NL8000260A - Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties. - Google Patents

Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties. Download PDF

Info

Publication number: NL8000260A
Authority: NL; Netherlands
Prior art keywords: peroxide; emulsion; aqueous; vinyl; emulsions
Prior art date: 1980-01-16

Application number

NL8000260A

Other languages

English (en)

Dutch (nl)

Original Assignee

Akzo Nv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-01-16

Filing date

1980-01-16

Publication date

1981-08-17

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=19834682&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NL8000260(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1980-01-16 Priority to NL8000260A priority Critical patent/NL8000260A/nl

1980-01-16 Application filed by Akzo Nv filed Critical Akzo Nv

1981-01-06 Priority to DE8181200005T priority patent/DE3160119D1/de

1981-01-06 Priority to EP81200005A priority patent/EP0032757B2/en

1981-01-09 Priority to CS81939A priority patent/CS239920B2/cs

1981-01-09 Priority to PT72334A priority patent/PT72334B/pt

1981-01-09 Priority to CS81206A priority patent/CS239913B2/cs

1981-01-14 Priority to JP328181A priority patent/JPS56139509A/ja

1981-01-14 Priority to DD81226989A priority patent/DD156970A5/de

1981-01-14 Priority to PL22921081A priority patent/PL229210A1/xx

1981-01-15 Priority to ES498542A priority patent/ES498542A0/es

1981-01-15 Priority to BR8100220A priority patent/BR8100220A/pt

1981-01-15 Priority to CA000368615A priority patent/CA1171847A/en

1981-01-15 Priority to AR283957A priority patent/AR226090A1/es

1981-01-15 Priority to AU66222/81A priority patent/AU541743B2/en

1981-01-15 Priority to NO810128A priority patent/NO156166C/no

1981-01-15 Priority to HU8186A priority patent/HU190362B/hu

1981-01-16 Priority to YU100/81A priority patent/YU41372B/xx

1981-08-17 Publication of NL8000260A publication Critical patent/NL8000260A/nl

1993-01-25 Priority to US08/008,894 priority patent/US5260390A/en

1993-10-22 Priority to US08/139,772 priority patent/US5369197A/en

Links

239000000839 emulsion Substances 0.000 title claims description 55
150000002978 peroxides Chemical class 0.000 title claims description 22
238000006116 polymerization reaction Methods 0.000 title claims description 10
239000000725 suspension Substances 0.000 title claims description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
150000001451 organic peroxides Chemical class 0.000 claims description 16
125000004432 carbon atom Chemical group C* 0.000 claims description 15
-1 alkane diol Chemical class 0.000 claims description 14
239000007788 liquid Substances 0.000 claims description 8
239000004094 surface-active agent Substances 0.000 claims description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 7
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 6
239000000084 colloidal system Substances 0.000 claims description 6
230000001681 protective effect Effects 0.000 claims description 6
BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 claims description 3
125000000547 substituted alkyl group Chemical group 0.000 claims description 2
238000010557 suspension polymerization reaction Methods 0.000 claims description 2
238000000034 method Methods 0.000 claims 2
239000000203 mixture Substances 0.000 description 8
150000001298 alcohols Chemical class 0.000 description 5
238000000465 moulding Methods 0.000 description 5
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
239000004372 Polyvinyl alcohol Substances 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
150000001735 carboxylic acids Chemical class 0.000 description 3
239000000178 monomer Substances 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
229920002451 polyvinyl alcohol Polymers 0.000 description 3
239000000243 solution Substances 0.000 description 3
229920001567 vinyl ester resin Polymers 0.000 description 3
XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
239000004342 Benzoyl peroxide Substances 0.000 description 2
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
235000019400 benzoyl peroxide Nutrition 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000001804 emulsifying effect Effects 0.000 description 2
FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
230000008018 melting Effects 0.000 description 2
238000002844 melting Methods 0.000 description 2
239000002245 particle Substances 0.000 description 2
150000002976 peresters Chemical class 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
150000003440 styrenes Chemical class 0.000 description 2
239000000126 substance Substances 0.000 description 2
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
ZXFHYTWKGJWGFM-UHFFFAOYSA-N 1-chloroethenyl acetate Chemical compound CC(=O)OC(Cl)=C ZXFHYTWKGJWGFM-UHFFFAOYSA-N 0.000 description 1
UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 1
OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical class CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
KUIZKZHDMPERHR-UHFFFAOYSA-N 1-phenylprop-2-en-1-one Chemical compound C=CC(=O)C1=CC=CC=C1 KUIZKZHDMPERHR-UHFFFAOYSA-N 0.000 description 1
SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
MENUHMSZHZBYMK-UHFFFAOYSA-N 2-cyclohexylethenylbenzene Chemical class C1CCCCC1C=CC1=CC=CC=C1 MENUHMSZHZBYMK-UHFFFAOYSA-N 0.000 description 1
VGZZAZYCLRYTNQ-UHFFFAOYSA-N 2-ethoxyethoxycarbonyloxy 2-ethoxyethyl carbonate Chemical compound CCOCCOC(=O)OOC(=O)OCCOCC VGZZAZYCLRYTNQ-UHFFFAOYSA-N 0.000 description 1
KBKNKFIRGXQLDB-UHFFFAOYSA-N 2-fluoroethenylbenzene Chemical group FC=CC1=CC=CC=C1 KBKNKFIRGXQLDB-UHFFFAOYSA-N 0.000 description 1
AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 1
PIAOLBVUVDXHHL-UHFFFAOYSA-N 2-nitroethenylbenzene Chemical compound [O-][N+](=O)C=CC1=CC=CC=C1 PIAOLBVUVDXHHL-UHFFFAOYSA-N 0.000 description 1
SAFZQLDSMLNONX-UHFFFAOYSA-N 2-phenoxyethenylbenzene Chemical compound C=1C=CC=CC=1OC=CC1=CC=CC=C1 SAFZQLDSMLNONX-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
HKADMMFLLPJEAG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-enylbenzene Chemical group FC(F)(F)C=CC1=CC=CC=C1 HKADMMFLLPJEAG-UHFFFAOYSA-N 0.000 description 1
DSSAWHFZNWVJEC-UHFFFAOYSA-N 3-(ethenoxymethyl)heptane Chemical compound CCCCC(CC)COC=C DSSAWHFZNWVJEC-UHFFFAOYSA-N 0.000 description 1
CEBRPXLXYCFYGU-UHFFFAOYSA-N 3-methylbut-1-enylbenzene Chemical class CC(C)C=CC1=CC=CC=C1 CEBRPXLXYCFYGU-UHFFFAOYSA-N 0.000 description 1
AIMDYNJRXHEXEL-UHFFFAOYSA-N 3-phenylprop-1-enylbenzene Chemical class C=1C=CC=CC=1CC=CC1=CC=CC=C1 AIMDYNJRXHEXEL-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical class CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
DJYCUKPICQCQKY-UHFFFAOYSA-N 4-ethenyl-1-(4-ethenyl-2-phenylphenoxy)-2-phenylbenzene Chemical compound C=1C=CC=CC=1C1=CC(C=C)=CC=C1OC1=CC=C(C=C)C=C1C1=CC=CC=C1 DJYCUKPICQCQKY-UHFFFAOYSA-N 0.000 description 1
208000002874 Acne Vulgaris Diseases 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
HETCEOQFVDFGSY-UHFFFAOYSA-N Isopropenyl acetate Chemical compound CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
229920001213 Polysorbate 20 Polymers 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical group Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 1
WEXOBAIZDAHLOL-UHFFFAOYSA-N [I].C=Cc1ccccc1 Chemical group [I].C=Cc1ccccc1 WEXOBAIZDAHLOL-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
206010000496 acne Diseases 0.000 description 1
239000013543 active substance Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical class CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 1
ZGPBOPXFOJBLIV-UHFFFAOYSA-N butoxycarbonyloxy butyl carbonate Chemical compound CCCCOC(=O)OOC(=O)OCCCC ZGPBOPXFOJBLIV-UHFFFAOYSA-N 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
229920003086 cellulose ether Polymers 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000000994 depressogenic effect Effects 0.000 description 1
ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
AFIQVBFAKUPHOA-UHFFFAOYSA-N ethenyl 2-methoxyacetate Chemical compound COCC(=O)OC=C AFIQVBFAKUPHOA-UHFFFAOYSA-N 0.000 description 1
FFYWKOUKJFCBAM-UHFFFAOYSA-N ethenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC=C FFYWKOUKJFCBAM-UHFFFAOYSA-N 0.000 description 1
MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
GFJVXXWOPWLRNU-UHFFFAOYSA-N ethenyl formate Chemical compound C=COC=O GFJVXXWOPWLRNU-UHFFFAOYSA-N 0.000 description 1
BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 description 1
XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
230000004927 fusion Effects 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical class CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
239000003999 initiator Substances 0.000 description 1
GHXZPUGJZVBLGC-UHFFFAOYSA-N iodoethene Chemical compound IC=C GHXZPUGJZVBLGC-UHFFFAOYSA-N 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
NUMHUJZXKZKUBN-UHFFFAOYSA-N methyl 4-ethenylbenzoate Chemical compound COC(=O)C1=CC=C(C=C)C=C1 NUMHUJZXKZKUBN-UHFFFAOYSA-N 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
229920000847 nonoxynol Polymers 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical class C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
125000005634 peroxydicarbonate group Chemical group 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
YPVDWEHVCUBACK-UHFFFAOYSA-N propoxycarbonyloxy propyl carbonate Chemical compound CCCOC(=O)OOC(=O)OCCC YPVDWEHVCUBACK-UHFFFAOYSA-N 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
238000010257 thawing Methods 0.000 description 1
KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
229940082509 xanthan gum Drugs 0.000 description 1
235000010493 xanthan gum Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Polymerization Catalysts (AREA)
Adhesives Or Adhesive Processes (AREA)

