EP0200163A3 - Bleaching agent, its preparation and its use - Google Patents

Bleaching agent, its preparation and its use Download PDF

Info

Publication number
EP0200163A3
EP0200163A3 EP86105669A EP86105669A EP0200163A3 EP 0200163 A3 EP0200163 A3 EP 0200163A3 EP 86105669 A EP86105669 A EP 86105669A EP 86105669 A EP86105669 A EP 86105669A EP 0200163 A3 EP0200163 A3 EP 0200163A3
Authority
EP
European Patent Office
Prior art keywords
granulate
weight
bleaching agent
inorganic salt
peroxycarboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86105669A
Other languages
German (de)
Other versions
EP0200163B1 (en
EP0200163A2 (en
Inventor
Jochen Dr. Jacobs
Edgar Dr. Koppelmann
Martin Dr. Witthaus
Manfred Dr. Dankowski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6269591&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0200163(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AT86105669T priority Critical patent/ATE46916T1/en
Publication of EP0200163A2 publication Critical patent/EP0200163A2/en
Publication of EP0200163A3 publication Critical patent/EP0200163A3/en
Application granted granted Critical
Publication of EP0200163B1 publication Critical patent/EP0200163B1/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3945Organic per-compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Glanulating (AREA)
  • Cosmetics (AREA)

Abstract

1. A bleaching agent in the form of a granulate of uniform composition which contains an aliphatic C4 -C36 peroxycarboxylic acid solid at room temperature and hydratable inorganic salt, characterized in that it contains 3 to 50% by weight of the peroxycarboxylic acid, 40 to 95% by weight, based on the anhydrous form, of hydratable inorganic salt and 0.2 to 10% by weight of an organic polymer compound soluble in alkaline-aqueous medium as granulation aid, the granulate being free from microcrystalline cellulose where microfine starch is present, all the components are uniformly distributed in the individual grains of the granulate and the granulates alone, 0.5% in water, have a pH value in the range from 3 to 7.
EP86105669A 1985-05-02 1986-04-24 Bleaching agent, its preparation and its use Expired EP0200163B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86105669T ATE46916T1 (en) 1985-05-02 1986-04-24 BLEACHING INGREDIENT, ITS PRODUCTION AND USE.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3515712 1985-05-02
DE19853515712 DE3515712A1 (en) 1985-05-02 1985-05-02 FLEACH, ITS PRODUCTION AND USE

Publications (3)

Publication Number Publication Date
EP0200163A2 EP0200163A2 (en) 1986-11-05
EP0200163A3 true EP0200163A3 (en) 1987-09-16
EP0200163B1 EP0200163B1 (en) 1989-10-04

Family

ID=6269591

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86105669A Expired EP0200163B1 (en) 1985-05-02 1986-04-24 Bleaching agent, its preparation and its use

Country Status (6)

