EP1303248A1 - Schminkgarnitur und verfahren für ein langhaftendes make-up - Google Patents
Schminkgarnitur und verfahren für ein langhaftendes make-upInfo
- Publication number
- EP1303248A1 EP1303248A1 EP01955395A EP01955395A EP1303248A1 EP 1303248 A1 EP1303248 A1 EP 1303248A1 EP 01955395 A EP01955395 A EP 01955395A EP 01955395 A EP01955395 A EP 01955395A EP 1303248 A1 EP1303248 A1 EP 1303248A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- adhesive material
- kit according
- temperature
- frequency
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
Definitions
- the subject of the present invention is a make-up kit and a method for improving the hold and / or the 'without transfer' of a composition, in particular make-up, such as for example foundations, powders, lipsticks , mascaras and nail polishes.
- Cosmetic compositions in particular makeup compositions such as lipsticks, foundations, body makeup products, concealers, eyeshadows or powders, generally comprise fatty substances such as oils and / or waxes, and a particulate phase generally composed of fillers and pigments. They can thus be in the form of an anhydrous gel, in the form of a stick or stick or in the form of flexible paste, such as for example certain foundations, eyeshadows or lipsticks. They can also be in the form of a powder, which can for example be free, compacted or pressed.
- the makeup compositions may also comprise water or a hydrophilic phase, and then be in particular in the form of an oil-in-water, water-in-oil emulsion, multiple emulsion, in particular when it is a question of a foundation, tinted cream, skincare cream or sunscreen.
- Nail varnishes are generally in the form of a solution of an organic solvent.
- compositions when applied to the skin, the mucous membranes or the semi-mucous membranes, do not always exhibit good resistance. It has in fact been found that certain compositions tend to propagate inside fine lines and / or wrinkles of the skin, in the case of foundations; in the fine lines that surround the lips, in the case of lipsticks; in the folds of the eyelid, in the case of eyeshadows. It has also been observed, in the case in particular of the eyeshadows, the appearance of streaks in the makeup, generated by the movements of the eyelids. Likewise, over time, the original color may change. In the case of nail polish, it happens that the product crackles, flakes or does not resist friction.
- certain makeup products can have the drawback of transferring. By this is meant that the composition is capable of being deposited, at least in part, on certain supports with which it is brought into contact, such as, for example, a glass, a garment or the skin.
- said composition leaves a trace on said support. It follows therefore a poor persistence of the composition on the skin or mucous membranes, hence the need to regularly renew its application.
- the present invention relates to a care or makeup kit comprising at least two cosmetic compositions A and B, characterized in that:
- composition A comprises at least one adhesive material meeting the following conditions:
- - G '(35 ° C) is the elastic shear modulus of said adhesive material, measured at the temperature of 35 ° C, for any frequency between 2 10 "2 and 2 Hz,
- the present invention also relates to a process for improving the properties of holding and without transfer of a cosmetic composition A or B consisting in applying to the skin and / or the mucous membranes and / or the semi-mucous membranes and / or the integuments successively and in random order the two compositions A and B, at least one of the two compositions A or B comprising at least one adhesive material meeting the following conditions:
- - G '(35 ° C) is the elastic shear modulus of said adhesive material, measured at the temperature of 35 ° C, for any frequency between 2 10 "2 and 2 Hz,
- the make-up or care product obtained on the skin or the integuments according to the above process has the advantage of having excellent hold and of transferring very little, if at all, while retaining its comfort and hydration.
- the composition according to the invention is a nail varnish, it does not flake, does not crumble, does not crack and resists friction.
- compositions according to the invention When the compositions according to the invention are applied to the skin, they make it possible inter alia to obtain makeup products having a slightly tacky texture, which remain comfortable to wear throughout the day.
- their cosmetic properties are very interesting: they provide great softness in the end and a unifying and comfortable makeup.
- the kit according to the invention finds in particular a particularly advantageous application in the field of care and / or make-up of the skin, mucous membranes, semi-mucous membranes, and integuments.
- the term “mucous membrane” is understood to mean in particular the internal part of the lower eyelid; among the semi-mucous membranes, we mean more particularly the lips of the face; by integuments is meant the eyelashes, eyebrows, hair and nails.
- the invention finds a very particular application in the field of care and / or makeup products for the lips, face and skin, such as foundations, concealers, eyeshadows, powders, body makeup products, lipsticks, self-tanners or sunscreens, mascaras and nail polishes.
- composition A according to the invention comprises at least one adhesive material, meeting the following conditions:
- - G '(35 ° C) is the elastic shear modulus of said adhesive material, measured at the temperature of 35 ° C, for any frequency between 2 10 "2 and 2 Hz,
- the term “material” means a polymer or a polymer system which may comprise one or more polymers of different natures. This adhesive material must have a certain tackiness defined by its viscoelastic properties.
