ES247912A1 - Un procedimiento para la alcohilacion de hidrocarburos aromaticos - Google Patents
Un procedimiento para la alcohilacion de hidrocarburos aromaticosInfo
- Publication number
- ES247912A1 ES247912A1 ES0247912A ES247912A ES247912A1 ES 247912 A1 ES247912 A1 ES 247912A1 ES 0247912 A ES0247912 A ES 0247912A ES 247912 A ES247912 A ES 247912A ES 247912 A1 ES247912 A1 ES 247912A1
- Authority
- ES
- Spain
- Prior art keywords
- olefin
- aromatic hydrocarbon
- boron trifluoride
- alkylation
- acting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000004945 aromatic hydrocarbons Chemical class 0.000 title abstract 5
- 230000029936 alkylation Effects 0.000 title abstract 2
- 238000005804 alkylation reaction Methods 0.000 title abstract 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 abstract 6
- 150000001336 alkenes Chemical class 0.000 abstract 4
- 229910015900 BF3 Inorganic materials 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 3
- ZQXCQTAELHSNAT-UHFFFAOYSA-N 1-chloro-3-nitro-5-(trifluoromethyl)benzene Chemical compound [O-][N+](=O)C1=CC(Cl)=CC(C(F)(F)F)=C1 ZQXCQTAELHSNAT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- C07C2/68—Catalytic processes with halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/12—Fluorides
- C07C2527/1213—Boron fluoride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para la alquilación de hidrocarburos aromáticos con compuestos que actúen como olefinas en presenciade un catalizador de trifluoruro de boroqeu comprende la introducción de un hidrocarburo aromático alquilableun compuesto qeu actúe como olefina y no más de 08g de trifluoruro de boro por molécula gramo de compuesto que actúa como olefina en una zona de reacciónreaccionando en ella dicho hidrocarburo aromático alquilable con el citado compuesto qeu actúa como olefina en presencia del citado trifluoruro de boro y de un óxido refractario modificado con trifluoruro de boroy recuperando el hidrocarburo aromático alquilado de la mezcla de reacción resultante.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US722121A US2939890A (en) | 1958-03-18 | 1958-03-18 | Alkylation of aromatic hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES247912A1 true ES247912A1 (es) | 1959-09-16 |
Family
ID=24900593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0247912A Expired ES247912A1 (es) | 1958-03-18 | 1959-03-14 | Un procedimiento para la alcohilacion de hidrocarburos aromaticos |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2939890A (es) |
| CH (1) | CH422739A (es) |
| DE (1) | DE1418446A1 (es) |
| ES (1) | ES247912A1 (es) |
| OA (1) | OA00552A (es) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3126421A (en) * | 1964-03-24 | Ttorneys | ||
| US3086998A (en) * | 1960-09-12 | 1963-04-23 | Universal Oil Prod Co | Selective alkylation of aromatic hydrocarbons |
| US3131230A (en) * | 1960-12-27 | 1964-04-28 | Universal Oil Prod Co | Alkylation of aromatic compounds |
| US3193591A (en) * | 1961-07-13 | 1965-07-06 | Universal Oil Prod Co | Process for removing boron compound deposits |
| FR1335526A (fr) * | 1962-05-10 | 1963-08-23 | Electrochimie Soc | Nouveaux alkylterphényles |
| US3197521A (en) * | 1962-05-21 | 1965-07-27 | Universal Oil Prod Co | Process for removing acid-forming hydrogen-containing compounds in an alkylation process |
