SU563419A1 - Способ получени солей 0,0=диметилдитиофосфорной кислоты - Google Patents

Способ получени солей 0,0=диметилдитиофосфорной кислоты

Info

Publication number: SU563419A1
Authority: SU; USSR - Soviet Union
Prior art keywords: acid; sulfur; water; weight; dimethyldithiophosphoric acid
Prior art date: 1972-06-30

Application number

SU7201860090A

Other languages

English (en)

Russian (ru)

Inventor

Кохман Вернер

Ветцке Герда

Дитрих Клаус

Фрочер Франк

Гебхардт Бригитте

Гриммер Фалко

Мюллер Юрген

Мюллер Клаус-Дитер

Зас Дитер

Шпрингер Райнхольд

Тиффе Зигрид

Original Assignee

Verner Kokhman

Gerda Vettske

Dittrich Klaus

Frank Frocher

Brigitte Gebkhardt

Falko Grimmer

Yurgen Myuller

Mueller Klaus Dieter

Diter Zas

Rajnkhold Shpringer

Zigrid Tiffe

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1972-06-30

Filing date

1972-12-20

Publication date

1977-06-30

1972-12-20 Application filed by Verner Kokhman, Gerda Vettske, Dittrich Klaus, Frank Frocher, Brigitte Gebkhardt, Falko Grimmer, Yurgen Myuller, Mueller Klaus Dieter, Diter Zas, Rajnkhold Shpringer, Zigrid Tiffe filed Critical Verner Kokhman

1977-06-30 Application granted granted Critical

1977-06-30 Publication of SU563419A1 publication Critical patent/SU563419A1/ru

Links

238000000034 method Methods 0.000 title claims description 12
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 20
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 20
229910052717 sulfur Inorganic materials 0.000 claims description 20
239000011593 sulfur Substances 0.000 claims description 20
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
230000007935 neutral effect Effects 0.000 claims description 12
238000006140 methanolysis reaction Methods 0.000 claims description 9
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
239000002253 acid Substances 0.000 claims description 7
229910052698 phosphorus Inorganic materials 0.000 claims description 7
239000011574 phosphorus Substances 0.000 claims description 7
238000006243 chemical reaction Methods 0.000 claims description 4
-1 ester salts Chemical class 0.000 claims description 4
230000003993 interaction Effects 0.000 claims description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
239000003960 organic solvent Substances 0.000 claims description 2
150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
239000000243 solution Substances 0.000 description 10
239000006227 byproduct Substances 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
239000008346 aqueous phase Substances 0.000 description 8
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 6
238000003756 stirring Methods 0.000 description 6
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
CZGGKXNYNPJFAX-UHFFFAOYSA-N Dimethyldithiophosphate Chemical class COP(S)(=S)OC CZGGKXNYNPJFAX-UHFFFAOYSA-N 0.000 description 5
239000012074 organic phase Substances 0.000 description 5
239000000047 product Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
229910021529 ammonia Inorganic materials 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000000203 mixture Substances 0.000 description 3
238000006386 neutralization reaction Methods 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
238000001914 filtration Methods 0.000 description 2
238000005375 photometry Methods 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
241000191291 Abies alba Species 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
VBKCWDRSJZAGJU-UHFFFAOYSA-L [Ni+2].P(=S)(SC)(OC)[O-].CSP(=S)(OC)[O-] Chemical compound [Ni+2].P(=S)(SC)(OC)[O-].CSP(=S)(OC)[O-] VBKCWDRSJZAGJU-UHFFFAOYSA-L 0.000 description 1
239000003513 alkali Substances 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
PPGORMGERPBFTJ-UHFFFAOYSA-N azane;dimethoxy-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound [NH4+].COP([S-])(=S)OC PPGORMGERPBFTJ-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
VXIVSQZSERGHQP-UHFFFAOYSA-N chloroacetamide Chemical class NC(=O)CCl VXIVSQZSERGHQP-UHFFFAOYSA-N 0.000 description 1
ILDHFYGNYDICFB-UHFFFAOYSA-N dimethoxy-methylsulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound COP(=S)(OC)SC ILDHFYGNYDICFB-UHFFFAOYSA-N 0.000 description 1
NBAUXRCSDWYKRP-UHFFFAOYSA-N dimethyl phosphorochloridothioate Chemical compound COP(Cl)(=O)SC NBAUXRCSDWYKRP-UHFFFAOYSA-N 0.000 description 1
NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical class OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 description 1
238000000227 grinding Methods 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
230000000749 insecticidal effect Effects 0.000 description 1
239000004571 lime Substances 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
XWSLYQXUTWUIKM-UHFFFAOYSA-N trimethoxy(sulfanylidene)-$l^{5}-phosphane Chemical compound COP(=S)(OC)OC XWSLYQXUTWUIKM-UHFFFAOYSA-N 0.000 description 1

SU7201860090A 1972-06-30 1972-12-20 Способ получени солей 0,0=диметилдитиофосфорной кислоты SU563419A1 (ru)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DD16411272A DD99380A1 (cs)	1972-06-30	1972-06-30

Publications (1)

Publication Number	Publication Date
SU563419A1 true SU563419A1 (ru)	1977-06-30

Family

ID=5487287

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU7201860090A SU563419A1 (ru)	1972-06-30	1972-12-20	Способ получени солей 0,0=диметилдитиофосфорной кислоты

Country Status (4)

Country	Link
CS (1)	CS180123B1 (cs)
DD (1)	DD99380A1 (cs)
RO (1)	RO62769A (cs)
SU (1)	SU563419A1 (cs)

1972
- 1972-06-30 DD DD16411272A patent/DD99380A1/xx unknown
- 1972-12-20 SU SU7201860090A patent/SU563419A1/ru active
- 1972-12-21 CS CS884472A patent/CS180123B1/cs unknown
- 1972-12-23 RO RO7327672A patent/RO62769A/ro unknown

Also Published As

Publication number	Publication date
DD99380A1 (cs)	1973-08-13
CS180123B1 (en)	1977-12-30
RO62769A (fr)	1977-10-15

Publication	Publication Date	Title
US2672459A (en)	1954-03-16	Thiophosphonic acid derivatives and method of preparing the same
US4369142A (en)	1983-01-18	Process for producing N-phosphonomethylglycine
US3959361A (en)	1976-05-25	Process of producing amino methylene phosphonic acids
USRE35389E (en)	1996-12-03	Process for the preparation of N-phosphonomethylglycine
US3816517A (en)	1974-06-11	Process of producing amino methylene phosphonic acids
US4486358A (en)	1984-12-04	Process for producing N-phosphonomethylglycine
SU563419A1 (ru)	1977-06-30	Способ получени солей 0,0=диметилдитиофосфорной кислоты
CS239903B2 (en)	1986-01-16	Processing of aminomethyl phosphoric acid derivatives
US4175206A (en)	1979-11-20	Process for preparing a hydroxyphenylglycine compound
US5210220A (en)	1993-05-11	Method for preparing derivatives of ascorbic acid
US3033891A (en)	1962-05-08	Mono salts of o-hydrocarbyl-carboalkylthiol phosphonic acids
JPH075537B2 (ja)	1995-01-25	イミノクタジン・３アルキルベンゼンスルホン酸塩の製造方法
US4076745A (en)	1978-02-28	Process for calcium salts α-ketocarboxylic acids
US4491548A (en)	1985-01-01	Process for preparing phosphonomethylated amino acids
IL99674A (en)	1995-08-31	Process for the preparation of acylamino-methanephosphonic acids
HU190428B (en)	1986-09-29	Process for the production of n-/phosphono-methyl/-glycine
FR2276312A1 (fr)	1976-01-23	Procede de preparation de n-phosphono-methylene-glycine et de son sel disodique
JPH056554B2 (cs)	1993-01-26
Kurzer	1951	281. Cyanamides. Part V. N-Aryl-N′-arylsulphonylureas
US4534904A (en)	1985-08-13	Process for producing N-phosphonomethylglycine
SU1109406A1 (ru)	1984-08-23	Способ получени калиевых солей @ , @ -диалкилдитиофосфорных кислот
JPS6148495B2 (cs)	1986-10-24
JPH0489466A (ja)	1992-03-23	Ｏ―メチルイソ尿素硫酸塩の製造方法
US3308132A (en)	1967-03-07	6, 8-dithiooctanoyl amides and intermediates
SU767028A1 (ru)	1980-09-30	Способ получени сульфата кали