- the viscous module which represents the viscous behavior of the material for a given frequency and which is conventionally denoted G ".
- the adhesive materials which can be used according to the present invention have viscoelastic properties which are measured at a reference temperature of 35 ° C. and within a certain frequency range.
- the elastic modulus of the material is measured at three different frequencies:
- the adhesive material also meets the following condition:
- the adhesive materials according to the invention meet the following four conditions:
- the adhesive materials according to the invention can be chosen from the “Pressure Sensitive Adhesives” type adhesives for example, such as those mentioned in the “Handbook of Pressure Sensitive Adhesive Technology” 3 rd edition, D. Satas .
- the pro-adhesive materials according to the invention are preferably adhesive polymers chosen from block or random copolymers comprising at least one monomer or a combination of monomers in which the resulting polymer has a glass transition temperature below room temperature (25 ° C), these monomers or combinations of monomers which can be chosen from butadiene, ethylene, propylene, isoprene, isobutylene, a silicone, and mixtures thereof.
- pro-adhesive materials are block polymers of the styrene-butadiene-styrene, styrene- (ethylene-butylene) -styrene, styrene-isoprene-styrene type, such as those sold under the trade name "Kraton” of Shell Chemical Co. or "Vector From Exxon.
- the pro-adhesive materials according to the invention are preferably adhesive polymers chosen from:
- the adhesive materials are chosen from polyisobutylenes having a relative molar mass Mv greater than or equal to 10,000 and less than or equal to 150,000. More preferably, this relative molar mass is greater than or equal to 18,000 and less than or equal to 150,000.
- the relative molar mass Mv can also be evaluated by GPC (Gel Permission Chromatography) according to the following protocol: 200 ⁇ l of a solution of polymer (adhesive material) at 0.5% is injected using a “Waters” type pump. 6000 A ”, the eluent being a 100% THF solution, flow rate 1 ml / min, at room temperature, through a set of 8 columns: ⁇ styragel 500 ⁇ + 10 4 A + 2x10 3 ⁇ + styragel HR0.5 + 2xHR1 + HR5E (300 x 7.8mm).
- GPC Gel Permission Chromatography
- the detection is done on a “Waters 410” type refractometer and on a “Waters 490” type UV detector at the wavelength 254 nm.
- a “Waters 410” type refractometer and on a “Waters 490” type UV detector at the wavelength 254 nm.
- polyisobutylenes of respective molar masses Mv 40,000, 55,000 and 85,000 sold under the respective trade names "Oppanol B 10", “Oppanol B 12" and “Oppanol B 15 "by the company BASF, and their mixtures.
- the adhesive materials are preferably present in composition A according to the invention at a content ranging from 0.1 to 99%, preferably from 0.1 to 30%, and more preferably from 0.1 to 10% by weight , relative to the total weight of the composition.
- composition A according to the invention can comprise any cosmetically acceptable support.
- cosmetically acceptable support is meant a medium compatible with all keratin materials such as the skin, nails, hair, eyelashes and eyebrows, mucous membranes and semi-mucous membranes, and any other cutaneous area of the body. and of the face as well as any substitute for these supports such as false nails, false eyelashes and hair prostheses.
- This support can comprise any water-soluble, water-dispersible, liposoluble, or lipodispersible compound which is cosmetically acceptable and conventionally used in cosmetics.
- This support can also include any compound soluble in a volatile organic solvent, in particular when composition A according to the invention is a nail varnish.
- the support can be in the form of a pulverulent composition, of an anhydrous fatty phase (gel or solution), in the form of an aqueous phase (gel or solution), in the form of a dispersion, d '' an O / W or W / O emulsion, or of a multiple emulsion, possibly stabilized by one or more organized systems.
- organized systems is meant, within the meaning of the present invention, reverse micelles or “lyotropic liquid crystal” structures which are formed temporarily. ambient temperature by the mixture of several surfactants or the mixture of surfactants and polar solvents or the mixture of several polar solvents, the polar solvents being for example chosen from water, glycerol, panthenol, propylene glycol , butylene glycol and / or mixtures thereof.
- the liquid crystalline state is an intermediate state between the solid state and the liquid state. It is often called a mesomorphic state.
- Composition A can thus be a makeup composition. It can then be in the form of a makeup product for the face or the skin, in particular the body, a foundation, a concealer, a mascara, an eyeliner, blush, face powder, blush or eyeshadow or lip makeup like lipstick or nail polish.
- Composition A can also be in the form of a dermatological or skin care composition, a basic makeup composition or also in the form of a sun protection composition. It can then optionally include cosmetic or dermatological active ingredients. It can also be used as a care base for the skin or the lips (lip balms, protecting the lips from the cold and / or from the sun and / or wind).
- the adhesive material according to the invention can be found within the support of composition A in the dissolved form or in the dispersed form, in an aqueous phase or in an anhydrous phase.
- the adhesive material according to the invention can thus be in the form of an aqueous dispersion of particles or in the form of an oily dispersion of particles.
- composition A according to the invention can comprise a fatty phase.
- This fatty phase may preferably comprise at least one cosmetically or physiologically acceptable oil, in particular chosen from oils of mineral, animal, vegetable or synthetic origin, carbonaceous, hydrocarbon bonées and / or silicone, alone and their mixtures, insofar as they are compatible with the intended use.
- the fatty phase can thus comprise at least one oil chosen from polyisobutylenes with a relative molar mass Mv of less than or equal to 10,000 such as polyisobutylene with molar mass 455 to 2000 sold under the trade name "Napvis” by the company BP Chemicals or polyisobutylene sold under the name "Parleam” by Ets B. Rossow et Cie.
- hydrocarbon oils such as paraffin oil or petrolatum oil, mink oil, turtle oil, soybean oil, perhydrosqualene, sweet almond oil, calophyllum oil, palm oil, grapes, sesame, corn, parlam, arara, rapeseed, sunflower, cotton, apricot, castor, avocado, jojoba, olive or cereal sprouts; esters of lanolic acid, oleic acid, lauric acid, stearic acid; fatty esters, such as isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, diisopropyl adipate, isononyl isononanoate, 2-ethyl-hexyl palmitate , 2-hexyl-decyl laurate, 2-octyl-decyl palmitate, 2-octyl-dodecyl myristate or lactate,
- hydrocarbon oils such
- At least one volatile oil can be used at room temperature.
- volatile oil is meant an oil capable of evaporating from the skin, at room temperature in less than an hour.
- the volatile oil has a viscosity ranging from 0.5 to 25 centistokes at 25 ° C. After evaporation of these oils, a deposit of particles is obtained, which does not stick to the skin or the mucous membranes.
- oils are used whose flash point is high enough to allow the use of these oils in formulation. These volatile oils also facilitate the application of the composition to the skin.
- oils can be hydrocarbon oils, silicone oils optionally comprising alkyl or alkoxy groups at the end of the silicone or pendant chain.
- volatile silicone oil which can be used in the invention, mention may be made of linear or cyclic silicones having from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups having from 1 to 10 carbon atoms. Mention may in particular be made of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexadecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane and / or their mixtures.
- C 8 -C 16 isoparaffins such as isododecane, isodecane, heptane, isohexadecane and / or mixtures thereof.
- composition A may be present in composition A according to the invention at a content ranging from 0.1 to 99% by weight, preferably from 0.1 to 60%, and more preferably from 0.1 to 40% , relative to the total weight of the composition.
- the weight ratio of volatile oil to the adhesive material according to the invention ranges from 1 to 20, more preferably from 1 to 10, and better still from 2 to 4.
- the fatty phase can also comprise at least one wax, at least one gum and / or at least one pasty fatty substance, of vegetable, animal, mineral or synthetic origin, or even silicone, and their mixtures.
- waxes solid at room temperature which may be present in the composition according to the invention, mention may be made of hydrocarbon waxes such as beeswax, Camauba, Candellila, Ouricoury, Japanese wax, cork or sugar cane fiber waxes, paraffin waxes, lignite waxes, microcrystalline waxes, lanolin wax, Montan wax, ozokerites, polyethylene waxes, waxes obtained by Fischer synthesis Tropsch, hydrogenated oils, fatty esters and concrete glycerides at 25 ° C. It is also possible to use silicone waxes, among which mention may be made of alkyl, alkoxy and / or polymethylsiloxane esters.
- hydrocarbon waxes such as beeswax, Camauba, Candellila, Ouricoury, Japanese wax, cork or sugar cane fiber waxes, paraffin waxes, lignite waxes, microcrystalline waxes, lanolin wax, Montan wax, ozokerites, polyethylene wax
- the waxes can be in the form of stable dispersions of colloidal particles of wax as they can be prepared according to known methods, such as those of "Microemulsions Theory and Practice", LM Prince Ed., Académie Press (1977) , pages 21-32.
- Menesojoba oil As liquid wax at room temperature, mention may be made of Jojoba oil.
- the waxes can be present in an amount of 0.1 to 30%, by weight, relative to the total weight of the composition.
- the pasty fatty compounds can be defined using at least one of the following physicochemical properties:
- the fatty phase may comprise polymers chosen from polyisobutylenes of relative molar mass greater than 150,000, such as, for example, polyisobutylenes of respective molar masses Mv 200,000, 400,000 and 1,110,000 sold under the respective trade names "Oppanol B 30 SF", “Oppanol B 50 SF” and “Oppanol B 100" by BASF, polyisobutylenes with relative molecular weights Mv between 900,000 and 2,200,000 sold under the trade name "Vistanex MM" by the company Exxon, and their mixtures.
