EP3933979A4 - ACTIVE MATERIAL, MIXED ELECTRODE POSITIVE USING SUCH MATERIAL AND SOLID STATE BATTERY - Google Patents

ACTIVE MATERIAL, MIXED ELECTRODE POSITIVE USING SUCH MATERIAL AND SOLID STATE BATTERY Download PDF

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Publication number
EP3933979A4
EP3933979A4 EP20762064.2A EP20762064A EP3933979A4 EP 3933979 A4 EP3933979 A4 EP 3933979A4 EP 20762064 A EP20762064 A EP 20762064A EP 3933979 A4 EP3933979 A4 EP 3933979A4
Authority
EP
European Patent Office
Prior art keywords
solid state
state battery
electrode positive
active material
mixed electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP20762064.2A
Other languages
German (de)
French (fr)
Other versions
EP3933979C0 (en
EP3933979A1 (en
EP3933979B1 (en
Inventor
Jun Omura
Daisuke WASHIDA
Tetsuya Mitsumoto
Hitohiko Ide
Yasuo Komoda
Yasuhiro Shibata
Yasunori Tabira
Tomoyuki Maeda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Kinzoku Co Ltd
Original Assignee
Mitsui Mining and Smelting Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Mining and Smelting Co Ltd filed Critical Mitsui Mining and Smelting Co Ltd
Publication of EP3933979A1 publication Critical patent/EP3933979A1/en
Publication of EP3933979A4 publication Critical patent/EP3933979A4/en
Application granted granted Critical
Publication of EP3933979C0 publication Critical patent/EP3933979C0/en
Publication of EP3933979B1 publication Critical patent/EP3933979B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/366Composites as layered products
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562Solid materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/30Three-dimensional structures
    • C01P2002/32Three-dimensional structures spinel-type (AB2O4)
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/60Compounds characterised by their crystallite size
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/80Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/51Particles with a specific particle size distribution
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/021Physical characteristics, e.g. porosity, surface area
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
EP20762064.2A 2019-02-27 2020-02-26 Active material, positive electrode mixture using same, and solid-state battery Active EP3933979B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019034984 2019-02-27
PCT/JP2020/007578 WO2020175506A1 (en) 2019-02-27 2020-02-26 Active material, positive electrode mixture using same, and solid-state battery

Publications (4)

Publication Number Publication Date
EP3933979A1 EP3933979A1 (en) 2022-01-05
EP3933979A4 true EP3933979A4 (en) 2022-07-27
EP3933979C0 EP3933979C0 (en) 2025-04-23
EP3933979B1 EP3933979B1 (en) 2025-04-23

Family

ID=72239921

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20762064.2A Active EP3933979B1 (en) 2019-02-27 2020-02-26 Active material, positive electrode mixture using same, and solid-state battery

Country Status (6)

Country Link
US (2) US20220149354A1 (en)
EP (1) EP3933979B1 (en)
JP (1) JP6940716B2 (en)
KR (1) KR102376785B1 (en)
CN (1) CN113396495B (en)
WO (1) WO2020175506A1 (en)

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Publication number Priority date Publication date Assignee Title
US11569503B2 (en) 2016-07-20 2023-01-31 Samsung Sdi Co., Ltd. Nickel-based active material for lithium secondary battery, method of preparing the same, and lithium secondary battery including positive electrode including the nickel-based active material
US11302919B2 (en) 2016-07-20 2022-04-12 Samsung Sdi Co., Ltd. Nickel-based active material for lithium secondary battery, method of preparing the same, and lithium secondary battery including positive electrode including the nickel-based active material
KR20230016122A (en) * 2021-07-23 2023-02-01 삼성에스디아이 주식회사 Positive electrode active material for all solid state battery, method of preparing the same, and all solid state battery
JP2020140837A (en) * 2019-02-27 2020-09-03 三井金属鉱業株式会社 Active material, positive electrode mixture using it, and solid-state battery
JP2020140839A (en) * 2019-02-27 2020-09-03 三井金属鉱業株式会社 Active material, positive electrode mixture using it, and solid-state battery
KR102869518B1 (en) * 2020-02-18 2025-10-10 삼성에스디아이 주식회사 Anode and All Solid secondary battery comprising anode
CN114171723A (en) * 2020-09-11 2022-03-11 丰田自动车株式会社 Method for producing coated active material and coated active material
JP7749972B2 (en) * 2020-09-11 2025-10-07 トヨタ自動車株式会社 Method for producing coated active material and coated active material
KR102686481B1 (en) * 2020-10-29 2024-07-19 주식회사 엘지에너지솔루션 Positive electrode material for lithium secondary battery, method for preparing same and lithium secondary battery comprising same
JP7732215B2 (en) * 2021-04-09 2025-09-02 日産自動車株式会社 secondary battery
JP2023106205A (en) * 2022-01-20 2023-08-01 住友金属鉱山株式会社 Cathode active material for coated lithium secondary battery, lithium secondary battery
KR20240047138A (en) * 2022-10-04 2024-04-12 에스케이온 주식회사 Anode active material for lithium secondary battery and lithium secondary battery including the same
CN116799337B (en) * 2023-08-21 2024-01-23 深圳海辰储能控制技术有限公司 Positive plate, method for determining uniform distribution of sodium supplementing particles and energy storage device
WO2025205475A1 (en) * 2024-03-28 2025-10-02 株式会社Aescジャパン Positive electrode for lithium-ion secondary battery, lithium-ion secondary battery, and lithium-ion secondary battery module

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WO2019035418A1 (en) * 2017-08-14 2019-02-21 三井金属鉱業株式会社 Positive electrode active material for all solid state lithium secondary battery
EP3859841A1 (en) * 2018-09-27 2021-08-04 Mitsui Mining & Smelting Co., Ltd. Active material, and positive electrode mixture and solid-state battery that use said active material

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WO2019035418A1 (en) * 2017-08-14 2019-02-21 三井金属鉱業株式会社 Positive electrode active material for all solid state lithium secondary battery
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HEITJANS PAUL ET AL: "NMR and impedance studies of nanocrystalline and amorphous ion conductors: lithium niobate as a model system", FARADAY DISCUSSIONS, vol. 134, 1 January 2007 (2007-01-01), GB, pages 67 - 82, XP055931119, ISSN: 1359-6640, Retrieved from the Internet <URL:https://pubs.rsc.org/en/content/articlepdf/2007/fd/b602887j> DOI: 10.1039/B602887J *
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Also Published As

Publication number Publication date
US20230074796A1 (en) 2023-03-09
EP3933979C0 (en) 2025-04-23
JP6940716B2 (en) 2021-09-29
EP3933979A1 (en) 2022-01-05
US20220149354A1 (en) 2022-05-12
KR20210112393A (en) 2021-09-14
CN113396495B (en) 2022-06-07
WO2020175506A1 (en) 2020-09-03
KR102376785B1 (en) 2022-03-21
CN113396495A (en) 2021-09-14
JPWO2020175506A1 (en) 2021-09-13
EP3933979B1 (en) 2025-04-23

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