FR2368457A1 - Procede de preparation de cetones contenant du fluor - Google Patents
Procede de preparation de cetones contenant du fluorInfo
- Publication number
- FR2368457A1 FR2368457A1 FR7731910A FR7731910A FR2368457A1 FR 2368457 A1 FR2368457 A1 FR 2368457A1 FR 7731910 A FR7731910 A FR 7731910A FR 7731910 A FR7731910 A FR 7731910A FR 2368457 A1 FR2368457 A1 FR 2368457A1
- Authority
- FR
- France
- Prior art keywords
- perfluoro
- radical
- denotes
- ketones
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 title 1
- 229910052731 fluorine Inorganic materials 0.000 title 1
- 239000011737 fluorine Substances 0.000 title 1
- 150000002576 ketones Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- IYRWEQXVUNLMAY-UHFFFAOYSA-N carbonyl fluoride Chemical compound FC(F)=O IYRWEQXVUNLMAY-UHFFFAOYSA-N 0.000 abstract 2
- -1 aliphatic perfluoro-ketones Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical class OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 abstract 1
- 239000013043 chemical agent Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 239000002798 polar solvent Substances 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D319/10—1,4-Dioxanes; Hydrogenated 1,4-dioxanes
- C07D319/12—1,4-Dioxanes; Hydrogenated 1,4-dioxanes not condensed with other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/48—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation involving decarboxylation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Procédé de préparation de perfluoro-cétones aliphatiques. On fait réagir un sel d'acide perfluoro-carboxylique de formule R1 -CO2 M dans laquelle M désigne un métal du groupe II formé par Li, Na, Rb, Cs et Ag et R 1 désigne un radical perfluoro-alkyle ayant de 2 à 50 atomes de carbone, radical qui peut de plus contenir un ou plusieurs atomes d'oxygène à liaison du type éther, avec un fluorure d'acide perfluoro-carboxylique de formule R2 -COF dans laquelle R2 désigne un radical perfluoro-alkyle ayant de 1 à 50 atomes de carbone, radical qui peut en outre contenir un ou plusieurs atomes d'oxygène liaison du type éther, dans un solvant polaire aprotique, à une température de 20 à 200 degrés C. Les perfluoro-cétones ainsi préparées résistent très bien aux différents agents chimiques ainsi qu'à la chaleur. Elles peuvent servir, entre autres, de liquides caloporteurs ou de lubrifiants.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19762648123 DE2648123C2 (de) | 1976-10-23 | 1976-10-23 | Verfahren zur Herstellung aliphatischer Perfluorketone |
| DE19772704607 DE2704607C2 (de) | 1977-02-04 | 1977-02-04 | Verfahren zur Herstellung fluorhaltiger Ketone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2368457A1 true FR2368457A1 (fr) | 1978-05-19 |
Family
ID=25771052
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7731910A Withdrawn FR2368457A1 (fr) | 1976-10-23 | 1977-10-24 | Procede de preparation de cetones contenant du fluor |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4136121A (fr) |
| CA (1) | CA1086756A (fr) |
| FR (1) | FR2368457A1 (fr) |
| GB (1) | GB1576402A (fr) |
| IT (1) | IT1086974B (fr) |
| NL (1) | NL7711424A (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2816306A1 (fr) * | 2000-11-06 | 2002-05-10 | Rhodia Chimie Sa | Procede de preparation de cetones fluorees |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2928602A1 (de) * | 1979-07-14 | 1981-02-05 | Hoechst Ag | Verfahren zur herstellung von 2.3- perfluor-1.4-dioxanen sowie einige spezielle vertreter dieser verbindungsklasse |
| FR2601946B1 (fr) * | 1986-07-25 | 1988-10-21 | Rhone Poulenc Chimie | Procede de preparation de perfluoroalkylcetones |
| JPH082893B2 (ja) * | 1991-04-16 | 1996-01-17 | 信越化学工業株式会社 | パーフルオロ環状ケトン及びその製造法 |
| ES2230125T5 (es) | 1999-07-20 | 2016-10-04 | 3M Innovative Properties Company | Uso de cetonas fluoradas en composiciones extintoras de incendios |
| WO2001081287A1 (fr) * | 2000-04-21 | 2001-11-01 | Daikin Industries, Ltd. | Procede de preparation de perfluoroalcanones |
| US6780220B2 (en) * | 2000-05-04 | 2004-08-24 | 3M Innovative Properties Company | Method for generating pollution credits while processing reactive metals |
| US6685764B2 (en) | 2000-05-04 | 2004-02-03 | 3M Innovative Properties Company | Processing molten reactive metals and alloys using fluorocarbons as cover gas |
| US6394107B1 (en) * | 2001-04-24 | 2002-05-28 | 3M Innovative Properties Company | Use of fluorinated ketones as wet cleaning agents for vapor reactors and vapor reactor components |
| US6403149B1 (en) | 2001-04-24 | 2002-06-11 | 3M Innovative Properties Company | Fluorinated ketones as lubricant deposition solvents for magnetic media applications |
| US8791254B2 (en) * | 2006-05-19 | 2014-07-29 | 3M Innovative Properties Company | Cyclic hydrofluoroether compounds and processes for their preparation and use |
| US8193397B2 (en) * | 2006-12-06 | 2012-06-05 | 3M Innovative Properties Company | Hydrofluoroether compounds and processes for their preparation and use |
| US8461382B2 (en) * | 2007-05-05 | 2013-06-11 | Basf Se | Ionic liquids |
| BRPI0924862A2 (pt) | 2009-06-12 | 2016-08-23 | Abb Technology Ag | meio de isolação dielétrica |
| DE202009009305U1 (de) | 2009-06-17 | 2009-11-05 | Ormazabal Gmbh | Schalteinrichtung für Mittel-, Hoch- oder Höchstspannung mit einem Füllmedium |
| US20120280189A1 (en) | 2010-01-25 | 2012-11-08 | Warren Karl J | Perfluoroketones as gaseous dielectrics |
| US8193393B2 (en) * | 2010-03-26 | 2012-06-05 | 3M Innovative Properties Company | Fluoroether diketones for high temperature heat transfer |
| US8535559B2 (en) * | 2010-03-26 | 2013-09-17 | 3M Innovative Properties Company | Nitrogen-containing fluoroketones for high temperature heat transfer |
| DK2652752T3 (en) | 2010-12-14 | 2016-01-11 | Abb Technology Ag | Dielectric INSULATION MEDIUM |
| KR20130128433A (ko) | 2010-12-14 | 2013-11-26 | 에이비비 리써치 리미티드 | 유전성 절연 매질 |
| RU2567754C2 (ru) | 2010-12-16 | 2015-11-10 | Абб Текнолоджи Аг | Диэлектрическая изолирующая среда |
| WO2013087700A1 (fr) | 2011-12-13 | 2013-06-20 | Abb Technology Ag | Environnement de convertisseur haute tension rendu étanche et isolé au gaz pour plateformes en mer |
| EP2747092A1 (fr) * | 2012-12-21 | 2014-06-25 | Solvay SA | Procédé pour pièces électriques actives diélectriquement isolantes |
| CN108440260A (zh) * | 2018-04-13 | 2018-08-24 | 天津市长芦化工新材料有限公司 | 一种回收利用hfpo二聚体合成八碳全氟酮的方法 |
| CN116143594A (zh) * | 2022-12-09 | 2023-05-23 | 天津长芦新材料研究院有限公司 | 双(七氟异丙基)酮的合成方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3185734A (en) * | 1960-10-25 | 1965-05-25 | Du Pont | Novel polyfluoro-substituted ketones and their preparation from polyfluoro acid fluorides |
| US3291843A (en) * | 1963-10-08 | 1966-12-13 | Du Pont | Fluorinated vinyl ethers and their preparation |
| FR1530862A (fr) * | 1966-07-11 | 1968-06-28 | Montedison Spa | Cétones fluorées et procédé pour les préparer |
| SU413772A1 (ru) * | 1972-02-04 | 1975-12-25 | Новосибирский институт органической химии СО АН СССР | Способ получени декафторбензофенона |
| FR2311015A1 (fr) * | 1975-05-15 | 1976-12-10 | Hoechst Ag | Cetones fluorees et leur preparation |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3012069A (en) * | 1959-06-19 | 1961-12-05 | Du Pont | Polyfluorinated products |
| US3240811A (en) * | 1961-09-06 | 1966-03-15 | Du Pont | Selected fluorinated acyloins and 1, 2-diketones and their preparation |
| US3513203A (en) * | 1966-07-11 | 1970-05-19 | Montedison Spa | Fluorinated ketones and process for their preparation |
-
1977
- 1977-10-18 NL NL7711424A patent/NL7711424A/xx not_active Application Discontinuation
- 1977-10-20 US US05/844,049 patent/US4136121A/en not_active Expired - Lifetime
- 1977-10-21 IT IT28891/77A patent/IT1086974B/it active
- 1977-10-21 CA CA289,210A patent/CA1086756A/fr not_active Expired
- 1977-10-24 GB GB44160/77A patent/GB1576402A/en not_active Expired
- 1977-10-24 FR FR7731910A patent/FR2368457A1/fr not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3185734A (en) * | 1960-10-25 | 1965-05-25 | Du Pont | Novel polyfluoro-substituted ketones and their preparation from polyfluoro acid fluorides |
| US3291843A (en) * | 1963-10-08 | 1966-12-13 | Du Pont | Fluorinated vinyl ethers and their preparation |
| FR1530862A (fr) * | 1966-07-11 | 1968-06-28 | Montedison Spa | Cétones fluorées et procédé pour les préparer |
| SU413772A1 (ru) * | 1972-02-04 | 1975-12-25 | Новосибирский институт органической химии СО АН СССР | Способ получени декафторбензофенона |
| FR2311015A1 (fr) * | 1975-05-15 | 1976-12-10 | Hoechst Ag | Cetones fluorees et leur preparation |
Non-Patent Citations (1)
| Title |
|---|
| CA1976 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2816306A1 (fr) * | 2000-11-06 | 2002-05-10 | Rhodia Chimie Sa | Procede de preparation de cetones fluorees |
| WO2002036536A1 (fr) * | 2000-11-06 | 2002-05-10 | Rhodia Chimie | Procede de preparation de cetones fluorees |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1576402A (en) | 1980-10-08 |
| CA1086756A (fr) | 1980-09-30 |
| IT1086974B (it) | 1985-05-31 |
| NL7711424A (nl) | 1978-04-25 |
| US4136121A (en) | 1979-01-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |