EP4435133A4 - Hot-rolled steel for enamelling with enamelling and firing strengthening properties and manufacturing process therefor - Google Patents

Hot-rolled steel for enamelling with enamelling and firing strengthening properties and manufacturing process therefor

Info

Publication number
EP4435133A4
EP4435133A4 EP22894826.1A EP22894826A EP4435133A4 EP 4435133 A4 EP4435133 A4 EP 4435133A4 EP 22894826 A EP22894826 A EP 22894826A EP 4435133 A4 EP4435133 A4 EP 4435133A4
Authority
EP
European Patent Office
Prior art keywords
enamelling
firing
hot
manufacturing process
rolled steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP22894826.1A
Other languages
German (de)
French (fr)
Other versions
EP4435133A1 (en
Inventor
Shuangcheng Wang
Quanshe Sun
Xiaoyong Tao
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Baoshan Iron and Steel Co Ltd
Original Assignee
Baoshan Iron and Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Baoshan Iron and Steel Co Ltd filed Critical Baoshan Iron and Steel Co Ltd
Publication of EP4435133A1 publication Critical patent/EP4435133A1/en
Publication of EP4435133A4 publication Critical patent/EP4435133A4/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/02Hardening articles or materials formed by forging or rolling, with no further heating beyond that required for the formation
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/84Controlled slow cooling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/02Modifying the physical properties of iron or steel by deformation by cold working
    • C21D7/04Modifying the physical properties of iron or steel by deformation by cold working of the surface
    • C21D7/06Modifying the physical properties of iron or steel by deformation by cold working of the surface by shot-peening or the like
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0278Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment 
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/20Ferrous alloys, e.g. steel alloys containing chromium with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • C23D5/02Coating with enamels or vitreous layers by wet methods
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
EP22894826.1A 2021-11-16 2022-11-16 Hot-rolled steel for enamelling with enamelling and firing strengthening properties and manufacturing process therefor Pending EP4435133A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202111351890.7A CN116136009B (en) 2021-11-16 2021-11-16 Hot-rolled enameling steel with enameling strengthening property and manufacturing method thereof
PCT/CN2022/132223 WO2023088294A1 (en) 2021-11-16 2022-11-16 Hot-rolled steel for enameling having enameling and firing strengthening property, and manufacturing method therefor

Publications (2)

Publication Number Publication Date
EP4435133A1 EP4435133A1 (en) 2024-09-25
EP4435133A4 true EP4435133A4 (en) 2025-07-09

Family

ID=86332502

Family Applications (1)

Application Number Title Priority Date Filing Date
EP22894826.1A Pending EP4435133A4 (en) 2021-11-16 2022-11-16 Hot-rolled steel for enamelling with enamelling and firing strengthening properties and manufacturing process therefor

Country Status (5)

Country Link
US (1) US20250003040A1 (en)
EP (1) EP4435133A4 (en)
CN (1) CN116136009B (en)
MX (1) MX2024005957A (en)
WO (1) WO2023088294A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114908285B (en) * 2021-02-09 2023-04-11 宝山钢铁股份有限公司 Low-cost hot rolled steel plate for high-temperature enameling and manufacturing method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008255445A (en) * 2007-04-06 2008-10-23 Nippon Steel Corp Cold rolled steel sheet for enamel processing and method for producing enamel processed product
CN100453678C (en) * 2005-11-16 2009-01-21 鞍钢股份有限公司 A hot-rolled double-sided enamel steel plate and its manufacturing method
US20100040872A1 (en) * 2006-09-19 2010-02-18 Hidekuni Murakami Product for enameling and enameled product
CN105316579B (en) * 2014-07-29 2017-05-24 上海梅山钢铁股份有限公司 Thin hot rolled pickled steel plate and fabrication method thereof for water heater enamel liner
CN108396235A (en) * 2017-02-05 2018-08-14 鞍钢股份有限公司 Hot-rolled thick steel plate for enamel matrix and manufacturing method thereof
CN108950423A (en) * 2017-05-27 2018-12-07 宝山钢铁股份有限公司 A kind of hot-rolled double-side enamel high-strength steel, counterenamel steel and its manufacturing method
JP6683294B1 (en) * 2018-05-17 2020-04-15 日本製鉄株式会社 Steel plate and enamel products
CN111996468A (en) * 2020-09-18 2020-11-27 山西太钢不锈钢股份有限公司 Enamel steel and preparation method and application thereof

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54134017A (en) * 1978-04-11 1979-10-18 Nippon Steel Corp Steel plate for enamelling
DE60143907D1 (en) * 2000-11-28 2011-03-03 Jfe Steel Corp COMPOSITE STRUCTURE STEEL PLATE WITH HIGH TENSILE STRENGTH, COATED COMPOSITSTRUCTURE STEEL PLATE WITH HIGH TENSILE STRENGTH AND THEIR PRODUCTION PROCESS
CN100547104C (en) * 2006-09-05 2009-10-07 宝山钢铁股份有限公司 A hot-rolled high-strength enamel steel plate and its manufacturing method
CN101812630B (en) 2009-02-25 2012-02-29 宝山钢铁股份有限公司 Hot-rolling high-strength enamel sheet for deep drawing and manufacturing method thereof
CN102181805B (en) 2011-04-07 2012-10-31 河北钢铁股份有限公司唐山分公司 A thin slab continuous casting and rolling line to produce steel plates for water heater inner tank enamel and method
CN102758137A (en) * 2011-04-25 2012-10-31 宝山钢铁股份有限公司 Alloy material, enameled steel, manufacturing method thereof, and purpose thereof
CN103540845B (en) 2013-11-07 2016-01-20 武汉钢铁(集团)公司 Yield strength is latten Glassed Steel and the manufacture method of 330MPa level
US20150267284A1 (en) * 2014-03-21 2015-09-24 Am/Ns Calvert Llc Methods for production of highly formable extra deep draw enameling steel -- product and process for manufacture thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100453678C (en) * 2005-11-16 2009-01-21 鞍钢股份有限公司 A hot-rolled double-sided enamel steel plate and its manufacturing method
US20100040872A1 (en) * 2006-09-19 2010-02-18 Hidekuni Murakami Product for enameling and enameled product
JP2008255445A (en) * 2007-04-06 2008-10-23 Nippon Steel Corp Cold rolled steel sheet for enamel processing and method for producing enamel processed product
CN105316579B (en) * 2014-07-29 2017-05-24 上海梅山钢铁股份有限公司 Thin hot rolled pickled steel plate and fabrication method thereof for water heater enamel liner
CN108396235A (en) * 2017-02-05 2018-08-14 鞍钢股份有限公司 Hot-rolled thick steel plate for enamel matrix and manufacturing method thereof
CN108950423A (en) * 2017-05-27 2018-12-07 宝山钢铁股份有限公司 A kind of hot-rolled double-side enamel high-strength steel, counterenamel steel and its manufacturing method
JP6683294B1 (en) * 2018-05-17 2020-04-15 日本製鉄株式会社 Steel plate and enamel products
CN111996468A (en) * 2020-09-18 2020-11-27 山西太钢不锈钢股份有限公司 Enamel steel and preparation method and application thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2023088294A1 *

Also Published As

Publication number Publication date
WO2023088294A1 (en) 2023-05-25
CN116136009A (en) 2023-05-19
CN116136009B (en) 2025-05-02
EP4435133A1 (en) 2024-09-25
MX2024005957A (en) 2024-08-15
US20250003040A1 (en) 2025-01-02

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Effective date: 20250605

RIC1 Information provided on ipc code assigned before grant

Ipc: C23D 5/02 20060101ALI20250602BHEP

Ipc: C22C 38/38 20060101ALI20250602BHEP

Ipc: C22C 38/32 20060101ALI20250602BHEP

Ipc: C22C 38/28 20060101ALI20250602BHEP

Ipc: C22C 38/24 20060101ALI20250602BHEP

Ipc: C22C 38/22 20060101ALI20250602BHEP

Ipc: C22C 38/20 20060101ALI20250602BHEP

Ipc: C22C 38/04 20060101ALI20250602BHEP

Ipc: C22C 38/02 20060101ALI20250602BHEP

Ipc: C21D 9/46 20060101ALI20250602BHEP

Ipc: C21D 8/02 20060101ALI20250602BHEP

Ipc: C21D 7/06 20060101ALI20250602BHEP

Ipc: C21D 6/00 20060101ALI20250602BHEP

Ipc: C21D 1/02 20060101AFI20250602BHEP