- polyisobutylenes of relative molar mass greater than 150,000 such as, for example, polyisobutylenes of respective molar masses Mv 200,000, 400,000 and 1,110,000 sold under the respective trade names "Oppanol B 30 SF", “Oppanol B 50 SF” and "Oppanol B 100" by BASF, polyisobutylenes with relative molecular weights
- compositions of the invention can also comprise at least one alkyl, alkoxy or phenyl-dimethicone such as, for example the product sold under the name of "Abil wax 2440" by the company GOLDSCHMIDT.
- compositions according to the invention can also comprise at least one silicone resin comprising a combination of the units R 3 Si0 1/2 , R 2 Si0 2/2 , RSi0 3/2 and Si0 4/2 , in which R denotes a radical alkyl having from 1 to 6 carbon atoms.
- the fatty phase can also contain at least one liposoluble dye.
- This fat-soluble dye is for example Sudan red, DC Red 17, DC Green 6, ⁇ -carotene, soybean oil, Sudan brown, DC Yellow, 11, DC Violet 2, DC orange 5 , quinoline yellow, and mixtures thereof. It can represent from 0.01 to 20% of the total weight of the composition and better still from 0.1 to 6%.
- the fatty phase may represent from 0.1 to 99%, preferably from 0.1 to 80%, by weight, relative to the total weight of the final composition.
- the support for composition A according to the invention can comprise at least one organic solvent phase, in particular when the composition is a nail varnish.
- organic solvent which can be used in the invention, there may be mentioned: - ketones which are liquid at room temperature such as methyl ethyl ketone, methyl sobutyl ketone, diisobutyl ketone, isophorone, cyclohexanone, acetone; - Alcohols liquid at room temperature such as ethanol, isopropanol, diacetone alcohol, 2-butoxyethanol, cyclohexanol;
- glycols which are liquid at room temperature such as ethylene glycol, propylene glycol, pentylene glycol, glycerol;
- propylene glycol ethers that are liquid at room temperature such as propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, dipropylene glycol mono n-butyl ether;
- esters having 3 to 8 carbon atoms in total
- ethyl acetate methyl acetate
- propyl acetate propyl acetate
- n-butyl acetate acetate isopentyl
- - ethers liquid at room temperature such as diethyl ether, dimethyl ether or dichlorodiethyl ether;
- alkanes which are liquid at room temperature such as decane, heptane, dodane, cyclohexane;
- aldehydes liquid at room temperature such as benzaldehyde, acetaldehyde
- the organic solvent may be present in the composition of the invention at a content ranging from 0.01 to 99% by weight, preferably from 50 to 99% by weight for a nail varnish application, relative to the total weight of the composition.
- composition A according to the invention can comprise an aqueous phase.
- This aqueous phase can comprise water, floral water such as blueberry water and / or mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or thermal water.
- the aqueous phase can also include solvents other than water, for example primary alcohols such as ethanol and isopropanol, glycols such as propylene glycol, butylene glycol, dipropylene glycol, diethylene glycol, glycol ethers such as alkyl (C ⁇ -C-4) mono, di- or tripropylene glycol, mono, di- or triethylene glycol ether, and mixtures thereof.
- solvents other than water for example primary alcohols such as ethanol and isopropanol, glycols such as propylene glycol, butylene glycol, dipropylene glycol, diethylene glycol, glycol ethers such as alkyl (C ⁇ -C-4) mono, di- or tripropylene glycol, mono, di- or triethylene glycol ether, and mixtures thereof.
- the aqueous phase can also comprise water-soluble dyes chosen from the usual dyes of the field under consideration such as the disodium salt of culvert, the disodium salt of alizarin green, quinoline yellow, the trisodium salt of amaranth, the salt disodium tartrazine, monosodium salt of rhodamine, disodium salt of fuchsin, xanthophyly.
- water-soluble dyes chosen from the usual dyes of the field under consideration such as the disodium salt of culvert, the disodium salt of alizarin green, quinoline yellow, the trisodium salt of amaranth, the salt disodium tartrazine, monosodium salt of rhodamine, disodium salt of fuchsin, xanthophyly.
- the aqueous phase can also comprise any compound compatible with an aqueous phase such as gelling agents, film-forming polymers, thickeners, surfactants, preservatives, pigment dispersions and their mixtures.
- the aqueous phase may consist essentially of water or of a hydroalcoholic mixture comprising in particular C1-C5 monoalcohols or C2-C8 glycols.
- the aqueous phase is present in the compositions of the invention at a content ranging from 0.1 to 99%, by weight, relative to the total weight of the composition.
- composition A can also comprise at least one amphiphilic compound, that is to say a compound comprising both a lipophilic part (apolar part) and a hydrophilic part (polar part) and capable of being adsorbed to a surface or interface.
