EP3322529A4 - Substituted bis indenyl metallocene catalyst compounds comprising-si-si-bridge - Google Patents

Substituted bis indenyl metallocene catalyst compounds comprising-si-si-bridge Download PDF

Info

Publication number: EP3322529A4
Authority: EP; European Patent Office
Prior art keywords: bridge; metallocene catalyst; catalyst compounds; substituted bis; indenyl metallocene
Prior art date: 2015-07-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP16824842.5A

Other languages

German (de)

French (fr)

Other versions

EP3322529A1 (en

Inventor

Jian Yang

Matthew W. Holtcamp

Gregory S. DAY

Xiongdong Lian

Xuan YE

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Chemical Patents Inc

Original Assignee

ExxonMobil Chemical Patents Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2015-07-15

Filing date

2016-05-20

Publication date

2019-04-03

2016-05-20 Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc

2018-05-23 Publication of EP3322529A1 publication Critical patent/EP3322529A1/en

2019-04-03 Publication of EP3322529A4 publication Critical patent/EP3322529A4/en

Status Withdrawn legal-status Critical Current

Links

YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 title 1
150000001875 compounds Chemical class 0.000 title 1
125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 title 1
239000012968 metallocene catalyst Substances 0.000 title 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/07—Catalyst support treated by an anion, e.g. Cl-, F-, SO42-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

EP16824842.5A 2015-07-15 2016-05-20 Substituted bis indenyl metallocene catalyst compounds comprising-si-si-bridge Withdrawn EP3322529A4 (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US201562192709P	2015-07-15	2015-07-15
EP15180117		2015-08-07
PCT/US2016/033583 WO2017011073A1 (en)	2015-07-15	2016-05-20	Substituted bis indenyl metallocene catalyst compounds comprising-si-si-bridge

Publications (2)

Publication Number	Publication Date
EP3322529A1 EP3322529A1 (en)	2018-05-23
EP3322529A4 true EP3322529A4 (en)	2019-04-03

Family

ID=53785544

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP16824842.5A Withdrawn EP3322529A4 (en)	2015-07-15	2016-05-20	Substituted bis indenyl metallocene catalyst compounds comprising-si-si-bridge

Country Status (4)

Country	Link
EP (1)	EP3322529A4 (en)
CN (1)	CN107847920A (en)
BR (1)	BR112018000843A2 (en)
WO (1)	WO2017011073A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US10807998B2 (en)	2017-01-13	2020-10-20	Exxonmobil Chemical Patents Inc.	Bridged bis(indenyl) transitional metal complexes, production, and use thereof
EP3710491B1 (en)	2017-11-14	2025-01-01	ExxonMobil Chemical Patents Inc.	(di)silicon bridged metallocenes that produce polyethylene broad molecular weight distribution and molecular weight
US11130827B2 (en)	2017-11-14	2021-09-28	Exxonmobil Chemical Patents Inc.	Polyethylene compositions and articles made therefrom
US10865258B2 (en)	2018-01-31	2020-12-15	Exxonmobil Chemical Patents Inc.	Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same
US10851187B2 (en)	2018-01-31	2020-12-01	Exxonmobil Chemical Patents Inc.	Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
CN110041529B (en) *	2019-04-04	2021-06-22	天津大学	A kind of butene-grafted polyethylene glycol copolymer and preparation method thereof
JP7757294B2 (en) *	2020-02-11	2025-10-21	エクソンモービルケミカルパテンツインコーポレイテッド	Ethylene-alpha olefin-diene monomer copolymers obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for their production

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6184402B1 (en) *	1998-08-03	2001-02-06	Chisso Corporation	Processes for the preparation of metallocene complexes
US6426395B1 (en) *	1998-08-03	2002-07-30	Chisso Corporation	μ-oxo-bis-metallocene complex compounds and catalysts using same for the polymerization of olefins as well as polymerization process

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BR9913221B1 (en) *	1998-08-26	2008-11-18		supported metallocene catalyst composition.
ATE300550T1 (en) *	2000-06-30	2005-08-15	Exxonmobil Chem Patents Inc	METALLOCENE COMPOUNDS WITH A BRIDGED 4-PHENYL-INDENYL LIGAND SYSTEM FOR POLYMERIZATION OF OLEFINS
US8637616B2 (en) *	2010-10-07	2014-01-28	Chevron Philips Chemical Company Lp	Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
EP2532687A3 (en) *	2011-06-10	2013-04-10	Borealis AG	Bridged Metallocene Catalysts
CN103649101A (en) *	2011-07-08	2014-03-19	博瑞立斯有限公司	catalyst
MX2014011850A (en) *	2012-04-02	2014-11-21	Chevron Phillips Chemical Co	Catalyst systems containing a bridged metallocene reference to related application.

