EP1175461A1 - Zusammensetzung und verfahren zur herstellung von metallischen produkten, bestimmt um in form gebracht zu werden durch einen mechanischen vorgang der plastischen deformation - Google Patents

Zusammensetzung und verfahren zur herstellung von metallischen produkten, bestimmt um in form gebracht zu werden durch einen mechanischen vorgang der plastischen deformation

Info

Publication number: EP1175461A1
Authority: EP; European Patent Office
Prior art keywords: composition according; binder; additive; composition; metal
Prior art date: 1999-04-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP00925364A

Other languages

English (en)

French (fr)

Inventor

Jacques Pierre Pouyfaucon

Bernard Jean Léon BOUTEVIN

Yves Hervaud

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ascoforge Safe

Original Assignee

Ascoforge Safe

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-04-30

Filing date

2000-04-28

Publication date

2002-01-30

2000-04-28 Application filed by Ascoforge Safe filed Critical Ascoforge Safe

2002-01-30 Publication of EP1175461A1 publication Critical patent/EP1175461A1/de

Status Withdrawn legal-status Critical Current

Links

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Classifications

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- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/046—Siloxanes with specific structure containing silicon-oxygen-carbon bonds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/046—Siloxanes with specific structure containing silicon-oxygen-carbon bonds
- C10M2229/0465—Siloxanes with specific structure containing silicon-oxygen-carbon bonds used as base material
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/047—Siloxanes with specific structure containing alkylene oxide groups
- C10M2229/0475—Siloxanes with specific structure containing alkylene oxide groups used as base material
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2229/04—Siloxanes with specific structure
- C10M2229/048—Siloxanes with specific structure containing carboxyl groups
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2229/04—Siloxanes with specific structure
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2229/04—Siloxanes with specific structure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2229/04—Siloxanes with specific structure
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- C10M2229/0515—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing halogen used as base material
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2229/04—Siloxanes with specific structure
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- C10M2229/052—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen
- C10M2229/0525—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen used as base material
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2229/04—Siloxanes with specific structure
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- C10M2229/053—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing sulfur
- C10M2229/0535—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing sulfur used as base material
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2010/08—Groups 4 or 14
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2010/12—Groups 6 or 16
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2040/244—Metal working of specific metals
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2040/245—Soft metals, e.g. aluminum
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

