JPS6046230A - Preparation of composite foamed body - Google Patents
Preparation of composite foamed bodyInfo
- Publication number
- JPS6046230A JPS6046230A JP58156062A JP15606283A JPS6046230A JP S6046230 A JPS6046230 A JP S6046230A JP 58156062 A JP58156062 A JP 58156062A JP 15606283 A JP15606283 A JP 15606283A JP S6046230 A JPS6046230 A JP S6046230A
- Authority
- JP
- Japan
- Prior art keywords
- mold
- container
- cavity
- core mold
- molded product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/04—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/38—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
- B29C44/44—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form
- B29C44/445—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form in the form of expandable granules, particles or beads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3415—Heating or cooling
- B29C44/3426—Heating by introducing steam in the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
Landscapes
- Molding Of Porous Articles (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は新規な複合発泡成形体の製造法に関し、更に詳
しくは容器の内側に発泡成形体を成形せしめ、しかも両
者の物理的一体化を可能とする複合発泡成形体の製造法
に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a novel method for producing a composite foam molded article, and more specifically, to a composite foam molded article that allows a foam molded article to be molded inside a container, and also enables physical integration of the two. This relates to a manufacturing method.
従来、ABS樹脂等のインジェクション成形体からなる
箱体と該箱体の外側に断熱材としての発泡ボリスヂレン
との一体成形品は公知である。しかし、ドレインパンの
如き容器にあっては、例えばABS樹脂のインジェクシ
ョン成形体の内側に発泡ポリスチレン成形体を内装複合
化した構成からなる構造のドレインパンを一体成形しよ
うとしても発泡性ポリスチレンビーズの充填が極めて困
難であり、またポリプロピレン等のポリオレフィンのイ
ンジェクション成形体と発泡ポリスチレン成形体の如く
相溶性が悪い場合には初期の目的を達成することが出来
ない。かくしてインジェクション成形体と発泡ボリスヂ
レン成形体とを別個につくり、後者を前者の内部に嵌め
込むか、薄肉の場合は押し出しシートを真空成形して接
着剤を介して複合化しているのが実情である。しかるに
、単に嵌め込む方法ではインジェクション品との接触形
状が出し難く一体化が不充分となり易く、嵌め込み工数
がかかり、また在庫のスベイースが必要となるという問
題があり、他方接着剤を用いる方法は工程が煩雑となり
、真空成形品のコストが高くなり、またインジェクショ
ン成形体と発泡ポリスチレン成形体との間に隙間が存在
すると接着できず、従って相当の成形精度が要求される
という問題がある。BACKGROUND ART Conventionally, an integrally molded product of a box made of an injection molded product of ABS resin or the like and foamed borisdyrene as a heat insulating material on the outside of the box is well known. However, when it comes to containers such as drain pans, for example, even if an attempt is made to integrally mold a drain pan with a structure in which a foamed polystyrene molded body is integrated inside an injection molded body of ABS resin, filling with foamed polystyrene beads is difficult. This is extremely difficult, and the initial objective cannot be achieved when the compatibility is poor, such as between an injection molded product of polyolefin such as polypropylene and a foamed polystyrene molded product. In this way, the actual situation is to make the injection molded product and the foamed borisdirene molded product separately, and either fit the latter inside the former, or in the case of thin walls, vacuum form an extruded sheet and combine it with an adhesive. . However, with the method of simply fitting, there are problems in that it is difficult to form a contact shape with the injection product, resulting in insufficient integration, requiring a lot of man-hours for fitting, and requiring inventory clearance.On the other hand, methods using adhesives The process becomes complicated, the cost of the vacuum-formed product increases, and if there is a gap between the injection molded product and the foamed polystyrene molded product, they cannot be bonded, so there is a problem that considerable molding precision is required.
本発明者はかかる実情に鑑み、上記問題点を克服するべ
く鋭意検討の結果、本発明を完成させたものである。In view of the above circumstances, the present inventor has completed the present invention as a result of intensive studies to overcome the above-mentioned problems.
即ち、本発明の第1は容器の内側に発泡成形体を内装し
てなる複合発泡成形体を製造するに際し、コア金型とキ
ャビティ金型とにより形成される型窩内のキャビティ金
型側寄りに予め少なくとも1以上の貫通孔を穿設した容
器を配置し、次いで該コア金型と容器との間に前記貫通
孔より発泡性樹脂ビーズを充填し、加熱成形することを
特徴とする複合発泡成形体の製造法を内容とし、本発明
の第2は排水管等の開口部を備えた容器の内側に発泡成
形体を内装してなる複合発泡成形体を製造するに際し、
コア金型とキャビティ金型とにより形成される型窩内の
キャビティ金型側寄りに予め少なくとも1以上の貫通孔
を穿設した容器を配置し、該開口部内にコア金型表面に
到達する棒状金具を挿入し、該開口部挿脱用の金型開口
部に板状金具で閉鎖し、次いで該コア金型と容器との間
に前記貫通孔より発泡性樹脂ビーズを充填し、加熱成形
することを特徴とする複合発泡成形体の製造法を内容と
するものである。That is, the first aspect of the present invention is that when manufacturing a composite foamed molded product in which a foamed molded product is installed inside a container, the molded material is removed near the cavity mold side in the mold cavity formed by the core mold and the cavity mold. Composite foaming characterized in that a container having at least one through hole bored in advance is placed in the core mold, and then foamable resin beads are filled between the core mold and the container through the through hole and heated and molded. The second aspect of the present invention is a method for producing a molded body, and the second aspect of the present invention is when manufacturing a composite foam molded body in which a foam molded body is placed inside a container having an opening such as a drain pipe,
A container with at least one through hole drilled in advance is arranged near the cavity mold side in the mold cavity formed by the core mold and the cavity mold, and a rod-shaped container that reaches the surface of the core mold is placed inside the opening. A metal fitting is inserted, the opening of the mold for inserting and removing the opening is closed with a plate metal fitting, and then foamed resin beads are filled through the through hole between the core mold and the container, and heated and molded. The content is a method for manufacturing a composite foam molded article characterized by the following.
本発明の実施態様を示す図面に基づいて説明すると、第
1図においてキャビティ金型(1)とコア金型(2)と
の間に形成された型窩内に、ポリプロピレン成形体(3
)がキャビティ金型(1)側寄りに配置される。ポリプ
ロピレン成形体(3)には少なくとも1以上の貫通孔(
4)が穿設されている。該貫通孔(4)は発泡性樹脂ビ
ーズの充愼孔となるばかりでなく、成形後は発泡成形体
が詰まり所謂アンカー効果によりポリプロピレン成形体
と物理的に一体化させるものであるから、かかる機能、
効果を充分発揮するよう適当数穿設される。An explanation will be given based on the drawings showing the embodiments of the present invention. In FIG. 1, a polypropylene molded body (3
) is placed closer to the cavity mold (1) side. The polypropylene molded body (3) has at least one through hole (
4) is perforated. The through holes (4) not only serve as filling holes for the foamable resin beads, but also become clogged with the foamed molded body after molding and are physically integrated with the polypropylene molded body due to the so-called anchor effect. ,
An appropriate number of holes are drilled to ensure the full effect.
次ぎに、フィーダー(5)を前記貫通孔(4)に密着さ
せ、該貫通孔(4)から発泡性樹脂ビーズとして発泡性
ポリスチレンビーズをコア金型(2)とポリプロピレン
成形体(3)との間に形成される空間部に充填した後、
蒸気により加熱成形し、ポリプロピレン成形体(3)と
ポリスチレン発泡成形体(6)との一体成形体を得る。Next, the feeder (5) is brought into close contact with the through hole (4), and the expandable polystyrene beads are inserted into the core mold (2) and the polypropylene molded body (3) as expandable resin beads through the through hole (4). After filling the space formed between
Heat molding is performed using steam to obtain an integral molded body of a polypropylene molded body (3) and a polystyrene foam molded body (6).
この場合、両面加熱の前に、一方加熱によりポリプロピ
レン成形体(3)を加熱することにより、ポリプロピレ
ン成形体と接する側のポリスチレン発泡成形体の表面を
滑らかに成形すること、が出来る。また、コア金型のス
リソトロを出来るだけ多くし、それでも充填不良が発生
する場合は小孔を設けるのが望ましい。また、発泡成形
体と接しないポリプロピレン成形体の部分が過熱により
変形を来すことがあるが、これはコア金型及び/又はキ
ャビティ金型のポリプロピレン成形体と接する面に過熱
防止体を設けることにより防止することが可能である。In this case, by heating the polypropylene molded body (3) by one-sided heating before double-sided heating, the surface of the polystyrene foam molded body on the side that comes into contact with the polypropylene molded body can be molded smoothly. It is also desirable to increase the number of slots in the core mold as much as possible, and if filling defects still occur, provide small holes. Additionally, parts of the polypropylene molded body that are not in contact with the foamed molded body may become deformed due to overheating, but this can be prevented by providing an overheating preventer on the surface of the core mold and/or cavity mold that comes into contact with the polypropylene molded body. This can be prevented by
過熱防止体としては出来るだけ薄いもので且つ成形温度
に耐える素材であれば良く、例えば布、耐熱性フィルム
等が挙げられる。The overheating preventer may be made of any material as long as it is as thin as possible and can withstand the molding temperature, such as cloth, heat-resistant film, etc.
本発明の製造法において、ポリプロピレン成形体の貫通
孔にポリスチレン発泡成形体が食い込み、両者は所謂ア
ンカー効果により物理的に一体化される。しかし、更に
両者を強固に複合一体化しようとする場合は、ポリプロ
ピレン成形体のポリスチレン発泡成形体と接する面に接
着剤を塗布しておけば良い。接着剤としては熱可塑性接
着剤が好適である。In the manufacturing method of the present invention, the polystyrene foam molded body bites into the through hole of the polypropylene molded body, and the two are physically integrated by the so-called anchor effect. However, if the two are to be more strongly integrated into a composite body, an adhesive may be applied to the surface of the polypropylene molded product that comes into contact with the polystyrene foam molded product. A thermoplastic adhesive is suitable as the adhesive.
第2図及び第3図は、第4図に示したドレインパンの如
き突出した排水管等の開口部を備えた容器の複合発泡成
形体の製造法を示す。FIGS. 2 and 3 illustrate a method of manufacturing a composite foam molding for a container having an opening such as a protruding drain pipe, such as the drain pan shown in FIG. 4. FIG.
同図において、キャビティ金型(1)の金型開口部より
ポリプロピレン成形体(3)に設けられた排水管等の開
口部(7)を挿通させた後、コア金型(2)をセットす
る。次いで、該開口部(7)内に棒状金! (8)を挿
入する。該棒状金具(8)はコア金型(2)の表面に到
達密着するように挿入される。次に金型開口部を板状金
具(9)で閉鎖した状態で発泡性ポリスチレンビーズを
充填し加熱成形する。本例においては棒状金具(8)と
板状金具(9)とは一体的に連結し、1個のエアシリン
ダー(10)により駆動し得るように構成されている。In the figure, after inserting an opening (7) such as a drain pipe provided in the polypropylene molded body (3) through the mold opening of the cavity mold (1), the core mold (2) is set. . Next, a bar of gold is placed inside the opening (7). Insert (8). The rod-shaped metal fitting (8) is inserted so as to reach and come into close contact with the surface of the core mold (2). Next, with the mold opening closed with a metal plate (9), expandable polystyrene beads are filled and heated to form the mold. In this example, the rod-shaped metal fitting (8) and the plate-shaped metal fitting (9) are integrally connected and configured to be driven by one air cylinder (10).
上記板状金具は加熱成形時にポリプロピレン成形体の変
形を阻止するものである。The plate-shaped metal fittings prevent the polypropylene molded body from deforming during heat molding.
本発明は容器の内側に発泡成形体容器を一体的に成形す
る方法であるから、本発明で使用される容器はABS樹
脂、ポリエチレン、ポリプロピレン等のプラスティック
成形体に限られず、金属製、陶磁器製等の容器も好適に
採用される。また発泡成樹脂ビーズとしては、ポリスチ
レンビーズの他にポリエチレンビーズ、ポリプロピレン
ビーズ等が例示される。更に、容器と同色の着色ビーズ
を用いることにより、容器と容器の貫通孔に食い込まれ
た発泡成形体とが同一色となり、不自然さをなくすこと
が出来る。Since the present invention is a method of integrally molding a foam molded container inside a container, the containers used in the present invention are not limited to plastic molded products such as ABS resin, polyethylene, and polypropylene, but are also made of metal, ceramic, etc. Containers such as the above are also suitably employed. Examples of foamed resin beads include polyethylene beads, polypropylene beads, etc. in addition to polystyrene beads. Furthermore, by using colored beads of the same color as the container, the container and the foamed molded product inserted into the through-hole of the container have the same color, making it possible to eliminate unnaturalness.
叙上の通り、本発明は
(1)容器内側に発泡成形体を一体的に成形することが
出来、従前の如く嵌め込みや接着工程を必要としない、
(2)発泡性樹脂ビーズの充填孔としての貫通孔に発泡
成形体が食い込まれ、所謂アンカー効果により物理的に
一体化される、
(3)容器と同色の着色ビーズを用いることにより、自
然な複合体を得ることが出来る、(4)発泡成形体の在
庫用スペースが不要である、等の数多くの利点を有し、
その実用性は頗る大である。As mentioned above, the present invention (1) allows the foamed molded body to be integrally molded inside the container, eliminating the need for fitting or gluing processes as in the past; (2) as a filling hole for foamed resin beads; (3) By using colored beads of the same color as the container, a natural composite can be obtained (4) It has many advantages such as no need for storage space for foam moldings,
Its practicality is extremely great.
第1図は本発明の実施態様を示す概略断面図、第2図及
び第3図は本発明の他の実施態様を示す平面断面図及び
側面断面図、第4図はドレインパンの一例を示す斜視図
である。
1・・・キャビティ金型
2・・・コア金型
3・・・ポリプロピレン成形体
4・・・貫通孔
5・・・フィーダー
6・・・ポリスチレン発泡成形体
7・・・排水管等の開口部
8・・・棒状金具
9・・・板状金具
10・・・エアシリンダー
特許出願人 鐘淵化学工業株式会社
代理人 弁理士 伊 丹 健 次
(10完)FIG. 1 is a schematic cross-sectional view showing an embodiment of the present invention, FIGS. 2 and 3 are plan and side cross-sectional views showing other embodiments of the present invention, and FIG. 4 is an example of a drain pan. FIG. 1 Cavity mold 2 Core mold 3 Polypropylene molded body 4 Through hole 5 Feeder 6 Polystyrene foam molded body 7 Opening of drain pipe, etc. 8... Rod-shaped metal fitting 9... Plate-shaped metal fitting 10... Air cylinder patent applicant Kaneji Kagaku Kogyo Co., Ltd. agent Patent attorney Kenji Itami (10 completed)
Claims (1)
形体を製造するに際し、コア金型とキャビティ金型とに
より形成される型窩内のキャビティ金型側寄りに予め少
なくとも1以上の貫通孔を穿設した容器を配置し、次い
で該コア金型と容器との間に前記貫通孔より発泡性樹脂
ビーズを充填し、加熱成形することを特徴とする複合発
泡成形体の製造法。 2、発泡成形体と接しない容器の部分のコア金型及び/
又はキャビティ金型の表面に過熱防止体を配設する特許
請求の範囲第1項記載の製造法。 3、容器の発泡成形体との接触面に接着剤を塗布する特
許請求の範囲第1項又は第2項記載の製造法。 4、排水管等の開口部を備えた容器の内側に発泡成形体
を内装してなる複合発泡成形体を製造するに際し、コア
金型とキャビティ金型とにより形成される型窩内のキャ
ビティ金型側寄りに予め少なくとも1以上の貫通孔を穿
設した容器を配置し、該開口部内にコア金型表面に到達
する棒状金具を挿入し、該開口部挿脱用の金型開口部に
板状金具で閉鎖し、次いで該コア金型と容器との間に前
記貫通孔より発泡性樹脂ビーズを充填し、加熱成形する
ことを特徴とする複合発泡成形体の製造法。 5、発泡成形体と接しない容器の部分のコア金型及び/
又はキャビティ金型の表面に過熱防止体を配設する特許
請求の範囲第4項記載の製造法。 6、容器の発泡成形体との接触面に接着剤を塗布する特
許請求の範囲第4項又は第5項記載の製造法。 7、前記棒状金具と板状金具とを一体的に連結し、1個
のエアシリンダーにより駆動する特許請求の範囲第4項
、第5項又は第6項記載の製造法。[Scope of Claims] When manufacturing a composite foam molded product in which a foamed molded product is placed inside a container, a mold cavity near the cavity mold side in a mold cavity formed by a core mold and a cavity mold. Composite foaming characterized in that a container having at least one through hole bored in advance is placed in the core mold, and then foamable resin beads are filled between the core mold and the container through the through hole and heated and molded. Method for manufacturing molded bodies. 2. Core mold and/or parts of the container that do not come into contact with the foam molded product.
Alternatively, the manufacturing method according to claim 1, wherein an overheating preventer is provided on the surface of the cavity mold. 3. The manufacturing method according to claim 1 or 2, wherein an adhesive is applied to the contact surface of the container with the foamed molded product. 4. When manufacturing a composite foam molded product in which a foamed molded product is placed inside a container equipped with an opening such as a drain pipe, a cavity mold in a mold cavity formed by a core mold and a cavity mold is used. A container with at least one through hole drilled in advance near the mold side is placed, a rod-shaped metal fitting that reaches the surface of the core mold is inserted into the opening, and a plate is inserted into the mold opening for inserting and removing the opening. 1. A method for producing a composite foam molded article, which comprises closing the core mold with a shaped metal fitting, then filling the gap between the core mold and the container with foamable resin beads through the through hole, and heat-molding the core mold. 5. Core mold and/or parts of the container not in contact with the foam molded product
Alternatively, the manufacturing method according to claim 4, wherein an overheating preventer is provided on the surface of the cavity mold. 6. The manufacturing method according to claim 4 or 5, wherein an adhesive is applied to the contact surface of the container with the foamed molded product. 7. The manufacturing method according to claim 4, 5, or 6, wherein the rod-shaped metal fitting and the plate-shaped metal fitting are integrally connected and driven by one air cylinder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58156062A JPS6046230A (en) | 1983-08-25 | 1983-08-25 | Preparation of composite foamed body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58156062A JPS6046230A (en) | 1983-08-25 | 1983-08-25 | Preparation of composite foamed body |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6046230A true JPS6046230A (en) | 1985-03-13 |
Family
ID=15619469
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58156062A Pending JPS6046230A (en) | 1983-08-25 | 1983-08-25 | Preparation of composite foamed body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6046230A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000062119A (en) * | 1999-03-29 | 2000-10-25 | 강석환 | Expandable polystyrene resin and a method of producing the same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS496458A (en) * | 1972-03-07 | 1974-01-21 | ||
| JPS4980737A (en) * | 1972-12-04 | 1974-08-03 | ||
| JPS5434377A (en) * | 1977-08-22 | 1979-03-13 | Sekisui Chem Co Ltd | Production of vessel |
| JPS55100133A (en) * | 1979-01-27 | 1980-07-30 | Meiwa Sangyo Kk | Manufacture of polystyrene beads foam-formed body |
-
1983
- 1983-08-25 JP JP58156062A patent/JPS6046230A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS496458A (en) * | 1972-03-07 | 1974-01-21 | ||
| JPS4980737A (en) * | 1972-12-04 | 1974-08-03 | ||
| JPS5434377A (en) * | 1977-08-22 | 1979-03-13 | Sekisui Chem Co Ltd | Production of vessel |
| JPS55100133A (en) * | 1979-01-27 | 1980-07-30 | Meiwa Sangyo Kk | Manufacture of polystyrene beads foam-formed body |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000062119A (en) * | 1999-03-29 | 2000-10-25 | 강석환 | Expandable polystyrene resin and a method of producing the same |
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