Country Link
US (1) US5091106A (en)
EP (1) EP0200163B1 (en)
JP (1) JPS61258072A (en)
AT (1) ATE46916T1 (en)
DE (2) DE3515712A1 (en)
ES (1) ES8704566A1 (en)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5093021A (en) * 1985-08-21 1992-03-03 The Clorox Company Encapsulated enzyme in dry bleach composition
ES2001074A6 (en) * 1985-08-21 1988-04-16 Clorox Co Dry peracid based bleaching product.
US5167854A (en) * 1985-08-21 1992-12-01 The Clorox Company Encapsulated enzyme in dry bleach composition
US5254287A (en) * 1985-08-21 1993-10-19 The Clorox Company Encapsulated enzyme in dry bleach composition
ATE72579T1 (en) * 1985-08-21 1992-02-15 Clorox Co STABLE PERSACID BLEACH.
US4863626A (en) * 1985-08-21 1989-09-05 The Clorox Company Encapsulated enzyme in dry bleach composition
GB8619953D0 (en) * 1986-08-15 1986-09-24 Unilever Plc Peroxyacid bleach composition
DE3644564A1 (en) * 1986-12-27 1988-07-07 Henkel Kgaa METHOD FOR THE PRODUCTION OF GIANT, STABLE PERSAEURE CONCENTRATES BY COMPACTING GRANULATION
GB8810630D0 (en) * 1988-05-05 1988-06-08 Unilever Plc Process for preparing bodies containing peroxyacid & compositions comprising said bodies
ES2055008T3 (en) * 1988-06-22 1994-08-16 Akzo Nv STABLE AND VERTIBLE AQUEOUS WHITENING COMPOSITIONS INCLUDING SOLID ORGANIC PEROXIACIDS AND AT LEAST TWO POLYMERS.
US5126066A (en) * 1988-06-22 1992-06-30 Akzo N.V. Stable, pourable aqueous bleaching compositions comprising solid organic peroxy acids and at least two polymers
US5358654A (en) * 1988-06-22 1994-10-25 Akzo Nobel N.V. Stable pourable aqueous bleaching compositions comprising solid organic peroxy acids and at least two polymers
DE3822798A1 (en) * 1988-07-06 1990-01-11 Huels Chemische Werke Ag METHOD FOR THE PRODUCTION OF PHLEGMATIZED ALIPHATIC DIPEROXIDICARBONE ACIDS
US4917811A (en) * 1988-09-20 1990-04-17 Lever Brothers Company Bleach compositions and process for making same
US5296156A (en) * 1988-11-25 1994-03-22 Akzo N.V. Bleaching granules
US5049298A (en) * 1988-11-25 1991-09-17 Akzo Nv Process for the preparation of bleaching granules
CA2015490A1 (en) * 1989-05-01 1990-11-01 Charles E. Kellner Agglomerated peroxyacid bleach granule and process for making same
GB8922179D0 (en) * 1989-10-02 1989-11-15 Rohm & Haas Polymer-containing granulates
US5279757A (en) * 1990-04-06 1994-01-18 Hoechst Aktiengesellschaft Stable peroxycarboxylic acid granule comprising an imidoperoxycarboxylic acid or salt thereof
US5055218A (en) * 1990-04-13 1991-10-08 The Procter & Gamble Company Bleach granules containing an amidoperoxyacid
DE4012769A1 (en) * 1990-04-21 1991-10-24 Hoechst Ag STABLE PEROXICARBONIC ACID GRANULES
TR25837A (en) * 1990-05-31 1993-09-01 Procter & Gamble  METHOD OF POWDERED PEROXIACID DEGREASER GRANULATED AND FOR THIS.
GB9016504D0 (en) * 1990-07-27 1990-09-12 Warwick Int Ltd Granular bleach activator compositions
SG54273A1 (en) * 1991-05-04 1998-11-16 Hoechst Ag Imidocarboxylic acid activators and sulfimidocarboxylic acid activators processes for their preparation and their use
US5234617A (en) * 1992-04-20 1993-08-10 Kathleen B. Hunter Aqueous liquid bleach compositions with fluorescent whitening agent and polyvinyl pyrrolidone or polyvinyl alcohol
EP0592033A1 (en) * 1992-10-07 1994-04-13 The Procter & Gamble Company Process for making peroxyacid containing particles
US5409632A (en) * 1992-11-16 1995-04-25 The Procter & Gamble Company Cleaning and bleaching composition with amidoperoxyacid
US5932532A (en) * 1993-10-14 1999-08-03 Procter & Gamble Company Bleach compositions comprising protease enzyme
AU3686895A (en) * 1994-09-26 1996-04-19 Fmc Corporation Stable peracid sols, gels and solids and a process therefor
US6017865A (en) * 1995-12-06 2000-01-25 The Procter & Gamble Company Perfume laundry detergent compositions which comprise a hydrophobic bleaching system
AU2075097A (en) * 1996-03-15 1997-10-01 Amway Corporation Discrete whitening agent particles, method of making, and powder detergent containing same
AU2074397A (en) * 1996-03-15 1997-10-01 Amway Corporation Powder detergent composition having improved solubility
US5714451A (en) * 1996-03-15 1998-02-03 Amway Corporation Powder detergent composition and method of making
US5714450A (en) * 1996-03-15 1998-02-03 Amway Corporation Detergent composition containing discrete whitening agent particles
US6177397B1 (en) 1997-03-10 2001-01-23 Amway Corporation Free-flowing agglomerated nonionic surfactant detergent composition and process for making same
GB2345701A (en) * 1999-01-12 2000-07-19 Procter & Gamble Particulate bleaching components
WO2000078915A1 (en) * 1999-06-21 2000-12-28 The Procter & Gamble Company Detergent composition
DE10361100A1 (en) * 2003-06-13 2005-01-05 Henkel Kgaa Storage-stable capsules based on peroxycarboxylic acids
US8034759B2 (en) * 2008-10-31 2011-10-11 Ecolab Usa Inc. Enhanced stability peracid compositions
GB201402257D0 (en) 2014-02-10 2014-03-26 Revolymer Ltd Novel Peracid - containing particle

