EP2822923A4 - PREPARATION OF ALPHA, BETA-UNSATURATED CARBOXYLIC ACIDS AND THEIR ESTERS - Google Patents

PREPARATION OF ALPHA, BETA-UNSATURATED CARBOXYLIC ACIDS AND THEIR ESTERS

Info

Publication number
EP2822923A4
EP2822923A4 EP13758082.5A EP13758082A EP2822923A4 EP 2822923 A4 EP2822923 A4 EP 2822923A4 EP 13758082 A EP13758082 A EP 13758082A EP 2822923 A4 EP2822923 A4 EP 2822923A4
Authority
EP
European Patent Office
Prior art keywords
beta
alpha
esters
preparation
carboxylic acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13758082.5A
Other languages
German (de)
French (fr)
Other versions
EP2822923A1 (en
Inventor
A Cenan Ozmeral
Joseph P Glas
Rajesh Dasari
Setrak Tanielyan
Ramesh Deoram Bhagat
Mohan Reddy Kasireddy
Ramnik Singh
Vijay Gnanadesikan
Robert L Augustine
Santosh More
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Myriant Corp
Original Assignee
Myriant Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Myriant Corp filed Critical Myriant Corp
Publication of EP2822923A1 publication Critical patent/EP2822923A1/en
Publication of EP2822923A4 publication Critical patent/EP2822923A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45Nanoparticles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/605Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/64Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06Washing
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP13758082.5A 2012-03-07 2013-03-06 PREPARATION OF ALPHA, BETA-UNSATURATED CARBOXYLIC ACIDS AND THEIR ESTERS Withdrawn EP2822923A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261608053P 2012-03-07 2012-03-07
US201313819035A 2013-02-26 2013-02-26
PCT/US2013/029368 WO2013134385A1 (en) 2012-03-07 2013-03-06 Preparation of alpha, beta-unsaturated carboxylic acids and esters thereof

Publications (2)

Publication Number Publication Date
EP2822923A1 EP2822923A1 (en) 2015-01-14
EP2822923A4 true EP2822923A4 (en) 2015-11-04

Family

ID=49117293

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13758082.5A Withdrawn EP2822923A4 (en) 2012-03-07 2013-03-06 PREPARATION OF ALPHA, BETA-UNSATURATED CARBOXYLIC ACIDS AND THEIR ESTERS

Country Status (7)

Country Link
EP (1) EP2822923A4 (en)
JP (1) JP2015510885A (en)
KR (1) KR20140131589A (en)
CN (1) CN104159883A (en)
CA (1) CA2866003A1 (en)
IN (1) IN2014DN07484A (en)
WO (1) WO2013134385A1 (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9452967B2 (en) * 2012-04-11 2016-09-27 The Procter & Gamble Company Process for production of acrylic acid or its derivatives
CN105705647B (en) 2013-09-03 2020-03-27 Ptt全球化学公众有限公司 Process for the production of acrylic acid, acrylonitrile and 1, 4-butanediol from 1, 3-propanediol
US9944586B2 (en) 2013-10-17 2018-04-17 Cargill, Incorporated Methods for producing alkyl hydroxyalkanoates
EP3145902B1 (en) * 2014-05-19 2018-08-15 Iowa Corn Promotion Board Process for the continuous production of ethylene glycol from carbohydrates
US10239819B2 (en) 2014-10-17 2019-03-26 Cargill, Incorporated Methods for producing an ester of an alpha, beta-unsaturated carboxylic acid
KR102336853B1 (en) * 2014-12-02 2021-12-09 아처 다니엘 미드랜드 캄파니 Process for making acrylic acid from dextrose
MY195498A (en) * 2015-06-10 2023-01-26 Ptt Global Chemical Public Co Ltd Novel method to produce acrylic acid with acetaldehyde as the main by-product
JP6694641B2 (en) * 2015-06-30 2020-05-20 国立研究開発法人産業技術総合研究所 Process for producing α, β-unsaturated carboxylic acid such as acrylic acid and its derivatives
CN106582784B (en) * 2015-10-14 2019-11-08 中国石油化工股份有限公司 Acrylate catalyst
JP6748719B2 (en) 2015-12-21 2020-09-02 ピュラック バイオケム ビー. ブイ. Method for producing acrylic acid
CN106905155B (en) * 2017-03-29 2020-04-10 万华化学集团股份有限公司 Method for generating butyl acrylate by cracking butyl acrylate heavy component
US10308568B2 (en) 2017-05-01 2019-06-04 Chevron Phillips Chemical Company Lp Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity
US11273434B2 (en) 2017-10-06 2022-03-15 The Procter & Gamble Company Regeneration method of solid catalyst
KR102474492B1 (en) * 2017-11-17 2022-12-06 푸락 바이오켐 비.브이. Method for producing methyl acrylate from methyl lactate
CN111253226B (en) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 A kind of method that catalyzes dihydroxyacetone and/or glyceraldehyde to prepare lactic acid
CN111253259B (en) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 Method for preparing lactate by catalyzing dihydroxyacetone and/or glyceraldehyde
CN111253238B (en) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 Method for preparing lactic acid
CN111253252B (en) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 Method for preparing lactate by catalyzing sugar
CN111253251B (en) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 Method for preparing lactate
CN111253239B (en) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 Method for preparing lactic acid by catalyzing methylglyoxal
CN111253248B (en) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 Method for preparing lactate by catalyzing methylglyoxal
CN111250157B (en) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 Method for preparing lactic acid by catalyzing sugar
CN111253237B (en) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 Method for preparing methylglyoxal by catalyzing sugar
CN110201716B (en) * 2019-05-21 2022-04-19 南京工业大学 An ordered mesoporous C/SiO2 supported heteropolyacid catalyst modified by an alcoholamine group and its preparation method and application
CN111905802B (en) * 2020-06-15 2022-01-18 厦门大学 Method for preparing lactate by using molybdenum-alkali metal/alkaline earth metal modified Lewis acid catalyst
CN115608406B (en) * 2021-07-13 2023-12-08 中国石油化工股份有限公司 Catalyst for synthesizing methyl methacrylate and preparation method and application thereof
CN119793523A (en) * 2023-10-10 2025-04-11 中国石油化工股份有限公司 Esterification catalyst and preparation method thereof and application in methyl methacrylate synthesis reaction

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4617405A (en) * 1984-09-25 1986-10-14 A. E. Staley Manufacturing Company Preparation of alpha, beta-unsaturated carbonyl compounds
US4729978A (en) * 1987-05-04 1988-03-08 Texaco Inc. Catalyst for dehydration of lactic acid to acrylic acid
FR2882053B1 (en) * 2005-02-15 2007-03-23 Arkema Sa METHOD FOR DEHYDRATING GLYCEROL IN ACROLENE
FR2884818B1 (en) * 2005-04-25 2007-07-13 Arkema Sa PROCESS FOR THE PREPARATION OF ACRYLIC ACID FROM GLYCEROL
FR2884817B1 (en) * 2005-04-25 2007-06-22 Arkema Sa PROCESS FOR THE PREPARATION OF ACRYLIC ACID FROM GLYCEROL
CN101352688A (en) * 2007-07-23 2009-01-28 湖南大学 Catalyst and Reaction Process of Dehydration of Lactic Acid to Acrylic Acid
WO2011033689A1 (en) * 2009-09-18 2011-03-24 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
US20130157328A1 (en) * 2010-09-07 2013-06-20 Myriant Corporation Catalytic dehydration of lactic acid and lactic acid esters

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
No further relevant documents disclosed *

Also Published As

Publication number Publication date
EP2822923A1 (en) 2015-01-14
WO2013134385A1 (en) 2013-09-12
CA2866003A1 (en) 2013-09-12
IN2014DN07484A (en) 2015-04-24
KR20140131589A (en) 2014-11-13
CN104159883A (en) 2014-11-19
JP2015510885A (en) 2015-04-13

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