RU2008139902A - Воздухозаборное устройство с функционализированной ионообменной мембраной для улавливания co2 из внешней среды - Google Patents
Воздухозаборное устройство с функционализированной ионообменной мембраной для улавливания co2 из внешней среды Download PDFInfo
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- RU2008139902A RU2008139902A RU2008139902/15A RU2008139902A RU2008139902A RU 2008139902 A RU2008139902 A RU 2008139902A RU 2008139902/15 A RU2008139902/15 A RU 2008139902/15A RU 2008139902 A RU2008139902 A RU 2008139902A RU 2008139902 A RU2008139902 A RU 2008139902A
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- 239000003014 ion exchange membrane Substances 0.000 title 1
- 239000000463 material Substances 0.000 claims abstract 24
- 238000000034 method Methods 0.000 claims abstract 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract 8
- 125000000129 anionic group Chemical group 0.000 claims abstract 6
- 238000005349 anion exchange Methods 0.000 claims abstract 4
- 241000264877 Hippospongia communis Species 0.000 claims abstract 2
- 239000004793 Polystyrene Substances 0.000 claims abstract 2
- 229920002678 cellulose Polymers 0.000 claims abstract 2
- 239000001913 cellulose Substances 0.000 claims abstract 2
- 239000012141 concentrate Substances 0.000 claims abstract 2
- 239000011159 matrix material Substances 0.000 claims abstract 2
- 239000012528 membrane Substances 0.000 claims abstract 2
- 229920000642 polymer Polymers 0.000 claims abstract 2
- 229920002223 polystyrene Polymers 0.000 claims abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 4
- 239000013535 sea water Substances 0.000 claims 4
- 239000011780 sodium chloride Substances 0.000 claims 4
- 238000009933 burial Methods 0.000 claims 1
- 239000000446 fuel Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 239000011435 rock Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/10—Separation by diffusion
- B01D59/12—Separation by diffusion by diffusion through barriers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/20—Organic adsorbents
- B01D2253/202—Polymeric adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/20—Organic adsorbents
- B01D2253/206—Ion exchange resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/306—Surface area, e.g. BET-specific surface
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/34—Specific shapes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/34—Specific shapes
- B01D2253/342—Monoliths
- B01D2253/3425—Honeycomb shape
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2257/00—Components to be removed
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- B01D2257/504—Carbon dioxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4508—Gas separation or purification devices adapted for specific applications for cleaning air in buildings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
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- Manufacture Of Macromolecular Shaped Articles (AREA)
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
1. Устройство для улавливания СО2 из атмосферы, содержащее анионообменный материал, сформированный в матрице, подвергающейся воздействию потока воздуха. ! 2. Устройство по п.1, в котором материал сформирован как множество многоугольников. ! 3. Устройство по п.1, в котором материал сформирован как множество квадратов, прямоугольников, треугольников, трапеций, пятиугольников или шестиугольников. ! 4. Устройство по п.1, в котором материал имеет форму спирально скрученного диска. ! 5. Устройство по п.1, в котором материал имеет форму множества концентрических слоев. ! 6. Устройство по п.1, в котором материал имеет форму усеченного конуса. ! 7. Устройство по п.1, в котором материал имеет форму множества жалюзи. ! 8. Устройство по п.1, в котором материал сформирован в виде сетки. ! 9. Устройство по п.1, в котором материал сформирован из анионообменного полимера на основе полистирола или целлюлозы. ! 10. Устройство по любому из пп. 1-9, установленное в башенный охладитель. ! 11. Устройство по любому из пп. 1-9, установленное в выпускную систему. ! 12. Устройство для улавливания СО2 из атмосферы, содержащее анионный мембранный материал, сформированный в виде сот или сетки. ! 13. Способ удаления СО2 из воздуха, включающий стадии, на которых пропускают воздух в контакте с устройством по любому из пп. 1-11, вследствие чего СО2 захватывается анионным материалом, и обрабатывают анионный материал для удаления и концентрирования захваченного СО2. ! 14. Способ по п.13, включающий стадию, на которой преобразуют захваченный СО2 в метан. ! 15. Способ по п.14, в котором захваченный СО2 преобразуется в метан с использованием процесса Сабатье. ! 16. Способ по п.13, в котором за
Claims (19)
1. Устройство для улавливания СО2 из атмосферы, содержащее анионообменный материал, сформированный в матрице, подвергающейся воздействию потока воздуха.
2. Устройство по п.1, в котором материал сформирован как множество многоугольников.
3. Устройство по п.1, в котором материал сформирован как множество квадратов, прямоугольников, треугольников, трапеций, пятиугольников или шестиугольников.
4. Устройство по п.1, в котором материал имеет форму спирально скрученного диска.
5. Устройство по п.1, в котором материал имеет форму множества концентрических слоев.
6. Устройство по п.1, в котором материал имеет форму усеченного конуса.
7. Устройство по п.1, в котором материал имеет форму множества жалюзи.
8. Устройство по п.1, в котором материал сформирован в виде сетки.
9. Устройство по п.1, в котором материал сформирован из анионообменного полимера на основе полистирола или целлюлозы.
10. Устройство по любому из пп. 1-9, установленное в башенный охладитель.
11. Устройство по любому из пп. 1-9, установленное в выпускную систему.
12. Устройство для улавливания СО2 из атмосферы, содержащее анионный мембранный материал, сформированный в виде сот или сетки.
13. Способ удаления СО2 из воздуха, включающий стадии, на которых пропускают воздух в контакте с устройством по любому из пп. 1-11, вследствие чего СО2 захватывается анионным материалом, и обрабатывают анионный материал для удаления и концентрирования захваченного СО2.
14. Способ по п.13, включающий стадию, на которой преобразуют захваченный СО2 в метан.
15. Способ по п.14, в котором захваченный СО2 преобразуется в метан с использованием процесса Сабатье.
16. Способ по п.13, в котором захваченный СО2 преобразуется в жидкое синтетическое топливо или пластик.
17. Способ по п.13, в котором захваченный СО2 пропускается в глубокую скважину или глубоководное океанское захоронение.
18. Способ удаления СО2 из воздуха, в котором СО2 удаляется из воздуха путем контакта с щелочной морской водой или солевым раствором, причем морская вода или солевой раствор распадается на H2, Cl2 и NaOH, и Cl2 вводится в основные горные породы для образования соли.
19. Способ по п.18, в котором NaOH добавляется обратно в морскую воду или солевой раствор для повышения щелочности и тем самым для усиления способности морской воды или солевого раствора поглощать атмосферный СО2.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78046706P | 2006-03-08 | 2006-03-08 | |
| US78046606P | 2006-03-08 | 2006-03-08 | |
| US60/780,466 | 2006-03-08 | ||
| US60/780,467 | 2006-03-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2008139902A true RU2008139902A (ru) | 2010-04-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008139902/15A RU2008139902A (ru) | 2006-03-08 | 2007-03-08 | Воздухозаборное устройство с функционализированной ионообменной мембраной для улавливания co2 из внешней среды |
Country Status (9)
| Country | Link |
|---|---|
| US (5) | US7993432B2 (ru) |
| EP (2) | EP1998871A4 (ru) |
| KR (1) | KR20090003206A (ru) |
| CN (1) | CN102441319A (ru) |
| AU (1) | AU2007233275B2 (ru) |
| CA (1) | CA2644676C (ru) |
| MX (1) | MX2008011464A (ru) |
| RU (1) | RU2008139902A (ru) |
| WO (1) | WO2007114991A2 (ru) |
Families Citing this family (79)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006023743A2 (en) * | 2004-08-20 | 2006-03-02 | The Trustees Of Columbia University In The City Of New York | Laminar scrubber apparatus for capturing carbon dioxide from air and methods of use |
| US7727374B2 (en) * | 2004-09-23 | 2010-06-01 | Skyonic Corporation | Removing carbon dioxide from waste streams through co-generation of carbonate and/or bicarbonate minerals |
| AU2006210619B2 (en) * | 2005-02-02 | 2010-09-09 | Global Research Technologies, Llc | Removal of carbon dioxide from air |
| EP1912724A2 (en) | 2005-07-28 | 2008-04-23 | Global Research Technologies, LLC | Removal of carbon dioxide from air |
