EP0851999B1 - Echangeur de chaleur a faisceau tubulaire places en aval d'installations thermiques de craquage, procede de revetement d'une plaque a tubes et utilisation d'un pise refractaire - Google Patents
Echangeur de chaleur a faisceau tubulaire places en aval d'installations thermiques de craquage, procede de revetement d'une plaque a tubes et utilisation d'un pise refractaire Download PDFInfo
- Publication number
- EP0851999B1 EP0851999B1 EP96931808A EP96931808A EP0851999B1 EP 0851999 B1 EP0851999 B1 EP 0851999B1 EP 96931808 A EP96931808 A EP 96931808A EP 96931808 A EP96931808 A EP 96931808A EP 0851999 B1 EP0851999 B1 EP 0851999B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat exchanger
- coating
- tubular heat
- tube plate
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 32
- 238000000576 coating method Methods 0.000 title claims abstract description 32
- 238000004227 thermal cracking Methods 0.000 title claims abstract description 8
- 238000009434 installation Methods 0.000 title claims abstract 6
- 238000000034 method Methods 0.000 title claims description 8
- 230000003628 erosive effect Effects 0.000 claims abstract description 16
- 229910000831 Steel Inorganic materials 0.000 claims description 9
- 239000010959 steel Substances 0.000 claims description 9
- 238000010276 construction Methods 0.000 claims description 5
- 230000000717 retained effect Effects 0.000 claims 2
- 238000005056 compaction Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 10
- 239000007789 gas Substances 0.000 description 24
- 239000000571 coke Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000005336 cracking Methods 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 208000018777 Vulvar intraepithelial neoplasia Diseases 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- -1 Hot naphtha Chemical class 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 238000005492 weld surfacing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
- F28F19/02—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F9/00—Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
- F28F9/02—Header boxes; End plates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4935—Heat exchanger or boiler making
- Y10T29/49364—Tube joined to flat sheet longitudinally, i.e., tube sheet
Definitions
- the invention relates to a thermal cracking system downstream tube bundle heat exchanger (RWÜ) with a tube bundle held between two tube plates of heat exchanger tubes, a method for coating a tube plate and the use of a ramming mass.
- RWÜ thermal cracking system downstream tube bundle heat exchanger
- Such RWÜ are used for example in ethylene plants for the production of ethylene by thermal splitting on the downstream side of a transfer line of a splitting furnace used and referred to as cracked gas cooler.
- Cracked gas coolers must meet extremely high requirements in terms of construction and the material properties are sufficient. That by pyrolysis of hydrocarbons like Hot naphtha, heavy gasoline or ethane emerging from the cracking furnace Reaction mixture (approx. 850 ° C) must be cooled quickly in the cracked gas coolers to avoid unwanted side reactions.
- the cracked gas cooler or RWÜ serves as Waste heat boiler, in which by evaporation from the jacket side Feed water high pressure steam is generated.
- the cracking gas coming out of the cracking furnace at high speed emerges usually via an axially arranged transfer line Hood socket from below into the cracked gas cooler and hits the lower tube plate, to one after passing through the heat exchanger tubes of the cracked gas cooler Oil washing and further processing to be fed.
- the cracked gas contains about 300 m / s already coke particles, which are strongly eroding at these speeds Act.
- the central areas of the floor slab and The pipes arranged in the area of the core zone are accordingly becoming stronger eroded as the peripheral areas.
- each Spout has a conical opening that narrows into a pipe section that in a heat exchanger tube protrudes.
- This solution does not provide a gas-tight seal between the individual cuboid elements. This would be in cracked gas coolers an olefin plant lead to coke formation in the spaces and the materials to destroy.
- the ends of the spouts used would have a tear-off edge in the Pipe form what at the flow velocities driven in cracked gas coolers Turbulence of approximately 300 m / s with the consequence of additional erosions would cause.
- DE-C-44 04068 discloses a ceramic cladding made of refractory Shaped bodies is formed. These can be hexagonal, for example, and are with Provide perforations through the welded to the underside of the tube sheet Can reach through pins or hooks. The molded body is in this way on Pipe base hung. This construction does not provide a seamless coating reached.
- the gas flowing from the gas at high speed should be in the area the core flow entrained coke particles slowed down and partially radially be steered outside so that they no longer cause erosion damage to the tube plate and lead the pipes.
- the gas flowing from the gas at high speed should be in the area the core flow entrained coke particles slowed down and partially radially be steered outside so that they no longer cause erosion damage to the tube plate and lead the pipes.
