JPH04198103A - Dispersant for bordeaux mixture - Google Patents
Dispersant for bordeaux mixtureInfo
- Publication number
- JPH04198103A JPH04198103A JP2331342A JP33134290A JPH04198103A JP H04198103 A JPH04198103 A JP H04198103A JP 2331342 A JP2331342 A JP 2331342A JP 33134290 A JP33134290 A JP 33134290A JP H04198103 A JPH04198103 A JP H04198103A
- Authority
- JP
- Japan
- Prior art keywords
- dispersant
- bordeaux
- adduct
- bordeaux mixture
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002270 dispersing agent Substances 0.000 title claims abstract description 23
- 239000005739 Bordeaux mixture Substances 0.000 title abstract 4
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 13
- 229920000768 polyamine Polymers 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims description 28
- 239000002245 particle Substances 0.000 abstract description 17
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract description 7
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 abstract description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract description 5
- 239000010419 fine particle Substances 0.000 abstract description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000002466 imines Chemical class 0.000 abstract 1
- PZZICILSCNDOKK-UHFFFAOYSA-N propane-1,2,3-triamine Chemical compound NCC(N)CN PZZICILSCNDOKK-UHFFFAOYSA-N 0.000 abstract 1
- 229960001124 trientine Drugs 0.000 abstract 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 229910000365 copper sulfate Inorganic materials 0.000 description 9
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 9
- 239000000292 calcium oxide Substances 0.000 description 5
- 235000012255 calcium oxide Nutrition 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920002873 Polyethylenimine Polymers 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 229930183217 Genin Natural products 0.000 description 1
- 244000141359 Malus pumila Species 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- BCHAIBIXCFCBIS-UHFFFAOYSA-N n'-(2-aminoethyl)ethane-1,2-diamine;oxirane Chemical compound C1CO1.NCCNCCN BCHAIBIXCFCBIS-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Landscapes
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は粒子径の細かい均一な粒子を含有するボルドー
液を得るための分散剤に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a dispersant for obtaining a Bordeaux liquor containing uniform particles with a fine particle size.
（従来の技術〕
ボルドー液は、リンゴ、ナシ、ブドウをはじめ様々な農
作物の防害虫、防菌用農薬として、長年にわたって伝統
的に使用されてきた。(Prior Art) Bordeaux liquid has been traditionally used for many years as an insecticide and fungicidal pesticide for various agricultural crops including apples, pears, and grapes.
ボルドー液は、安価であるばかりでなく、近年とみに問
題となっている蓄積性の有機塩素系農薬を避ける傾向か
らも、すたれることなく、却ってその使用量が漸増して
いる。Bordeaux liquid is not only cheap, but also because there is a trend to avoid accumulating organic chlorine pesticides, which have become a problem in recent years.
このボルドー液の調製は、従来より、原料となる硫酸銅
と生石灰とを別々に水溶液または水分散液としたのち、
たとえば冷時撹拌しながら石灰乳液に硫酸銅水溶液を混
合することにより、行われてきた。硫酸銅と生石灰との
混合比率は、防害虫や防菌の目的により異なるが、いず
れにしても上記のように混合し反応させて得た分散体を
、スプレーによって農作物に散布している。Traditionally, this Bordeaux liquid is prepared by separately making an aqueous solution or dispersion of the raw materials copper sulfate and quicklime, and then
For example, this has been done by mixing an aqueous copper sulfate solution with a lime emulsion while stirring in the cold. The mixing ratio of copper sulfate and quicklime varies depending on the purpose of preventing pests and bacteria, but in any case, the dispersion obtained by mixing and reacting as described above is sprayed onto agricultural crops.
このようなボルドー液の調製や散布法に関する技術とし
ては、たとえば特開昭５１−４４６２９号公報、同５２
−３８３７１号公報などにその記載がみられ、また長期
間安定なボルドー液を得るために、たとえば特開昭５３
−５２６２２号公報にはりゲニンスルホン酸塩などの保
護コロイド剤を用いることが開示されている。Techniques related to the preparation and spraying of Bordeaux liquid include, for example, Japanese Patent Application Laid-Open Nos. 51-44629 and 52
The description can be found in Japanese Patent Laid-Open No. 38371, etc., and in order to obtain Bordeaux liquid that is stable for a long period of time, for example,
JP-A-52622 discloses the use of a protective colloid agent such as genin sulfonate.
しかるに、ボルドー液は、石灰乳液のつくり方やこの乳
液と硫酸銅水溶液との混合の仕方などで、品質、安定性
などが大きく影響され、上記公知の技術で粒子径の細か
い均一な粒子を含有するボルドー液を得るのは容易では
なく、かなりの熟練が要求される。However, the quality and stability of Bordeaux liquor are greatly affected by the way the lime emulsion is made and the way this emulsion is mixed with the aqueous copper sulfate solution. Obtaining Bordeaux liquid is not easy and requires considerable skill.
粒子径が大きくなると、散布したときの農作物への展着
性が悪く雨などが降った場合に簡単に流れ落ちたり、噴
霧液の容器内で沈降してノズルが詰まったり濃度がばら
ついたりして均一な散布ができないといった問題を生し
る。If the particle size becomes large, it will not spread easily on crops when sprayed, and it will easily wash off when it rains, or it will settle in the spray liquid container, clogging the nozzle, and causing uneven concentration. This results in problems such as not being able to spray properly.
本発明は、以上の観点から、粒子径の細かい均一な粒子
を含有するボルドー液の調製を可能とし、また分散粒子
の安定化や高濃度化にも寄与するボルドー液用の分散剤
を提供することを目的としている。From the above points of view, the present invention aims to provide a dispersant for Bordeaux liquid that enables the preparation of Bordeaux liquid containing uniform particles with a fine particle size and also contributes to stabilization and high concentration of dispersed particles. The purpose is
本発明者らは、上記の目的を達成するために鋭意検討し
た結果、ボルドー液の調製に際し、分散剤として特定の
化合物を添加混合すると、粒子径の細かい均一な粒子を
含有するボルドー液が得られ、しかもこのボルドー液は
分散粒子の安定性にすくれ、また高濃度としたときでも
低粘度で安定な性状を示すものであることを知り、本発
明に到達した。As a result of intensive studies to achieve the above object, the present inventors found that when a specific compound is added and mixed as a dispersant during the preparation of Bordeaux liquid, a Bordeaux liquid containing uniform particles with a fine particle size can be obtained. Furthermore, it was discovered that this Bordeaux liquid has poor stability of dispersed particles, and exhibits stable properties with low viscosity even when the concentration is high, leading to the present invention.
すなわち、本発明は、ポリアミンのアルキレンオキシド
付加物からなるボルドー液用分散剤に係るものである。That is, the present invention relates to a dispersant for Bordeaux liquid comprising an alkylene oxide adduct of a polyamine.
本発明に用いられるポリアミンとしては、エチレンジア
ミン、トリメチレンジアミン、ヘキサメチレンジアミン
、ジエチレントリアミン、１，２゜３−トリアミノプロ
パン、トリエチレンテトラミンなどのほか、分子量５０
０〜５００，０００のポリエチレンイミンが挙げられる
。Examples of polyamines used in the present invention include ethylenediamine, trimethylenediamine, hexamethylenediamine, diethylenetriamine, 1,2゜3-triaminopropane, triethylenetetramine, etc.
0 to 500,000 polyethyleneimine.
本発明の分散剤は、上記のポリアミンのアルキレンオキ
シド付加物、つまり上記のポリアミンにエチレンオキシ
ド、プロピレンオキシド、ブチレンオキシドなどのアル
キレンオキシドを単独または二種以上のブロックまたは
ランダム状付加物として付加重合させてなるものである
。The dispersant of the present invention is an alkylene oxide adduct of the above polyamine, that is, an alkylene oxide such as ethylene oxide, propylene oxide, butylene oxide, etc. is addition-polymerized to the above polyamine alone or as a block or random adduct of two or more types. It is what it is.
このようなアルキレンオキシド付加物は、公知の方法に
よって容易に得られ、その分子量も特に規定されないが
、一般には、重量平均分子量で１゜０００〜１，０００
，０００の範囲にあるものが好ましく用いられる。Such an alkylene oxide adduct can be easily obtained by a known method, and its molecular weight is not particularly limited, but it generally has a weight average molecular weight of 1°000 to 1,000.
,000 is preferably used.
本発明の分散剤として用いる上記アルキレンオキシド付
加物の具体例としては、たとえばエチレンジアミンのエ
チレンオキシド（３０モル）付加物、トリメチレンジア
ミンのプロピレンオキシド（１０モル）エチレンオキシ
ド（５０モル）付加物、ヘキサメチレンジアミンのブチ
レンオキシド（２５モル）エチレンオキシド（１００モ
ル）付加物、ジエチレントリアミンのエチレンオキシド
（５０モル）付加物、ポリエチレンイミン（分子量＝３
，０００）のエチレンオキシド（３０モル）付加物、ポ
リエチレンイミン（分子量＝２０．０００）のプロピレ
ンオキシド（２０モル）エチレンオキシド（８０モル）
付加物、ポリエチレンイミン（分子量−２００，０００
）のプロピレンオキシド（２００モル）エチレンオキシ
ド（８００モル）付加物などが挙げられる。Specific examples of the alkylene oxide adducts used as the dispersant of the present invention include ethylene oxide (30 mol) adduct of ethylene diamine, propylene oxide (10 mol) ethylene oxide (50 mol) adduct of trimethylene diamine, and hexamethylene diamine. Butylene oxide (25 mol) ethylene oxide (100 mol) adduct, diethylenetriamine ethylene oxide (50 mol) adduct, polyethyleneimine (molecular weight = 3
,000), propylene oxide (20 moles) and ethylene oxide (80 moles) of polyethyleneimine (molecular weight = 20,000).
Adduct, polyethyleneimine (molecular weight -200,000
) with propylene oxide (200 mol) and ethylene oxide (800 mol).
なお、本発明では、必要により上記のアルキレンオキシ
ド付加物の種々の変成物を分散剤として用いることもで
きる。この変成物としては、たとえば末端ＯＨ基とエピ
ハロヒドリンとの反応物、分子中に含まれる窒素原子の
アルキル化（第四級化物を含む）または中和物、末端Ｏ
Ｈ基の硫酸エステル化物やリン酸エステル化物、末端Ｏ
Ｈ基のカルボン酸エステル化物などがある。In addition, in the present invention, various modified products of the above-mentioned alkylene oxide adducts can also be used as a dispersant, if necessary. Examples of this modified product include a reaction product of a terminal OH group and epihalohydrin, an alkylated (including quaternized product) or neutralized product of the nitrogen atom contained in the molecule, and a product of the terminal O
H group sulfate esters, phosphoric esters, terminal O
Examples include carboxylic acid esters of H groups.
本発明の分散剤である上記ポリアミンのアルキレンオキ
シド付加物の添加量は、ボルドー液の固形分あたり通常
０．０１〜２０重量％、好ましくは０．１〜５重量％と
なるようにするのがよい。この添加量が過少では本発明
の効果が十分に得られず、過多になっても効果の顕著な
向上がみられないので経済的に不利である。The amount of the alkylene oxide adduct of the polyamine, which is the dispersant of the present invention, is usually 0.01 to 20% by weight, preferably 0.1 to 5% by weight, based on the solid content of the Bordeaux liquid. . If the amount added is too small, the effect of the present invention will not be sufficiently obtained, and if the amount added is too small, no significant improvement in the effect will be observed, which is economically disadvantageous.
本発明において、上記ポリアミンのアルキレンオキシド
付加物の添加時期は特に規定されるものではなく、硫酸
銅または硫酸銅水溶液にあらかじめ添加してもよいし、
生石灰、消石灰またはこれらの水分散液に添加してもよ
く、さらにはボルドー液の調製後に添加してもよい。In the present invention, the timing of addition of the alkylene oxide adduct of the polyamine is not particularly defined, and it may be added in advance to the copper sulfate or copper sulfate aqueous solution,
It may be added to quicklime, slaked lime, or an aqueous dispersion thereof, or may be added after the Bordeaux liquid is prepared.
なお、本発明の分散剤を用いるボルドー液の調製に際し
て、必要に応じて適宜他の界面活性剤を併用することが
できる。この界面活性剤としては、陽イオン界面活性剤
、陰イオン界面活性剤、非イオン界面活性剤、両性界面
活性剤など公知の各種の界面活性剤が広く包含される。In addition, when preparing a Bordeaux liquid using the dispersant of the present invention, other surfactants can be appropriately used in combination as necessary. The surfactant includes a wide variety of known surfactants such as cationic surfactants, anionic surfactants, nonionic surfactants, and amphoteric surfactants.
また、上記の界面活性剤のほか、珪酸ナトリウムやリン
酸ナトリウムなどの各種のアルカリ剤、キレート剤、防
腐剤などの公知の添加剤を併用しても差し支えない。In addition to the above-mentioned surfactants, known additives such as various alkali agents such as sodium silicate and sodium phosphate, chelating agents, and preservatives may be used in combination.
以上のように、ポリアミンのアルキレンオキシド付加物
からなる分散剤を用いることにより、粒子径の細かい均
一な粒子を含有するボルドー液を容易に調製でき、また
分散粒子の安定性にすぐれており、高濃度にしたときで
も低粘度で安定な性状を示すボルドー液を調製すること
ができる。As described above, by using a dispersant made of an alkylene oxide adduct of polyamine, Bordeaux liquid containing fine and uniform particles can be easily prepared, and the stability of the dispersed particles is excellent, resulting in high concentration. It is possible to prepare a Bordeaux liquid that exhibits low viscosity and stable properties even when
つぎに、本発明の実施例を記載してより具体的に説明す
る。Next, examples of the present invention will be described in more detail.
実施例
第１表に示すポリアミンのアルキレンオキシド付加物を
本発明の実施例１〜７のボルドー液用分散剤とし、この
各分散剤を用いて以下の調製法Ａ。EXAMPLES The alkylene oxide adducts of polyamines shown in Table 1 were used as dispersants for Bordeaux liquors in Examples 1 to 7 of the present invention, and each of these dispersants was used in the following preparation method A.
Ｂによりそれぞれ二種のボルドー液を調製した。Two types of Bordeaux liquors were prepared using B.
分散剤の使用量は、調製法Ａ、Ｂ共に、調製後のボルド
ー液の固形分に対する割合が第１表に示す量（重量％）
となるようにした。For both preparation methods A and B, the amount of dispersant used is the amount (wt%) shown in Table 1, based on the solid content of Bordeaux liquid after preparation.
I made it so that
〈調製法人〉
硫酸銅（ＣｕＳＯ４・５Ｈ２０）４ｇを１２ｍ１の水に
溶解したものと、生石灰１２ｇを４８ｍ１の水に分散し
たものとを用意し、実施例１〜７の各分散剤の所定量を
溶解した水９４０ｍｌの中に撹拌しながらまず石灰乳液
を分散し、さらに続いて硫酸銅水溶液を少しずつ滴下し
て、ボルドー液を調製した。<Preparation corporation> Prepare 4 g of copper sulfate (CuSO4.5H20) dissolved in 12 ml of water and 12 g of quicklime dispersed in 48 ml of water, and add the prescribed amount of each dispersant of Examples 1 to 7. A lime emulsion was first dispersed in 940 ml of dissolved water with stirring, and then an aqueous copper sulfate solution was added dropwise little by little to prepare a Bordeaux liquid.
〈調製法Ｂ〉
生石灰１２ｇを３０ｍｆｆの水に分散したものに、実施
例１〜７の各分散剤の所定量を添加したのち、硫酸銅（
ＣｕＳＯａ −５Ｈ２０）４ｇを１２ｍｆの水に溶解
したものを撹拌しながら少しずつ滴下して、濃度が約２
５重量％である高濃度のボルドー液を調製した。<Preparation method B> To a dispersion of 12 g of quicklime in 30 mff of water, a predetermined amount of each dispersant of Examples 1 to 7 was added, and then copper sulfate (
Dissolve 4g of CuSOa-5H20) in 12mf of water and drop it little by little while stirring until the concentration is about 2.
A highly concentrated Bordeaux liquor of 5% by weight was prepared.
このようにして調製した各二種のボルドー液につき、下
記の要領で、安定性評価試験および粒子径測定試験を行
った結果を、分散剤を添加せずに上記と同様にして調製
した比較例のボルドー液の結果と合わせて、第１表に示
す。For each of the two types of Bordeaux liquors prepared in this way, stability evaluation tests and particle size measurement tests were conducted in the manner described below. The results are shown in Table 1 together with the results for Bordeaux liquid.
〈安定性評価試験〉
５礼１■法Ａによるボルドー゛
１００ｍｊ！の共栓付きメスシリンダーに、ボルドー液
を、上記シリンダーの目盛りが１００のところまで入れ
、共栓をしたのち１０回激しく振って混合してから静置
し、３０分後の沈降層の目盛りを読み、数値が大きいも
のが安定であると判定した。<Stability evaluation test> 5 bows 1 ■ Bordeaux by method A 100mj! Pour the Bordeaux liquid into a graduated cylinder with a stopper until the scale of the cylinder reaches 100, close the stopper, shake vigorously 10 times to mix, then let stand, and read the scale of the sediment layer after 30 minutes. , it was determined that the larger the value, the more stable.
