FR3076745B1 - Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante - Google Patents

Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante Download PDF

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FR3076745B1
FR3076745B1 FR1850246A FR1850246A FR3076745B1 FR 3076745 B1 FR3076745 B1 FR 3076745B1 FR 1850246 A FR1850246 A FR 1850246A FR 1850246 A FR1850246 A FR 1850246A FR 3076745 B1 FR3076745 B1 FR 3076745B1
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Prior art keywords
hydrosilylation
dehydrogening
catalysts
nanoparticles useful
nanoparticles
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FR1850246A
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FR3076745A1 (fr
Inventor
Valerie Meille
Chloe Thieuleux
Laurent Veyre
Iurii Suleimanov
Thomas Galeandro-Diamant
Magali Bousquie
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Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Chimie Physique Electronique de Lyon
Elkem Silicones France SAS
Universite Claude Bernard Lyon 1
Original Assignee
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Chimie Physique Electronique de Lyon
Elkem Silicones France SAS
Universite Claude Bernard Lyon 1
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Priority to FR1850246A priority Critical patent/FR3076745B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Ecole Superieure de Chimie Physique Electronique de Lyon, Elkem Silicones France SAS, Universite Claude Bernard Lyon 1 filed Critical Centre National de la Recherche Scientifique CNRS
Priority to KR1020207023073A priority patent/KR102408313B1/ko
Priority to US16/961,643 priority patent/US11633728B2/en
Priority to CN201980008074.0A priority patent/CN111936231B/zh
Priority to EP19703165.1A priority patent/EP3737497A1/fr
Priority to JP2020559032A priority patent/JP7003293B2/ja
Priority to PCT/FR2019/050054 priority patent/WO2019138194A1/fr
Publication of FR3076745A1 publication Critical patent/FR3076745A1/fr
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Publication of FR3076745B1 publication Critical patent/FR3076745B1/fr
Priority to US18/123,609 priority patent/US12179187B2/en
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract

La présente invention concerne des nanoparticules utilisables comme catalyseurs, notamment comme catalyseurs d'hydrosilylation et de silylation déshydrogénante. Plus spécifiquement, la présente invention concerne des nanoparticules d'au moins un métal de transition au degré d'oxydation 0, choisi parmi les métaux des colonnes 8, 9 et 10 du tableau périodique des éléments, et comprenant au moins un ligand carbonyle.
FR1850246A 2018-01-12 2018-01-12 Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante Active FR3076745B1 (fr)

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FR1850246A FR3076745B1 (fr) 2018-01-12 2018-01-12 Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante
US16/961,643 US11633728B2 (en) 2018-01-12 2019-01-11 Nanoparticles of CO complexes of zero-valent metals that can be used as hydrosilylation and dehydrogenative silylation catalysts
CN201980008074.0A CN111936231B (zh) 2018-01-12 2019-01-11 可以用作硅氢加成反应和脱氢硅烷化催化剂的零价金属co络合物的纳米颗粒
EP19703165.1A EP3737497A1 (fr) 2018-01-12 2019-01-11 Catalyseurs de nanoparticules de complexes co de métaux zerovalents pour l'hydrosilylation] et la silylation deshydrogenante
KR1020207023073A KR102408313B1 (ko) 2018-01-12 2019-01-11 하이드로실릴화 및 탈수소 실릴화 촉매로서 유용한 나노입자
JP2020559032A JP7003293B2 (ja) 2018-01-12 2019-01-11 ヒドロシリル化及び脱水素化シリル化触媒として有用なナノ粒子
PCT/FR2019/050054 WO2019138194A1 (fr) 2018-01-12 2019-01-11 Catalyseurs de nanoparticules de complexes co de métaux zerovalents pour l'hydrosilylation] et la silylation deshydrogenante
US18/123,609 US12179187B2 (en) 2018-01-12 2023-03-20 Nanoparticles of co complexes of zero-valent metals that can be used as hydrosilylation and dehydrogenative silylation catalysts

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CN114901669B (zh) * 2019-12-18 2025-06-24 美国陶氏有机硅公司 乙烯基官能化氯硅烷和乙基官能化氯硅烷的选择性制备
EP4077339A1 (fr) * 2019-12-18 2022-10-26 Dow Silicones Corporation Particules de catalyseur et procédés de silylation déshydrogénante
WO2025133480A1 (fr) 2023-12-22 2025-06-26 Elkem Silicones France Sas Composition silicone réticulable par polyaddition pour la préparation d'élastomère silicone thermoconducteur
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US4252672A (en) * 1979-12-04 1981-02-24 Xerox Corporation Preparation of colloidal iron dispersions by the polymer-catalyzed decomposition of iron carbonyl and iron organocarbonyl compounds
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US4705765A (en) * 1985-12-19 1987-11-10 General Electric Company Hydrosilylation catalyst, method for making and use
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DE102004059375A1 (de) 2004-12-09 2006-06-22 Consortium für elektrochemische Industrie GmbH Auf nanoskaligem Titandioxid geträgerte Platin-Katalysatoren, deren Verwendung in der Hydrosilylierung, ein Hydrosilylierungsverfahren mit solchen Katalysatoren und Zusammensetzungen enthaltend solche Katalysatoren
US20090182091A1 (en) 2006-02-16 2009-07-16 Kaneka Corporation Curable composition
US20090215615A1 (en) 2006-07-11 2009-08-27 3M Innovative Properties Company Method of forming supported nanoparticle catalysts
WO2009150173A1 (fr) 2008-06-10 2009-12-17 Dsm Ip Assets B.V. Utilisation de nanoparticules de fer dissous en tant que catalyseur dans des réactions d’addition
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EP3737497A1 (fr) 2020-11-18
JP7003293B2 (ja) 2022-02-10
CN111936231B (zh) 2023-10-27
KR102408313B1 (ko) 2022-06-15
US20230264183A1 (en) 2023-08-24
US20200353454A1 (en) 2020-11-12
JP2021510349A (ja) 2021-04-22
WO2019138194A1 (fr) 2019-07-18
US12179187B2 (en) 2024-12-31
FR3076745A1 (fr) 2019-07-19
CN111936231A (zh) 2020-11-13
US11633728B2 (en) 2023-04-25

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