- the invention takes a different approach by reinforcing the floor slab effective erosion protection is sought.
- the erosions on the lower tube plate made periodic shutdowns of the cracked gas cooler necessary, one so has helped the base plates to the required again by means of weld surfacing Bring wall thickness.
- This process is complex and can be done in terms of Resistance of the material applied by build-up welding also unsatisfactory.
- the base plate does not only act like a baffle plate and therefore special erosion is exposed, but at the same time should be relatively thin in order to make one possible to be able to achieve a low interface temperature. This is from apparatus engineering Desirable reasons and also advantageous because the entering gases should be cooled as quickly as possible, without previously undesirable To enter into side reactions.
- the coating can have a thickness of 10 to 50, preferably 15 to 30 mm.
- Pipe plate anchor preferably in V, T, S or Y shape, especially with a Diameter of about 5 mm or a sheet metal structure in honeycomb structure, preferably with a height of 5 to 10 mm, are welded on.
- Such anchors are available as ECO-VINs for various lining thicknesses Sheet steel welded linings with backing in firing Systems known, the legs of the to better anchor the ramming mass Anchor can be bent to about 60 ° C. The anchors can be spread out or welded onto the lower tube plate in a spread version.
- the coating with the ramming mass from a chemically bound, against Erosion resistant refractory material is made either by hand or for larger areas are applied by spraying and manually, for example by means of Flat steel and hammer, or compacted using machine tools.
- ramming compounds sometimes also known as ramming compounds
- chemically setting compounds consisting primarily of inorganic raw materials are used.
- the setting takes place in the presence of air.
- An important raw material is corundum, for example.
- a typical composition of such compositions is, for example, 85 percent by weight Al 2 O 3 , 7 percent by weight SiO 2 , 0.3 percent by weight Fe 2 O 3 , 3.1 percent by weight MgO, 4.5 percent by weight P 2 O 5 and 0.1 percent by weight alkalis (approx -Values).
- the maximum grain size of the individual components should not exceed 4 mm.
- This inorganic mixture is mixed with water for processing or for the manufacture of the ramming mass and then processed. After the ramming compound has been applied, it is usually allowed to set for at least 24 hours. Then drying or
- the thermal conductivity of the set ramming compound or coating is between 1.5 and 3.5 W / mK.
- the abrasion of this coating is less than 8 cm 3 (according to ASTM C-704)
- RESCO-CAST a product of RESCO
- RESCO is suitable as ramming paste Products Inc.
- Other suitable products on the market are as Rammasse called PLIRAM Cyclone-Mix D from Plibrico GmbH.
- the above Products are from practice z. B. for the inner lining of FCC (Fluid Catalytic Cracker) -System parts known. Such system parts are lined in which the fluidized FCC catalyst with temperatures of about 750 ° C Moving speed from 20 to 30 m / s.
- FCC Fluid Catalytic Cracker
- the invention further relates to a method for coating a tube plate in an RWÜ according to the features of claim 1.
- the pipe openings are on the input tube plate Plug closed. These plugs protrude at least to the height of the layer coating to be applied out of the pipes. Then the Pounded mass applied. This can be done manually using a spatula or trowel or also by spraying.
- the ramming mass is then mechanically compressed e.g. B. by hammer blows transmitted by means of flat iron. After setting the The plugs are removed from tamped mass of usually at least 24 hours and the ramming mass may be dried or baked.
- the ramming compounds described are for coating floor slabs in Ideally, downstream tube bundle heat exchangers downstream of thermal cracking systems suitable.
- V-anchors or ECO-VIN anchors are placed on a base plate Figures 1 and 2 of the drawing embodiment shown from a austenitic steel (1.4841) welded on.
- the inner tubes of the RWÜ are closed by conical wooden plugs, so that the ramming mass holds on both the anchors and the plugs.
- the one from PLIRAM Cyclone-Mix D existing ramming mass is corrugated with 2 wt .-% Steel fibers C-Mix 25 (material 1.4841) mixed.
- the ramming compound is applied manually using a spatula and trowel.
- the ramming compound applied is then section by section hammer blows transmitted by means of flat iron to a void-free Coating compacted. After a setting time of approx. 25 hours at the conical wooden plugs are removed again at normal outside temperature.
- the ramming mass is dried and then burned in according to a specified temperature curve according to the manufacturer's instructions.
