NO20084415L - Azabicyclo [3.1.0] hexyl derivatives as modulators of dopamine D3 receptors - Google Patents

Azabicyclo [3.1.0] hexyl derivatives as modulators of dopamine D3 receptors

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Publication number
NO20084415L
NO20084415L NO20084415A NO20084415A NO20084415L NO 20084415 L NO20084415 L NO 20084415L NO 20084415 A NO20084415 A NO 20084415A NO 20084415 A NO20084415 A NO 20084415A NO 20084415 L NO20084415 L NO 20084415L
Authority
NO
Norway
Prior art keywords
group
haloc1
4alkoxy
4alkyl
4alkanoyl
Prior art date
Application number
NO20084415A
Other languages
Norwegian (no)
Inventor
Alessandra Pasquarello
Romano Di Fabio
Silvia Terreni
Anna Maria Capelli
Gabriella Gentile
Fabrizio Micheli
Giorgio Bonanomi
Giovanna Tedesco
Barbara Bertani
Anna Checchia
Original Assignee
Glaxo Group Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/EP2007/053074 external-priority patent/WO2007113232A1/en
Application filed by Glaxo Group Ltd filed Critical Glaxo Group Ltd
Publication of NO20084415L publication Critical patent/NO20084415L/en

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Abstract

Den foreliggende oppfinnelse vedrører nyskapende forbindelser av formel (I)' eller et salt derav: hvori G er utvalgt fra en gruppe som består av: fenyl, en 5- eller 6-leddet monosyklisk heteroarylgruppe, eller en 8- til 11-leddet heteroarylbisyklisk gruppe; A er en gruppe P1 eller en gruppe P2 hvori 0 p er et helt tall som spenner fra 0 til 5; R1 er halogen, hydroksy, cyano, C1-4alkyl, haloC1-4alkyl, C1-4alkoksy, haloC1-4alkoksy, C1-4alkanoyl og SF5; eller korresponderer til en gruppe R6; og når p er et helt tall som spenner fra 2 til 5, kan hver R1 være lik eller forskjellig; R2 er hydrogen eller C1-4alkyl; n er 3, 4, 5 eller 6; R6 er en enhet valgt fra gruppen som består av: isoksazolyl, -CH2-N-pyrrolyl, 1,1 dioksido-2-isotiazolidinyl, tienyl, tiazolyl, pyridyl, 2-pyrrolidinonyl og en slik R6 gruppe er valgfritt substituert med en eller to substituenter valgt fra: halogen, cyano, C1-4alkyl, haloC1-4alkyl, C1-4alkoksy, C1-4alkanoyl; R4 er utvalgt innen den gruppen som består av: hydrogen, halogen, hydroksy, cyano, C1-4alkyl, C3-7 cykloalkyl, haloC1-4alkyl, C1-4alkoksy, haloC1-4alkoksy, C1-4alkanoyl og NR'R"; eller R4 er en fenylgruppe, en 5- eller 14-leddet heterosyklisk gruppe; og enhver av slik fenyl- eller heterosyklisk gruppe er valgfritt substituert med 1, 2, 3 eller 4 substituenter valgt fra gruppen som består av: halogen, cyano, C1-4 alkyl, haloC1-4alkyl, C1-4alkoksy, C1-4alkanoyl, haloC1-4alkoksy og SF5; R5 er utvalgt innen den gruppen som består av: hydrogen, halogen, hydroksy, cyano, C1-4alkyl, C3-7cykloalkyl, haloC1-4alkyl, C1-4alkoksy, haloC1-4alkoksy, C1-4alkanoyl og NR'R"; eller R5 er en fenylgruppe, en 5- til 14-leddet heterosyklisk gruppe; og enhver av slike fenyl- eller heterosykliske grupper er valgfritt substituert med 1, 2, 3 eller 4 substituenter valgt fra gruppen som består av: halogen, cyano, C1-4 alkyl, haloC1-4alkyl, C1-4alkoksy, C1-4alkanoyl, haloC1-4alkoksy og SF5; R7 er hydrogen eller C1-2alkyl; R' er H, C1-4alkyl eller C1-4alkanoyl; R" er definert som W; R' og R" tatt sammen med det sammenbindende nitrogenatom kan danne en 5- eller 6-leddet mettet eller umettet heterosyklisk ring; hvori minst en av R4 og R5 er hydrogen; og hvori bare en R2-gruppe kan være forskjellig fra hydrogen; fremgangsmåter for deres fremstilling, mellomprodukter benyttet i disse fremgangsmåter, farmasøytiske preparater som inneholder dem og deres anvendelse i terapi, som modulatorer for dopamin D3 reseptorer, for eksempel for å