Definitions

the present invention relates to the preparation and protection of metal products intended to be shaped by at least one mechanical deformation operation.
shaping operations which, depending on the destination of the parts produced, may be carried out, according to known techniques essentially according to two routes: ⁇ a machining which involves removing material from a workpiece blank, as cast, casting or drawing on a bulkier piece machining operated by turning, milling, planing, threading, tapping, etc. All these methods lead to metal removal, because they are carried out using cutting tools, with production of chips, that is to say of waste.
a mechanical treatment which uses the properties of plasticity, deformability, that all metallic materials exhibit to varying degrees, this treatment being carried out by deformation of a blank, which does not require removal of metal and which is carried out in one or more progressive shaping operations.
the part undergoes high pressures on the deformed parts, pressures which simultaneously cause a local rise in temperature which improves the deformability of the metal used.
the technique of shaping not by machining but by deformation, concerns the greatest quantities of metals and alloys, for the production of an incalculable number of metallic parts.
This lubricant must withstand, without decomposition, temperatures in the region of 400 ° C, resist oxidation and have qualities compatible with the extreme pressures to which it is subjected, the work always being carried out in the limit lubrication regime. It should also improve the "slip" between the deformed metal and the tool, which results in low values of the static and dynamic friction coefficients.
EP 0 278 029 which describes anticorrosion products containing aldehydes and formalin, the use of which is unanimously condemned because of the pollution they cause during their application and then their elimination. They are therefore to be absolutely excluded and are never found in a composition in accordance with the invention.
EP 0 376 591 which exclusively describes the use of phosphates, whereas the invention considers them alone insufficient for the intended applications, namely the plastic deformation of metals. Indeed, the phosphates have an oxygen atom in an intermediate position which gives them an undesirable hydrolysis instability.
the objective of the present invention is to provide a composition and a process for the preparation of metal products which must undergo at least one mechanical operation of shaping by plastic deformation, making it possible to remedy the aforementioned drawbacks, which are simple and economical and in particular make it possible to provide metal products with a surface suitable for shaping by satisfactory deformation, in particular avoiding the polluting means, the water and energy consumption of conventional processes.
the subject of the invention is a process for the preparation of metal products intended to be shaped by at least one mechanical operation of plastic deformation such as drawing, rolling, calendering, forging, stamping and the like, without significant withdrawal of substance, charac t érisé in that is applied to the metal product a composition as described below.
the metal products to be treated having an excessively oxidized surface without, however, being scalded, they are subjected to a coarse brushing in order to reduce the oxidation of their surface to a low value, not necessarily zero, then applied to them composi t ion;
the metal products to be treated being excessively greasy on the surface, they are subjected to a coarse cleaning which must bring the grease from their surface to a low value, not necessarily zero, then the composition is applied to them;
a subject of the invention is also a composition to be applied to metallic products intended to be shaped by at least one mechanical plastic deformation operation such as drawing, rolling, calendering, forging, stamping and the like, without significant shrinkage of the substance, characterized in that it comprises a film forming binder, at least one reactive additive with the metal, at least a lubricating additive and at least one addi t if corrosion.
the invention also relates to a composition for the preparation of metal products intended to be shaped by at least one mechanical operation of plastic deformation such as wire drawing, rolling, calendering, forging, stamping and the like, without significant withdrawal of substance, characterized in that it comprises a film-forming binder, at least one additive for reactivity with the metal, at least one lubrication additive and at least one anticorrosion additive.
the invention has, if its subject is a composition for the preparation of metal products intended to be shaped by at least one mechanical plastic deformation operation such as wire drawing, embossing, calendering, forging, stamping and the like, without significant withdrawal of substance , characterized in that it comprises a film-forming binder reactive with respect to the metal product treated, optionally one or more additive (s) of reactivity with the metal, at least one lubrication additive and at least one anticorrosion additive.
a composition for the preparation of metal products intended to be shaped by at least one mechanical plastic deformation operation such as wire drawing, embossing, calendering, forging, stamping and the like, without significant withdrawal of substance
a film-forming binder reactive with respect to the metal product treated optionally one or more additive (s) of reactivity with the metal, at least one lubrication additive and at least one anticorrosion additive.
the reactivity additive is a phosphonate or a phosphate, the molecular chains of which are either hydrocarbon-based, fluorinated or chlorofluorinated; "The reactivity additive is formed by at least one component selected from:
the binder is organic, oligomer, polymer or copolymer in nature
the binder is organo-metallic in nature
the binder is of carboxyl type such as a copolymer of mayic anhydride and vinyl ether, styrene or allyl ether;
the binder is of phosphonated type
the binder is non-reactive but has a structure capable of receiving at least one lubricant additive
the binder is of vinyl butyral type; ⁇ the binder is a styrene-butadiene copolymer;
the binder is an aceto-vinyl chloride copolymer