| US9266051B2 (en) | 2005-07-28 | 2016-02-23 | Carbon Sink, Inc. | Removal of carbon dioxide from air |
| AU2007233275B2 (en) | 2006-03-08 | 2012-07-26 | Carbon Sink, Inc. | Air collector with functionalized ion exchange membrane for capturing ambient CO2 |
| ES2784490T3 (es) | 2006-10-02 | 2020-09-28 | Carbon Sink Inc | Método para extraer dióxido de carbono del aire |
| AU2007319211A1 (en) * | 2006-11-15 | 2008-05-22 | Global Research Technologies, Llc | Removal of carbon dioxide from air |
| GB2452169A (en) * | 2007-02-25 | 2009-02-25 | Puregeneration | Carbon dioxide sequestering fuel synthesis system and use thereof |
| AU2008242845B2 (en) | 2007-04-17 | 2012-08-23 | Carbon Sink, Inc. | Capture of carbon dioxide (CO2) from air |
| US20080289495A1 (en) | 2007-05-21 | 2008-11-27 | Peter Eisenberger | System and Method for Removing Carbon Dioxide From an Atmosphere and Global Thermostat Using the Same |
| US8500857B2 (en) | 2007-05-21 | 2013-08-06 | Peter Eisenberger | Carbon dioxide capture/regeneration method using gas mixture |
| US20140130670A1 (en) | 2012-11-14 | 2014-05-15 | Peter Eisenberger | System and method for removing carbon dioxide from an atmosphere and global thermostat using the same |
| US8163066B2 (en) | 2007-05-21 | 2012-04-24 | Peter Eisenberger | Carbon dioxide capture/regeneration structures and techniques |
| US7910220B2 (en) | 2007-07-25 | 2011-03-22 | Alcoa Inc. | Surfaces and coatings for the removal of carbon dioxide |
| US8122704B2 (en) * | 2007-08-07 | 2012-02-28 | Efficient Hydrogen Motors | Motor system for diminution of carbon dioxide in the atmosphere |
| PL2205341T3 (pl) | 2007-09-20 | 2012-08-31 | Skyonic Corp | Usuwanie dwutlenku węgla ze strumieni gazów spalinowych poprzez współwytwarzanie minerałów węglanów i/lub wodorowęglanów |
| WO2009061836A1 (en) * | 2007-11-05 | 2009-05-14 | Global Research Technologies, Llc | Removal of carbon dioxide from air |
| US7984613B2 (en) * | 2007-11-08 | 2011-07-26 | Mine-Rg, Inc. | Geothermal power generation system and method for adapting to mine shafts |
| MX2010004447A (es) * | 2007-11-20 | 2010-05-13 | Global Res Technologies Llc | Colector de aire con membrana de intercambio ionico funcional para capturar co2 del ambinete. |
| MX339437B (es) | 2008-02-19 | 2016-05-26 | Global Res Technologies Llc | Extraccion y formacion de complejos del dioxido de carbono. |
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2007
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- 2007-03-08 MX MX2008011464A patent/MX2008011464A/es active IP Right Grant
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- 2007-03-08 EP EP07758183A patent/EP1998871A4/en not_active Ceased
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- 2007-03-08 WO PCT/US2007/063607 patent/WO2007114991A2/en not_active Ceased
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| US20070217982A1 (en) | 2007-09-20 |
| US10150112B2 (en) | 2018-12-11 |
| US9205372B2 (en) | 2015-12-08 |
| US20120279397A1 (en) | 2012-11-08 |
| KR20090003206A (ko) | 2009-01-09 |
| EP1998871A4 (en) | 2010-07-21 |
| US20110209614A1 (en) | 2011-09-01 |
| WO2007114991A2 (en) | 2007-10-11 |
| WO2007114991A3 (en) | 2008-04-10 |
| MX2008011464A (es) | 2008-09-24 |
| US20170043333A1 (en) | 2017-02-16 |
| CA2644676C (en) | 2015-02-10 |
| US8246723B2 (en) | 2012-08-21 |
| AU2007233275A1 (en) | 2007-10-11 |
| EP1998871A2 (en) | 2008-12-10 |
| EP2668992A2 (en) | 2013-12-04 |
| CA2644676A1 (en) | 2007-10-11 |
| US8221527B1 (en) | 2012-07-17 |
| AU2007233275B2 (en) | 2012-07-26 |
| EP2668992A3 (en) | 2014-04-02 |
| US7993432B2 (en) | 2011-08-09 |
| CN102441319A (zh) | 2012-05-09 |
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