JPH0737863B2 - Reversible exothermic cold heat generator - Google Patents
Reversible exothermic cold heat generatorInfo
- Publication number
- JPH0737863B2 JPH0737863B2 JP1143720A JP14372089A JPH0737863B2 JP H0737863 B2 JPH0737863 B2 JP H0737863B2 JP 1143720 A JP1143720 A JP 1143720A JP 14372089 A JP14372089 A JP 14372089A JP H0737863 B2 JPH0737863 B2 JP H0737863B2
- Authority
- JP
- Japan
- Prior art keywords
- adsorption
- adsorbed
- metal
- adsorbing
- cold heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000002441 reversible effect Effects 0.000 title claims description 12
- 239000002184 metal Substances 0.000 claims description 27
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000003463 adsorbent Substances 0.000 claims description 9
- 239000000835 fiber Substances 0.000 claims description 6
- 238000001179 sorption measurement Methods 0.000 description 30
- 239000007788 liquid Substances 0.000 description 23
- 238000001816 cooling Methods 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 13
- 230000007420 reactivation Effects 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- -1 CFC compound Chemical class 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
Landscapes
- Sorption Type Refrigeration Machines (AREA)
Description
【発明の詳細な説明】 産業上の利用分野 本発明は被吸着動作液体蒸気の吸着と、吸着後の再活性
化処理にかかわる吸着動作体の加熱による被吸着動作液
体成分の脱離が効果的に行える可逆発熱冷熱発生器に関
するものである。TECHNICAL FIELD The present invention is effective in adsorbing a liquid vapor to be adsorbed and desorbing a liquid component to be adsorbed by heating an adsorbing body involved in a reactivation process after adsorption. The present invention relates to a reversible exothermic cold heat generator that can be used in
従来の技術 従来、吸着材を動作体とし、これと被吸着動作液体をそ
れぞれの容器に収容し、遮断と開口を任意に行えるバル
ブを配設した連通管で連結し、系を真空とした可逆加熱
冷却の行える装置は例えば、特公昭61-4008、特公昭61-
6307、特開昭60-232242等によって公知である。これら
の技術はいずれも動作体たる吸着材は単体でフレーク、
粒状あるいは成型体によるものであった。また、動作体
たる吸着材は被吸着動作液体蒸気の吸着の容易化とこれ
による発熱の移動を向上させ再活性化処理にかかわる被
動作吸着液体成分の脱離を効果的におこなう目的から、
特開昭60-232242、特開昭59-206047では金属多孔質体の
三次元的ネット構成の空隙部分にゼオライトを充填する
という方策を講じていた。Conventional technology Conventionally, an adsorbent was used as an operating body, and this and the liquid to be adsorbed were housed in respective containers and connected by a communication pipe equipped with a valve that can arbitrarily block and open, and the system was vacuumized and reversible. Devices capable of heating and cooling are, for example, Japanese Patent Publication No. 61-4008 and Japanese Patent Publication No. 61-
6307, JP-A-60-232242 and the like. In each of these technologies, the adsorbent that is the moving body is a single flake,
It was a granular or molded product. In addition, the adsorbent as an operating body facilitates adsorption of the adsorbed operating liquid vapor and improves the transfer of heat due to this, thereby effectively desorbing the adsorbed operating liquid component involved in the reactivation process,
In Japanese Patent Laid-Open Nos. 60-232242 and 59-206047, a measure is taken to fill the voids in the three-dimensional net structure of the metal porous body with zeolite.
発明が解決しようとする課題 このような従来の可逆加熱冷却発生器では、被吸着動作
液体蒸気が吸着動作体の粒子の間隙をぬってゆるやかに
拡散がおこるため、吸着が進行するのに時間を要し、極
めて緩慢なものとなる。また被動作液体蒸気の吸着に伴
う吸着動作体の発熱は拡散が十分でなく、これによって
吸着動作体が十分吸着能力を有する温度域よりも高温に
なってしまうため、迅速な吸着動作が期待できなかっ
た。さらに吸着能力が尽きた吸着動作体の再活性化処理
時の加熱による熱の伝搬も悪く、さらに脱離した被吸着
動作液体蒸気の飛散もスムーズでなかったので、この操
作に時間を要するものであった。DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention In such a conventional reversible heating / cooling generator, the liquid vapor to be adsorbed penetrates the gaps between the particles of the adsorbing body and gently diffuses, so that it takes time for the adsorption to proceed. It's very slow. In addition, the heat generated by the adsorbing body due to the adsorption of the liquid vapor to be operated is not sufficiently diffused, which causes the adsorbing body to reach a temperature higher than the temperature range in which it has a sufficient adsorbing ability. There wasn't. Furthermore, the heat transfer due to heating during the reactivation treatment of the adsorption operation body that has exhausted the adsorption capacity was poor, and the desorbed operation target liquid vapor was not scattered smoothly, so this operation requires time. there were.
