JPH0744106A - label - Google Patents

Abstract

PURPOSE:To facilitate mounting and facilitate reading of characters, etc., even after fabrication without receiving the influence of the fabrication by printing one surface of a transparent plastic film having resistant to heat, water and chemicals and coating the printed surface thereof with a tacky adhesive having the resistant to heat, water and chemicals. CONSTITUTION:The printed surface side of the label is adhered on cloth via the tacky adhesive applied thereon. The printing appears on the front surface side of the label through the transparent plastic film and, therefore, the front surface side is subjected to printing inside out. Both of the transparent plastic film as the base material and the tacky adhesive which have the resistant to heat, water and chemicals are used. The label stuck on the cloth exhibits the high resistant to heat, water and chemicals. There are films consisting of polyolefin, polyamide, polyester, fluororesins, etc., as the transparent plastic film. There are polyethylene, etc., as the polyolefin, nylon 6, etc., as the polyamide and polytetrafluoroethylene, etc., as the fluororesins.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a label having excellent heat resistance, water resistance and chemical resistance attached to a cloth product.

[0002]

2. Description of the Related Art An original fabric of a cloth product made by weaving or knitting a thread uses a special marker which is not affected by the dyeing at the end of the fabric for lot control in the dyeing process. The operator manually writes the lot number, processing instruction number, and so on.

However, it is the current situation that production efficiency cannot be improved due to mistakes when writing or reading and transcribing, and troublesome writing and reading. Therefore, it is desired to attach a label on which characters or symbols are printed instead of writing with a marker.

As a method of attaching a management label to an original fabric product, for example, the methods described in Japanese Utility Model Publication No. 1-70894 and Japanese Utility Model Publication No. 3-14193 are known.

[0005]

However, in the methods disclosed in the above-mentioned Japanese Utility Model Laid-Open No. 1-70894 and Japanese Utility Model Laid-Open No. 3-14193, the paper or sheet on which the bar code is printed is sewn to the cloth with a sewing machine. , Is very time-consuming. In addition, the cloth to be attached is limited to kijyaku cloth and kimono cloth.

In view of the above, the present invention eliminates the above-mentioned drawbacks of the prior art, and is easy to install in the process of dyeing various fabrics and the like, and the characters and symbols can be read without being affected by the process. It is intended to provide an easy cloth label.

[0007]

The label of the present invention for this purpose is printed on one surface of a heat-resistant, water-resistant and chemical-resistant transparent plastic film, and the printed surface is adhered with heat-, water- and chemical-resistant adhesiveness. It consists of a coated adhesive.

A feature of the present invention is the use of a tacky adhesive to attach the label to the cloth. By using a tacky adhesive, it is possible to temporarily fix the position on the cloth and at the same time, react with moisture, heat, light, radiation, etc. to significantly increase the adhesive strength, so that the cloth can be firmly attached. Can be glued to. However, if this is an adhesive, the position can be fixed by pressing it against the cloth, but there is a risk that it will peel off in the dyeing process etc. due to insufficient adhesive strength. In addition, if a simple adhesive is used, it cannot be adhered only by pressing it against the cloth, so that the attachment position cannot be fixed, and it takes a lot of time and effort to attach the product, which lowers the productivity.

In the label of the present invention, the label printing surface side is adhered to a cloth or a cloth product via a coated adhesive agent. Since the print appears on the label surface side through the transparent plastic film, the print is turned upside down. Both the transparent plastic film as the base material and the adhesive are heat resistant
Since it is water and chemical resistant, it can exhibit high heat, water and chemical resistance even when used as a label attached to cloth.

Examples of the transparent plastic film of the present invention include films made of polyolefin, polyamide, polyester, fluororesin and the like. As the above-mentioned polyolefin, polyethylene, polypropylene, 4
-Methylpentene-1 resin, polybutene-1 resin and the like, and copolymers and blends thereof.

Polyamides include nylon 46, nylon 6, nylon 66, nylon 610, nylon 61.
2, nylon 11, nylon 12, nylon MXD-6
And copolymers and blends thereof.

Examples of the above polyester include polyethylene terephthalate, polyethylene-2,6-naphthalate, polyethylene-α, βbis (2-chlorophenoxy) ethane-4,4'-dicarboxylate, polycyclohexanedimethylene terephthalate and These copolymers and blended products are mentioned.

Further, as the above-mentioned fluororesin, generally widely known fluororesins such as polytetrafluoroethylene (PTFE) and polytetrafluoroethylene-
Perfluoroalkyl vinyl ether copolymer (PF
A), polytetrafluoroethylene-polyhexafluoropropylene copolymer (FEP), polytetrafluoroethylene-ethylene copolymer (ETFE), polychlorotrifluoroethylene (PCTFE), polyvinylidene fluoride (PVDF), polyfluorination Examples thereof include vinyl (PVF).