- FIG. 1 shows a tube sheet according to the invention in plan view (viewed from below).
- Fig. 2 shows a section through a cracked gas cooler with an inventive Coating in the area of the base plate.
- Base plates are protected from further erosion. They are also subject to Bottom plates equipped according to the invention against erosion by coke particles. in the The erosion is compared to the unprotected metallic material of the base plate Bottom plates coated according to the invention are significantly slower, so that a improved availability of the corresponding plant parts results. Incidentally, at Wear removal and reapplication of the invention Coating possible.
- the metal base plate no longer has to be as thin, but can be carried out more. Because of the constructive achieved thereby Stabilization can be at least partly due to the fact that thin floor slabs are used Stabilization necessary tie rods are dispensed with.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Non-Disconnectible Joints And Screw-Threaded Joints (AREA)
- Electroplating Methods And Accessories (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Vehicle Body Suspensions (AREA)
Claims (8)
- Procédé de revêtement sans laisser d'intervalle d'une plaque à tubes d'un échangeur de chaleur à faisceau tubulaire en aval d'une installation thermique de craquage,
caractérisé en ce queon ferme avec des bouchons les tubes échangeurs de chaleur tenus par la plaque à tubes, ces bouchons dépassant après mise en place, au moins de la hauteur de l'épaisseur d'une couche de revêtement à mettre en place,on met en place une masse de bourrage à prise chimique comme couche de revêtement de la plaque à tubes,on compacte mécaniquement la masse,on laisse prendre la masse,on enlève les bouchons, etle cas échéant on cuit la masse. - Procédé selon la revendication 1,
caractérisé en ce qu'
avant d'appliquer la masse, on soude sur la plaque à tubes une construction en tôle en forme de nids d'abeilles ou des organes d'accrochage. - Echangeur de chaleur à faisceau tubulaire en aval d'installations thermiques de craquage, comprenant un faisceau de tubes échangeurs de chaleur tenu entre deux plaques à tubes et sur la plaque à tubes du côté de l'entrée, un revêtement résistant à l'érosion, réfractaire, laissant dégagées les ouvertures des tubes échangeurs de chaleur, du côté de la plaque à tubes tourné vers l'arrivée des gaz,
caractérisé en ce que
le revêtement est formé d'une masse de bourrage à prise chimique appliquée selon le procédé de la revendication 1. - Echangeur de chaleur à faisceau tubulaire selon la revendication 3,
caractérisé en ce que
le revêtement formé de la masse de bourrage après prise a une épaisseur de 10 à 50, de préférence de 15 à 30 mm. - Echangeur de chaleur à faisceau tubulaire selon la revendication 3 ou 4,
caractérisé en ce que
pour améliorer l'accrochage de la masse de bourrage sur la plaque à tubes, on soude sur celle-ci une construction en tôle en nids d'abeilles ou des organes d'accrochage de préférence en forme de V, T, S, ou Y. - Echangeur de chaleur à faisceau tubulaire selon l'une quelconque des revendications 3 à 5,
caractérisé en ce que
la masse de bourrage contient des fibres d'acier ondulées. - Echangeur de chaleur à faisceau tubulaire selon l'une quelconque des revendications 3 à 6,
caractérisé par
une chambre d'entrée qui s'élargit à partir du diamètre de la conduite de transfert venant de l'installation thermique de craquage jusqu'au diamètre de la plaque à tubes du côté de l'entrée. - Application d'une masse de bourrage à prise chimique pour revêtir les plaques de fond d'échangeurs de chaleur à faisceau tubulaire en aval d'installations thermiques de craquage selon la revendication 3.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19534823 | 1995-09-20 | ||
| DE19534823A DE19534823C2 (de) | 1995-09-20 | 1995-09-20 | Rohrbündel-Wärmeübertrager |
| PCT/EP1996/004045 WO1997011330A1 (fr) | 1995-09-20 | 1996-09-14 | Echangeurs de chaleur a faisceau tubulaire places en aval d'installations thermiques de craquage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0851999A1 EP0851999A1 (fr) | 1998-07-08 |
| EP0851999B1 true EP0851999B1 (fr) | 2001-06-20 |
Family
ID=7772623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP96931808A Expired - Lifetime EP0851999B1 (fr) | 1995-09-20 | 1996-09-14 | Echangeur de chaleur a faisceau tubulaire places en aval d'installations thermiques de craquage, procede de revetement d'une plaque a tubes et utilisation d'un pise refractaire |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6155337A (fr) |
| EP (1) | EP0851999B1 (fr) |
| JP (1) | JP3891589B2 (fr) |
| AT (1) | ATE202415T1 (fr) |
| AU (1) | AU700338B2 (fr) |
| CA (1) | CA2230134C (fr) |
| CZ (1) | CZ294937B6 (fr) |
| DE (3) | DE19534823C2 (fr) |
| DK (1) | DK0851999T3 (fr) |
| ES (1) | ES2159042T3 (fr) |
| GR (1) | GR3036096T3 (fr) |
| HU (1) | HU226917B1 (fr) |
| PL (1) | PL183641B1 (fr) |
| PT (1) | PT851999E (fr) |
| WO (1) | WO1997011330A1 (fr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19962391A1 (de) * | 1999-12-23 | 2001-06-28 | Behr Industrietech Gmbh & Co | Ladeluftkühler |
| DE10028568C1 (de) * | 2000-06-09 | 2001-06-07 | Uwe Schwerdtfeger | Röhrchen-Wärmetauscher |
| DE102005032118A1 (de) * | 2005-07-07 | 2007-01-11 | Ruhr Oel Gmbh | Rohrbündelwärmeübertrager mit verschleißbeständiger Rohrbodenauskleidung |
| DE102006055973A1 (de) * | 2006-11-24 | 2008-05-29 | Borsig Gmbh | Wärmetauscher zur Kühlung von Spaltgas |
| US9575479B2 (en) * | 2013-11-27 | 2017-02-21 | General Electric Company | System and method for sealing a syngas cooler |
| DE102017003380A1 (de) * | 2017-04-06 | 2018-10-11 | Linde Aktiengesellschaft | Wärmetauscher, Verwendung eines Wärmetauschers und Verfahren zur Herstellung eines Wärmetauschers |
| JP7738496B2 (ja) * | 2022-02-04 | 2025-09-12 | 三菱重工業株式会社 | 熱交換器 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1894956A (en) * | 1929-01-16 | 1933-01-24 | Babcock & Wilcox Co | Air heater |
| US3017696A (en) * | 1957-03-11 | 1962-01-23 | Griscom Russell Co | Corrosion-resistant surface |
| GB1175157A (en) * | 1966-03-19 | 1969-12-23 | Ernst Kreiselmaier | Improvements in or relating to Steam Condensers |
| GB1195309A (en) * | 1967-11-29 | 1970-06-17 | Idemitsu Petrochemical Co | Quenching Apparatus for Use with Thermal Cracking Systems |
| US3751295A (en) * | 1970-11-05 | 1973-08-07 | Atomic Energy Commission | Plasma arc sprayed modified alumina high emittance coatings for noble metals |
| DE2160372C3 (de) * | 1971-12-02 | 1975-07-17 | 1000 Berlin | Vorrichtung zur gleichmäßigen Durchströmung eines Rohrbündelwärmetauschers |
| DE2458308A1 (de) * | 1974-12-10 | 1976-06-24 | Siegener Ag Geisweid | Gaskuehler zum kuehlen von spaltgas oder synthesegas |
| US3990862A (en) * | 1975-01-31 | 1976-11-09 | The Gates Rubber Company | Liquid heat exchanger interface and method |
| US4124068A (en) * | 1977-05-16 | 1978-11-07 | Uop Inc. | Heat exchange tube for fluidized bed reactor |
| US4479337A (en) * | 1980-04-14 | 1984-10-30 | Standard Oil Company (Indiana) | Refractory anchor |
| JPS58205084A (ja) * | 1982-05-26 | 1983-11-29 | Hitachi Ltd | 薄膜蒸発式熱交換器 |