本発明は上記の課題を解決した可逆発熱冷却発生器の提
供を目的とするものである。An object of the present invention is to provide a reversible exothermic cooling generator that solves the above problems.
課題を解決するための手段 本発明は上記の課題を解決するために、吸着材を担持し
たハニカム状構造体の多数の個体間に、金属網・パンチ
ングメタル板・多孔性金属体・金属繊維から選ばれた１
種またはそれ以上を挟み込み積層して吸着動作体とな
し、これを装着した構成の可逆加熱冷却発生器とするも
のである。Means for Solving the Problems In order to solve the above problems, the present invention is provided between a large number of individual honeycomb-shaped structures carrying an adsorbent, from a metal net, a punching metal plate, a porous metal body, and metal fibers. Chosen 1
A reversible heating / cooling generator having a structure in which one or more kinds are sandwiched and laminated to form an adsorbing body, and the adsorbing body is mounted.
作用 本発明に使用する吸着構造体は、吸着材を担持したハニ
カム状構造体の多数の個体となし、この個体間に熱の良
導体である金属網・パンチメタル板・多孔性金属体・金
属繊維から選ばれた１種またはそれ以上を組合せ、挟み
込んだ状態で積層している。このためハニカム構造体の
通孔中に流入した被吸着動作液体蒸気は順次吸着されな
がら通過し、上記の挟み込んだ金属層に流出する。ここ
でこの被吸着動作液体蒸気は攪乱されて、その濃度が均
質化された後、次のハニカム状個体の通孔へと移動す
る。このような動きを挟み込んだ金属体によって多数回
繰り返すことになるため、切断されていない従来のハニ
カム単体や粒子状やフレーク状の吸着動作体の場合に比
較して被吸着動作液体蒸気の吸着動作体への吸着速度と
その量が大幅に向上するものとなる。吸着動作体は一般
に熱伝導率が断熱レンガと同等で悪く、その吸着による
自己発熱の放散を、ハニカム状個体間に配設した金属体
が促進する役割も果たすことから吸着動作体が吸着力を
有する温度範囲下に保持することが可能となるため、本
来有している吸着能力を持続できる。また吸着力の尽き
た吸着動作体は、加熱することにより吸着した被吸着動
作液体蒸気を吐き出し、吸着活性を取り戻すことができ
る。この再活性時の熱源からの熱の伝達をスムーズに吸
着動作体に伝達する役割をも果たすことからも時間短縮
がはかれる。加えて再活性処理後の冷却に際してこの急
速化が可能となる。Action The adsorption structure used in the present invention is composed of a large number of honeycomb-shaped structures carrying an adsorbent, and a metal net, a punch metal plate, a porous metal body, and metal fibers which are good conductors of heat among these individuals. One or more selected from the above are combined and laminated in a sandwiched state. Therefore, the liquid vapor to be adsorbed, which has flowed into the through holes of the honeycomb structure, successively passes while being adsorbed, and flows out to the sandwiched metal layer. Here, the liquid vapor to be adsorbed is disturbed, its concentration is homogenized, and thereafter, it is moved to the next through hole of the honeycomb-shaped solid. Since such a movement is repeated many times depending on the sandwiched metal body, the adsorption operation of the liquid vapor is performed as compared with the case of the conventional uncut honeycomb or the adsorption operation body in the form of particles or flakes. The rate and amount of adsorption to the body will be greatly improved. In general, the adsorption action body is not as good in heat conductivity as the heat insulating brick, and the adsorption action body also plays a role of promoting the dissipation of self-heating due to the adsorption by the metal body arranged between the honeycomb-shaped solids. Since it is possible to keep the temperature within the temperature range that the toner has, it is possible to maintain the inherent adsorption capacity. Further, the adsorption operation body that has exhausted the adsorption force can discharge the adsorption-targeted operation liquid vapor adsorbed by heating and regain the adsorption activity. The time can be shortened because it also plays the role of smoothly transmitting the heat from the heat source at the time of reactivation to the adsorption operation body. In addition, this speeding up becomes possible upon cooling after the reactivation treatment.
実施例 以下に本発明の一実施例を添付図面にもとずいて説明す
る。Embodiment An embodiment of the present invention will be described below with reference to the accompanying drawings.