| US3217059A (en) * | 1962-12-04 | 1965-11-09 | Universal Oil Prod Co | Process for shifting the double bond in an olefinic hydrocarbon |
| US3217062A (en) * | 1962-12-04 | 1965-11-09 | Universal Oil Prod Co | Process for shifting the double bond in an olefinic hydrocarbon |
| US3217063A (en) * | 1962-12-04 | 1965-11-09 | Universal Oil Prod Co | Process for shifting the double bond in an olefinic hydrocarbon |
| US3217060A (en) * | 1962-12-04 | 1965-11-09 | Universal Oil Prod Co | Process for shifting the double bond in an olefinic hydrocarbon |
| US3217061A (en) * | 1962-12-04 | 1965-11-09 | Universal Oil Prod Co | Process for shifting the double bond in an olefinic hydrocarbon |
| US3367981A (en) * | 1963-05-10 | 1968-02-06 | Ethyl Corp | Phenol alkylation process |
| US3248444A (en) * | 1965-02-26 | 1966-04-26 | Universal Oil Prod Co | Hydrocarbon conversion process and catalyst therefor |
| US3238268A (en) * | 1965-03-31 | 1966-03-01 | Universal Oil Prod Co | Sorption process |
| US4009217A (en) * | 1975-05-06 | 1977-02-22 | Universal Oil Products Company | Process for production and dehydrogenation of ethylbenzene |
| US4407731A (en) * | 1982-11-08 | 1983-10-04 | Uop Inc. | Preparation of metal oxide-supported boron fluoride catalysts |
| US4570027A (en) * | 1984-04-27 | 1986-02-11 | Exxon Research And Engineering Co. | Alkylation of aromatic molecules using a silica-alumina catalyst derived from zeolite |
| US4956518A (en) * | 1988-07-15 | 1990-09-11 | Mobil Oil Corp. | Heterogeneous isoparaffin/olefin alkylation |
| US4918255A (en) * | 1988-07-15 | 1990-04-17 | Mobil Oil Corp. | Heterogeneous isoparaffin/olefin alkylation with isomerization |
| US4992616A (en) * | 1988-07-15 | 1991-02-12 | Mobil Oil Corporation | Heterogeneous isoparaffin/olefin aklylation process |
| DE68910977T2 (de) * | 1988-07-15 | 1994-03-17 | Mobil Oil Corp | Heterogenes isoparaffin/olefin-alkylierungsverfahren. |
| US5030785A (en) * | 1988-10-06 | 1991-07-09 | Mobil Oil Corp. | Process for preparing long chain alkyl aromatic compounds employing Lewis acid-promoted zeolite catalysts |
| US5012033A (en) * | 1988-10-06 | 1991-04-30 | Mobil Oil Corp. | Isoparaffin-olefin alkylation process and catalyst composition thereof |
| US4992615A (en) * | 1990-01-25 | 1991-02-12 | Mobil Oil Corp. | Isoparaffin-olefin alkylation process |
| US5107048A (en) * | 1990-01-25 | 1992-04-21 | Mobil Oil Corp. | Process for preparing long chain alkyl aromatic compounds employing lewis acid-promoted amorphous inorganic oxide |
| US5157197A (en) * | 1990-09-26 | 1992-10-20 | Catalytica, Inc. | Isoparaffin alkylation using a lewis acid promoted transition alumina catalyst |
| US5365010A (en) * | 1990-09-26 | 1994-11-15 | Catalytica, Inc. | Method for regenerating Lewis acid-promoted transition alumina catalysts used for isoparaffin alkylation by calcination |
| US5326923A (en) * | 1990-09-26 | 1994-07-05 | Catalytica, Inc. | Method for regenerating certain acidic hydrocarbon conversion catalysts by solvent extraction |
| US5095167A (en) * | 1991-02-04 | 1992-03-10 | Mobil Oil Corporation | Isoparaffin:olefin alkylation process |
| US5304698A (en) * | 1992-08-10 | 1994-04-19 | Mobil Oil Corporation | Solid catalyzed supercritical isoparaffin-olefin alkylation process |
| US5347064A (en) * | 1993-04-12 | 1994-09-13 | Mobil Oil Corporation | Multiple split feed isoparaffin-olefin alkylation |