| IT1209532B (it) * | 1984-04-20 | 1989-08-30 | Snam Progetti | Processo per la sintesi di urea e materiale utilizzato nello stesso. |
| DE3531150A1 (de) * | 1985-08-31 | 1987-03-05 | Kreiselmaier Ernst Gmbh Co | Verfahren zur beschichtung von rohrboeden od.dgl. von kondensatoren, kuehlern, waermetauschern od.dgl. mit einem korrosionsschutzmittel |
| US4753849A (en) * | 1986-07-02 | 1988-06-28 | Carrier Corporation | Porous coating for enhanced tubes |
| DE3640970A1 (de) * | 1986-11-29 | 1988-06-09 | Gutehoffnungshuette Man | Rohrbuendelwaermetauscher |
| DE3842727A1 (de) * | 1988-12-19 | 1990-06-21 | Borsig Gmbh | Waermetauscher insbesondere zum kuehlen von spaltgas |
| US5141049A (en) * | 1990-08-09 | 1992-08-25 | The Badger Company, Inc. | Treatment of heat exchangers to reduce corrosion and by-product reactions |
| JPH0570248A (ja) * | 1991-04-02 | 1993-03-23 | Harima Ceramic Co Ltd | 高炉出銑樋用不定形耐火物 |
| DE59200074D1 (de) * | 1992-04-29 | 1994-03-31 | Borsig Babcock Ag | Wärmetauscher zum Kühlen von in einer Kohlevergasungsanlage erzeugtem Synthesegas. |
| DE4404068C1 (de) * | 1994-02-09 | 1995-08-17 | Wolfgang Engelhardt | Wärmetauscher |
| US5518066A (en) * | 1994-05-27 | 1996-05-21 | Connell Limited Partnership | Heat exchanger |
| US5699852A (en) * | 1996-08-22 | 1997-12-23 | Korea Institute Of Energy Research | Heat exchanger having a resin-coated pipe |
-
1995
- 1995-09-20 DE DE19534823A patent/DE19534823C2/de not_active Expired - Lifetime
- 1995-09-20 DE DE29515406U patent/DE29515406U1/de not_active Expired - Lifetime
-
1996
- 1996-09-14 DE DE59607138T patent/DE59607138D1/de not_active Expired - Lifetime
- 1996-09-14 CA CA002230134A patent/CA2230134C/fr not_active Expired - Fee Related
- 1996-09-14 JP JP51237997A patent/JP3891589B2/ja not_active Expired - Fee Related
- 1996-09-14 WO PCT/EP1996/004045 patent/WO1997011330A1/fr not_active Ceased
- 1996-09-14 DK DK96931808T patent/DK0851999T3/da active
- 1996-09-14 HU HU9903453A patent/HU226917B1/hu not_active IP Right Cessation
- 1996-09-14 AU AU70855/96A patent/AU700338B2/en not_active Ceased
- 1996-09-14 ES ES96931808T patent/ES2159042T3/es not_active Expired - Lifetime
- 1996-09-14 AT AT96931808T patent/ATE202415T1/de active
- 1996-09-14 CZ CZ1998866A patent/CZ294937B6/cs not_active IP Right Cessation
- 1996-09-14 EP EP96931808A patent/EP0851999B1/fr not_active Expired - Lifetime
- 1996-09-14 PT PT96931808T patent/PT851999E/pt unknown
- 1996-09-14 PL PL96326272A patent/PL183641B1/pl not_active IP Right Cessation
-
1998
- 1998-09-14 US US09/029,264 patent/US6155337A/en not_active Expired - Fee Related
-
2001
- 2001-06-21 GR GR20010400937T patent/GR3036096T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE19534823C2 (de) | 2002-08-22 |
| EP0851999A1 (fr) | 1998-07-08 |
| DK0851999T3 (da) | 2001-09-03 |
| HU226917B1 (en) | 2010-03-01 |
| US6155337A (en) | 2000-12-05 |
| CZ86698A3 (cs) | 1999-08-11 |
| HUP9903453A3 (en) | 2001-10-29 |
| CZ294937B6 (cs) | 2005-04-13 |
| CA2230134A1 (fr) | 1997-03-27 |
| DE29515406U1 (de) | 1997-01-30 |
| ES2159042T3 (es) | 2001-09-16 |
| PL326272A1 (en) | 1998-08-31 |
| PL183641B1 (pl) | 2002-06-28 |
| WO1997011330A1 (fr) | 1997-03-27 |
| PT851999E (pt) | 2001-09-28 |
| ATE202415T1 (de) | 2001-07-15 |
| JP3891589B2 (ja) | 2007-03-14 |
| JPH11512514A (ja) | 1999-10-26 |
| DE59607138D1 (de) | 2001-07-26 |
| AU7085596A (en) | 1997-04-09 |
| HUP9903453A2 (hu) | 2000-04-28 |
| CA2230134C (fr) | 2008-03-25 |
| AU700338B2 (en) | 1998-12-24 |
| DE19534823A1 (de) | 1997-03-27 |
| GR3036096T3 (en) | 2001-09-28 |
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