The transparent plastic film may be subjected to a known surface treatment such as corona treatment or plasma treatment in order to improve the adhesion of the print or the readability of the print.

Particles having heat resistance, water resistance and chemical resistance may be added to the above-mentioned adhesive / adhesive. Heat-resistant, water-resistant, and chemical-resistant particles are inorganic or organic particles that show the adhesive layer white, and examples of the inorganic particles include zinc carbonate, zinc oxide, zinc sulfide, talc, kaolin, heavy and light particles. Or synthetic calcium carbonate, titanium oxide, silica, lithium fluoride, calcium fluoride, barium sulfate, alumina,
Examples thereof include zirconia, calcium phosphate, natural or synthetic swelling or non-swelling mica, and the organic particles include, for example, polystyrene, polymethylstyrene,
Examples thereof include polymethoxystyrene, polyvinyl chloride, polyethylene, polypropylene, polyvinylidene chloride, and polymethacrylate, and at least one selected from these is applied, but not particularly limited. Further, the pigment may be in a hollow porous state or a non-hollow porous state. Furthermore, the pigment may be surface-treated in order to improve the dispersibility in the resin.

Since the adhesive layer has a white color as described above, good readability of printing can be maintained even after processing steps such as dyeing and washing of the original fabric.

In the present invention, heat resistance means heat resistance to 130 ° C., preferably 150 ° C. If the heat resistance is less than 130 ° C., dimensional change may occur or the color may change to make it difficult to read the print, or the label may peel off, which is not preferable.

The water resistance in the present invention is a property that does not change the appearance, the adhesion, the adhesive force, etc. even when immersed in water at 70 ° C., preferably 90 ° C. for 1 hour.

The chemical resistance in the present invention refers to various soaps, synthetic detergents, detergents such as hydrogen peroxide and hypozinc acid, dyes, and various chemicals used when processing a raw fabric cloth. That is, the color does not change or the print is sufficiently readable even if the color changes, and the property that the label does not peel off or the print does not come off.

The tacky-adhesive in the present invention has the above-mentioned heat resistance, water resistance and chemical resistance, and further includes cotton, Tetoron,
It has a peel strength of preferably 500 g / 25 mm or more, more preferably 800 g / 25 mm or more when attached to a cloth product such as nylon. As such an adhesive, a silicone resin-based adhesive,
Examples thereof include urethane-based, acrylic-based, polyester-based, polyamide-based, elastomer-based, etc., but are not particularly limited thereto. The coating method is also gravure coating method, reverse coating method, kiss coating method, die coating method,
Known methods such as a metalling bar coating method, a knife coating method and an extrusion coating method can be applied. Before applying the adhesive, if necessary, a known surface treatment such as corona discharge treatment in air or other various atmospheres may be performed to improve the adhesion between the transparent plastic film and the adhesive. Can be improved. The adhesive thickness of the adhesive is preferably 10 to 150 μm, more preferably 20 to 80 μm.

When the label of the present invention is applied to a cloth, the adhesive, water, light, oxygen, and a cross-linking agent are added in order to increase the adhesive strength by temporarily adhering to the cloth, fixing the position, and then curing the adhesive. Are contacted with each other, physical treatment such as heat is applied, or a chemical reaction initiator or energy is used. Further, regarding the pasting conditions, appropriate temperature, time, pressure, reaction agent, radiation, etc. may be set depending on the type of the adhesive used.

The effects of the present invention are evaluated by the following measuring methods and standards. (Evaluation of heat resistance, water resistance, and chemical resistance) (1) Washing test A label was attached to a cloth, and 1 g of detergent "Attack" (manufactured by Kao Corporation) was dissolved in 60 liters of water per 1 liter of water. The label was discolored, peeled off, and the adhesive strength was measured by immersing for 30 minutes and stirring. (A) Discoloration is good (no discoloration) ..... ○ Inferior (There is discoloration but the print is legible) ..... Possible) ・ ・ ・ ・ × (b) Peeling is good (no peeling) ・ ・ ・ ・ ・ ・ ・ ・ ・ ○ Inferior (peeling of less than 20%) ・ ・ ・ ・ ・ ・・ ・ △ Poor (20% or more peeling) ・ ・ ・ ・ ・ ・ ・ ・ ・ ・ × (c) Adhesive strength good (500g / 25mm or more) ・ ・ ・ ○ Poor (500-250g / 25mm) ) ・ ・ △ Bad (less than 250g / 25mm) ・ ・ ・ ・ ・ ・ ×

(2) Dyeing test A label was attached to the cloth and dyed with a direct dye (black). Then, the label was discolored, peeled off, and the adhesive strength was measured. The measurement and evaluation criteria are the same as in (1) above.

[0024]

EXAMPLES The present invention will be described below based on examples.
The present invention is not limited to this. Example A fluorine film having a thickness of 50 μm (“Toyofuron” manufactured by Toray Synthetic Film Co., Ltd.) was used as a base film and the surface was subjected to electric discharge treatment. BC-8M made by Autonics for discharge treatment
kII printer (Ribbon D105 manufactured by Ricoh Co., Ltd.)
A, printing condition 10.5v, 4.25ms) 4m
A number with a size of m × 4 mm was printed. This is sheet A
And Next, for the adhesive with epoxy resin as the main component,
White particles of titanium oxide (average particle size 0.3 μm) were added so as to be 10 parts by weight and uniformly kneaded, and this was applied to the printing surface side of the sheet A by a comma coat method to reduce the thickness of the adhesive layer. A 50 μm sheet was obtained. This is Sheet B.

From the sheet B thus prepared, 20
A label of mm × 50 mm is cut and the adhesive layer side is brought into contact with a polyester woven cloth, and a flat plate press (14
Bonding was performed at 0 ° C. and 300 g / cm ² , 10 sec.
The heat resistance, water resistance and chemical resistance of this label were evaluated. The results are shown in Table 1.

Comparative Example 1 A material obtained by impregnating nylon taffeta with a coating material (“Nick Seven” # 108SX manufactured by Dynic Co., Ltd.) was used as a base material, and BC-8M manufactured by Autonics Co., Ltd. was placed on the printed side of the material.
kII printer (Ribbon D105 manufactured by Ricoh Co., Ltd.)
A, printing condition 10.5v, 4.25ms) 4m
A number with a size of m × 4 mm was printed. Acrylic ester adhesive (manufactured by Nippon Carbide Industry Co., Ltd.) was applied on the side opposite to the printed side by a comma coat method to form a coating layer 1
After drying at 20 ° C. for 1 minute, a label having an adhesive thickness of 30 μm was obtained. The label thus prepared was attached to a nylon woven fabric and rubbed with an acrylic plate having a radius R 10 times. The heat resistance, water resistance and chemical resistance of this label were evaluated. The results are shown in Table 1.

Comparative Example 2 A polyester film having a thickness of 50 μm (“Lumirror” 50S105 manufactured by Toray Industries, Inc.) was used as a base film, and then heat-crosslinking acrylic was added to a diluted solvent of toluene / ethyl acetate = 1/1. Resin (“Cotax” Tg manufactured by Toray Industries, Inc.)
(75 ° C.) A white hiding pigment titanium oxide (0.3 μm on average) was uniformly dispersed in a kneaded composition such that the solid content was 60 parts by weight, and titanium oxide (average 0.3 μm) was added at a concentration of 10 parts by weight.
A wt% coating was made. This coating material was applied to the film by the gravure coating method, and the applied layer was dried at 130 ° C. for 1 minute to obtain a film having a print receiving layer of 2 μm.

BC-8MkII printer manufactured by Autonics Co., Ltd. (ribbon is D105A manufactured by Ricoh Co., Ltd., printing conditions 10.5v, 4.25m) on the print receiving layer side of the film.
s) was used to print a number having a size of 4 mm × 4 mm. This is Sheet A. Next, the surface of a 38 μm thick fluorine film (“Toyofuron” manufactured by Toray Synthetic Film Co., Ltd.) was subjected to electric discharge treatment, and an acrylic ester adhesive (manufactured by Nippon Carbide Industry Co., Ltd.) was applied by a comma coat method, The coating layer was dried at 120 ° C. for 1 minute to obtain a sheet having an adhesive thickness of 20 μm. This is Sheet B. The adhesive side of sheet B is laminated on the printed side of sheet A and laminated, and a silicone adhesive (SD4570 manufactured by Toray Dow Corning Silicone Co., Ltd.) is formed on the opposite side of the printed side of sheet A to a thickness of 30 μm. As applied. The label thus prepared was attached to a nylon woven fabric and rubbed with an acrylic plate having a radius R 10 times. The heat resistance, water resistance and chemical resistance of this label were evaluated. The results are shown in Table 1.

[0029]

[Table 1]

[0030]

Since the label of the present invention is excellent in heat resistance, water resistance and chemical resistance, there is no possibility that the printed information becomes unreadable due to dyeing or discoloration in the processing steps such as dyeing of the fabric. The optimum control label for fabric processing can be obtained.

Claims (2)

[Claims] 1. A label characterized by being printed on one surface of a heat-resistant, water-resistant, chemical-resistant transparent plastic film, and coating a heat-resistant, water-resistant, chemical-resistant adhesive on the printed surface. 2. The label according to claim 1, wherein particles of heat resistance, water resistance and chemical resistance are added to the adhesive.