NL8000260A 1980-01-16 1980-01-16 Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties. NL8000260A (nl)

Priority Applications (19)

Application Number	Priority Date	Filing Date	Title
NL8000260A NL8000260A (nl)	1980-01-16	1980-01-16	Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties.
DE8181200005T DE3160119D1 (en)	1980-01-16	1981-01-06	Aqueous peroxide emulsion and its use in suspension (co)polymerization reactions
EP81200005A EP0032757B2 (en)	1980-01-16	1981-01-06	Aqueous peroxide emulsion and its use in suspension (co)polymerization reactions
CS81939A CS239920B2 (en)	1980-01-16	1981-01-09	Method of polymerization in peroxide environment
PT72334A PT72334B (en)	1980-01-16	1981-01-09	Aqueous peroxide emulsion and its use in suspension (co)polyme-rization reaction
CS81206A CS239913B2 (en)	1980-01-16	1981-01-09	Water-peroxide emulsion
JP328181A JPS56139509A (en)	1980-01-16	1981-01-14	Aqueous peroxide emulsion and use in suspension polymerization or copolymerization
DD81226989A DD156970A5 (de)	1980-01-16	1981-01-14	Waessrige peroxidemulsion und ihre verwendung bei suspensions (ko)-polymerisations-reaktionen
PL22921081A PL229210A1 (cs)	1980-01-16	1981-01-14
ES498542A ES498542A0 (es)	1980-01-16	1981-01-15	Un procedimiento para preparar una emulsion acuosa de un peroxido organico.
HU8186A HU190362B (en)	1980-01-16	1981-01-15	Aqueous peroxide emulsion aqeuous peroxid emulsion
BR8100220A BR8100220A (pt)	1980-01-16	1981-01-15	Emulsao de peroxido aquosa e processo para a (co) polimerizacao em suspensao de um composto etilenciamente insaturado e para a polimerizacao em suspensao de cloreto de vinila
CA000368615A CA1171847A (en)	1980-01-16	1981-01-15	Peroxide emulsions containing an antifreezing compound
AR283957A AR226090A1 (es)	1980-01-16	1981-01-15	Emulsion acuosa de peroxido,util en la polimerizacion de compuestos etilenicamente insaturados
AU66222/81A AU541743B2 (en)	1980-01-16	1981-01-15	Peroxide catalyst
NO810128A NO156166C (no)	1980-01-16	1981-01-15	Vandig peroksydemulsjon for bruk ved suspensjon(ko)-polymerisering.
YU100/81A YU41372B (en)	1980-01-16	1981-01-16	Process for the suspension (co) polymerization of an ethylenically unsaturated compounds
US08/008,894 US5260390A (en)	1980-01-16	1993-01-25	Peroxide emulsions containing an antifreezing compound
US08/139,772 US5369197A (en)	1980-01-16	1993-10-22	Peroxide emulsions containing an antifreezing compound

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL8000260A NL8000260A (nl)	1980-01-16	1980-01-16	Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties.
NL8000260		1980-01-16

Publications (1)

Publication Number	Publication Date
NL8000260A true NL8000260A (nl)	1981-08-17

Family

ID=19834682

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8000260A NL8000260A (nl)	1980-01-16	1980-01-16	Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties.

