-09-28
GB1372966A (en)	1974-11-06
JPS5125076B1 (2)	1976-07-28

Legal Events

Date	Code	Title	Description
1980-05-29	OI	Miscellaneous see part 1
1980-06-12	OI	Miscellaneous see part 1
1980-09-18	OD	Request for examination
1983-01-13	AC	Divided out of	Ref country code: DE Ref document number: 2203465 Format of ref document f/p: P
1983-01-13	D2	Grant after examination
1983-07-07	8364	No opposition during term of opposition

Publication	Publication Date	Title
DE2757329C2 (de)	1980-02-07	Verfahren zur Herstellung von Polymerisaten der Acrylsäure oder Methacrylsäure
DE2542280C3 (de)	1980-04-30	Verfahren zur Polymerisation von Vinylidenfluorid
DE1030563B (de)	1958-05-22	Verfahren zur Herstellung von Trifluorchloraethylenpolymeren
DE1044410B (de)	1958-11-20	Verfahren zur Polymerisation und Mischpolymerisation von Perfluorolefinen
DE971364C (de)	1959-01-15	Verfahren zur Herstellung von kolloidalen Dispersionen durch Emulsionspolymerisation von Tetrafluoraethylen
DE2265612C2 (de)	1983-01-13	Verfahren zur Herstellung von wäßrigen Dispersionen von Polytetrafluoräthylen
DE2433486B2 (de)	1977-08-25	Verfahren zur herstellung von emulsionen, konzentrierten dispersionen und pasten von hydrophilen polymeren fuellstoffen in weichmachern
DE4232241A1 (de)	1993-04-01	Verfahren zur herstellung eines wasserloeslichen polymeren
DE1226790B (de)	1966-10-13	Verfahren zur Herstellung von Pfropfpolymerisaten auf Basis von Vinylchlorid
DE1520549A1 (de)	1969-05-22	Verfahren zur Herstellung von Pfropfpolymerisaten
DE2729628C2 (2)	1990-04-26
DE1152263B (de)	1963-08-01	Verfahren zur Herstellung von Polymerisaten oder Mischpolymerisaten des Acrylnitrils
DE2157170A1 (de)	1972-05-25	Polytetrafluoräthylenteilchen und Verfahren zu deren Herstellung
DE2315998A1 (de)	1973-12-13	Verfahren zur polymerisation oder copolymerisation von vinylchlorid
DE828595C (de)	1952-01-17	Verfahren zur Polymerisation fluor- und chlorhaltiger AEthylenderivate
DE862681C (de)	1953-01-12	Verfahren zur Herstellung chlorierter Polyaethylene
DE2748470C3 (de)	1980-06-04	Verfahren zur Herstellung von Vinylhalogenidpolymeren
DE928369C (de)	1955-05-31	Verfahren zur Herstellung von Polymerisaten
DE838065C (de)	1952-05-05	Verfahren zur Herstellung makromolekularer Verbindungen aus alpha-substituierten cycloaliphatischen Verbindungen und anderen polymerisierbaren Verbindungen, z. B. Dienen
DE852764C (de)	1952-10-20	Verfahren zur Polymerisation von AEthylenverbindungen
DE873745C (de)	1953-04-16	Verfahren zur Polymerisation von ungesaettigten, halogenhaltigen organischen Verbindungen in waessriger Emulsion
DE1620989A1 (de)	1970-07-09	Verfahren zur Polymerisation und Copolymerisation von Vinylfluorid
DE1063805B (de)	1959-08-20	Verfahren zur Herstellung von acetonloeslichen, perlfoermigen Mischpolymerisaten ausAcrylnitril und Vinylidenchlorid
DE1795705C3 (de)	1979-01-04	Verfahren zur Herstellung von hochmolekularen wasserlöslichen PoIyacrylainiden
DE2931102A1 (de)	1980-02-14	Verfahren zur herstellung von vinylhalogenidpolymeren oder -copolymeren