| AU6700794A (en) * | 1993-04-22 | 1994-11-08 | Mobil Oil Corporation | Isoparaffin/olefin alkylation |
| CN106278797B (zh) * | 2015-06-12 | 2018-11-20 | 中国石油化工股份有限公司 | 催化干气生产乙苯的方法 |
| CN106278795B (zh) * | 2015-06-12 | 2018-10-23 | 中国石油化工股份有限公司 | 利用催化干气生产乙苯的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2584103A (en) * | 1949-07-16 | 1952-02-05 | Universal Oil Prod Co | Alkylation of aromatic hydrocarbons |
| FR1028700A (fr) * | 1949-12-05 | 1953-05-27 | Ici Ltd | Perfectionnements relatifs à la production de catalyseurs |
| US2804491A (en) * | 1956-09-14 | 1957-08-27 | American Oil Co | Ethylation process |
-
1958
- 1958-03-18 US US722121A patent/US2939890A/en not_active Expired - Lifetime
-
1959
- 1959-03-14 ES ES0247912A patent/ES247912A1/es not_active Expired
- 1959-03-17 DE DE19591418446 patent/DE1418446A1/de active Pending
- 1959-03-18 CH CH7092159A patent/CH422739A/de unknown
-
1964
- 1964-11-18 OA OA50639A patent/OA00552A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1418446A1 (de) | 1968-10-10 |
| OA00552A (fr) | 1966-07-15 |
| CH422739A (de) | 1966-10-31 |
| US2939890A (en) | 1960-06-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES247912A1 (es) | Un procedimiento para la alcohilacion de hidrocarburos aromaticos | |
| ES465674A1 (es) | Procedimiento mejorado para la preparacion ed hidrocarburos alcohilaromaticos. | |
| GB1369890A (en) | Process for producing 2-methyl-2-methoxypropane and alkylate | |
| ES416672A1 (es) | Un procedimiento para la obtencion de un producto de reac- cion de alcohilacion. | |
| ES335022A1 (es) | Un procedimiento para la deshidrogenacion de un hidrocarburo saturado. | |
| ES335098A1 (es) | Procedimiento para la epoxidacion de olefinas. | |
| GB796130A (en) | Polyalkylindanes and process for manufacturing the same | |
| ES246256A1 (es) | UN PROCEDIMIENTO PARA LA ALCOHILACION DE UN HIDROCARBURO AROMáTICO | |
| GB863688A (en) | Catalytic isomerization | |
| ES228204A1 (es) | UN PROCEDIMIENTO DE ALCOHILACIoN DE UN COMPUESTO AROMáTICO | |
| ES294655A2 (es) | Procedimiento para la oxidacion parcial de hidrocarburos en fase liquida. | |
| US3214486A (en) | Method for preparing radioactive hydrocarbons | |
| GB1402896A (en) | Alkylation of aromatic hydrocarbons | |
| GR20088B (el) | Μεθοδος δια την αλκυλιωσιν αρωματικων υδρογονανθρακων. | |
| ES353481A1 (es) | Un procedimiento para producir un hidrocarburo aromatico monoalcohilado. | |
| GB1486296A (en) | Alkylation process | |
| ES329490A1 (es) | Procedimiento para la isomerizacion de alfa-pineno a beta- pineno. | |
| ES374286A3 (es) | Proceso de polimerizacion de olefinas con oxido del grupo 6a. | |
| ES385794A1 (es) | Procedimiento de adicion de hidrocarburos al anillo bence- nico de compuestos aromaticos mediante olefinas. | |
| SU149415A1 (ru) | Способ совместного пиролиза легких углеводородов с толуолом | |
| ES273632A1 (es) | Procedimiento de polimeraziën de hidrocarbonos con catalizador | |
| ES260749A3 (es) | Un procedimiento para producir hidrocarburos alcohil aromaticos | |
| ES278427A1 (es) | Procedimiento para la desalcohilación de hidrocarburos | |
| ES258338A1 (es) | Un procedimiento para producir compuestos aromaticos monoalcohilados | |
| ES228202A1 (es) | UN PROCEDIMIENTO PARA LA ALCOHILACIoN DE HIDROCARBUROS PARAFiLICOS |