Country Status (16)

Country	Link
EP (1)	EP0032757B2 (cs)
JP (1)	JPS56139509A (cs)
AR (1)	AR226090A1 (cs)
AU (1)	AU541743B2 (cs)
BR (1)	BR8100220A (cs)
CA (1)	CA1171847A (cs)
CS (2)	CS239920B2 (cs)
DD (1)	DD156970A5 (cs)
DE (1)	DE3160119D1 (cs)
ES (1)	ES498542A0 (cs)
HU (1)	HU190362B (cs)
NL (1)	NL8000260A (cs)
NO (1)	NO156166C (cs)
PL (1)	PL229210A1 (cs)
PT (1)	PT72334B (cs)
YU (1)	YU41372B (cs)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS58134103A (ja) *	1982-02-02	1983-08-10	Nippon Oil & Fats Co Ltd	塩化ビニル系不飽和単量体の懸濁重合方法
US4515928A (en) *	1982-07-20	1985-05-07	Ppg Industries, Inc.	Organic peroxide composition containing trihydric alcohol, alkali or alkaline earth metal chloride, or monosaccharide
US4552682A (en) *	1982-09-30	1985-11-12	Ppg Industries, Inc.	Peroxide composition containing phenolic antioxidant
US4515929A (en) *	1983-07-28	1985-05-07	Ppg Industries, Inc.	Peroxide composition
JPS60258212A (ja) *	1984-06-05	1985-12-20	Nippon Oil & Fats Co Ltd	塩化ビニル系不飽和単量体の懸濁重合方法
JPS61130315A (ja) *	1984-11-30	1986-06-18	Nippon Oil & Fats Co Ltd	塩化ビニル系不飽和単量体の懸濁重合方法
JPS61130372A (ja) *	1984-11-30	1986-06-18	Nippon Oil & Fats Co Ltd	有機過酸化物含有水性懸濁液
JPH0717690B2 (ja) *	1986-10-07	1995-03-01	日本油脂株式会社	有機過酸化物水性分散液
TW341579B (en) *	1996-06-24	1998-10-01	Akzo Nobel Nv	Process for enhancing the melt strength of polypropylene (co)polymers
TW426707B (en)	1997-07-24	2001-03-21	Akzo Nobel Nv	Emulsions of peroxyesters
JPH11171914A (ja) *	1997-12-16	1999-06-29	Kayaku Akzo Corp	有機過酸化物のエマルション配合物
EP1373198B2 (en)	2001-03-23	2015-02-25	Akzo Nobel N.V.	Storage stable aqueous organic peroxide emulsions
JP4271141B2 (ja) †	2002-05-08	2009-06-03	アクゾノーベルナムローゼフェンノートシャップ	低い化学的酸素要求量値を有する非常に濃厚で安定かつ安全なジアシルパーオキシドおよびパーオキシジカーボネートエマルジョン
FR2851245B1 (fr) *	2003-02-14	2007-03-23		Emulsion non gelee d'hydroxyperoxyester
ES2528676T3 (es) *	2004-02-10	2015-02-11	Arkema France	Emulsión no gelificada de hidroxiperoxiéster
PL2462114T3 (pl)	2009-08-06	2014-07-31	Akzo Nobel Chemicals Int Bv	Stabilne podczas przechowywania i bezpieczne emulsje nadtlenków o wysokiej zawartości aktywnego tlenu
CN105246925B (zh) *	2013-05-27	2017-08-25	大金工业株式会社	含氟聚合物的制造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB931629A (en) *	1959-07-11	1963-07-17	Distillers Co Yeast Ltd	Vinyl chloride polymerisation process
GB1095914A (en) *	1965-03-12	1967-12-20	U S Peroxygen Corp	Pigmented peroxide compositions
US3507800A (en) *	1966-10-05	1970-04-21	U S Peroxygen Corp	Flame resistant peroxides
US3988261A (en) *	1975-07-28	1976-10-26	Ppg Industries, Inc.	Frozen organic peroxide emulsion
SE389811B (sv) *	1975-07-29	1976-11-22	Kema Nord Ab	Sett att framstella stabila, vattenhaltiga dispersioner av fasta dialkyl-peroxidikarbonat med bibehallet aktivt peroxidinnehall, varvid en uppslamning av vatten, dispergeringsmedel och peroxidkarbonat dispergeras...
DE2629467A1 (de) *	1976-06-30	1978-01-05	Wacker Chemie Gmbh	Waessrige katalysatorkonfektion

