TW200420344A - A lithium aluminate layered catalyst and a selective oxidation process using the catalyst - Google Patents

A lithium aluminate layered catalyst and a selective oxidation process using the catalyst

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Publication number
TW200420344A
TW200420344A TW092128883A TW92128883A TW200420344A TW 200420344 A TW200420344 A TW 200420344A TW 092128883 A TW092128883 A TW 092128883A TW 92128883 A TW92128883 A TW 92128883A TW 200420344 A TW200420344 A TW 200420344A
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TW
Taiwan
Prior art keywords
catalyst
selective oxidation
lithium aluminate
oxidation process
hydrogen
Prior art date
Application number
TW092128883A
Other languages
English (en)
Other versions
TWI321493B (en
Inventor
Guy B Woodle
Andrew S Zarchy
Jeffery C Bricker
Andrzej Z Ringwelski
Original Assignee
Uop Llc
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Publication date
Application filed by Uop Llc filed Critical Uop Llc
Publication of TW200420344A publication Critical patent/TW200420344A/zh
Application granted granted Critical
Publication of TWI321493B publication Critical patent/TWI321493B/zh

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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
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    • B01J23/04—Alkali metals
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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW092128883A 2002-10-18 2003-10-17 A lithium aluminate layered catalyst and a selective oxidation process using the catalyst TWI321493B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/274,693 US6858769B2 (en) 2002-10-18 2002-10-18 Lithium aluminate layered catalyst and a selective oxidation process using the catalyst

Publications (2)

Publication Number Publication Date
TW200420344A true TW200420344A (en) 2004-10-16
TWI321493B TWI321493B (en) 2010-03-11

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TW092128883A TWI321493B (en) 2002-10-18 2003-10-17 A lithium aluminate layered catalyst and a selective oxidation process using the catalyst

Country Status (12)