the binder is an acrylonitrile-butadiene copolymer
the binder is a styrene - acrylic copolymer
the haunt is a wax
® at least one pigmentation additive is of the reactive type such as phosphonate, molybdate and the like; • at least one pigmentation additive is of the opacifying non-reactive type; "A wetting product is formed by at least one component selected from the following:
the binder is organic, ohgomeric, polymeric or copolymeric, or organometallic in nature.
the lubrication additive can be present only in a reduced amount or even eliminated depending on the lubricating properties of the binder.
the binder can be a support for lubricants of a thermoplastic nature capable of undergoing and accompanying a deformation operation all the time of the application thereof, and without breaking the coating.
Waxes of natural origin (bees, camauba, etc.) of fossil origin (of MONT AN) of petroleum origin (paraffins, microcrystals, etc.) of synthesis (high molecular weight amides: " ERUCAMLDE “,” OLEYLAMIDE ",
Vinyl ether anhydride copolymers for example the product called "GANTREZ" from the company ISP.
the very reactive monomers are used by radical co-polymerization, respectively:
Copolymers of vinylidene chloride, with phosphonated acrylates by radical polymerization of formula:
polyolefins polyethylene and polypropylene
waxes of these polymers to obtain reactive lubricants.
Si-CH CH 2 present in the silicone chains.
the products have the following structures:
oils of the "FOMBLIN Z" brand from the AUSIMONT company which have alcohol functions at the chain ends can be modified as follows:
R chain poiymèr ⁇
R ' alkyl
CK 2 CF 2 + HPO (OE 5 H— (CF 2 - CH,) -? ⁇ O OR
phosphates With regard to phosphates, the synthesis is carried out from the corresponding alcohols on phosphonated derivatives such as POCl 3 , Cl P (OR) 2 . etc.
reactive additives which can be used in the case of formulations based on non-reactive binders, there are also phosphonic acids, alkyl phosphonic acids, phosphoric acids, aminotrimethylene phosphonic acid, 1-hydroxyethylidene-11-diphosphonic acid, ethylenediamine tetramethylene phosphonic acid, acid hexamethylene diamine tetra methylene phosphonic, di-ethylene triamin ⁇ p ⁇ ntamethyiene phosphonic.
the term “reactant” or “reactivity” relates to the reactivity with respect to the treated metal product, in other words the metal or metals constituting the treated metal product, in particular located (s) at the surface thereof intended to undergo the action of the deformation during the shaping operation on iaqu ⁇ ll ⁇ the composition is applied.
the purpose of this reactivity is to allow the chemical conversion of the abovementioned metal or metals to ensure the best possible adhesion of the binder which can itself be reactive or act as an interface linked to the metals, in the non-reactive part of the film-forming agent.
Polyvinylidene fluoride grafted with a phosphonated acrylate is obtained by synthesis of a type known per se, by ⁇ x ⁇ mple as described in patent EP 0 704 465.
R CH 3 or C 2 H 4
R F R H, CH 3 or C 2 H 5 Q ⁇ (CH 2 ) 3 or C 2 H 4 or C 2 H 4 - S - C 3 H 6
a neighboring number of 6000 containing 5% ⁇ r are added.
months of hy ⁇ rogenomsthyisiloxane units. 9g of aliylphcsphonat ⁇ d ⁇ diethyl ⁇ t spinach ⁇ s drops d ⁇ reactive d ⁇ SPEIER. , ⁇ 2 PtCl 6 in isopropanol).
the mixture is brought to reflux for approximately four hours, that is to say until the mixture takes on the black color.
67 g of oily product are collected, the absence of SiH bond being checked for ⁇ n LR and ⁇ n NMR.
Dissolved in THF the product is treated with isomian bromotrim ⁇ th, then with methanol.
the final product is phosphonic acid dosed with sodium hydroxide and its equivalent weight is d ⁇ 850.
FOMBLIN Z which is a polyether perfluoride of molar mass 2700 dissolved in 200 ml of 112 trichiorotrifiuoroethanes, a solution of allyl bromide (5 g) in THF (10 ml) is added. Then, drop by drop, 10 ml of THF containing 2 g of solder are added. The mixture is refluxed for 10 hours and, after neutralization and washed with water, the solvents are evaporated off to collect approximately 28 g of a product soluble only in trichlorotrifluoroethane.
composition according to the invention can be applied to most metals and alloys, in particular iron alloys, steel, galvanized or galvanized steel or aluminum alloys including, for example, GALFAN® and GALVALUME®? designated here by the general term "metal products".
the compositions according to the invention can be present in liquid or pulverulent form.
organic or aqueous media acting in particular as a solvent for the film-forming fraction of the composition and as a dispersant for insoluble additives such as, for example, lubricants or solid pigments.
composition according to the invention can be applied to the metal product by immersion or by spraying, preferably electrostatically according to a continuous or discontinuous process depending on the nature of the metal product to be coated and the nature of the deformations to be carried out subsequently (forged. drawing, drawing, extrusion, cold stamping, etc.).
the thickness of the coatings obtained depends in particular on the roughness of the treated surface, on the method of application as well as on the nature and the importance of the deformation to be carried out.
the thickness of the coating obtained using the composition according to the invention ranges from 4 to 15 micrometers.
the other specific products have been described previously.
Polyvinyl alcohol 1g 120 5.0
Chlorinated paraffin E5G (ICI) 54.0 Graphit ⁇ Ko (LONZA) 5.0
Triarylphosphit ⁇ (IRGAPHOS TNPP) (CIBA) 2.0
the pigments D can be made up of reactive pigments of the type known in the trade under the trade name "HEUCOPHOS” from the company HEUB ACH and which are available in: "ZC?” - orthophosphates of zinc, calcium, modified strontium “ZPA” - orthophosphates of zinc, modified aluminum
ZPO zinc orthophosphates
(D) - will also contain opacifying pigments, which can provide the final shades of coatings sought
the assembly is more particularly suitable for obtaining coatings produced by co-extrusion.
the treatments according to the invention are applied to a single work post, in a single operation, and in addition, the composition thus applied provides a coating which has a satisfactory level allowing the most restrictive mechanical treatments, including cold forging .

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Wood Science & Technology (AREA)
Lubricants (AREA)

EP00925364A 1999-04-30 2000-04-28 Zusammensetzung und verfahren zur herstellung von metallischen produkten, bestimmt um in form gebracht zu werden durch einen mechanischen vorgang der plastischen deformation Withdrawn EP1175461A1 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
FR9905554		1999-04-30
FR9905554A FR2792949B1 (fr)	1999-04-30	1999-04-30	Compose reactif non polluant pour le revetement de metaux, en vue de les proteger de la corrosion et de faciliter leur deformation mecanique
PCT/FR2000/001169 WO2000066667A1 (fr)	1999-04-30	2000-04-28	Composition et procede pour la preparation de produits metalliques destines a etre faconnes par une operation mecanique de deformation plastique

Publications (1)

Publication Number	Publication Date
EP1175461A1 true EP1175461A1 (de)	2002-01-30

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Application Number	Title	Priority Date	Filing Date
EP00925364A Withdrawn EP1175461A1 (de)	1999-04-30	2000-04-28	Zusammensetzung und verfahren zur herstellung von metallischen produkten, bestimmt um in form gebracht zu werden durch einen mechanischen vorgang der plastischen deformation

Country Status (4)

Country	Link
EP (1)	EP1175461A1 (de)
AU (1)	AU4411300A (de)
FR (1)	FR2792949B1 (de)
WO (1)	WO2000066667A1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1323147C (zh) *	2003-03-28	2007-06-27	中国科学院长春应用化学研究所	一种聚苯胺防腐脂及其制备方法
US10023944B2 (en)	2014-04-01	2018-07-17	Honda Motor Co., Ltd.	Compositions and integrated processes for advanced warm-forming of light metal alloys

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1999
- 1999-04-30 FR FR9905554A patent/FR2792949B1/fr not_active Expired - Lifetime
2000
- 2000-04-28 WO PCT/FR2000/001169 patent/WO2000066667A1/fr not_active Ceased
- 2000-04-28 EP EP00925364A patent/EP1175461A1/de not_active Withdrawn
- 2000-04-28 AU AU44113/00A patent/AU4411300A/en not_active Abandoned

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Publication number	Publication date
FR2792949B1 (fr)	2001-06-29
WO2000066667A1 (fr)	2000-11-09
AU4411300A (en)	2000-11-17
FR2792949A1 (fr)	2000-11-03

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EP1175461A1 - Zusammensetzung und verfahren zur herstellung von metallischen produkten, bestimmt um in form gebracht zu werden durch einen mechanischen vorgang der plastischen deformation - Google Patents

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