５調製法Ｂによるボルドー゛
１００ｍ７！のマヨネーズ瓶にボルドー液を入れて１力
月間放置したのち、ガラス棒で軽く撹拌したときに、低
粘度の分散液が再び得られたものを○、軽く撹拌しただ
けではもとに戻らないものを×、と評価した。5 Bordeaux by Preparation Method B 100m7! If Bordeaux liquid is poured into a mayonnaise bottle and left for one month, then a low viscosity dispersion is obtained again when stirred lightly with a glass rod. It was evaluated as ×.
〈粒子径測定試験〉
調製法Ａ、Ｂによる各ボルドー液につき、マイクロトラ
ック〔日機装側製〕を用いて、平均粒子径を測定した。<Particle Size Measurement Test> The average particle size of each of the Bordeaux liquors produced by Preparation Methods A and B was measured using a Microtrack (manufactured by Nikkiso).
上記の第１表の結果から明らかなように、本発明の分散
剤を用いると、希薄溶液において粒子径の小さい均一で
安定性の良い粒子を含有するボルドー液が得られるだけ
でなく、高濃度のボルドー液においても容易に再分散可
能なソフトバッキングなものが得られるのに対し、分散
剤を用いない比較例ではこのようなボルドー液は得られ
ないことがわかる。As is clear from the results in Table 1 above, when the dispersant of the present invention is used, not only can a Bordeaux liquid containing uniform and stable particles with a small particle size be obtained in a dilute solution, but also a Bordeaux liquid containing highly concentrated particles can be obtained. It can be seen that a soft backing that can be easily redispersed can be obtained even in Bordeaux liquid, whereas such a Bordeaux liquid cannot be obtained in the comparative example in which no dispersant is used.
Claims (1)
ボルドー液用分散剤。(1) A dispersant for Bordeaux liquid consisting of an alkylene oxide adduct of polyamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2331342A JPH04198103A (en) | 1990-11-28 | 1990-11-28 | Dispersant for bordeaux mixture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2331342A JPH04198103A (en) | 1990-11-28 | 1990-11-28 | Dispersant for bordeaux mixture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04198103A true JPH04198103A (en) | 1992-07-17 |
Family
ID=18242613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2331342A Pending JPH04198103A (en) | 1990-11-28 | 1990-11-28 | Dispersant for bordeaux mixture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04198103A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997020879A1 (en) * | 1995-12-01 | 1997-06-12 | Basf Aktiengesellschaft | Process for the preparation of hydroxyalkylated polyethyleneimines |
| EP1342413A1 (en) * | 2002-03-08 | 2003-09-10 | BMS Micro-Nutrients N.V. | Plant protection formulation containing a copper-polyamine chelate |
| JP2006504759A (en) * | 2002-10-30 | 2006-02-09 | クラリアント・ゲゼルシヤフト・ミト・ベシユレンクテル・ハフツング | Pesticide formulations containing alkoxylated amines |
| JP2007056016A (en) * | 2005-07-29 | 2007-03-08 | Inoue Sekkai Kogyo Kk | Method for producing high concentration Bordeaux liquid composition |
| EP1910250A4 (en) * | 2005-07-12 | 2011-11-30 | Adelaide Res & Innovation Pty | CHELATORS FOR FERTILIZERS BASED ON MICRONUTRIENTS |
| JP2014205088A (en) * | 2013-04-10 | 2014-10-30 | 日油株式会社 | Aqueous dispersant and aqueous dispersion composition |
-
1990
- 1990-11-28 JP JP2331342A patent/JPH04198103A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997020879A1 (en) * | 1995-12-01 | 1997-06-12 | Basf Aktiengesellschaft | Process for the preparation of hydroxyalkylated polyethyleneimines |
| EP1342413A1 (en) * | 2002-03-08 | 2003-09-10 | BMS Micro-Nutrients N.V. | Plant protection formulation containing a copper-polyamine chelate |
| JP2006504759A (en) * | 2002-10-30 | 2006-02-09 | クラリアント・ゲゼルシヤフト・ミト・ベシユレンクテル・ハフツング | Pesticide formulations containing alkoxylated amines |
| EP1910250A4 (en) * | 2005-07-12 | 2011-11-30 | Adelaide Res & Innovation Pty | CHELATORS FOR FERTILIZERS BASED ON MICRONUTRIENTS |
| JP2007056016A (en) * | 2005-07-29 | 2007-03-08 | Inoue Sekkai Kogyo Kk | Method for producing high concentration Bordeaux liquid composition |
| JP2014205088A (en) * | 2013-04-10 | 2014-10-30 | 日油株式会社 | Aqueous dispersant and aqueous dispersion composition |
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