JPS61238789A - ナトリウムジアルキルアルミニウムジハイドライドの溶解方法 - Google Patents

ナトリウムジアルキルアルミニウムジハイドライドの溶解方法

Info

Publication number: JPS61238789A
Authority: JP; Japan
Prior art keywords: dihydride; alkali metal; dialkylalminum; solution; hydride
Prior art date: 1985-04-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP7981485A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0119397B2 (2

Inventor

Akira Yamane

山根　昭

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

TOYO SUTOUFUAA CHEM KK

Tosoh Finechem Corp

Original Assignee

TOYO SUTOUFUAA CHEM KK

Tosoh Finechem Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-04-15

Filing date

1985-04-15

Publication date

1986-10-24

1985-04-15 Application filed by TOYO SUTOUFUAA CHEM KK, Tosoh Finechem Corp filed Critical TOYO SUTOUFUAA CHEM KK

1985-04-15 Priority to JP7981485A priority Critical patent/JPS61238789A/ja

1986-10-24 Publication of JPS61238789A publication Critical patent/JPS61238789A/ja

1989-04-11 Publication of JPH0119397B2 publication Critical patent/JPH0119397B2/ja

Status Granted legal-status Critical Current

Links

229930195733 hydrocarbon Natural products 0.000 title claims abstract description 19
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 19
239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 16
229910052783 alkali metal Inorganic materials 0.000 title claims abstract description 16
150000001340 alkali metals Chemical class 0.000 title claims abstract description 16
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 16
-1 alkyl aluminum compound Chemical class 0.000 claims description 11
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 25
239000002904 solvent Substances 0.000 abstract description 10
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 5
239000008096 xylene Substances 0.000 abstract description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 3
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract description 3
229910052708 sodium Inorganic materials 0.000 abstract description 3
239000011734 sodium Substances 0.000 abstract description 3
239000012312 sodium hydride Substances 0.000 abstract description 3
229910000104 sodium hydride Inorganic materials 0.000 abstract description 3
230000001603 reducing effect Effects 0.000 abstract description 2
150000001875 compounds Chemical class 0.000 abstract 2
150000004678 hydrides Chemical class 0.000 abstract 2
230000006866 deterioration Effects 0.000 abstract 1
CGKRFDXHYBJWPO-UHFFFAOYSA-N C(C)[AlH]CC.[Na] Chemical compound C(C)[AlH]CC.[Na] CGKRFDXHYBJWPO-UHFFFAOYSA-N 0.000 description 8
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 7
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
125000005234 alkyl aluminium group Chemical group 0.000 description 6
HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 4
239000000203 mixture Substances 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
BKROBWQGDCDWJN-UHFFFAOYSA-N C(C(C)C)[AlH]CC(C)C.[Na] Chemical compound C(C(C)C)[AlH]CC(C)C.[Na] BKROBWQGDCDWJN-UHFFFAOYSA-N 0.000 description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
239000002879 Lewis base Substances 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
150000007527 lewis bases Chemical class 0.000 description 2
238000000034 method Methods 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
JPUHCPXFQIXLMW-UHFFFAOYSA-N aluminium triethoxide Chemical compound CCO[Al](OCC)OCC JPUHCPXFQIXLMW-UHFFFAOYSA-N 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
YFNGCPVGPCKWAL-UHFFFAOYSA-N bis(2-methylpropyl)-propan-2-yloxyalumane Chemical compound CC(C)[O-].CC(C)C[Al+]CC(C)C YFNGCPVGPCKWAL-UHFFFAOYSA-N 0.000 description 1
SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
QYRVKEFNJZPMKU-UHFFFAOYSA-N diethyl(propan-2-yloxy)alumane Chemical compound CC(C)[O-].CC[Al+]CC QYRVKEFNJZPMKU-UHFFFAOYSA-N 0.000 description 1
CPDVHGLWIFENDJ-UHFFFAOYSA-N dihexylalumane Chemical compound C(CCCCC)[AlH]CCCCCC CPDVHGLWIFENDJ-UHFFFAOYSA-N 0.000 description 1
GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 1
XGAIERUWZADBAO-UHFFFAOYSA-N ethoxy-bis(2-methylpropyl)alumane Chemical compound CCO[Al](CC(C)C)CC(C)C XGAIERUWZADBAO-UHFFFAOYSA-N 0.000 description 1
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
PQYRGTGTFRXFEN-UHFFFAOYSA-N methoxy-bis(2-methylpropyl)alumane Chemical compound CC(C)C[Al](OC)CC(C)C PQYRGTGTFRXFEN-UHFFFAOYSA-N 0.000 description 1
238000001953 recrystallisation Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
DAOVYDBYKGXFOB-UHFFFAOYSA-N tris(2-methylpropoxy)alumane Chemical compound [Al+3].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-] DAOVYDBYKGXFOB-UHFFFAOYSA-N 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1

JP7981485A 1985-04-15 1985-04-15 ナトリウムジアルキルアルミニウムジハイドライドの溶解方法 Granted JPS61238789A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP7981485A JPS61238789A (ja)	1985-04-15	1985-04-15	ナトリウムジアルキルアルミニウムジハイドライドの溶解方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP7981485A JPS61238789A (ja)	1985-04-15	1985-04-15	ナトリウムジアルキルアルミニウムジハイドライドの溶解方法

Publications (2)

Publication Number	Publication Date
JPS61238789A true JPS61238789A (ja)	1986-10-24
JPH0119397B2 JPH0119397B2 (2)	1989-04-11

Family

ID=13700670

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP7981485A Granted JPS61238789A (ja)	1985-04-15	1985-04-15	ナトリウムジアルキルアルミニウムジハイドライドの溶解方法

Country Status (1)

Country	Link
JP (1)	JPS61238789A (2)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5443485A (en) *	1977-09-12	1979-04-06	Hitachi Ltd	Photo detector

1985
- 1985-04-15 JP JP7981485A patent/JPS61238789A/ja active Granted

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5443485A (en) *	1977-09-12	1979-04-06	Hitachi Ltd	Photo detector

Also Published As

Publication number	Publication date
JPH0119397B2 (2)	1989-04-11

Publication	Publication Date	Title
JP3246756B2 (ja)	2002-01-15	メチルアルミンオキサン化合物の炭化水素溶液
CA2265621A1 (en)	1998-04-16	Production of hydrocarbon-soluble hydrocarbylaluminoxanes
JPH05194539A (ja)	1993-08-03	ゲルを含まないアルキルアルミノキサン溶液の製造法
EP0818456A2 (en)	1998-01-14	Modified Polyalkylaluminoxane composition formed using reagent containing aluminum trialkyl siloxide
JPS6135998B2 (2)	1986-08-15
NO147757B (no)	1983-02-28	Fremgangsmaate til polymerisasjon av propen.
JPH0529371B2 (2)	1993-04-30
US3318931A (en)	1967-05-09	Method of producing alkylgalliums
JPH05140171A (ja)	1993-06-08	アルミノキサンの製造法
US4207207A (en)	1980-06-10	Hydrocarbon soluble magnesium compositions of high magnesium content
JPS60221301A (ja)	1985-11-06	水素化ゲルマニウムの製造方法
JPS61238789A (ja)	1986-10-24	ナトリウムジアルキルアルミニウムジハイドライドの溶解方法
JP2866434B2 (ja)	1999-03-08	アルミノキサンの製造方法
AU620106B2 (en)	1992-02-13	Non-aqueous process for the preparation of alumoxanes
JPS5817206B2 (ja)	1983-04-05	エチレンの重合法
US3493592A (en)	1970-02-03	Preparation of dialkyltins and dialkyltin oxides
JPS607637B2 (ja)	1985-02-26	ジアルキルアルミニウムハイドライド類の製法
JPH05331218A (ja)	1993-12-14	安定化された遷移金属化合物及びその保存方法
US3702309A (en)	1972-11-07	Polymerization of ethylene using reduced group iv-b,v-b and vi-b metal salts as the polymerization catalyst
JPS62116586A (ja)	1987-05-28	ジアルキル亜鉛化合物の生成法
JPS6217004A (ja)	1987-01-26	ゲルマン類の製造方法
CA1149547A (en)	1983-07-05	Hydrocarbon-soluble magnesium aluminum compositions
US4698437A (en)	1987-10-06	Alkali metal dialkylaluminum dihydrides and solutions thereof in aromatic hydrocarbons
JP2554071B2 (ja)	1996-11-13	オレフイン系共重合体およびその製造方法
JP2547208B2 (ja)	1996-10-23	オレフイン系重合体およびその製造方法