- amphiphilic compounds that is to say a compound comprising both a lipophilic part (apolar part) and a hydrophilic part (polar part) and capable of being adsorbed to a surface or interface.
- amphiphilic compound that is to say a compound comprising both a lipophilic part (apolar part) and a hydrophilic part (polar part) and capable of being adsorbed to a surface or interface.
- Such compounds are, for example, emulsifiers and co-emulsifiers.
- the emulsifiers and coemulsifiers used in composition A when it is in the form of an emulsion are chosen from those conventionally used in the cosmetic and dermatological fields.
- the emulsifier and the coemulsifier may be present in the composition in a proportion ranging from preferably from 0.3 to 30% by weight, and better still from 0.5 to 20% by weight relative to the total weight of the composition.
- CTFA cetearyl glucoside
- PEG-40 stearate cetearyl glucoside
- sorbitan tristearate sorbitan stearate
- polysorbate 60 sorbitan stearate / sucrose cocoate mixture
- glyceryl stearate mixture / PEG-100 stearate
- PEG-400 glyceryl stearate
- the mixture of PEG-6 / PEG-32 / glycol stearate the mixture of PEG-6 / PEG-32 / glycol stearate.
- W / O surfactant mention may in particular be made of the 4-polyglyceryl-isostearate / cetyldimethicone copolyol / hexyl laurate mixture and the mineral oil / petrolatum / ozokerite / glyceryl oleate / lanolin alcohol mixture.
- the support for composition A according to the invention can also comprise at least one pulverulent compound.
- the pulverulent compounds can be chosen from pigments and / or nacres and / or fillers and / or their mixtures usually used in cosmetic compositions.
- the pulverulent compounds are present in a content ranging from 0.1 to 99.9%, preferably from 60 to 99.9%, more preferably from 80 to 99.9% by weight, relative to the total weight of the composition.
- the pigments can be white or colored, mineral and / or organic.
- mineral pigments mention may be made of titanium dioxide, optionally surface-treated, zirconium or cerium oxides . m, as well as iron or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue.
- organic pigments there may be mentioned carbon black, pigments of the D & C type, and lakes based on cochineal carmine, barium, strontium, calcium, aluminum.
- the pearlescent pigments can be chosen from white pearlescent pigments such as mica coated with titanium or bismuth oxychloride, colored pearlescent pigments such as mica titanium with iron oxides, mica titanium with especially ferric blue or chromium oxide, titanium mica with a gold pigment ganic of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride.
- the fillers can be mineral or organic, lamellar or spherical. Mention may be made of talc, mica, silica, kaolin, nylon powders (Orgasol from Atochem or Nylon 12), poly- ⁇ -alanine and polyethylene, Teflon, bismuth oxychloride, lauroyl-lysine, starch, boron nitride, powders of tetrafluoroethylene polymers, hollow microspheres such as Expancel (Nobel Industry), polytrap (Dow Corning) and microbeads of silicone resin (Tospearis from Toshiba, for example), precipitated calcium carbonate, magnesium carbonate and hydro-carbonate, hydroxyapatite, hollow silica microspheres (SILICA BEADS from MAPRECOS), glass or ceramic microcapsules, metallic soaps derivatives of organic carboxylic acids having from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate,
- the support of composition A can also contain at least one adjuvant customary in the cosmetic or dermatological field, such as hydrophilic or lipophilic gelling agents, thickeners, hydrophilic or lipophilic additives, preservatives, antioxidants, solvents , perfumes, sun filters, active ingredients, odor absorbers and coloring matters.
- adjuvants customary in the cosmetic or dermatological field, such as hydrophilic or lipophilic gelling agents, thickeners, hydrophilic or lipophilic additives, preservatives, antioxidants, solvents , perfumes, sun filters, active ingredients, odor absorbers and coloring matters.
- the amounts of these various adjuvants are those conventionally used in these fields, and for example from 0.01 to 10% of the total weight of the composition.
- These adjuvants depending on their nature, can be introduced into the fatty phase, into the organic phase, into the aqueous phase and / or into organized systems.
- hydrophilic gelling agents which can be used in the invention, mention may be made of carboxyvinyl polymers (carbomer), acrylic copolymers such as acrylate / alkylacrylate copolymers, polyacrylamides, polysaccharides such as hydroxypropylcellulose, natural gums and clays like laponi- tes, associative thickeners such as associative polyurethanes, and, as lipophilic gelling agents, mention may be made of modified clays such as bentones, metal salts of fatty acids such as aluminum stearates.