behandle stoffavhengighet, som antipyskotiske midler, for å behandle lidelser i det obsessive kompulsive spekter, eller prematur ejakulasjon.The present invention relates to novel compounds of formula (I) or a salt thereof: wherein G is selected from a group consisting of: phenyl, a 5- or 6-membered monocyclic heteroaryl group, or an 8- to 11-membered heteroarylbicyclic group ; A is a group P1 or a group P2 wherein 0 p is an integer ranging from 0 to 5; R1 is halogen, hydroxy, cyano, C1-4alkyl, haloC1-4alkyl, C1-4alkoxy, haloC1-4alkoxy, C1-4alkanoyl and SF5; or corresponds to a group R6; and when p is an integer ranging from 2 to 5, each R1 may be the same or different; R 2 is hydrogen or C 1-4 alkyl; n is 3, 4, 5 or 6; R6 is a moiety selected from the group consisting of: isoxazolyl, -CH2-N-pyrrolyl, 1,1 dioxido-2-isothiazolidinyl, thienyl, thiazolyl, pyridyl, 2-pyrrolidinonyl and such R6 group is optionally substituted by one or two substituents selected from: halogen, cyano, C1-4alkyl, haloC1-4alkyl, C1-4alkoxy, C1-4alkanoyl; R4 is selected from the group consisting of: hydrogen, halogen, hydroxy, cyano, C1-4alkyl, C3-7 cycloalkyl, haloC1-4alkyl, C1-4alkoxy, haloC1-4alkoxy, C1-4alkanoyl and NR'R "; or R4 is a phenyl group, a 5- or 14-membered heterocyclic group, and any such phenyl or heterocyclic group is optionally substituted with 1, 2, 3 or 4 substituents selected from the group consisting of: halogen, cyano, C1-4 alkyl , haloC1-4alkyl, C1-4alkoxy, C1-4alkanoyl, haloC1-4alkoxy and SF5; R5 is selected from the group consisting of: hydrogen, halogen, hydroxy, cyano, C1-4alkyl, C3-7cycloalkyl, haloC1-4alkyl, C1 -4alkoxy, haloC1-4alkoxy, C1-4alkanoyl and NR'R "; or R 5 is a phenyl group, a 5- to 14-membered heterocyclic group; and any of such phenyl or heterocyclic groups are optionally substituted with 1, 2, 3 or 4 substituents selected from the group consisting of: halogen, cyano, C1-4 alkyl, haloC1-4alkyl, C1-4alkoxy, C1-4alkanoyl, haloC1 -4alkoxy and SF5; R 7 is hydrogen or C 1-2 alkyl; R 1 is H, C 1-4 alkyl or C 1-4 alkanoyl; R "is defined as W; R 'and R" taken together with the bonding nitrogen atom may form a 5- or 6-membered saturated or unsaturated heterocyclic ring; wherein at least one of R4 and R5 is hydrogen; and wherein only one R 2 group may be different from hydrogen; methods for their preparation, intermediates used in these methods, pharmaceutical compositions containing them and their use in therapy, as modulators of dopamine D3 receptors, for example to treat drug dependence, as antipsychotics, to treat disorders of the obsessive compulsive spectrum, or premature ejaculation.

NO20084415A 2006-04-03 2008-10-21 Azabicyclo [3.1.0] hexyl derivatives as modulators of dopamine D3 receptors NO20084415L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0607892A GB0607892D0 (en) 2006-04-03 2006-04-03 Novel compounds
PCT/EP2007/053074 WO2007113232A1 (en) 2006-04-03 2007-03-30 Azabicyclo [3. 1. 0] hexyl derivatives as modulators of dopamine d3 receptors

Publications (1)

Publication Number Publication Date
NO20084415L true NO20084415L (en) 2008-12-08

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CN (1) CN101460485A (en)
GB (1) GB0607892D0 (en)
NO (1) NO20084415L (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112012000657A2 (en) * 2009-06-26 2016-11-16 Panacea Biotec Ltd new azabicylhexanes
CN116655604B (en) * 2022-02-17 2025-09-16 苏州第四制药厂有限公司 Synthesis method of Pa Luo Weide

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CN101460485A (en) 2009-06-17
GB0607892D0 (en) 2006-05-31

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