本発明の可逆発熱冷熱発生器の基本構成を示した第１図
において、１は下記に示す構成に基ずいてなされた本発
明で使用する吸着動作体２を収容する容器、３は被吸着
動作液体４を収容する容器である。バルブ５は被吸着動
作液体蒸気６を導くパイプ９・9aに連結され、初期の加
熱真空処理を終えて系内は真空系を維持している。In FIG. 1, which shows the basic configuration of the reversible exothermic cold heat generator of the present invention, 1 is a container for accommodating the adsorption operation body 2 used in the present invention, which is based on the configuration shown below, and 3 is the operation to be adsorbed. This is a container for containing the liquid 4. The valve 5 is connected to the pipes 9 and 9a for guiding the liquid vapor 6 to be adsorbed, and the vacuum system is maintained after the initial heating vacuum processing is completed.
次に、この動作を説明する。第１図において、バルプ５
を開くと容器１に収容されている吸着動作体２の強い吸
着力によって、容器３に収容されている被吸着動作液体
４が蒸発し、その蒸気６がパイプ９・9aを通って容器１
に収容されている吸着動作体２に吸着されて行く。この
時に吸着動作体２は被吸着動作液体蒸気６の吸着を強力
に推進するため、容器１の温度が上昇し加熱部が形成さ
れる。継続して被吸着動作液体蒸気６の発生が断熱的に
かつ急激に促進されて行くことから、被吸着動作液体４
の温度の急激な低下を出現させる。したがって容器１が
冷却部として利用できるものとなる。Next, this operation will be described. In Fig. 1, valve 5
When opened, the liquid to be adsorbed 4 contained in the container 3 evaporates due to the strong adsorption force of the adsorption body 2 contained in the container 1, and the vapor 6 passes through the pipes 9 and 9a to form the container 1
Will be adsorbed by the adsorbing body 2 housed in. At this time, the adsorbing body 2 strongly promotes the adsorption of the liquid vapor 6 to be adsorbed, so that the temperature of the container 1 rises and a heating part is formed. Since the generation of the adsorbed working liquid vapor 6 is continuously adiabatically and rapidly accelerated, the adsorbed working liquid 4 is generated.
A sudden drop in temperature. Therefore, the container 1 can be used as a cooling unit.
ここに示した本実施例の可逆加熱冷却発生器は一例であ
り、その吸着によって加熱冷却が行える原理が満足され
るものであれば形状はこれに限定するものではない。The reversible heating and cooling generator of the present embodiment shown here is an example, and the shape is not limited to this as long as the principle of heating and cooling by adsorption is satisfied.
次に、本実施例で使用する吸着動作体について説明す
る。第２図は容器に収容した本実施例の吸着動作体を示
した断面の部分図である。この図において、容器１に収
容した吸着動作体２はハニカム状基体としてアルミナシ
リカ繊維の集積体を使用し、これに吸着材としてゼオラ
イト13Xを付着担持させて形成し、ハニカム状構造体の
通孔に対して直角方向に切断した厚み5mmのものの各々
の個体間に、線径1mmの銅線による金網10を挟み込み幾
重にも積層して吸着動作体となしたものである。また、
吸着動作液体として水を使用した場合の動作は、ゼオラ
イトの強い吸着力のため移動してきた水蒸気4aがハニカ
ム構造体の通孔をゼオライトに吸着されながら通過し、
吸着されなかった水蒸気が挟み込まれた金属網で攪乱さ
れ濃度が均一化された上で次の通孔へ移動し吸着されて
いく。この動作時の冷却器の温度降下は第３図中曲線１
に示すように、従来の直径約3mmの粒子状成形体を充填
していた場合の曲線２に示す冷却効果に比較して大き
く、強い冷却性を示している。このような吸着動作の継
続により吸着動作体の吸着能力が消失した場合、吸着動
作体を外部から加熱し再活性処理を行う。この場合の状
態は、処理時間を横軸に脱離する水の量を縦軸に示した
第４図中曲線１に示した本実施例によるものに比較し
て、従来品を示す曲線２は水の脱離量が少なく、したが
って再活性化処理のための時間が短縮できる。本実施例
で有効に使用される吸着動作体を形成するためのハニカ
ム基体としては、上記の他にセラミック焼結体・多孔性
炭素繊維・金属薄板によればよい。また吸着材成分とし
ては上記の他にゼオライト10X・A3・A4・A5・Ｙ形やシ
リカゲル・シリカアルミナゲル・活性炭が有効である。
本実施例で使用される被吸着動作液体は、単一組成の水
は勿論のこと、有機溶剤単体、水と有機溶剤との混合
物、さらにはフロン化合物・アンモニアが使用できる。
本実施例で使用するハニカム状構造体の切断厚みは特に
限定するものではなく、この固体間に挟み込む金属体へ
の熱の伝達が良好で、さらに吸着する被吸着液体蒸気の
攪乱が頻繁に発生する状態となる厚みであればよい。ま
た本実施例では金属体は導線による場合を示したが、他
にパンチメタル板・多孔性金属体・金属繊維によっても
同様の結果をもたらし、これらの併用によっても同様の
結果をもたらすものである。Next, the suction operation body used in this embodiment will be described. FIG. 2 is a partial cross-sectional view showing the suction operation body of this embodiment housed in a container. In this figure, the adsorbing body 2 housed in the container 1 is formed by using an aggregate of alumina-silica fibers as a honeycomb substrate and adsorbing and carrying zeolite 13X as an adsorbent on the aggregate. A wire mesh 10 made of a copper wire having a wire diameter of 1 mm is sandwiched between individual pieces each having a thickness of 5 mm cut in a direction perpendicular to the above to form an adsorbing body. Also,