- moisturizers As cosmetic, dermatological and hygienic active agents which can be used in the composition of the invention, mention may be made of moisturizers, antioxidants, vitamins, essential fatty acids, sphingolipids. Mention may be made, for example, of polyols such as glycerin, glycols and sugar derivatives, enzymes, vitamins such as vitamin C (ascorbic acid), vitamin A (retinol), vitamin D, vitamin E (tocopherol), vitamin K and derivatives of these vitamins such as esters, ceramides, depigmentants such as kojic acid and caffeic acid, beta-hydroxy acids such as salicylic acid and its derivatives, alpha-hydroxy acids such as lactic acid and glycolic acid, moisturizers such as protein hydrolysates, softeners such as allantoin and mixtures thereof.
- polyols such as glycerin, glycols and sugar derivatives, enzymes, vitamins such as vitamin C (ascorbic acid), vitamin A (retinol), vitamin D
- These active agents can be present in an amount of 0.001 to 20% by weight of the total weight of the composition.
- Composition A may be in all dosage forms for topical use normally used and may in particular be in the form of an oily suspension or dispersion, of a solution containing a volatile solvent (varnish), of emulsions obtained by dispersion of a fatty phase in a aqueous phase (O / W) or vice versa (W / O), triple emulsions (W / O / W or O / W / O) or vesicular dispersions of ionic and / or nonionic type, anhydrous gel , free, compact or pressed powders.
- composition A is in the form of a W / O, O / W, or multiple emulsion, or a gel and is a base makeup composition.
- Composition B according to the invention is a conventional cosmetic composition comprising at least one cosmetically acceptable support as defined above for composition A. It may optionally also include an adhesive material as defined above.
- compositions B according to the invention are preferably compositions for making up the skin, semi-mucous membranes, mucous membranes and / or integuments, and are then for example in the form of a foundation, a blush or eyeshadow, concealer, body makeup, powder, lipstick, mascara, eyeliner, or nail polish nails. They can be presented in all the classic forms of makeup compositions such as sticks, sticks, flexible pastes, creams, fluids, free, compact or pressed powders.
- compositions A and B are prepared according to the usual methods known to those skilled in the art. They come in the form of a makeup or care kit.
- one of the two compositions A or B is applied to the skin and / or the mucous membranes and / or the semi-mucous membranes and / or the integuments. Then the second composition is applied over the first one.
- the makeup product obtained on the skin by this process has remarkable hold and transfer properties.
- Example 1 the amounts are given as a percentage by weight relative to the total weight of the composition.
- the Applicant has produced the following cosmetic base A in the form of a W / O emulsion:
- Composition A A:
- Phase A was first prepared by mixing. Then phase B1 was added with stirring while heating. Phase B2 is added after having previously dissolved the polyisobutylene in the isododecane while heating. This results in an oily phase which is heated for 5 min at 80 ° C. This mixture is cooled to 20 ° C. All the compounds of phase C are mixed and then heated until the preservative dissolves. Then, phase C is cooled to 20 ° C and then added slowly to the mixture A + B1 + B2.
- composition B This composition is a powder for the face.
- Composition B1 is a composition of Composition B1:
- composition A is applied, for example to the face of a person.
- composition B is then applied.
- the product obtained exhibits remarkable hold and transfers very little.
- the Applicant has produced the following cosmetic base A in the form of a solution:
- Composition A A:
- composition B which is a nail varnish.
- Composition B is a composition of Composition B:
- the composition was prepared by simple mixing of the different compounds.
- composition A base
- composition B varnish
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0009216 | 2000-07-13 | ||
| FR0009216A FR2811546B1 (fr) | 2000-07-13 | 2000-07-13 | Kit et procede de maquillage longue tenue |
| PCT/FR2001/002222 WO2002005762A1 (fr) | 2000-07-13 | 2001-07-10 | Kit et procede de maquillage longue tenue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1303248A1 true EP1303248A1 (de) | 2003-04-23 |
Family
ID=8852480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01955395A Withdrawn EP1303248A1 (de) | 2000-07-13 | 2001-07-10 | Schminkgarnitur und verfahren für ein langhaftendes make-up |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20040052745A1 (de) |
| EP (1) | EP1303248A1 (de) |
| JP (1) | JP2004503574A (de) |
| FR (1) | FR2811546B1 (de) |
| WO (1) | WO2002005762A1 (de) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2811547B1 (fr) * | 2000-07-13 | 2003-09-26 | Oreal | Composition cosmetique longue tenue comprenant un materiau pro-adhesif particulier |
| WO2003061611A2 (fr) * | 2002-01-18 | 2003-07-31 | L'oreal | Composition cosmetique longue tenue comprenant un materiau pro-adhesif et un compose diffusant separes |
| FR2834884B1 (fr) * | 2002-01-18 | 2004-10-22 | Oreal | Composition cosmetique longue tenue comprenant un materiau pro-adhesif et un compose diffusant separes |
| US20040086474A1 (en) * | 2002-06-17 | 2004-05-06 | The Procter & Gamble Company | Multi-step cosmetic benefit foundation kit and associated methods |
| US20040086473A1 (en) * | 2002-06-17 | 2004-05-06 | The Procter & Gamble Company | Multi-step sebum and perspiration absorption foundation kit and associated methods |
| MXPA03008714A (es) | 2002-09-26 | 2004-09-10 | Oreal | Polimeros secuenciados y composiciones cosmeticas que comprenden tales polimeros. |
| US20060134051A1 (en) * | 2002-09-26 | 2006-06-22 | Xavier Blin | Glossy non-transfer composition comprising a sequenced polymer |
| US20040228819A1 (en) * | 2003-05-16 | 2004-11-18 | The Procter & Gamble Company | Cosmetic system for application as a multi-step cosmetic product |
| FR2855405B1 (fr) * | 2003-05-26 | 2006-07-14 | Oreal | Kit de maquillage ou de soin des ongles |
| FR2860142B1 (fr) * | 2003-09-26 | 2007-08-17 | Oreal | Produit cosmetique bicouche, ses utilisations et kit de maquillage contenant ce produit |
| FR2860143B1 (fr) * | 2003-09-26 | 2008-06-27 | Oreal | Composition cosmetique comprenant un polymere sequence et une huile siliconee non volatile |
| US20050074483A1 (en) * | 2003-10-06 | 2005-04-07 | Kimberly-Clark Worldwide, Inc. | Pre-packaged multi-step skin care system |
| US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
| US8728451B2 (en) | 2004-03-25 | 2014-05-20 | L'oreal | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
| FR2882926B1 (fr) * | 2005-03-10 | 2007-05-11 | Oreal | Kit comprenant une emulsion cosmetique |
| US20060275232A1 (en) * | 2005-06-01 | 2006-12-07 | L'oreal | Two-composition product, uses thereof, and makeup kit containing this product |
| JP4538377B2 (ja) * | 2005-06-03 | 2010-09-08 | マルホ株式会社 | 油中水型乳化組成物 |
| US9168216B2 (en) | 2005-06-17 | 2015-10-27 | Vital Health Sciences Pty. Ltd. | Carrier comprising one or more di and/or mono-(electron transfer agent) phosphate derivatives or complexes thereof |
| JP2008546746A (ja) * | 2005-06-22 | 2008-12-25 | ロレアル | ケラチン物質をメイクアップするための組成物 |
| KR20080082995A (ko) * | 2005-12-20 | 2008-09-12 | 로레알 | 속눈썹 상에서 함께 반응할 수 있는 실리콘 오일 및 실리콘화합물 x 또는 y 를 포함하는 키트 |
| US20070140991A1 (en) * | 2005-12-21 | 2007-06-21 | Prithwiraj Maitra | Pressure sensitive adhesives for cosmetic applications |
| US8586016B2 (en) * | 2006-03-13 | 2013-11-19 | L'oreal | Hydrocarbon complex mascara |
| US8673284B2 (en) * | 2006-05-03 | 2014-03-18 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and a selective solvent for hard blocks |
| US8673282B2 (en) * | 2006-05-03 | 2014-03-18 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and a selective solvent for soft blocks |
| US8557230B2 (en) * | 2006-05-03 | 2013-10-15 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and shine enhancing agents |
| US8673283B2 (en) * | 2006-05-03 | 2014-03-18 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and a solvent mixture |
| US8778323B2 (en) * | 2006-05-03 | 2014-07-15 | L'oréal | Cosmetic compositions containing block copolymers, tackifiers and modified silicones |
| US8758739B2 (en) * | 2006-05-03 | 2014-06-24 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and gelling agents |
| FR2904320B1 (fr) * | 2006-07-27 | 2008-09-05 | Oreal | Polymeres sequences, et leur procede de preparation |
| FR2907009A1 (fr) * | 2006-10-16 | 2008-04-18 | Oreal | Composition cosmetique |
| FR2909844B1 (fr) * | 2006-12-14 | 2009-09-11 | Oreal | Stylo a pointe feutre pour le maquillage des ongles |
| FR2910284B1 (fr) * | 2006-12-20 | 2009-04-17 | Oreal | Produit cosmetique comprenant des composes silicones et un polymere amphiphile |
| FR2910312A1 (fr) * | 2006-12-20 | 2008-06-27 | Oreal | Procede de traitement des cheveux par une silicone reactive vinylique capable de reagir par hydrosilylation |
| FR2910301B1 (fr) * | 2006-12-20 | 2009-04-03 | Oreal | Procede de traitement des fibres capillaires avec des compositions contenant des silicones reactives |
| FR2910313A1 (fr) * | 2006-12-20 | 2008-06-27 | Oreal | Obtention de coiffures structurees mettant en oeuvre une composition comprenant des composes silicones reactifs |
| FR2910314B1 (fr) * | 2006-12-20 | 2009-05-08 | Oreal | Traitement de fibres capillaires a partir d'une composition comprenant des composes silicones reactifs avant ou apres un procede de coloration |
| FR2910311B1 (fr) | 2006-12-20 | 2009-02-13 | Oreal | Composition comprenant un compose silicone et un organosilane particulier |
| FR2910303A1 (fr) | 2006-12-20 | 2008-06-27 | Oreal | Composition comprenant un compose x et un compose y dont l'un au moins est silicone et un colorant direct hydrophobe |
| FR2910345A1 (fr) * | 2006-12-20 | 2008-06-27 | Oreal | Particules coeur/ecorce a base de composes silicones |
| US8658141B2 (en) | 2007-01-12 | 2014-02-25 | L'oreal | Cosmetic composition containing a block copolymer, a tackifier, a silsesquioxane wax and/or resin |
| US20080196737A1 (en) * | 2007-02-21 | 2008-08-21 | Juliet Stewart | Method of applying cosmetics |
| KR101439854B1 (ko) | 2007-11-26 | 2014-09-17 | (주)아모레퍼시픽 | 피부 부착성과 지속성이 높은 소성 타입 메이크업 화장료조성물 및 제조 방법 |
| FR2946871B1 (fr) * | 2009-06-19 | 2013-01-04 | Oreal | Procede de maquillage des fibres keratiniques |
| FR2946870A1 (fr) * | 2009-06-19 | 2010-12-24 | Oreal | Procede de maquillage des cils |
| FR2952820B1 (fr) * | 2009-11-24 | 2015-10-30 | Oreal | Procede de traitement cosmetique |
| EP2531047B1 (de) | 2010-02-05 | 2024-11-13 | Phosphagenics Limited | Träger mit einem nichtneutralisierten tocopherylphosphat |
| KR101756885B1 (ko) * | 2010-02-05 | 2017-07-11 | 가부시키가이샤 시세이도 | 메이크업 화장료 및 그 메이크업 화장료와 탑코팅제를 포함하는 메이크업 키트 |
| ES2829386T3 (es) | 2010-03-30 | 2021-05-31 | Phosphagenics Ltd | Parche de administración transdérmica |
| US20120219516A1 (en) | 2011-02-25 | 2012-08-30 | L'oreal S.A. | Cosmetic compositions having long lasting shine |
| WO2012122586A1 (en) | 2011-03-15 | 2012-09-20 | Phosphagenics Limited | New composition |
| JP5841374B2 (ja) * | 2011-08-05 | 2016-01-13 | 株式会社 資生堂 | 水中油型乳化下地化粧料 |
| MX383940B (es) | 2015-12-09 | 2025-03-14 | Phosphagenics Ltd | Formulación farmacéutica que contiene tocol fosfato. |
| CN109843259B (zh) * | 2016-10-31 | 2022-04-26 | 株式会社资生堂 | 水包油型皮肤外用组合物 |
| IL267006B2 (en) | 2016-12-21 | 2024-11-01 | Phosphagenics Ltd | Process for phosphorylation of a complex alcohol with p4o10 at high temperatures, and products thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57169414A (en) * | 1981-04-10 | 1982-10-19 | Tokyo Eizai Kenkyusho:Kk | Skin-protecting agent |
| LU85304A1 (fr) * | 1984-04-13 | 1985-11-27 | Oreal | Composition solaire filtrante contenant du polyisobutylene et son utilisation pour la protection de l'epiderme humain contre les radiations ultraviolettes |
| US5059189A (en) * | 1987-09-08 | 1991-10-22 | E. R. Squibb & Sons, Inc. | Method of preparing adhesive dressings containing a pharmaceutically active ingredient |
| JPH0753646B2 (ja) * | 1989-01-31 | 1995-06-07 | 東レ・ダウコーニング・シリコーン株式会社 | 化粧料 |
| JPH03133916A (ja) * | 1989-10-18 | 1991-06-07 | Kao Corp | 水系美爪料 |
-
2000
- 2000-07-13 FR FR0009216A patent/FR2811546B1/fr not_active Expired - Fee Related
-
2001
- 2001-07-10 JP JP2002511696A patent/JP2004503574A/ja not_active Withdrawn
- 2001-07-10 US US10/332,774 patent/US20040052745A1/en not_active Abandoned
- 2001-07-10 EP EP01955395A patent/EP1303248A1/de not_active Withdrawn
- 2001-07-10 WO PCT/FR2001/002222 patent/WO2002005762A1/fr not_active Ceased
Non-Patent Citations (1)
| Title |
|---|
| See references of WO0205762A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2004503574A (ja) | 2004-02-05 |
| FR2811546B1 (fr) | 2003-09-26 |
| US20040052745A1 (en) | 2004-03-18 |
| WO2002005762A1 (fr) | 2002-01-24 |
| FR2811546A1 (fr) | 2002-01-18 |
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