EP2688923A4 - Branched vinyl terminated polymers and methods for production thereof - Google Patents

Branched vinyl terminated polymers and methods for production thereof

Info

Publication number
EP2688923A4
EP2688923A4 EP20120762766 EP12762766A EP2688923A4 EP 2688923 A4 EP2688923 A4 EP 2688923A4 EP 20120762766 EP20120762766 EP 20120762766 EP 12762766 A EP12762766 A EP 12762766A EP 2688923 A4 EP2688923 A4 EP 2688923A4
Authority
EP
European Patent Office
Prior art keywords
production
methods
vinyl terminated
terminated polymers
branched vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20120762766
Other languages
German (de)
French (fr)
Other versions
EP2688923A2 (en
Inventor
Peijun Jiang
Patrick Brant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to EP20120762766 priority Critical patent/EP2688923A4/en
Publication of EP2688923A2 publication Critical patent/EP2688923A2/en
Publication of EP2688923A4 publication Critical patent/EP2688923A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
EP20120762766 2011-03-25 2012-03-05 Branched vinyl terminated polymers and methods for production thereof Withdrawn EP2688923A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP20120762766 EP2688923A4 (en) 2011-03-25 2012-03-05 Branched vinyl terminated polymers and methods for production thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201161467681P 2011-03-25 2011-03-25
EP11165831 2011-05-12
EP20120762766 EP2688923A4 (en) 2011-03-25 2012-03-05 Branched vinyl terminated polymers and methods for production thereof
PCT/US2012/027675 WO2012134715A2 (en) 2011-03-25 2012-03-05 Branched vinyl terminated polymers and methods for production thereof

Publications (2)

Publication Number Publication Date
EP2688923A2 EP2688923A2 (en) 2014-01-29
EP2688923A4 true EP2688923A4 (en) 2015-05-20

Family

ID=46932222

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20120762766 Withdrawn EP2688923A4 (en) 2011-03-25 2012-03-05 Branched vinyl terminated polymers and methods for production thereof

Country Status (4)

Country Link
EP (1) EP2688923A4 (en)
JP (1) JP5793820B2 (en)
CN (1) CN103443137A (en)
WO (1) WO2012134715A2 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014189776A (en) * 2013-03-28 2014-10-06 Mitsubishi Chemicals Corp Modified propylenic polymer composition
US9249239B2 (en) 2013-07-17 2016-02-02 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
CN110845546A (en) 2013-07-17 2020-02-28 埃克森美孚化学专利公司 Substituted metallocene catalysts
EP3022236B1 (en) * 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
ES2703344T3 (en) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metallocenes and catalytic compositions derived from them
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
SG10201802959WA (en) 2013-07-17 2018-05-30 Exxonmobil Chemical Patents Inc Cyclopropyl substituted metallocene catalysts
EP3082023A4 (en) 2013-12-13 2017-08-23 LG Chem, Ltd. Touch sensor and method for manufacturing same
CN106132924B (en) * 2014-03-31 2019-03-19 埃克森美孚化学专利公司 Phenylene Bridged SALALEN Catalyst
US9988471B2 (en) 2015-12-16 2018-06-05 Exxonmobil Chemical Patents Inc Catalysts for producing polymers with enhanced properties
KR101810317B1 (en) * 2016-04-06 2017-12-19 롯데케미칼 주식회사 High melt strength polypropylene resin composition
CN111788239B (en) 2018-05-04 2023-08-18 Lg化学株式会社 Ethylene/α-olefin copolymer and its preparation method
WO2021025903A1 (en) * 2019-08-02 2021-02-11 Exxonmobil Chemical Patents Inc. Non-coordinating anion type activators for use with polyolefin polymerization catalysts
KR102898201B1 (en) * 2020-02-11 2025-12-09 엑손모빌 케미칼 패턴츠 인코포레이티드 Ethylene-alpha-olefin-diene monomer copolymer obtained using a transition metal bis(phenolate) catalyst complex and a homogeneous preparation method thereof
US12410273B2 (en) 2020-03-30 2025-09-09 Exxonmobil Chemical Patents Inc. Comb-block copolymers and methods thereof
JP7024842B2 (en) * 2020-10-16 2022-02-24 日本ポリプロ株式会社 Propene homopolymer