2016
- 2016-05-20 EP EP16824842.5A patent/EP3322529A4/en not_active Withdrawn
- 2016-05-20 WO PCT/US2016/033583 patent/WO2017011073A1/en not_active Ceased
- 2016-05-20 BR BR112018000843A patent/BR112018000843A2/en not_active Application Discontinuation
- 2016-05-20 CN CN201680041437.7A patent/CN107847920A/en active Pending

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6184402B1 (en) *	1998-08-03	2001-02-06	Chisso Corporation	Processes for the preparation of metallocene complexes
US6426395B1 (en) *	1998-08-03	2002-07-30	Chisso Corporation	μ-oxo-bis-metallocene complex compounds and catalysts using same for the polymerization of olefins as well as polymerization process

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
NEDOREZOVA P M ET AL: "STEREOSPECIFIC POLYMERIZATION OF PROPYLENE ON HIGHLY EFFICIENT METALLOCENE CATALYSTS", POLYMER SCIENCE, INTERPERIODICA, BIRMINGHAM, AL, US, vol. 43, no. 4, 1 April 2001 (2001-04-01), pages 356 - 365, XP001063661, ISSN: 0965-545X *
SCHNEIDER M J ET AL: "INFLUENCE OF INDENYL LIGAND SUBSTITUTION PATTERN ON METALLOCENE-CATALYZED ETHENE COPOLYMERIZATION WITH 1-OCTENE", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, UNITED STATES, vol. 30, no. 11, 2 June 1997 (1997-06-02), pages 3164 - 3168, XP000691133, ISSN: 0024-9297, DOI: 10.1021/MA961844Z *
See also references of WO2017011073A1 *
SPALECK W ET AL: "STEREOSPECIFIC METALLOCENE CATALYSTS: SCOPE AND LIMITS OF RATIONAL CATALYST DESIGN", MACROMOLECULAR SYMPOSIA, WILEY VCH VERLAG, WEINHEIM, DE, vol. 89, 1 January 1995 (1995-01-01), pages 237 - 247, XP000509170, ISSN: 1022-1360 *
T J SPALEK: "he First Example of an Ethylene Selective Soluble Ziegler Catalyst of the Zirconocene Class", ANGEWANDTE CHEMIE, 1 January 1989 (1989-01-01), pages 1511 - 1512, XP055682571, Retrieved from the Internet <URL:https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.198915111> [retrieved on 20200402] *

Also Published As

Publication number	Publication date
EP3322529A1 (en)	2018-05-23
WO2017011073A1 (en)	2017-01-19
BR112018000843A2 (en)	2018-09-11
CN107847920A (en)	2018-03-27

Legal Events

Date	Code	Title	Description
2017-01-20	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE
2018-04-20	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
2018-04-20	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE
2018-05-23	17P	Request for examination filed	Effective date: 20180209
2018-05-23	AK	Designated contracting states	Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
2018-05-23	AX	Request for extension of the european patent	Extension state: BA ME
2018-10-24	DAV	Request for validation of the european patent (deleted)
2018-10-24	DAX	Request for extension of the european patent (deleted)
2019-04-03	A4	Supplementary search report drawn up and despatched	Effective date: 20190306
2019-04-03	RIC1	Information provided on ipc code assigned before grant	Ipc: C08F 4/659 20060101ALI20190228BHEP Ipc: C08F 210/16 20060101AFI20190228BHEP
2020-04-05	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: EXAMINATION IS IN PROGRESS
2020-05-13	17Q	First examination report despatched	Effective date: 20200408
2020-06-12	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN
2020-07-15	18W	Application withdrawn	Effective date: 20200610

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