When water is used as the adsorption operation liquid, the water vapor 4a that has moved due to the strong adsorption force of the zeolite passes through the through holes of the honeycomb structure while being adsorbed by the zeolite,
The unadsorbed water vapor is disturbed by the sandwiched metal net to make the concentration uniform, then moves to the next through hole and is adsorbed. The temperature drop of the cooler during this operation is curve 1 in FIG.
As shown in FIG. 3, the cooling effect is larger and stronger than the cooling effect shown in the curve 2 when the conventional particulate compact having a diameter of about 3 mm is filled. When the adsorbing ability of the adsorbing body disappears due to the continuation of such adsorbing operation, the adsorbing body is heated from the outside to perform the reactivation process. In this case, the state of the curve 2 showing the conventional product is compared with that of the present example shown in the curve 1 in FIG. 4 in which the abscissa represents the treatment time and the ordinate represents the amount of desorbed water. The amount of desorbed water is small and therefore the time for the reactivation treatment can be shortened. In addition to the above, a ceramic sintered body, a porous carbon fiber, or a metal thin plate may be used as the honeycomb substrate for forming the adsorption operation body effectively used in this embodiment. In addition to the above, zeolite 10X / A3 / A4 / A5 / Y type and silica gel / silica-alumina gel / activated carbon are effective as adsorbent components.
As the liquid to be adsorbed used in this embodiment, not only water having a single composition but also an organic solvent alone, a mixture of water and an organic solvent, and a CFC compound / ammonia can be used.
The cutting thickness of the honeycomb-shaped structure used in the present embodiment is not particularly limited, heat transfer to the metal body sandwiched between the solids is good, and the disturbance of the adsorbed liquid vapor frequently occurs. Any thickness will suffice as long as it is ready. Further, in the present embodiment, the case where the metal body is the conductive wire is shown, but the punch metal plate, the porous metal body, and the metal fiber also bring the same result, and the combination thereof also brings the same result. .
発明の効果 以上に説明したように吸着材を担持したハニカム状構造
体を切断した多数の個体間に、金属網・パンチメタル板
・多孔性金属体・金属繊維から選ばれた１種またはそれ
以上を組み合わせて挟み込み積層して吸着動作体とし、
これを装着して可逆発熱冷却発生器となすことで、優れ
た加熱と冷却性能が得られ、再活性処理にかかわる加熱
時間と冷却時間の短縮化が図れる可逆発熱冷熱発生器の
提供を可能にした。EFFECTS OF THE INVENTION As described above, one or more selected from a metal net, a punched metal plate, a porous metal body, and a metal fiber are provided among a large number of pieces obtained by cutting a honeycomb-shaped structure supporting an adsorbent. By combining and sandwiching to make a suction operation body,
By installing this to form a reversible heat generation cooling generator, it is possible to provide a reversible heat generation heat generator that can obtain excellent heating and cooling performance and shorten the heating time and cooling time involved in the reactivation process. did.
第１図は本発明の一実施例にもとずく可逆発熱冷熱発生
器の構成図、第２図は同じく容器に装着したハニカム状
吸着動作体の部分断面図、第３図は同じく可逆発熱冷熱
発生器の冷却性能図、第４図は同じく吸着動作時間に対
する吸着量の変化図である。 １・３…容器、２…吸着動作体、４…被吸着動作液体、
６…被吸着動作液体蒸気。FIG. 1 is a block diagram of a reversible exothermic cold heat generator according to an embodiment of the present invention, FIG. 2 is a partial cross-sectional view of a honeycomb-shaped adsorbing body similarly mounted in a container, and FIG. FIG. 4 is a diagram showing the cooling performance of the generator, and FIG. 4 is a diagram showing changes in the adsorption amount with respect to the adsorption operation time. 1, 3 ... container, 2 ... adsorption operation body, 4 ... adsorption target liquid,
6 ... Adsorbed operation liquid vapor.