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2229766A1 (en) * 1973-05-14 1974-12-13 Procter & Gamble
US4013581A (en) * 1975-07-10 1977-03-22 The Procter & Gamble Company Bleach tablet composition
FR2332322A1 (en) * 1975-11-18 1977-06-17 Interox Chemicals Ltd BLEACHING OR DETERGENT COMPOSITIONS AND USE OF THESE COMPOSITIONS FOR WASHING, BLEACHING AND FOR TREATING HARD SURFACES
EP0212976A2 (en) * 1985-08-21 1987-03-04 The Clorox Company Stable peracid bleaching composition

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA651777A (en) * 1962-11-06 Unilever Limited Bleaching compositions
DE1240508B (en) * 1963-04-01 1967-05-18 Degussa Process for granulating perborate
US3639285A (en) * 1969-07-23 1972-02-01 Ppg Industries Inc Novel bleaching compositions and use thereof
US3770816A (en) * 1969-07-23 1973-11-06 Ppg Industries Inc Diperisophthalic acid compositions
US3664961A (en) * 1970-03-31 1972-05-23 Procter & Gamble Enzyme detergent composition containing coagglomerated perborate bleaching agent
GB1387167A (en) * 1972-09-28 1975-03-12 Procter & Gamble Ltd Bleaching agent
CA1029153A (en) * 1973-05-14 1978-04-11 Thomas W. Gougeon Bleaching composition and methods
CA1001361A (en) * 1973-05-16 1976-12-14 Ppg Industries, Inc. Bleaching formulation
DE2413561A1 (en) * 1974-03-21 1975-10-02 Henkel & Cie Gmbh STORAGE-RESISTANT, EASILY-RELEASE DETERGENT ADDITIVE AND METHOD FOR MANUFACTURING IT
LU70331A1 (en) * 1974-06-17 1976-05-31
GB1534261A (en) * 1974-11-08 1978-11-29 Reckitt & Colmann Prod Ltd Cleaning composition
GB1568358A (en) * 1975-11-18 1980-05-29 Interox Chemicals Ltd Aromatic peroxyacids and their use in bleaching processes
DE2622463C3 (en) * 1976-05-20 1985-06-05 Basf Ag, 6700 Ludwigshafen Process for the purification of copolymers containing crotonic acid
US4126573A (en) * 1976-08-27 1978-11-21 The Procter & Gamble Company Peroxyacid bleach compositions having increased solubility
US4170453A (en) * 1977-06-03 1979-10-09 The Procter & Gamble Company Peroxyacid bleach composition
US4287135A (en) * 1978-10-25 1981-09-01 Reinhard Stober Stabilized diperoxyalkanedioic acids and aromatic peroxycarboxylic acids
DE3064301D1 (en) * 1979-10-18 1983-08-25 Interox Chemicals Ltd Magnesium salts of peroxycarboxylic acids, processes for their preparation and their use as bleaching agents in washing compositions, and processes
US4259201A (en) * 1979-11-09 1981-03-31 The Procter & Gamble Company Detergent composition containing organic peracids buffered for optimum performance
DE3266563D1 (en) * 1981-09-08 1985-10-31 Interox Chemicals Ltd Granulation
US4497757A (en) * 1983-01-31 1985-02-05 The Procter & Gamble Company Energy efficient hydration process
DE3305637A1 (en) * 1983-02-18 1984-08-23 Basf Ag, 6700 Ludwigshafen COPOLYMERISATE, THEIR PRODUCTION AND THEIR USE AS AUXILIARIES IN DETERGENT AND CLEANING AGENTS
JPS6060905A (en) * 1983-09-08 1985-04-08 Nippon Peroxide Co Ltd Manufacture of peroxide having superior disintegrability in water
GB8332682D0 (en) * 1983-12-07 1984-01-11 Procter & Gamble Laundry additive products

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2229766A1 (en) * 1973-05-14 1974-12-13 Procter & Gamble
US4013581A (en) * 1975-07-10 1977-03-22 The Procter & Gamble Company Bleach tablet composition
FR2332322A1 (en) * 1975-11-18 1977-06-17 Interox Chemicals Ltd BLEACHING OR DETERGENT COMPOSITIONS AND USE OF THESE COMPOSITIONS FOR WASHING, BLEACHING AND FOR TREATING HARD SURFACES
EP0212976A2 (en) * 1985-08-21 1987-03-04 The Clorox Company Stable peracid bleaching composition

