EP2797869A4 - PREPARATION OF alpha,beta-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES - Google Patents

PREPARATION OF alpha,beta-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES

Info

Publication number
EP2797869A4
EP2797869A4 EP12861287.6A EP12861287A EP2797869A4 EP 2797869 A4 EP2797869 A4 EP 2797869A4 EP 12861287 A EP12861287 A EP 12861287A EP 2797869 A4 EP2797869 A4 EP 2797869A4
Authority
EP
European Patent Office
Prior art keywords
alkenes
beta
alpha
preparation
ethylenically unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12861287.6A
Other languages
German (de)
French (fr)
Other versions
EP2797869A1 (en
Inventor
Michael Limbach
Ronald Lindner
Michael Ludwik Lejkowski
Takeharu Kageyama
Gabriella Eva Bodizs
Stephan Schunk
Cornelia Futter
Jörg Rother
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP12861287.6A priority Critical patent/EP2797869A4/en
Publication of EP2797869A1 publication Critical patent/EP2797869A1/en
Publication of EP2797869A4 publication Critical patent/EP2797869A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C07B41/10—Salts, halides or anhydrides of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
EP12861287.6A 2011-12-29 2012-12-27 PREPARATION OF alpha,beta-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES Withdrawn EP2797869A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12861287.6A EP2797869A4 (en) 2011-12-29 2012-12-27 PREPARATION OF alpha,beta-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11196025 2011-12-29
PCT/IB2012/057750 WO2013098772A1 (en) 2011-12-29 2012-12-27 PREPARATION OF α,β-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES
EP12861287.6A EP2797869A4 (en) 2011-12-29 2012-12-27 PREPARATION OF alpha,beta-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES

Publications (2)

Publication Number Publication Date
EP2797869A1 EP2797869A1 (en) 2014-11-05
EP2797869A4 true EP2797869A4 (en) 2015-08-05

Family

ID=48696433

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12861287.6A Withdrawn EP2797869A4 (en) 2011-12-29 2012-12-27 PREPARATION OF alpha,beta-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES

Country Status (6)

Country Link
EP (1) EP2797869A4 (en)
JP (1) JP6122030B2 (en)
CN (1) CN104011004B (en)
CA (1) CA2862155A1 (en)
IN (1) IN2014CN04656A (en)
WO (1) WO2013098772A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9416087B2 (en) 2014-10-08 2016-08-16 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9725393B2 (en) 2014-10-08 2017-08-08 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2861552A1 (en) 2012-06-13 2015-04-22 Basf Se Method for producing macrocyclic ketones
CN104418719B (en) * 2013-08-30 2016-04-13 中国石油化工股份有限公司 A kind of synthesis of conjugated carboxylic alkeneacid
DE102014203951A1 (en) * 2014-03-05 2015-09-10 Evonik Degussa Gmbh Synthesis of alpha, beta-unsaturated carboxylic acids (meth) acrylates from olefins
WO2015173307A1 (en) 2014-05-16 2015-11-19 Basf Se Preparing an unsaturated carboxylic acid salt from an alkene and carbon dioxide using a heterogeneous alkalinity reservoir
EP3142995B1 (en) * 2014-05-16 2018-03-21 Basf Se Process for preparing an unsaturated carboxylic acid salt using an aryloxide
WO2015173295A1 (en) * 2014-05-16 2015-11-19 Basf Se Preparing an unsaturated carboxylic acid salt from an alkene and carbon dioxide using a covalently immobilized transition metal complex
SG11201609591PA (en) * 2014-05-16 2016-12-29 Basf Se Process for preparing an unsaturated carboxylic acid salt
WO2015173296A1 (en) * 2014-05-16 2015-11-19 Basf Se Preparing an unsaturated carboxylic acid salt from an alkene and carbon dioxide using a heterogeneous base
JP6253570B2 (en) * 2014-12-15 2017-12-27 旭化成株式会社 Method for producing organic acid
JP6272791B2 (en) * 2015-02-24 2018-01-31 旭化成株式会社 Method for producing organic acid
KR20180008621A (en) 2015-05-13 2018-01-24 바스프 에스이 Preparation of unsaturated carboxylic acid salt
US10160711B2 (en) 2015-12-15 2018-12-25 Chevron Phillips Chemical Company Lp Formation of α,β-unsaturated carboxylic acids and salts thereof from metalalactones and anionic polyelectrolytes
EP3426627A1 (en) * 2016-04-06 2019-01-16 Chevron Phillips Chemical Company LP Methods for the production of , -unsaturated carboxylic acids and salts thereof
EP3442939B1 (en) 2016-04-11 2020-08-26 Basf Se Process for preparing an unsaturated carboxylic acid salt
JP6814573B2 (en) * 2016-08-26 2021-01-20 株式会社日本触媒 Method for producing unsaturated carboxylate
US10544080B2 (en) * 2017-06-14 2020-01-28 Chevron Phillips Chemical Company Lp Continuous process for the conversion of olefins and carbon dioxide to acrylates via solution phase reactor
US20180362435A1 (en) * 2017-06-14 2018-12-20 Chevron Phillips Chemical Company Lp High porosity aromatic resins as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
US10550061B2 (en) 2017-06-14 2020-02-04 Chevron Phillips Chemical Company Lp Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
CN111587246B (en) 2017-12-25 2023-05-26 Ptt全球化学公共有限公司 Catalyst composition for a process for the production of unsaturated carboxylates and derivatives thereof from carbon dioxide and olefins
WO2019188507A1 (en) * 2018-03-28 2019-10-03 積水化学工業株式会社 METHOD FOR PRODUCING α，β-UNSATURATED CARBOXYLATE
US11174213B2 (en) 2018-10-12 2021-11-16 Chevron Phillips Chemical Company, Lp Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates
CN112745210B (en) * 2019-10-30 2022-02-15 中国科学院大连化学物理研究所 A kind of method for preparing α,β-unsaturated carboxylic acid compound
WO2021185879A1 (en) * 2020-03-20 2021-09-23 Basf Se CATALYTIC PROCESS FOR PREPARING AN α,β-ETHYLENICALLY UNSATURATED CARBOXYLIC ACID SALT
CN115959987B (en) * 2022-12-16 2025-05-09 华东理工大学 Catalyst composition for preparing unsaturated carboxylate from carbon dioxide and ethylene

