EP0519798A1 - Verfahren zur Herstellung einer Hochleistung-Sprengladung und Vorrichtung zur Durchführung dieses Verfahren - Google Patents
Verfahren zur Herstellung einer Hochleistung-Sprengladung und Vorrichtung zur Durchführung dieses Verfahren Download PDFInfo
- Publication number
- EP0519798A1 EP0519798A1 EP92401657A EP92401657A EP0519798A1 EP 0519798 A1 EP0519798 A1 EP 0519798A1 EP 92401657 A EP92401657 A EP 92401657A EP 92401657 A EP92401657 A EP 92401657A EP 0519798 A1 EP0519798 A1 EP 0519798A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mold
- mixture
- filtration
- binder
- explosive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002360 explosive Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 43
- 238000001914 filtration Methods 0.000 claims abstract description 33
- 239000011230 binding agent Substances 0.000 claims abstract description 27
- 239000007788 liquid Substances 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 17
- 239000002245 particle Substances 0.000 claims abstract description 9
- 235000011837 pasties Nutrition 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000007711 solidification Methods 0.000 claims abstract description 4
- 230000008023 solidification Effects 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims description 13
- 239000000028 HMX Substances 0.000 claims description 12
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 claims description 12
- 239000004744 fabric Substances 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 3
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 238000007906 compression Methods 0.000 description 4
- 230000000295 complement effect Effects 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000005266 casting Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- JVJQPDTXIALXOG-UHFFFAOYSA-N nitryl fluoride Chemical compound [O-][N+](F)=O JVJQPDTXIALXOG-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B9/00—Presses specially adapted for particular purposes
- B30B9/02—Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B9/00—Presses specially adapted for particular purposes
- B30B9/02—Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material
- B30B9/04—Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material using press rams
- B30B9/06—Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material using press rams co-operating with permeable casings or strainers
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
- C06B21/0033—Shaping the mixture
- C06B21/005—By a process involving melting at least part of the ingredients
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B33/00—Manufacture of ammunition; Dismantling of ammunition; Apparatus therefor
- F42B33/02—Filling cartridges, missiles, or fuzes; Inserting propellant or explosive charges
- F42B33/0207—Processes for loading or filling propulsive or explosive charges in containers
Definitions
- the present invention relates to a method for manufacturing a high-powered explosive charge, of the type consisting in mixing a high-power explosive in the form of solid particles with a liquid or molten binder, in pouring the pasty mixture obtained into a mold, evacuate the excess liquid binder and then allow the mixture to solidify to form said explosive charge.
- the field of application of the present invention is that of secondary explosives for charges, in particular explosives intended for hollow charges and for which charges are desired whose rate of high-powered explosive is very high, the very low degree of porosity and the lowest possible axial density gradient.
- the industrial manufacture of hollow charges is preferably obtained by a casting method.
- One such method consists in mixing high-power explosive, for example hexogen and / or octogen, with an inert liquid component, for example a hardenable plastic resin, or an active one, for example molten TNT, the pasty mixture thus obtained being poured into the envelopes of hollow charges. Then the binder is allowed to harden.
- the binder whether inert or active, inevitably constitutes a power reducer. The problem is therefore to reduce the rate of use of this binder as much as possible.
- the object of the invention is to design a method and a device which make it possible to overcome the abovementioned drawbacks while providing other advantages.
- the invention provides a method of manufacturing a high-powered explosive charge, of the aforementioned type and which is characterized in that it consists in removing the excess of liquid binder by filtration through porous walls of the mold, this filtration taking place substantially over the entire height thereof
- the conventional method casting-compression is replaced by a casting-filtration process.
- the evacuation of the excess of the liquid binder is carried out either by natural filtration, or by forced filtration by vibrating the mixture for a predetermined time, of the order of a few minutes.
- the invention also provides a device for implementing this method and which is characterized in that the mold has porous walls to allow filtration of the excess liquid binder.
- the mold consists of a rigid perforated grid against which a filtering envelope is applied, for example made of fabric, metallic or plastic fabric, or even filter paper, the envelope possibly comprising several filtering thicknesses.
- the mold is advantageously of cylindrical shape and has a bottom wall bordered by a side wall open at its free end, and it is removably attached to a holding support.
- the holding support comprises a hollow body of cylindrical shape open at one end or upper end, and a receptacle into which opens the lower end of the body, the mold being housed in a removable manner inside this body by providing an annular space between the mold and the internal wall of the body for the free passage of the excess liquid binder which falls by gravity into the recovery receptacle.
- the implementation device is equipped with complementary means capable of creating in the body of the support for holding a depression around the mold and / or an overpressure at the level of the surface of the mixture. , as well as a porous or unmounted piston sliding in order to exert a compressive force on the surface of the mixture.
- FIG. 1 Before explaining in detail the different phases of the process for manufacturing a high-powered explosive charge, according to the invention, a device for its implementation will be described beforehand as illustrated in FIG. 1.
- the device 1 for implementing the method mainly comprises a mold 2 advantageously of cylindrical shape which has a bottom wall 3 bordered by a side wall 4 open at its free end and determined by a radially external rim 4a, and a support for holding 5 to which the mold 2 is fixed removably.
- the bottom wall 3 and the side wall 4 of the mold 2 are porous walls which are constituted, with reference to FIGS. 1a and 1b, by a rigid support 6 such as sheet metal having perforations 6a each having an opening of the order of 10 mm, and by a filter envelope 7 which covers the interior wall of the mold 2.
- This envelope 7 is constituted by a filtering material, for example, metallic canvas, plastic canvas or filter paper for example.
- the casing 7 can be made up of two thicknesses 7a and 7b made up of different filtering materials.
- the internal diameter of the mold 2 is slightly greater, of the order of 3 to 5 mm, than that of the filler that it is desired to obtain, and its height is sufficient to contain in addition to the filler , the extension which will then be removed by machining.
- the mold 2 can advantageously be made in two parts in the form of two semi-cylindrical shells and / or flaring slightly at its upper part by delimiting a frustoconical shoulder 8 extended by the aforementioned radially external rim 4a.
- Such a mold 2 is removably attached to the holding support 5 as described below with reference to FIG. 1.
- the support 5 includes a cylindrical hollow body 9 where the mold 2 is housed, means 10 for fixing the mold 2 to the body 9, and a receptacle 11 into which the lower end of the body 9 opens.
- the body 9 has, towards its end opposite to that opposite the receptacle 11, an internal wall which widens slightly outwards to form a frustoconical shoulder 9a of a shape complementary to that of the mold shoulder 8
- the internal diameter of the body 9 is greater than the external diameter of the mold 2, so that the mold 2 can be freely mounted inside the body 9 by delimiting between them an annular space E.
- the mold 2 is retained in the body 9 by means of its shoulder 8 which bears on the complementary shoulder 9a of the body 9. In this position, the external rim 4a of the mold 2 is supported on the upper end surface of the body 9, the rim 4a forming the mold retaining element 2 in the absence of the shoulders 8 and 9a.
- the fastening means 10 of the mold 2 inside the body 9 consist of a ring 10a with a diameter substantially equal to that of the body 9.
- This ring 10a is attached coaxially to the body 9, so as to come to bear on the rim 4a of the mold 2 to immobilize the latter, the ring 10a being itself fixed to the body 9 by any suitable means, known per se.
- the receptacle 11 comprises a bottom wall 12 bordered by a lateral cylindrical wall 13 whose diameter is substantially equal to that of the body 9, and it forms a recovery chamber 14. This receptacle 11 once positioned under the body 9 is fixed to the latter by any suitable means known in oneself.
- This device 1 makes it possible to manufacture a charge of explosive containing a high percentage of high-powered explosive according to the process according to the invention which takes place generally according to four main stages.
- a mixture of high power explosives is prepared, for example octogen and / or hexogen in the form of solid particles with a liquid binder such as molten TNT.
- the pasty mixture which must then be able to be poured inside the mold 2 comprises around 75% by weight of explosive and 25% by weight of TNT. Specific examples will be given later.
- a third step, or filtration step the excess liquid binder in the mixture is evacuated naturally through the porous walls 3 and 4 of the mold 2 and is collected in the chamber 14 of the receptacle 11, after having passed through the filter envelope 7 and the perforations 6a of the perforated sheet 6 of the mold 2.
- the duration of the filtration step is of the order of a few minutes, and in general, the mold 2 is kept at a temperature higher than that of the melting of the binder.
- the mixture is allowed to solidify inside the mold 2, and the explosive charge is then removed from the mold.
- the filtration operation takes place in a natural way.
- the device 1 is equipped with vibrating means shown diagrammatically at 20 and which act directly on the holding support (5) of the mold 2.
- These means can for example consist of a vibrating table on which the holding support 5 is fixed. .
- a depression is created inside the space E provided between the mold 2 and the retaining body 5, so as to facilitate the filtration operation of the mixture contained in the mold 2.
- a conduit 21 which is connected to a device 22 known per se which makes it possible to create this depression.
- an overpressure is created at the level of the upper surface of the mixture contained in the mold 2 to also favor the filtration operation.
- the implementation device is completed by a cover 25 which closes the upper end of the holding support 5 which then forms a closed enclosure.
- a passage 26 is provided which communicates with a device 27, known per se, for sending pressurized air inside the holding body 5.
- the mixture is slightly compressed always to facilitate the filtration operation of the excess liquid binder in the mixture contained in the mold 2.
- This compression is ensured by means of a hollow piston 28 which is mounted sliding in the retaining body 5 and at the upper part thereof.
- the piston 28 is hollow and its end surface adjacent to the mixture contained in the mold 2 is advantageously porous and constituted for example by a filtering wall 29 having the same constitution as the walls of the mold 2.
- FIG. 5 shows an alternative embodiment of FIG. 4, in which the piston 28 is a full piston.
- the step of solidifying the mixture, after natural or forced evacuation of the excess liquid binder, is accompanied by an operation for cooling the mixture.
- This operation is advantageously carried out when the binder used is a fusible product, because it allows the shrinkage phenomenon to be limited to the upper part of the solidified block, part which is then eliminated.
- this cooling operation there is provided in the holding support 5, a continuous channel 30 in the form of a serpentine which extends over the entire height of the mold 2.
- This inner channel 30 opens out to the outside. towards the lower and upper parts of the retaining body 5, and it communicates via outward and return conduits 32 with a cooling device 33, known per se, which circulates a coolant and comprises a circulation pump and an exchanger of heat for example.
- FIG. 7 is illustrated a variant of the embodiment of FIG. 6 to improve the cooling operation of the mixture during solidification.
- the bottom wall 3 of the mold 2 is pierced with a central opening 35 on which rests by the base a conical block 36 supporting the hollow charge coating 37.
- a hollow charge consists of a metallic coating of conical shape onto which the explosive is poured.
- the device for implementing the method according to the invention in the example considered in FIG. 7 includes this coating of hollow charge 37 supported by the block conical 36, so as to directly obtain a hollow charge after solidification of the mixture which sticks to the coating.
- the solidified mixture once demolded when it is intended to constitute the explosive of a hollow charge, it must undergo a machining operation consisting in digging a conical recess in which the hollow charge coating is then bonded.
- these other implementing devices can be equipped with these means 36 and 37 for manufacturing hollow charges.
- a cooling circuit of the mixture which comprises by two circuits respectively external and internal.
- the external circuit is similar to that shown in FIG. 6 with an internal channel 30 in the retaining body 5 which is connected by outward and return conduits 32 to a cooling device 33.
- the internal cooling circuit comprises a continuous channel 40 in the form of a coil which is housed inside the conical block 36, channel 40 which is connected by outward and return conduits 42 to a cooling device 43 similar to the device 33.
- the pasty mixture produced during the first step of the process initially contains 76% by weight of industrial quality octogen according to a particle size between 0 and 800 ⁇ m, and 24% of molten TNT.
- the pasty mixture produced during the first step of the process contains 80% by weight of octogen according to a particle size between 0 and 1600 ⁇ m, and 20% by weight of molten TNT.
- the pasty mixture produced during the first step of the process contains 83% by weight of octogen according to a particle size between 0 and 1000 ⁇ m and 17% by weight of molten TNT.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Manufacturing & Machinery (AREA)
- General Engineering & Computer Science (AREA)
- Filtering Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9107606A FR2677977A1 (fr) | 1991-06-21 | 1991-06-21 | Procede de fabrication d'une charge explosive de grande puissance et dispositif de mise en óoeuvre du procede. |
| FR9107606 | 1991-06-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0519798A1 true EP0519798A1 (de) | 1992-12-23 |
| EP0519798B1 EP0519798B1 (de) | 1996-04-17 |
Family
ID=9414094
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19920401657 Expired - Lifetime EP0519798B1 (de) | 1991-06-21 | 1992-06-16 | Verfahren zur Herstellung einer Hochleistung-Sprengladung und Vorrichtung zur Durchführung dieses Verfahren |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0519798B1 (de) |
| DE (1) | DE69209905T2 (de) |
| FR (1) | FR2677977A1 (de) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2270181C1 (ru) * | 2004-08-03 | 2006-02-20 | ФГУП "Бийский олеумный завод" | Состав литого взрывчатого вещества (варианты) |
| FR2954308A1 (fr) * | 2009-12-23 | 2011-06-24 | Nexter Munitions | Composition explosive fusible/coulable et a vulnerabilite reduite |
| CN109400425A (zh) * | 2018-10-25 | 2019-03-01 | 山西北方兴安化学工业有限公司 | 一种包覆层反向浇铸模具 |
| CN109485529A (zh) * | 2018-10-31 | 2019-03-19 | 四川大学 | 一种用于发射药挤压机的药料均流装置 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1469114A (en) * | 1921-11-14 | 1923-09-25 | Simpson James | Fruit press |
| FR52514E (fr) * | 1942-07-24 | 1945-04-17 | Procédé de traitement et de séchage de la tourbe | |
| US2800072A (en) * | 1954-04-28 | 1957-07-23 | American Viscose Corp | Cylindrical press assembly |
| GB888858A (en) * | 1951-08-15 | 1962-02-07 | Hercules Powder Co Ltd | Method and apparatus for manufacture of cast plastic compositions |
| DE3529123C1 (en) * | 1985-08-14 | 1987-04-23 | Messerschmitt Boelkow Blohm | Process and device for producing explosive charges |
| DE8904735U1 (de) * | 1989-04-14 | 1989-06-01 | Pettay, Franz, 8900 Augsburg | Fruchtsaft-Filterpresse |
-
1991
- 1991-06-21 FR FR9107606A patent/FR2677977A1/fr active Granted
-
1992
- 1992-06-16 EP EP19920401657 patent/EP0519798B1/de not_active Expired - Lifetime
- 1992-06-16 DE DE1992609905 patent/DE69209905T2/de not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1469114A (en) * | 1921-11-14 | 1923-09-25 | Simpson James | Fruit press |
| FR52514E (fr) * | 1942-07-24 | 1945-04-17 | Procédé de traitement et de séchage de la tourbe | |
| GB888858A (en) * | 1951-08-15 | 1962-02-07 | Hercules Powder Co Ltd | Method and apparatus for manufacture of cast plastic compositions |
| US2800072A (en) * | 1954-04-28 | 1957-07-23 | American Viscose Corp | Cylindrical press assembly |
| DE3529123C1 (en) * | 1985-08-14 | 1987-04-23 | Messerschmitt Boelkow Blohm | Process and device for producing explosive charges |
| DE8904735U1 (de) * | 1989-04-14 | 1989-06-01 | Pettay, Franz, 8900 Augsburg | Fruchtsaft-Filterpresse |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2270181C1 (ru) * | 2004-08-03 | 2006-02-20 | ФГУП "Бийский олеумный завод" | Состав литого взрывчатого вещества (варианты) |
| FR2954308A1 (fr) * | 2009-12-23 | 2011-06-24 | Nexter Munitions | Composition explosive fusible/coulable et a vulnerabilite reduite |
| WO2011086246A1 (fr) * | 2009-12-23 | 2011-07-21 | Nexter Munitions | Composition explosive fusible/coulable et a vulnerabilite reduite |
| US9242906B2 (en) | 2009-12-23 | 2016-01-26 | Nexter Munitions | Melt-cast insensitive explosive composition |
| CN109400425A (zh) * | 2018-10-25 | 2019-03-01 | 山西北方兴安化学工业有限公司 | 一种包覆层反向浇铸模具 |
| CN109400425B (zh) * | 2018-10-25 | 2020-12-08 | 山西北方兴安化学工业有限公司 | 一种包覆层反向浇铸模具 |
| CN109485529A (zh) * | 2018-10-31 | 2019-03-19 | 四川大学 | 一种用于发射药挤压机的药料均流装置 |
| CN109485529B (zh) * | 2018-10-31 | 2019-07-12 | 四川大学 | 一种用于发射药挤压机的药料均流装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0519798B1 (de) | 1996-04-17 |
| FR2677977A1 (fr) | 1992-12-24 |
| DE69209905D1 (de) | 1996-05-23 |
| DE69209905T2 (de) | 1996-09-05 |
| FR2677977B1 (de) | 1994-07-13 |
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