Also Published As

Publication number Publication date
JPS61258072A (en) 1986-11-15
DE3666048D1 (en) 1989-11-09
ATE46916T1 (en) 1989-10-15
EP0200163B1 (en) 1989-10-04
ES554586A0 (en) 1987-04-01
ES8704566A1 (en) 1987-04-01
DE3515712A1 (en) 1986-11-06
EP0200163A2 (en) 1986-11-05
US5091106A (en) 1992-02-25

Similar Documents

Publication Publication Date Title
DE3666048D1 (en) Bleaching agent, its preparation and its use
ES8106513A1 (en) Salts of (+)-catechine, their preparation and use, and compositions containing these salts
JPS54125624A (en) Phenoxyyphenoxyyalkane carboxylic acid derivative*its manufacture and herbicide and plant growth controlling agent as active component of said compound
SI0948318T1 (en) Granulates comprising a water soluble compound and cellulose
ES8304047A1 (en) Granular substrate comprising kieselguhr
JPS559060A (en) Thia(oxa)zolidinecarboxylic acid derivative and its prepatation
JPS56140981A (en) Substituted acetanilide compound, its preparation and herbicide containing the same as active constituent
JPS55104994A (en) Manufacture of fibrous magnesium hydroxide
JPS5645454A (en) Cyclohexanecarboxylic acid derivative and its preparation
JPS57188552A (en) Tert-butylacetamide derivative, its preparation, and agricultural and horticultural fungicide containing said derivative as active component
JPS54118399A (en) Preparation of silica
JPS5531027A (en) N-phenetyl acetamide derivative
JPS57193466A (en) Novel 1,2,4-triazole derivative
JPS57185216A (en) Preparation of glucomannan tablet
JPS5492622A (en) Fungicidal composition for agricultural use
JPS5649309A (en) Control agent against algae
JPS54109985A (en) 1,4-benzoazine derivative and bactericidal agent containing the same it component for agriculture and floriculture
JPS5651483A (en) 1-azaxanthone 3-carboxylic acid derivative and its preparation
JPS57128696A (en) Powdery composition of ligninsulfonic acid salt
EP0750661A4 (en) PELLET BLEACHING COMPOSITIONS
JPS5511503A (en) Condensed heterocyclic compound
JPS54144392A (en) Cephalosporin derivative
JPS5653685A (en) Production of cephalosporin derivative
JPS5651458A (en) Agricultural and horticultural microbicide containing 4-amino-6-halogeno-3-phenylpyridazine derivative
JPS56128787A (en) Cephalosporin derivative and its preparation

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH DE FR GB IT LI NL SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE FR GB IT LI NL SE

17P Request for examination filed

Effective date: 19880229

17Q First examination report despatched

Effective date: 19880829

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE FR GB IT LI NL SE

REF Corresponds to:

Ref document number: 46916

Country of ref document: AT

Date of ref document: 19891015

Kind code of ref document: T

ET Fr: translation filed
REF Corresponds to:

Ref document number: 3666048

Country of ref document: DE

Date of ref document: 19891109

ITF It: translation for a ep patent filed
GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)
PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

26 Opposition filed

Opponent name: UNILEVER N.V.

Effective date: 19900704

NLR1 Nl: opposition has been filed with the epo

Opponent name: UNILEVER N.V.

ITTA It: last paid annual fee
PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19920416

Year of fee payment: 7

R26 Opposition filed (corrected)

Opponent name: UNILEVER N.V.

Effective date: 19900704

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19930324

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19930327

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19930408

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19930414

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19930419

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19930425

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19930430

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19930608

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19940424

Ref country code: AT

Effective date: 19940424

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19940430

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19940430

Ref country code: BE

Effective date: 19940430

BERE Be: lapsed

Owner name: HENKEL K.G.A.A.

Effective date: 19940430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19941101

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19940424

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Effective date: 19941229

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19950103

EUG Se: european patent has lapsed

Ref document number: 86105669.5

Effective date: 19931110

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

RDAG Patent revoked

Free format text: ORIGINAL CODE: 0009271

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT REVOKED

27W Patent revoked

Effective date: 19950213

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO