EP4194078A4 - MEMBRANE REACTOR - Google Patents

MEMBRANE REACTOR Download PDF

Info

Publication number
EP4194078A4
EP4194078A4 EP22820242.0A EP22820242A EP4194078A4 EP 4194078 A4 EP4194078 A4 EP 4194078A4 EP 22820242 A EP22820242 A EP 22820242A EP 4194078 A4 EP4194078 A4 EP 4194078A4
Authority
EP
European Patent Office
Prior art keywords
membrane reactor
reactor
membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP22820242.0A
Other languages
German (de)
French (fr)
Other versions
EP4194078A1 (en
Inventor
Hirofumi Kan
Atsushi Torii
Kazuki IIDA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NGK Insulators Ltd
Original Assignee
NGK Insulators Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NGK Insulators Ltd filed Critical NGK Insulators Ltd
Publication of EP4194078A1 publication Critical patent/EP4194078A1/en
Publication of EP4194078A4 publication Critical patent/EP4194078A4/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34Apparatus, reactors
    • C10G2/341Apparatus, reactors with stationary catalyst bed
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/152Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2475Membrane reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/248Reactors comprising multiple separated flow channels
    • B01J19/2485Monolithic reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/06Surface irregularities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06Tubular membrane modules
    • B01D63/066Tubular membrane modules with a porous block having membrane coated passages
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14Dynamic membranes
    • B01D69/141Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/145Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing embedded catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212Plates; Jackets; Cylinders
    • B01J2208/00238Adjusting the heat-exchange profile by adapting catalyst tubes or the distribution thereof, e.g. by using inserts in some of the tubes or adding external fins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00884Means for supporting the bed of particles, e.g. grids, bars, perforated plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/021Processes carried out in the presence of solid particles; Reactors therefor with stationary particles comprising a plurality of beds with flow of reactants in parallel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023Details

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
EP22820242.0A 2021-06-08 2022-06-08 MEMBRANE REACTOR Pending EP4194078A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2021095823 2021-06-08
PCT/JP2022/023071 WO2022260063A1 (en) 2021-06-08 2022-06-08 Membrane reactor

Publications (2)

Publication Number Publication Date
EP4194078A1 EP4194078A1 (en) 2023-06-14
EP4194078A4 true EP4194078A4 (en) 2024-09-18

Family

ID=84426068

Family Applications (1)

Application Number Title Priority Date Filing Date
EP22820242.0A Pending EP4194078A4 (en) 2021-06-08 2022-06-08 MEMBRANE REACTOR

Country Status (6)

Country Link
US (1) US20230220283A1 (en)
EP (1) EP4194078A4 (en)
JP (2) JP7500781B2 (en)
CN (1) CN116157194A (en)
AU (2) AU2022288464B2 (en)
WO (1) WO2022260063A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4477729A4 (en) * 2022-02-08 2025-08-06 Ngk Insulators Ltd REACTOR
WO2023157861A1 (en) * 2022-02-21 2023-08-24 日本碍子株式会社 Reactor
US20250065279A1 (en) * 2023-08-25 2025-02-27 Gti Energy Catalytic membrane reactor for in-situ water removal in the synthesis of valuable chemicals
WO2025249936A1 (en) * 2024-05-29 2025-12-04 한국과학기술원 Reactor

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4938522B2 (en) * 2007-03-26 2012-05-23 日本碍子株式会社 Permselective membrane reactor
JP2018008940A (en) * 2016-07-04 2018-01-18 公益財団法人地球環境産業技術研究機構 Methanol production method and methanol production apparatus

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2631244B2 (en) * 1990-10-19 1997-07-16 川崎重工業株式会社 Method and apparatus for producing hydrogen for fuel cells
CH687004A5 (en) * 1994-04-08 1996-08-30 Methanol Casale Sa Membrane reactor for the conversion of houses on gaseous precursors.
JP3599370B2 (en) * 1994-05-23 2004-12-08 日本碍子株式会社 Hydrogen production equipment
US6440895B1 (en) * 1998-07-27 2002-08-27 Battelle Memorial Institute Catalyst, method of making, and reactions using the catalyst
JP4204273B2 (en) 2002-08-09 2009-01-07 日本碍子株式会社 DDR type zeolite membrane composite and method for producing the same
JP4347129B2 (en) * 2004-04-28 2009-10-21 東京瓦斯株式会社 Reaction tube and reaction plate for hydrogen production
JP2006314876A (en) * 2005-05-11 2006-11-24 Ngk Spark Plug Co Ltd Hydrogen separator
JP2007055970A (en) * 2005-08-26 2007-03-08 Mitsui Eng & Shipbuild Co Ltd Methanol production reactor and methanol production method
JP5057684B2 (en) * 2006-03-31 2012-10-24 日本特殊陶業株式会社 Hydrogen production equipment
US7717272B2 (en) 2006-10-18 2010-05-18 Ngk Insulators, Ltd. Ceramic porous membrane and ceramic filter
JP2011116603A (en) * 2009-12-04 2011-06-16 Tokyo Gas Co Ltd Protective film for hydrogen separation membrane in cylindrical hydrogen separation type reformer and method for forming the same
JP2017149616A (en) * 2016-02-25 2017-08-31 日本碍子株式会社 Hydrogen recovery membrane reactor, hydrogen recovery system, and hydrogen recovery method
US10150721B2 (en) 2016-07-15 2018-12-11 Gas Technology Institute Catalytic membrane reactor for dimethyl ether synthesis from carbon dioxide and hydrogen
JP7076229B2 (en) 2018-03-08 2022-05-27 Jfeスチール株式会社 How to reuse carbon dioxide

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4938522B2 (en) * 2007-03-26 2012-05-23 日本碍子株式会社 Permselective membrane reactor
JP2018008940A (en) * 2016-07-04 2018-01-18 公益財団法人地球環境産業技術研究機構 Methanol production method and methanol production apparatus

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
M.R. RAHIMPOUR ET AL: "Palladium membranes applications in reaction systems for hydrogen separation and purification: A review", CHEMICAL ENGINEERING AND PROCESSING: PROCESS INTENSIFICATION, vol. 121, 1 November 2017 (2017-11-01), CH, pages 24 - 49, XP055482108, ISSN: 0255-2701, DOI: 10.1016/j.cep.2017.07.021 *
See also references of WO2022260063A1 *

Also Published As

Publication number Publication date
JP7500781B2 (en) 2024-06-17
AU2024219588A1 (en) 2024-10-03
AU2024219588B2 (en) 2026-04-02
CN116157194A (en) 2023-05-23
WO2022260063A1 (en) 2022-12-15
JPWO2022260063A1 (en) 2022-12-15
JP2024103728A (en) 2024-08-01
US20230220283A1 (en) 2023-07-13
AU2022288464A1 (en) 2023-04-13
EP4194078A1 (en) 2023-06-14
AU2022288464B2 (en) 2024-06-13

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