ES2059781T3 - Sintesis con alto rendimiento de piridina y/o alquilpiridina(s) a traves de condensacion de mezclas ternarias de aldehidos y/o cetonas con amoniaco. - Google Patents
Sintesis con alto rendimiento de piridina y/o alquilpiridina(s) a traves de condensacion de mezclas ternarias de aldehidos y/o cetonas con amoniaco.Info
- Publication number
- ES2059781T3 ES2059781T3 ES89311154T ES89311154T ES2059781T3 ES 2059781 T3 ES2059781 T3 ES 2059781T3 ES 89311154 T ES89311154 T ES 89311154T ES 89311154 T ES89311154 T ES 89311154T ES 2059781 T3 ES2059781 T3 ES 2059781T3
- Authority
- ES
- Spain
- Prior art keywords
- aldehydes
- ketones
- mixtures
- pyridine
- ternarian
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 150000001299 aldehydes Chemical class 0.000 title abstract 3
- 150000002576 ketones Chemical class 0.000 title abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title 2
- 229910021529 ammonia Inorganic materials 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000009833 condensation Methods 0.000 title 1
- 230000005494 condensation Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 150000003222 pyridines Chemical class 0.000 abstract 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 abstract 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 abstract 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
- C07D213/08—Preparation by ring-closure
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
- C07D213/08—Preparation by ring-closure
- C07D213/09—Preparation by ring-closure involving the use of ammonia, amines, amine salts, or nitriles
- C07D213/10—Preparation by ring-closure involving the use of ammonia, amines, amine salts, or nitriles from acetaldehyde or cyclic polymers thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
UNA TERCERA QUETONA O ALDEHIDO SE AÑADE A UNA MEZCLA BINARIA DE ALDEHIDOS Y/O KETONAS USANDAS EN LA PREPARACION DE MEZCLAS DE PIRIDINA O PIRIDINAS SUSTITUIDAS DE ALKIL EN UN PROCESO CONTINUO DE AMPLIA ESCALA. LA CANTIDAD DEL TERCER COMPONENTE SE AJUSTA APROPIADAMENTE MEDIANTE LO CUAL LAS RELACIONES RELATIVAS DE LOS PRODUCTOS SE AJUSTAN Y LA PRODUCCION TOTAL DE PIRIDINAS O PIRIDINAS ALKIL-SUSTITUIDAS ES ALTA, TODO ELLO SIN NINGUNA PARADA DE LA PLANTA. EN UN SISTEMA MAS APROPIADO, EL PROPIONALDEHIDO SE AÑADE A UNA MEZCLA BINARIA DE ACETALDEHIDO Y FORMALDEHIDO PARA PRODUCIR SORPRENDENTEMENTE ALTAS CANTIDADES DE BETA-PIRIDINA Y PIRIDINA.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26375488A | 1988-10-28 | 1988-10-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2059781T3 true ES2059781T3 (es) | 1994-11-16 |
Family
ID=23003100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES89311154T Expired - Lifetime ES2059781T3 (es) | 1988-10-28 | 1989-10-30 | Sintesis con alto rendimiento de piridina y/o alquilpiridina(s) a traves de condensacion de mezclas ternarias de aldehidos y/o cetonas con amoniaco. |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0371615B1 (es) |
| AT (1) | ATE111896T1 (es) |
| DE (1) | DE68918412T2 (es) |
| ES (1) | ES2059781T3 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU6288596A (en) * | 1995-06-23 | 1997-01-22 | Reilly Industries, Inc. | Pyridine base synthesis |
| US6495695B2 (en) * | 2001-03-30 | 2002-12-17 | Council Of Scientific And Industrial Research | Process for the preparation of a collidine and 2,3,5,6-tetramethyl pyridine |
| CN119100973A (zh) * | 2024-08-30 | 2024-12-10 | 北京弗莱明科技有限公司 | 一种提高吡啶碱合成过程中副产物3-甲基吡啶产量的方法、及吡啶碱的合成方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB929694A (en) * | 1961-04-07 | 1963-06-26 | Distillers Co Yeast Ltd | Production of pyridine bases |
| GB966264A (en) * | 1961-08-31 | 1964-08-06 | Distillers Co Yeast Ltd | Production of alkyl pyridines |
| BE758201A (fr) * | 1969-11-08 | 1971-04-29 | Koei Chemical Cy Ltd | Procede de preparation de bases pyridiques |
| US3946020A (en) * | 1970-12-28 | 1976-03-23 | Koei Chemical Co., Ltd. | Process for producing pyridine bases |
| US4220783A (en) * | 1979-05-09 | 1980-09-02 | Mobil Oil Corporation | Synthesis of pyridine and alkylpyridines |
| EP0131887B1 (en) * | 1983-07-11 | 1989-01-25 | Nepera, Inc. | Improved process for preparing pyridine-type bases in a fluid bed using a crystalline aluminosilicate zeolite catalyst |
| US4810794A (en) * | 1986-02-06 | 1989-03-07 | Koei Chemical Co., Ltd. | Process for producing pyridine bases |
-
1989
- 1989-10-30 DE DE68918412T patent/DE68918412T2/de not_active Expired - Lifetime
- 1989-10-30 EP EP89311154A patent/EP0371615B1/en not_active Expired - Lifetime
- 1989-10-30 AT AT89311154T patent/ATE111896T1/de not_active IP Right Cessation
- 1989-10-30 ES ES89311154T patent/ES2059781T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0371615B1 (en) | 1994-09-21 |
| EP0371615A1 (en) | 1990-06-06 |
| DE68918412D1 (de) | 1994-10-27 |
| DE68918412T2 (de) | 1995-03-30 |
| ATE111896T1 (de) | 1994-10-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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