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
US20030050411A1 (en) * 2001-06-12 2003-03-13 Dow Global Technologies Inc. Use of polar monomers in olefin polymerization and polymers thereof
US20040127649A1 (en) * 2002-10-24 2004-07-01 Palanisamy Arjunan Branched crystalline polypropylene
US20090318646A1 (en) * 2008-06-20 2009-12-24 Patrick Brant Functionalized High Vinyl Terminated Propylene Based Oligomers
US7700707B2 (en) * 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US20100152388A1 (en) * 2005-06-22 2010-06-17 Peijun Jiang In-Reactor Polymer Blends
WO2010074815A1 (en) * 2008-12-15 2010-07-01 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions
EP2261292A2 (en) * 2002-10-15 2010-12-15 ExxonMobil Chemical Patents Inc. Polyolefin adhesive compositions

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3772331D1 (en) 1986-11-13 1991-09-26 Idemitsu Kosan Co METHOD FOR OLIGOMERIZING PROPEN.
US6197910B1 (en) * 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
EP1209173A4 (en) * 1999-07-26 2003-04-16 Idemitsu Petrochemical Co BRANCHED OLEFINIC MACROMONOMER, GRAFTED OLEFINIC COPOLYMER, AND COMPOSITION OF AN OLEFINIC RESIN
CN100588663C (en) * 2002-10-15 2010-02-10 埃克森美孚化学专利公司 Multi-catalyst system for olefin polymerization and polymers produced therefrom
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
JP5286154B2 (en) * 2008-05-13 2013-09-11 日本ポリプロ株式会社 Propylene polymer
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US7799879B2 (en) * 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
US20030050411A1 (en) * 2001-06-12 2003-03-13 Dow Global Technologies Inc. Use of polar monomers in olefin polymerization and polymers thereof
US7700707B2 (en) * 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
EP2261292A2 (en) * 2002-10-15 2010-12-15 ExxonMobil Chemical Patents Inc. Polyolefin adhesive compositions
US20040127649A1 (en) * 2002-10-24 2004-07-01 Palanisamy Arjunan Branched crystalline polypropylene
US20100152388A1 (en) * 2005-06-22 2010-06-17 Peijun Jiang In-Reactor Polymer Blends
US20090318646A1 (en) * 2008-06-20 2009-12-24 Patrick Brant Functionalized High Vinyl Terminated Propylene Based Oligomers
WO2010074815A1 (en) * 2008-12-15 2010-07-01 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
RESCONI L ET AL: "CHAIN TRANSFER REACTIONS IN PROPYLENE POLYMERIZATION WITH ZIRCONOCENE CATALYSTS", TOPICS IN CATALYSIS, BALTZER SCIENCE PUBLISHERS, BUSSUM, NL, vol. 7, 1 March 1999 (1999-03-01), pages 145 - 163, XP001027865, ISSN: 1022-5528, DOI: 10.1023/A:1019115801193 *
See also references of WO2012134715A2 *
WEIQING WENG ET AL: "Long Chain Branched Isotactic Polypropylene", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, US, vol. 35, no. 10, 7 May 2002 (2002-05-07), pages 3838 - 3843, XP002668104, ISSN: 0024-9297, [retrieved on 20020416], DOI: 10.1021/MA020050J *
WEIQING WENG ET AL: "Synthesis of vinyl-terminated isotactic poly(propylene)", MACROMOLECULAR RAPID COMMUNICATIONS, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 21, 1 January 2000 (2000-01-01), pages 1103 - 1107, XP002667876, ISSN: 1022-1336 *

Also Published As

Publication number Publication date
WO2012134715A2 (en) 2012-10-04
EP2688923A2 (en) 2014-01-29
JP5793820B2 (en) 2015-10-14
JP2014508848A (en) 2014-04-10
WO2012134715A3 (en) 2013-01-17
CN103443137A (en) 2013-12-11

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