Country Link
US (1) US6858769B2 (zh)
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JP (1) JP4804756B2 (zh)
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Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7635461B2 (en) * 2003-06-06 2009-12-22 University Of Utah Research Foundation Composite combustion catalyst and associated methods
DE102004015800A1 (de) * 2004-03-29 2005-10-20 Basf Ag Katalysator für die Oxidation von Wasserstoff, sowie Verfahren zur Dehydrierung von Kohlenwasserstoffen
GB0420245D0 (en) * 2004-09-13 2004-10-13 Johnson Matthey Plc Improvements in catalyst coatings
US7601671B2 (en) 2004-10-28 2009-10-13 Umicore Ag & Co. Kg Drying method for exhaust gas catalyst
US7605109B1 (en) * 2004-10-28 2009-10-20 Nanostellar, Inc. Platinum-bismuth catalysts for treating engine exhaust
US7611680B2 (en) * 2004-10-28 2009-11-03 Nanostellar, Inc. Platinum-bismuth catalysts for treating engine exhaust
US7638459B2 (en) * 2005-05-25 2009-12-29 Uop Llc Layered composition and processes for preparing and using the composition
GB0512791D0 (en) * 2005-06-23 2005-07-27 Johnson Matthey Plc Catalysts
US7871961B2 (en) * 2006-07-18 2011-01-18 Sud-Chemie Inc. Catalyst for production of hydrogen and synthesis gas
TW200912061A (en) 2007-05-31 2009-03-16 Showa Denko Kk Carbon nanofiber, method for producing the same, and use of the same
CN101428238B (zh) * 2007-11-07 2011-02-09 中国石油化工股份有限公司上海石油化工研究院 热稳定性的层状复合载体
CN101491776B (zh) * 2008-01-23 2010-12-01 中国石油化工股份有限公司 氧化铝涂层浆料及其制备方法
US7901640B2 (en) * 2008-05-13 2011-03-08 Uop Llc Optimized counter-current flow baffle
US7906081B2 (en) * 2008-05-13 2011-03-15 Uop Llc Internal grids for adsorbent chambers and reactors
US7718146B2 (en) * 2008-05-13 2010-05-18 Uop Llc Enhanced bed separation in a styrene monomer reactor using milled plates
FR2935103B1 (fr) * 2008-08-19 2011-02-11 Inst Francais Du Petrole Procede de preparation d'un materiau coeur-couche ayant une bonne resistance mecanique
CN102189001A (zh) * 2010-03-03 2011-09-21 中国石油化工股份有限公司 耐磨的热稳定的氧化铝涂层载体
CN102189007B (zh) * 2010-03-03 2013-01-09 中国石油化工股份有限公司 氧化铝涂层浆料及其制备方法
CN102219213B (zh) * 2010-04-15 2013-08-14 中国石油化工股份有限公司 Co混合气体选择氧化除氢气的方法
CN102463145B (zh) * 2010-11-17 2013-09-18 中国石油化工股份有限公司 用于氢气氧化催化剂涂层的浆料及其制备方法
CN102463146B (zh) * 2010-11-17 2013-12-04 中国石油化工股份有限公司 喷涂用的氧化铝浆料及其制备方法
CN102463143B (zh) * 2010-11-17 2014-03-26 中国石油化工股份有限公司 制备薄壳形催化剂的复合载体
CN102463144B (zh) * 2010-11-17 2013-09-18 中国石油化工股份有限公司 制备复合载体涂层的氧化铝浆料及其制备方法
CN102649561B (zh) * 2011-02-25 2014-07-02 中国石油化工股份有限公司 Co混合气体选择氧化除氢气的方法
US8822370B2 (en) * 2011-05-16 2014-09-02 Uop Llc Substantially non-porous substrate supported noble metal-and lanthanide-containing catalysts
US20120322650A1 (en) * 2011-06-15 2012-12-20 Uop, Llc Layered catalyst
CN103626623B (zh) * 2012-08-23 2015-05-13 中国石油天然气股份有限公司 用于生产苯乙烯的乙苯脱氢-氢气选择性氧化方法
CN103623819B (zh) * 2012-08-23 2015-08-19 中国石油天然气股份有限公司 一种用于氢气选择性氧化反应的薄壳形贵金属催化剂及其制备方法
CN112892612B (zh) * 2019-12-03 2023-01-17 中国石化集团金陵石油化工有限责任公司 一种用于烃类转化反应的催化剂
US11000832B1 (en) * 2020-03-13 2021-05-11 Uop Llc Dehydrogenation catalyst with minimized aromatic production

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4467050A (en) * 1982-07-08 1984-08-21 Energy Research Corporation Fuel cell catalyst member and method of making same
US4565898A (en) 1985-03-06 1986-01-21 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4812597A (en) 1987-09-02 1989-03-14 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4914249A (en) 1988-12-29 1990-04-03 Uop Dehydrogenation of dehydrogenatable hydrocarbons
BE1004608A3 (fr) 1990-11-16 1992-12-22 Solvay Procede pour la fabrication du chloroforme a partir de tetrachlorure de carbone, compositions catalytiques et procede pour leur obtention.
FR2713957B1 (fr) 1993-12-16 1996-02-02 Inst Francais Du Petrole Catalyseurs de déshydrogénation de paraffines C3-C20 et sa préparation.
DE69613759T2 (de) 1995-05-22 2001-10-31 Ube Industries, Ltd. Verfahren zur Herstellung von Karbonatdiester
JP3985349B2 (ja) * 1997-07-17 2007-10-03 三菱化学株式会社 スチレンの製造方法
KR100500182B1 (ko) 1997-07-17 2005-07-12 미쓰비시 가가꾸 가부시키가이샤 스티렌의 제조방법
US6177381B1 (en) 1998-11-03 2001-01-23 Uop Llc Layered catalyst composition and processes for preparing and using the composition
US6184416B1 (en) 2000-04-28 2001-02-06 Air Products And Chemicals, Inc. Lithium aluminate as a catalyst support for hydrogenation of aromatic amines

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