JP2005287304A - Titanium dioxide photocatalytic light-shielding agent - Google Patents

Titanium dioxide photocatalytic light-shielding agent Download PDF

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Publication number
JP2005287304A
JP2005287304A JP2004102438A JP2004102438A JP2005287304A JP 2005287304 A JP2005287304 A JP 2005287304A JP 2004102438 A JP2004102438 A JP 2004102438A JP 2004102438 A JP2004102438 A JP 2004102438A JP 2005287304 A JP2005287304 A JP 2005287304A
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light
shielding agent
titanium dioxide
photocatalytic
water
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JP2004102438A
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Japanese (ja)
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Kazuhiro Shiki
和博 志岐
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SARUTA SHIKI NOSAN KK
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SARUTA SHIKI NOSAN KK
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/25Greenhouse technology, e.g. cooling systems therefor

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  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)
  • Protection Of Plants (AREA)
  • Greenhouses (AREA)
  • Housing For Livestock And Birds (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a titanium dioxide photocatalytic light-shielding agent enabling optional setting of a light shielding period of time, and provided with odor eliminating, deodorizing, antibacterial and anti-virus effects. <P>SOLUTION: The titanium dioxide photocatalytic light-shielding agent comprises 5-60 wt.% of an anatase-type titanium dioxide having a particle size of 0.1-550 μm and efficiently exhibiting photocatalytic reaction with ultraviolet light, and contains either of polyvinyl acetate resin-based emulsion, or synthetic resin-based alkyd, acrylic, urethane or polyvinyl alcohol in its ingredient as a binder. The light shielding agent can be diluted with water such as ground water, running water or water in a water channel by about 2-100 times so as to be dispersed at the scene when used, and easily sprayed using a power sprayer or the like normally used at a farmhouse or the like. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、二酸化チタンを使用することで施設ハウス・畜舎等の内部温度を下げ、臭気成分を分解し雑菌・ウイルス等も分解する事のできる光触媒式遮光剤に関するものである。   The present invention relates to a photocatalytic light-shielding agent capable of lowering the internal temperature of facility houses, livestock houses, etc. by using titanium dioxide, decomposing odor components, and decomposing bacteria and viruses.

今まで施設園芸農家等では、作物によっては夏場の高温時に、高温障害・日焼け等から作物を守り施設内温度を下げる為に色々な工夫がなされ、カーテン資材からダイオネット資材また、高価なガラス温室では発泡スチロール等が使用され、簡易的にはカルシウム粉末・セラミックス粉体・二酸化チタン粉体・白色ペイント等が施設の天井・屋根・外壁等に使用されている。   Up until now, some horticultural horticultural farmers have been devised to protect crops from high temperature damage and sunburn at high temperatures in the summer, and to reduce the temperature inside the facility, from curtain materials to dionet materials and expensive glass greenhouses. In Japan, styrene foam is used. For simplicity, calcium powder, ceramic powder, titanium dioxide powder, white paint, etc. are used on the ceiling, roof, outer wall, etc. of facilities.

遮光資材の中で簡易的に使用されているものの中には、現場において粉体を水等に希釈するタイプでは、水等に良く分散できず攪拌しながら散布しないと沈殿してしまうと言う問題と、接着剤が上手く馴染まず雨等にてはがれやすいと言う問題があった。又逆に接着剤によっては、長い期間遮光剤がはげずに困ると言う問題もあった。   Among the light shielding materials that are used in a simple manner, the type that dilutes the powder in water etc. in the field cannot be well dispersed in water etc. and will precipitate if not sprayed while stirring. There was a problem that the adhesive did not get used well and was easy to peel off due to rain. On the other hand, depending on the adhesive, there is a problem that the shading agent is not peeled off for a long period of time.

又畜産農家等では、夏場の高温時には、畜産動物の体温からだけでなく糞尿から出るアンモニアガス等により、ある種の夏ばて状態になっていた。このような状態がつづく限り畜産動物からの生産性は低下を免れず畜産農家の経営を圧迫していた。   Moreover, in the case of livestock farmers, at the time of high temperatures in summer, some kind of summer was in the state of not only from the body temperature of livestock animals but also ammonia gas from manure. As long as this situation continued, productivity from livestock animals was unavoidable, and pressured the management of livestock farmers.

従来、施設等の天井など内側に散布する方法もあったが、散布するときに施設内の作物等に遮光剤等がかかってしまい、又、天井等では施設内湿度の影響で遮光剤が長く持たないと言う問題もあった。
特開平11−124546 特開2001−286226 学会出版センター「光が関わる触媒化学」 季刊化学総説No.23,1994 藤嶋 昭・橋本和仁・渡部俊也共著「光クリーン革命」太陽印刷1997年
Conventionally, there was a method of spraying inside the ceiling of the facility, etc., but when spraying, the crop inside the facility was covered with light shielding agent, etc., and on the ceiling, etc., the light shielding agent was long due to the humidity of the facility. There was also a problem of not having it.
JP-A-11-124546 JP 2001-286226 A Academic Publishing Center "Catalyst Chemistry with Light" Quarterly Chemistry Review No. 23, 1994 Akira Fujishima, Kazuhito Hashimoto, Toshiya Watanabe “Light Clean Revolution” Taiyo Printing 1997

解決しようとする問題点は、遮光量・遮光期間の任意設定並びに消臭・脱臭・抗菌・抗ウイルス効果を持たせることである。   Problems to be solved are to arbitrarily set the light shielding amount and the light shielding period and to provide a deodorizing / deodorizing / antibacterial / antiviral effect.

本発明は、遮光剤に二酸化チタンを使うことで温度を下げるだけでなく、光触媒反応を利用することで消臭・脱臭・抗菌・抗ウイルス効果が得られ、又、バインダーとして酢酸ビニール樹脂系エマルジョン・合成樹脂系のアルキド・アクリル・ウレタン・ポリビニールアルコールの種類を使い分けることにより遮光期間の調整もできるようになった。   The present invention not only lowers the temperature by using titanium dioxide as a light-shielding agent, but also provides a deodorizing, deodorizing, antibacterial, and antiviral effect by utilizing a photocatalytic reaction, and a vinyl acetate resin emulsion as a binder -The light shielding period can be adjusted by using different types of synthetic resin alkyd, acrylic, urethane, and polyvinyl alcohol.

本発明の二酸化チタン光触媒式遮光剤を使用することにより、畜舎内・ハウス内温度を約3〜5度下げることができ、消臭・脱臭・抗菌・抗ウイルス効果が得られる。   By using the titanium dioxide photocatalytic light-shielding agent of the present invention, the temperature in the barn / house can be lowered by about 3 to 5 degrees, and deodorizing / deodorizing / antibacterial / antiviral effects are obtained.

使用する現場において、地下水・水道水・水路等の水で容易に、約2倍〜100倍に希釈・分散でき、通常農家等で使用されている動力噴霧機等により容易に散布できるフロアブル状にすること。   In the field where it is used, it can easily be diluted and dispersed about 2 to 100 times with water such as groundwater, tap water, and waterways, and can be easily sprayed with a power sprayer or the like normally used by farmers. To do.

実施例1 精制水を500ccの容器に5本準備しそれぞれに酢酸ビニール樹脂系Aエマルジョン・合成樹脂系のBアルキド・Cアクリル・Dウレタン・Eポリビニールアルコールを各1種類2gづつ入れ攪拌し分散させたものに、アナターゼ型二酸化チタンを10gづつ分散させ、1m×1mの5枚のビニールにA〜Eの5種類をそれぞれ、30cc散布し遮光期間と遮光量の試験をした。 Example 1 Five pieces of purified water are prepared in a 500 cc container, and 2 g each of vinyl acetate resin-based A emulsion, synthetic resin-based B alkyd, C acrylic, D urethane, and E polyvinyl alcohol are added and stirred to disperse. 10 g of anatase type titanium dioxide was dispersed in the product, and 5 types of A to E were spread on 5 vinyl pieces of 1 m × 1 m, respectively, and a light shielding period and a light shielding amount were tested.

遮光期間については、短い順にA・E・C・B・Dであった。遮光量紫外線カット率については、5種類ともに約55%〜60%であまり差がなかった。又、ハウスでの使用方法は、10a当たり水60Lに二酸化チタン4%〜5%2Kg〜3kg・バインダーは1.6%1kg攪拌・分散して、施設等の屋根・外壁等に散布する。 The light shielding periods were A, E, C, B, and D in ascending order. Regarding the light shielding amount and the ultraviolet cut rate, the five types were about 55% to 60%, and there was not much difference. Moreover, the usage method in a house is 4% to 5% 2 kg to 3 kg of titanium dioxide in 60 L of water per 10 a, 1.6% of 1 kg of the binder is stirred and dispersed, and is spread on the roof, outer wall, etc. of the facility.

二酸化チタン光触媒とバインダーとして酢酸ビニール樹脂系エマルジョン・合成樹脂系のアルキド・アクリル・ウレタン・ポリビニールアルコールの組み合わせによって、遮光し温度を下げるだけでなく同時に抗菌・抗ウイルス・消臭・脱臭作用が得られることから施設栽培だけでなく畜産農家等では様々な臭気成分の発生などの光触媒作用が不可欠な用途にも使用できる。   The combination of titanium dioxide photocatalyst and vinyl acetate resin emulsion as binder and synthetic resin-based alkyd, acrylic, urethane, polyvinyl alcohol not only shields the light and lowers the temperature, but also provides antibacterial, antiviral, deodorant, and deodorizing effects. Therefore, it can be used not only for in-house cultivation but also for applications where photocatalytic action such as generation of various odor components is indispensable for livestock farmers.

Claims (6)

二酸化チタンを使用する場合は、紫外線の光にて効率よく光触媒反応をする0.1ミクロン〜50ミクロンのアナターゼ型二酸化チタンを、5%〜60%で構成するフロアブル状の光触媒式遮光剤。   When titanium dioxide is used, it is a flowable photocatalytic light-shielding agent comprising 5% to 60% of anatase type titanium dioxide of 0.1 to 50 microns that efficiently performs photocatalytic reaction with ultraviolet light. 成分中に、バインダーとして酢酸ビニール樹脂系エマルジョン・合成樹脂系のアルキド・アクリル・ウレタン・ポリビニールアルコールのいずれか1〜2種類が、5%〜50%の割合で配合していることを特徴とする請求項1記載の光触媒式遮光剤。 One or two kinds of vinyl acetate resin emulsion / synthetic resin type alkyd / acrylic / urethane / polyvinyl alcohol are blended in the component at a ratio of 5% to 50%. The photocatalytic light-shielding agent according to claim 1. 使用する現場において、地下水・水道水・水路等に水で容易に、約2倍〜100倍に希釈・分散でき、超低コストで散布できる請求項2記載の光触媒式遮光剤。 3. The photocatalytic light-shielding agent according to claim 2, which can be easily diluted and dispersed about 2 to 100 times with water in groundwater, tap water, waterways, etc., and can be sprayed at an ultra-low cost. 通常、農家等で使用されている動力噴霧機等により容易に散布できる請求項3記載の光触媒式遮光剤。 The photocatalyst type | mold light-shielding agent of Claim 3 which can be easily spread | dispersed with the power sprayer etc. which are normally used by the farmer. 施設栽培・ビニールハウス・ガラス温室等において屋根・外壁等に二酸化チタンをコーティングすることによって紫外線をカットし室内温度を下げることを特徴とする請求項4記載の光触媒式遮光剤。 5. The photocatalytic light-shielding agent according to claim 4, wherein ultraviolet rays are cut and indoor temperature is lowered by coating titanium dioxide on a roof, an outer wall or the like in a greenhouse, a greenhouse, a glass greenhouse, or the like. 畜産農家等の、畜舎では畜産動物自体の体温と夏場の温度により畜産動物が耐え難い室内温度となっている。屋根・外壁等に二酸化チタンをコーティングすることによって畜舎内温度を下げるだけでなく,畜舎内から出る様々な臭気成分の分解もでき又、雑菌・ウイルス等の分解もできることを特徴とする請求項4記載の光触媒式遮光剤。 In livestock farms, such as livestock farmers, the temperature of livestock animals themselves and the temperature in summer make room temperatures unbearable by livestock animals. 5. The coating of titanium dioxide on the roof, outer wall, etc. not only lowers the temperature in the barn, but also can decompose various odor components coming out of the barn, and can also decompose germs and viruses. The photocatalyst type light shielding agent as described.
JP2004102438A 2004-03-31 2004-03-31 Titanium dioxide photocatalytic light-shielding agent Pending JP2005287304A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007289018A (en) * 2006-04-21 2007-11-08 Nakada Sangyo Kk Deodorant barn, deodorant outdoor facility and deodorant net
CN102573448A (en) * 2009-10-09 2012-07-11 富士通株式会社 Protective bag
JP2012231795A (en) * 2012-07-30 2012-11-29 Toshiro Ito Greenhouse for plant cultivation
JP2020068740A (en) * 2018-11-02 2020-05-07 アキレス株式会社 Agricultural light-shielding agent

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007289018A (en) * 2006-04-21 2007-11-08 Nakada Sangyo Kk Deodorant barn, deodorant outdoor facility and deodorant net
CN102573448A (en) * 2009-10-09 2012-07-11 富士通株式会社 Protective bag
CN102573448B (en) * 2009-10-09 2014-07-16 富士通株式会社 Protective bag
JP2012231795A (en) * 2012-07-30 2012-11-29 Toshiro Ito Greenhouse for plant cultivation
JP2020068740A (en) * 2018-11-02 2020-05-07 アキレス株式会社 Agricultural light-shielding agent

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