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011107559A2 (en) * 2010-03-03 2011-09-09 Basf Se Production of ethylenically unsaturated carboxylic acid salts by the carboxylation of alkenes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4435598A (en) * 1977-10-28 1984-03-06 National Distillers And Chemical Corporation Process for the catalytic oxidation of propylene to acrylic acid
US20090299094A1 (en) * 2005-06-13 2009-12-03 Mitsubishi Rayon Co., Ltd. Process for producing alpha, beta-unsaturated carboxylic acid

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011107559A2 (en) * 2010-03-03 2011-09-09 Basf Se Production of ethylenically unsaturated carboxylic acid salts by the carboxylation of alkenes

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
DAVID C. GRAHAM ET AL: "Production of Acrylic Acid through Nickel-Mediated Coupling of Ethylene and Carbon DioxideA DFT Study", ORGANOMETALLICS, vol. 26, no. 27, 1 December 2007 (2007-12-01), pages 6784 - 6792, XP055008539, ISSN: 0276-7333, DOI: 10.1021/om700592w *
H. HOBERG ET AL: "A l-Oxa-2-nickela-5-cyclopentanone from Ethene and Carbon Dioxide: Preparation, Structure, and Reactivity", ANGEWANDTE CHEMIE. INTERNATIONAL EDITION., vol. 26, no. 8, 1987, DEVCH VERLAG, WEINHEIM., pages 771 - 773, ISSN: 0570-0833 *
MICHAEL L. LEJKOWSKI ET AL: "The First Catalytic Synthesis of an Acrylate from CO2 and an Alkene - A Rational Approach", CHEMISTRY - A EUROPEAN JOURNAL, vol. 18, no. 44, 20 September 2012 (2012-09-20), pages 14017 - 14025, XP055131168, ISSN: 0947-6539, DOI: 10.1002/chem.201201757 *
See also references of WO2013098772A1 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9416087B2 (en) 2014-10-08 2016-08-16 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9725393B2 (en) 2014-10-08 2017-08-08 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9783478B2 (en) 2014-10-08 2017-10-10 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9896405B2 (en) 2014-10-08 2018-02-20 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US10155711B2 (en) 2014-10-08 2018-12-18 Chevron Phillips Chemical Company Lp Methods for the production of alpha, beta-unsaturated carboxylic acids and salts thereof
US10155712B2 (en) 2014-10-08 2018-12-18 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof

Also Published As

Publication number Publication date
WO2013098772A1 (en) 2013-07-04
JP2015503547A (en) 2015-02-02
EP2797869A1 (en) 2014-11-05
CN104011004A (en) 2014-08-27
CA2862155A1 (en) 2013-07-04
CN104011004B (en) 2016-04-20
JP6122030B2 (en) 2017-04-26
IN2014CN04656A (en) 2015-09-18

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