1980
- 1980-01-16 NL NL8000260A patent/NL8000260A/nl not_active Application Discontinuation
1981
- 1981-01-06 DE DE8181200005T patent/DE3160119D1/de not_active Expired
- 1981-01-06 EP EP81200005A patent/EP0032757B2/en not_active Expired - Lifetime
- 1981-01-09 PT PT72334A patent/PT72334B/pt unknown
- 1981-01-09 CS CS81939A patent/CS239920B2/cs unknown
- 1981-01-09 CS CS81206A patent/CS239913B2/cs unknown
- 1981-01-14 DD DD81226989A patent/DD156970A5/de unknown
- 1981-01-14 PL PL22921081A patent/PL229210A1/xx unknown
- 1981-01-14 JP JP328181A patent/JPS56139509A/ja active Granted
- 1981-01-15 AU AU66222/81A patent/AU541743B2/en not_active Expired
- 1981-01-15 ES ES498542A patent/ES498542A0/es active Granted
- 1981-01-15 HU HU8186A patent/HU190362B/hu unknown
- 1981-01-15 AR AR283957A patent/AR226090A1/es active
- 1981-01-15 NO NO810128A patent/NO156166C/no not_active IP Right Cessation
- 1981-01-15 BR BR8100220A patent/BR8100220A/pt not_active IP Right Cessation
- 1981-01-15 CA CA000368615A patent/CA1171847A/en not_active Expired
- 1981-01-16 YU YU100/81A patent/YU41372B/xx unknown

Also Published As

Publication number	Publication date
EP0032757B1 (en)	1983-03-23
HU190362B (en)	1986-08-28
ES8203838A1 (es)	1982-04-16
NO156166C (no)	1987-08-05
PT72334B (en)	1981-12-18
AU6622281A (en)	1981-07-23
JPS6345405B2 (cs)	1988-09-09
PL229210A1 (cs)	1981-10-02
JPS56139509A (en)	1981-10-31
NO156166B (no)	1987-04-27
YU10081A (en)	1983-10-31
CS239913B2 (en)	1986-01-16
NO810128L (no)	1981-07-17
EP0032757B2 (en)	1990-03-07
EP0032757A3 (en)	1981-08-05
PT72334A (en)	1981-02-01
YU41372B (en)	1987-02-28
CS239920B2 (en)	1986-01-16
AU541743B2 (en)	1985-01-17
EP0032757A2 (en)	1981-07-29
CA1171847A (en)	1984-07-31
ES498542A0 (es)	1982-04-16
AR226090A1 (es)	1982-05-31
BR8100220A (pt)	1981-08-04
DD156970A5 (de)	1982-10-06
DE3160119D1 (en)	1983-04-28

Legal Events

Date	Code	Title	Description
1981-08-17	A1B	A search report has been drawn up
1982-09-01	BV	The patent application has lapsed

Publication	Publication Date	Title
NL8000260A (nl)	1981-08-17	Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties.
US4552682A (en)	1985-11-12	Peroxide composition containing phenolic antioxidant
US4515929A (en)	1985-05-07	Peroxide composition
NL8103526A (nl)	1982-02-16	Waterige emulsies van organische peroxyden.
US5260390A (en)	1993-11-09	Peroxide emulsions containing an antifreezing compound
US6350835B1 (en)	2002-02-26	Emulsions of peroxyesters
KR20010033043A (ko)	2001-04-25	유기 퍼옥시드 에멀션
NO772297L (no)	1978-01-02	Vandig katalysatormaterialer for polymerisasjon
EP0071116B1 (en)	1986-02-26	Suspension polymerization with cosolvent partitioning
TWI510463B (zh)	2015-12-01	具有高活性氧含量之貯存安定及安全之過氧化物乳液
US4950422A (en)	1990-08-21	Peroxide emulsions containing an anti-freezing compound
JPS61130315A (ja)	1986-06-18	塩化ビニル系不飽和単量体の懸濁重合方法
RU2232776C2 (ru)	2004-07-20	Водные эмульсии пероксидов
SK57299A3 (en)	2000-02-14	Process to make initiator compositions comprising polyvinyl alcohol and surfactant
JPH0635484B2 (ja)	1994-05-11	有機過酸化物のエマルジヨン配合物
JP3403487B2 (ja)	2003-05-06	水エマルジョン化有機過酸化物
JPH0565524B2 (cs)	1993-09-17
US6677409B2 (en)	2004-01-13	Method of producing vinyl-based polymer
JP2003183311A (ja)	2003-07-03	ビニル系重合体の製造方法
JPH11209418A (ja)	1999-08-03	水エマルション化有機過酸化物の製造方法
JPS6228163B2 (cs)	1987-06-18
JPH08109213A (ja)	1996-04-30	有機過酸化物の水性エマルション
JPH04117405A (ja)	1992-04-17	有機過酸化物の水性エマルジョン組成物およびその用途
JPH0676445B2 (ja)	1994-09-28	水性エマルション化有機過酸化物及び同過酸化物を実質的成分とする重合開始剤
CS230056B1 (sk)	1984-07-16	Sposob výroby stabilných emulzií iniciátorov