Claims (1)
の個体間に、金属網・パンチメタル板・多孔性金属体・
金属繊維から選ばれた１種またはそれ以上を組合せて挟
み込み積層して吸着動作体となし、これを装着してなる
可逆発熱冷熱発生器。1. A metal net, a punched metal plate, a porous metal body, between a number of individual honeycomb-shaped structures carrying an adsorbent.
A reversible exothermic cold heat generator in which one or more kinds selected from metal fibers are combined and sandwiched to form an adsorbing body, which is mounted.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1143720A JPH0737863B2 (en) | 1989-06-06 | 1989-06-06 | Reversible exothermic cold heat generator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1143720A JPH0737863B2 (en) | 1989-06-06 | 1989-06-06 | Reversible exothermic cold heat generator |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH037860A JPH037860A (en) | 1991-01-16 |
| JPH0737863B2 true JPH0737863B2 (en) | 1995-04-26 |
Family
ID=15345425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1143720A Expired - Fee Related JPH0737863B2 (en) | 1989-06-06 | 1989-06-06 | Reversible exothermic cold heat generator |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0737863B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009097733A (en) * | 2007-10-12 | 2009-05-07 | Denso Corp | Adsorption heat exchanger and manufacturing method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3347700C2 (en) * | 1983-12-31 | 1994-07-07 | Zeolith Tech | Zeolite molding with high heat conduction and process for its production |
| JPS61175283A (en) * | 1985-01-30 | 1986-08-06 | Hitachi Ltd | Adsorption compressor |
-
1989
- 1989-06-06 JP JP1143720A patent/JPH0737863B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH037860A (en) | 1991-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP7213401B2 (en) | Composite material and its manufacturing method | |
| US7291271B2 (en) | Meso-frequency traveling wave electro-kinetic continuous adsorption system | |
| JP2021533972A (en) | Metal-organic framework-based water trap | |
| US7172645B1 (en) | Gas filtration and storage using activated carbon/graphite foam monoliths | |
| EP1080771B1 (en) | Gas separation process using composite adsorbent particles | |
| JPH0339735B2 (en) | ||
| US20100043635A1 (en) | PSA Method Using A Composite Adsorption Bed Comprising An Adsorbent And PCM Agglomerates | |
| US20110230331A1 (en) | ADSORBING MOLDED BODY, ADSORPTION RECOVERY TREATMENT APPARATUS, AND ADSORBATE DESORBING METHOD (amended | |
| JPH07257917A (en) | Process for producing active complex and active complex produced by the process | |
| EP2483536A1 (en) | Connected heat conducting structures in solid ammonia storage systems | |
| Guilleminot et al. | Heat and mass transfer characteristics of composites for adsorption heat pumps | |
| Green et al. | The adsorption of oxygen on clean silicon surfaces | |
| JP3337398B2 (en) | Adsorbent for evaporative fuel processing apparatus and method for producing the same | |
| Akhtar et al. | Thin zeolite laminates for rapid and energy-efficient carbon capture | |
| Kok et al. | Effect of alloying on the adsorption of CO on palladium; A comparison of the behaviour of PdAg (111), PdCu (111) and Pd (111) surfaces | |
| JP6114928B1 (en) | Gas adsorbent and vacuum heat insulating material provided with gas adsorbent | |
| JPH0737863B2 (en) | Reversible exothermic cold heat generator | |
| JP2875542B2 (en) | Gas separation method | |
| Li et al. | The introduction of Mn component improves the selectivity of NO adsorption separation in simulated flue gas of Co‐MOF‐74 at ambient conditions | |
| US6270609B1 (en) | Hard disk drive filter | |
| JP4663044B2 (en) | Heat transfer accelerator for gas adsorption / desorption reaction material and gas adsorption / desorption reaction material with excellent heat transfer | |
| Kim et al. | IR spectroscopic measurement of diffusion kinetics of chemisorbed pyridine through nanocrystalline MgO particles. The involvement of surface defect sites in slow diffusion | |
| EP1491256A1 (en) | Method for regenerating adsorbent by heating | |
| Antonyshyn et al. | Chemical behaviour of CaAg2 under ethylene epoxidation conditions | |
| Schoukens et al. | Enhancing desorption performance of a compressible hybrid structured adsorbent via localized magnetic induction heating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |