TW200936172A - Compositions and uses thereof - Google Patents

Abstract

A cosmetic composition comprises (a) an ester of an optionally substituted aromatic acid (for example benzoic acid) and a C12 primary alcohol and (b) an ester of an optionally substituted aromatic acid (for example benzoic acid) and a C14 primary alcohol. The esters (a) and (b) improve the emolliency of cosmetic compositions including sunscreen, antiperspirant and personal cleansing compositions. There is described an additive composition comprising esters (a) and (b) in substantial proportion, which can be mixed with other components to produce the cosmetic composition.

Description

200936172 VI. Description of the invention:

C invention belongs to the technical section J 5 Ο 10 15 The present invention relates to the use of aromatic esters of Cu and CM fatty alcohols (e.g., benzoate) for use in cosmetic compositions, and for inclusion in blends. Its additive composition. US 4,275,222 describes the benzoate of the C!2, Cn, CiACi 5-alcoholic tear compound and its use as a diluent, solvent, plasticizer and liquid carrier, especially in cleaning or cosmetic products, dyes Use in raw materials or fabrics. It has been determined that a particular ester consisting essentially or substantially in combination with a group injury in a mixture as described in U. BRIEF DESCRIPTION OF THE INVENTION According to a first aspect of the present invention, an additive composition is provided to enhance a makeup composition. The additive composition comprises (4) an ester of an optionally substituted aromatic acid and a Cl2 primary alcohol. The dopants of (3) the optionally substituted aromatic acid and the C14 primary alcohol, wherein the compounds (8) and (b) together provide at least 60 wt% of the additive composition. A preferred series (4) is an optionally substituted custonic acid and a branched Ci2-terriol vinegar. A preferred vinegar (b) is an optionally substituted benzoic acid and a branched C14 primary alcohol. 20 200936172 Preferred esters (a) or (b) have the following formula

(I) wherein Q is a substituent, as will be defined hereinafter; m is 〇 or an integer from 1 to 5 (Q groups may be the same or not 5 when they are 42, 3, 4 or 5) And the ruler thereof is a C12 alkyl group in the compound (a) or a C14 group in the compound (8). 8 曰 (a) or (b) of the stupid ring (or other aromatic ring system) can be substituted to 5 groups (except for the acid group C 〇 〇 H of the reaction). For example, it may be tri- or di-substituted or preferably monosubstituted in the ring (or ring system). Substituents may be in the ortho, and/or in between, and/or in the opposite position. The benzene ring (or other aromatic ring) of the ester (a) is substituted, and the benzene ring (or other aromatic ring system) of the vinegar (b) is unsubstituted; or the benzoquinone of the ester (or other aromatic ring) The system) is substituted, and the benzene ring (or other aromatic ring) of the ester (a) is unsubstituted; or both are substituted, different or the same; or more preferably, unsubstituted. 15 Substituents or each substituent of the benzene ring of vinegar (a) or (b) (or other aromatic ring system) may be any of the general groups used for the substitution of a benzene ring (or other aromatic ring system), For example, at least one of the following: an alkyl group (other than a particularly preferred substituent), an alkenyl group, a mono-alkyl group, an alkynyl group, a nitrile group, a monocarboxylic acid (except the reactive tick acid group), a monoester , monoether, monoalkoxy, monofunctional alkoxy, 20-hydroxyl, monohydroxy, monothiol, monoalkylthiol, monoalkylsulfonyl, monosulfonyl, An aryl group, a monoarylalkyl group, a monosubstituted or unsubstituted amine group or a nitro group. Among such substituents, a monoalkyl group including a group containing an alkane 4 200936172 group (e.g., an alkoxy group or a halogen alkyl group) is suitably a Ci_4 danyl group, more preferably a methyl group. However, if it has been 'better for mother, a bad (or other aromatic ring system) is unsubstituted (i.e., m is 0). 5 ❹ 10 15 Ο The primary alcohol chain of each of the esters (a) and (b) may be branched at one or more positions of the chain of the primary alcohol. Preferably, however, each chain frame is linear. The primary alcohol chain of each of the esters (a) and (b) may be unsaturated or it may be saturated. Preferably, the esters (a) and (b) in the first aspect of the invention together provide at least 70% by weight of the additive composition, more preferably at least 80% by weight, more preferably at least 90% by weight, most preferably at least 95wt%. More preferably, it provides at least 98% by weight of the additive composition. In a particularly preferred embodiment, the additive composition consists essentially of esters (a) and (b). Preferably, in the additive composition of the first aspect of the invention, the weight ratio of ester (a) to vinegar (b) is at least 1:1. Preferably, the ester (a) is present in an amount exceeding the amount of the ester (b). More preferably, the weight ratio of the ester (a) to the ester (b) is at least 1.5: more preferably at least 2:1 Torr. Preferably, in the additive composition of the first aspect of the invention, the ester ( a) The weight ratio of ester (b) is up to 5: i, preferably up to 4: i, and more preferably up to 3: 1. A particularly preferred ratio is from 2 to 2.75 parts by weight of vinegar (4) to 1 part by weight of the ester (8). It has been found that the additive composition of the present invention can produce enhanced properties when added to a cosmetic composition. These enhanced properties make this additive composition useful in cosmetic products such as skin care, topical and personal care products. These products may be in the form of creams, lotions, soaps or pastes. The additive composition of the present invention has new and unpredictable properties as a cosmetic additive. 20 200936172 ^ It is a solvent and liquid carrier for an active material which can be used not only as an emollient but also as a cosmetic in the preparation of cosmetics. The (four) compound of the first aspect or the second aspect can be made by the same type of hydrazine, and should be prepared together with other fatty alcohols and acid groups (4). A second aspect of the present invention provides a composition for use in an individual, such as for hair, skin or nails, comprising (8) an optionally substituted aromatic acid and - Q2-grade leaven vinegar and (b) one The substituted aromatic acid and a Cm-class alcohol are selected. The composition may also be referred to herein as a cosmetic composition or a topical composition or a skin-favorable composition. A cosmetic composition of the second aspect, wherein the weight ratio of vinegar (4) to vinegar (9) is defined as, for example, the additive composition of the aforementioned first aspect. However, vinegars (8) and (8) can be separately introduced into the cosmetic composition. Thus, the vinegars (4) and (b) in the additive composition form of the first aspect may be added to other components to form the composition of the second aspect of the invention, but the present invention is not as in the second aspect. The definition of a way is limited. The additional component of the composition of the second aspect of the invention may comprise a carrier or diluent or solvent; and/or - an active ingredient for cosmetics. This additional component is described later. Preferably, the esters (a) and (b) of the composition of the second aspect of the invention constitute at least 40% by weight of the total weight of the Cn-C 5 fatty alcohol-aromatic acid in the cosmetic composition. Preferably, at least 50% by weight is more preferably at least 7%, most preferably at least 90% by weight. More preferably, the cosmetic composition is substantially free of the compound (a) and (bMC^-C) 5 fatty alcohol-aromatic acid vinegar. 200936172 The composition of the second aspect of the invention is in the vinegar (8) and (9) composition. All of the aliquots and acids _ (four) at least 40 鸠 ^ constitute 5 10 15 at least 50 ·, more preferably at least 7 〇鸠, optimally at least 9 hearts, : ground, the composition is essentially absent (4) and (_ The fat alcohol and the acid two cores can impart valuable properties to the composition of the second aspect. In the secret towel _(a) and the discussion, the spider is greasy, ^ >, oily and oily has a very low Point and touch, : ^ taste, low toxicity and stable. _ and, (b) in the blend: good tactile properties, coatability, solubility in / with sunscreen, low viscosity = ( Hysteresis), low oiliness on the skin, good suspending properties (for example, and effective in wetting and dispersing colorants. This chain granule can be used as a carrier or carrier emollient for cleansing and cosmetic formulations). Or co-solvent, formula such as sunscreen cream, hair cream, hand cream, cold cream, composition before, during and after artificial and electric, nail polish, topical Use cream, cream, skin lotion and (4), other formulas. The invention (4) (4) special use as an antiperspirant, body lotion, sunscreen and personal cleansing emollients. S (8) and b) when added to the cosmetic composition, one or more or all of the following characteristics are introduced in the cosmetic composition: ease of emulsification; high refractive index; good emollient after feeling; non-greasy/pleasant Skin touch; oil-free but imparts good emollient properties; 20 200936172 low turbidity point and pour point; high expansion factor; alcohol solubility; low toxicity; 5 hydrolytic stability; and used in many skin and hair additives including sunscreen The esters (a) and (b) have properties other than those mentioned above when used as an emollient in sunscreens. In this respect, it has been found that when the ester mixture is incorporated, the sunscreen is used as a An emollient that 'increases the sun protection factor ("SPF") of 10 agents in these sunscreen compositions. In this manner, in a sunscreen composition containing vinegar (&) and (b) , the sun protection effect obtained by it is not It is attributed solely to sunscreens but also to the esters. Therefore, sunscreens with lower sun protection factors can utilize sunscreen compositions containing esters (4) and (b) to achieve a sun protection factor for higher protective sunscreens. 15 For the best results, esters (a) and (b) should be added to a composition when it is substantially pure and substantially free of aromatic acids and other esters of fatty alcohols. In this way, the most reliable Good results. However, this should not preclude the use of other fatty acid esters or fatty acids in such compositions, conveniently within the aforementioned percentage limits, since the use of esters (a) and (b) still provides their incorporation. 20 Enhancement Results of Cosmetic Compositions. The esters (a) and (b) may be added to the cosmetic composition as an emollient to impart advantageous properties to the aforementioned compositions of the present invention. Stuffing (4) and (8), either separately or together, in the form of a first aspect additive composition, which can be used as a topical or cosmetic composition not only as a skin-filling agent but also as a diluent, 200936172 solvent and liquid carrier Ingredients, the cosmetic composition includes skin, nails, lips, and hair top compositions. As a solvent, the esters (a) and (b) can be used as an effective solubilizing agent for the cosmetic active agents used in these cosmetic compositions. 5 Ο 10 15 酯 In accordance with the present invention, the esters (a) and (b) are suitably incorporated into the cosmetic composition in an amount effective as an emollient. In this manner, the esters (a) and (b) are provided in an amount sufficient to provide at least an emollient property of the cosmetic composition. An emollient is an acceptable composition on the skin and is intended to lubricate the skin, to increase the softness and suppleness of the skin, to prevent or alleviate the skin and/or to protect the skin from drying. These emollients are basically water-dispersible, oily or blister materials, and in order to provide improved results of the present invention, the esters (a) and (b) are used in an amount sufficient to impart emollientness or improvement to the cosmetic composition. It is to a certain extent. The amounts of vinegar (a) and (b) in these cosmetic compositions depend on the form and amount of the other ingredients used and the amount and form of the functional additive utilized. Typically, the amounts of the esters (a) and (b) incorporated into such cosmetic compositions range from about 0.1% by weight to about 3% by weight, such as from about 0.3% by weight to about 20%, based on the total weight of the cosmetic composition. Between wt%, preferably from about 5 wt% to about 15 wt% of the total weight of the cosmetic composition. A second aspect of the present invention provides a method for preparing a cosmetic composition, wherein the esters (a) and (b) are formed separately or together with the first aspect additive composition, and can be mixed with other components, so that it can be produced. A composition of the second aspect of the invention. The esters (4) and (b) can be utilized to produce the advantageous properties described in any of the conventional topical cosmetic compositions such as sunscreen creams, hair creams, hand creams, lipsticks, skin lotions and creams, and other formulations. Cosmetic Composition 20 200936172 祠 includes cosmetic, personal cleansing and skin care compositions, and includes hair and nail compositions which can be topically applied to the human body to obtain a beneficial effect on the applied surface. δ 曰 (a) and (b) are advantageous in that they are non-oily, odorless, inert, substantially non-toxic and non-insensitive, and one or more of them are stable. It can be used as one or more of an emollient, a solubilizer, a moisturizer, a plasticizer, a sunscreen carrier/solvent, a degreaser/degreasing agent, and an emulsifier/co-emulsifier. The esters (a) and (b) have unusual property-chemical properties, in particular, their excellent expansion factor makes them an advantageous and unique component system in complex delivery systems, such as for one hand, face, and Body creams, lotions, soaps and creams. Further, S (8) and (b) may be a solvent and/or a carrier of a solid organic ultraviolet (uv) absorbent. It is used as a plasticizer for the polymer contained in the skin care composition, and can be used as an auxiliary suspending agent for assisting the suspension of the ingredients in the skin care composition, and can also be used as a dye leveling agent and/or Dye carrier. 15 Thus, when esters (a) and (b) are used in skin care (or other cosmetic) compositions, they are not only used as an emollient but also as a carrier; and they may also exhibit such other functions. According to the present invention, the cosmetic composition which can be enhanced by the addition of the esters (a) and (b) can be any conventional active material for cosmetics, which provides medical care or a cosmetic effect on the human body, especially Leather f, lips, hair or armor. The cosmetic composition may be in the form of a cream, lotion, cream, spray, soap, cream, or the like, which contains an active material for cosmetics. According to the present invention, the active material of the cosmetic composition may include an anti-aging component, an anti-wrinkle agent, a mineral, a preservative antioxidant, a moisturizer, a vitamin, a sunscreen, an anti-acne agent, a deodorant for 200936172, an antiperspirant, and the like. The preferred active materials for cosmetics are vitamins such as vitamin A, Β, Β2, Β3, β5, B6, B丨2, biotin, vitamin C, vitamin D, vitamin E, folic acid and vitamin K. Other preferred cosmetic active ingredients which can be used in the cosmetic compositions of the present invention include anti-antidote agents, anti-acne agents, humectants such as vitamins, mineral oils and diisopropyl adipates. The right cosmetic composition is in liquid form which may comprise a liquid aqueous carrier medium for the cosmetic composition. The liquid aqueous carrier medium can be water or it can be a liquid emulsion of oil in water or oil in water. According to the present invention, any water-compatible cosmetic acceptable carrier can be combined with water to form an aqueous carrier medium for the second component system. The aqueous carrier medium can contain at least oil damage. The oil component can be any pharmaceutically or cosmetically acceptable oily material which is insoluble in water. Such materials can be found, for example, in the CTFA International Dictionary of Cosmeetic 15 Ingredients and the U.S. Pharmacopoeia or other equivalent sources. Suitable oil components include, but are not limited to, natural oils such as coconut oil; hydrocarbons such as mineral oils and hydrogenated isobutylene; sterol derivatives such as lanolin; animal waxes such as bee stings; plant waxes such as standard paste; minerals such as minerals Wax (〇z〇kerite); petroleum wax, such as paraffin; synthetic wax, such as polyethylene; and mixtures thereof. If the cosmetic composition is in a solid form, such as a body balm, soap or soap, it typically contains a solid carrier medium in the cosmetic composition. Any conventional solid carrier medium for formulating such a solid cosmetic composition can be used in accordance with the present invention. The second aspect of the cosmetic composition may comprise additional stabilizing ingredients including a plurality of antioxidants, stabilizers, humectants, preservatives, and emulsifiers, 11 200936172, as mentioned in the month. Any conventional antioxidant, humectant, stabilizer, preservative, or emulsifier which is stable in the carrier medium may be present. In the second aspect of the cosmetic composition, it is possible to add a known conventional cosmetic additive, adjuvant and carrier substrate. Emulsifiers such as glycerol 5 stearic acid or decyl sesquisulphate may also be present. Organic solvents may also be present, such as lower aliphatic alcohols from 1 to 61⁄4 atoms, such as ethanol, isopropanol or propanol, or monoalcohols such as glycerol or 1,2-propanediol. The following ingredients may also be included in the final cosmetic mi product: sesame oil; opacifying agents such as ethylene glycol distearate; wetting or emulsifying agents; antibacterial and antifungal ingredients; thickeners (eg bentonite); Substance 'humectant, perfume or perfume; sesame oil; colorant (such as natural or synthetic direct dyes and coloring agents such as fluorescein sodium salt); sunscreen or UV agent, preservatives; antioxidants (such as fermented yeast); Strontium citrate; complexing agent; and also physiologically tolerable organic or organic acids, such as phosphoric acid, acetic acid, formic acid, hexamic acid, lactic acid, tartaric acid or citric acid; alkali; salt (such as sodium carbonate); buffer ( Such as sodium citrate or sodium phosphate; consistency additives; and natural, modified, partially or fully synthesized polymers (such as chitin, FMOC chitin and PVP). Of course, one skilled in the art will recognize a variety of additional © adjuvants and carrier materials to achieve the desired formulation of the topical cosmetic preparations of the present invention. However, in accordance with a preferred aspect of the present invention, the cosmetic compositions are free of 2% non-ester fatty esters of fatty alcohol esters of (a) and (b); or if such additional esters are preferred The aforementioned limited amount exists. According to a fourth aspect of the invention, it is possible to use (a) an optionally substituted aromatic acid and an ester of a C12-alcohol and (b) an ester of an optionally substituted aromatic acid with a ~C14 primary alcohol. Provides a method of treating individual skin or hair. 12 200936172 5 Ο 10 15 20 According to a fifth aspect of the invention, there is provided an (a)-selectively substituted aromatic acid and a C12-for any purpose or for obtaining any of the advantages of the invention. An ester of an alcohol and (b) an ester of an optionally substituted aromatic acid and a mono-alcohol; and especially one or more of not only improved sunscreen properties, improved moisturizing properties, and improved emollient properties . Preferred features of the first and second aspects are also preferred features of the third, fourth or fifth aspect. L Embodiment 3 The present invention is further illustrated by the following examples. In an embodiment, the additive mixture A is a benzoic acid g-mixed mixture of C12 and C14 fatty alcohols sold under the trade name "C12-C丨4 Midcut Fatty Alcohol," by Procter and Gamble, Inc., at about 1 mole. Esterification is obtained. Under the standard esterification conditions, the pure mixture of the alcohol particularly contains about 70 wt% of η-dodecaol and 3 〇wt% of 2n-tetradecyl alcohol, and] benzoic acid (ie, unsubstituted). The resulting product has an acid value of less than 0.1 mg KOH/g and is filtered by a Whitman 4 filter paper p叩α No. 4). - an odorless liquid having a freezing point of -12 C, a refractive index of i 485 〇 and a specific gravity of 0.930. In the examples, the chemical names of the trade names or common names described in the examples are illustrated in the following list: 13 200936172 Identification of the commodity or common name of the prepared ingredients

Trade name or common name identification source Finsolv SUN Phenylethyl alcohol indole ester Innospec Performance Chemicals Aminol HCA Cocoamine aglycone PEG/PPG-20/30 Innospec Performance Chemicals Finsolv SLB-101 Hydrophilic alkoxylated benzene Formate Innospec Performance Chemicals Finsolv SLB-201 Ingredi PEG-8 Benzoate Innospec Performance Chemicals Finsolv TN C12-C15 Alkyl Benzoate Innospec Performance Chemicals Finester EH 25 C12-C15 Alkyl Caprylate Innospec Performance Chemicals Finsolv PL-62 Poloxamer 182 Dibenzoic acid g Innospec Performance Chemicals Finester DOM-R Dioctyl maleate Innospec Performance Chemicals Finsolv EMG.20 Indenoglucose-20 Benzoate Innospec Performance Chemicals Finsolv PL- 355 Poloxamer 105 Panoate Innospec Performance Chemicals Finsolv BCO-115 Castor Oil Benzoate Innospec Performance Chemicals Finsolv BCR-111 Restorative Castor Oil Sour Acid Innospec Performance Chemicals Finsolv BOHS-111 Ethylhexyl Hydroxyl Stearate benzoate Innospec Performance Chemicals Crothix PEG-150 Pentaerythritol Tetrastearate Innospec Performance Chemicals Tauranol 178C Sodium Cocoyl Sodium Isethionate Innospec Performance Chemicals Tauranol WS (cone) Sodium Cocoyl Sodium Taurate Innospec Performance Chemicals Surfine-AZI-A Nonylphenol polyether-10carboxylic acid Innospec Performance Chemicals Natrlfine 137-T Samantic benzoate, Titanium dioxide Innospec Performance Chemicals Solulan 16 Lauryl polyether-16, cetethene-16, oleyl alcohol- 16 and Stearyl Polyether-16 Chemron Corp. Drakeol 9 Light Mineral Oil Panorco Hystrene 9718 Ethylenediamine Stearate Witco Corporation Hampine Na 4 Tetraacetate Sodium Salt Hampshire Chemical Corp. Polyglycol E400 Polyethylene Glycol 400 DVC Limited Inc Sodium Stearate C7 Sodium Stearate Witco Corporation Dow Coming Fluid 344 Cyclodecyl Hydrate Dow Corning Fluid 200 矽 Dow Corning Carbopol ETD 2001 Resin BF Goodrich Brii 78 Stearyl -20 ICI 200936172 Triclosan Igason DP 300 Ciba Geigy Dow Corning Fluid 345 Cyclodecylester Dow Corning Adol 62 Stearyl Alcohol '~~— Witco Corporation Castor Wax MP70 Hydrogenated Castor Oil Cas Chem.(NJ) Reach AZP908 Ming Zirconium-Glycine Reheis Inc. Cerium Oxide Cabosil M- 5 ~~ Cabot Corp Germaben II Diazoalkylimidazolium - ISP(NJ) Escalol 567 Dibenzophenone-3 ISP Escalol 587 Octyloxy cinnamic acid ISP Parsol MCX Octyloxy cinnamate Roche Vitamins Witconol 2314 Isopropyl myristate Witco Corporation Witconol 2316 Isopropyl palmitate Witco Corporation 5 TX Finsolv SB Isostearic acid benzoate Innospec Performance Chemicals Finsolv PG22 Dipropylene glycol dibenzoate Innospec Performance Chemicals Finsolv BOD octyldodecyl benzoate Innospec Performance Chemicals Example 1 Solubility of sunscreen in esters (25 ° C) The two most commonly used solid organic crystalline sunscreens are 2-hydroxy 4-methoxydi 5 Benzophenone (called benzophenone-3) and Parsol 1789 (butyl-methoxydiphenylmethylmethane). These two sunscreens are also difficult to dissolve and remain in solution for the sunscreen formulation of the desired SPF (sun protection factor). Expectation of sunscreen activity 较高 Higher solvency because it allows for a higher concentration of sunscreen active ingredients in the formulation. This facilitates an increase in the SPF rating of the formulation. As can be seen from the above table, the addition of 10 doses of Mixture A outperforms the general and commercial cosmetic emollients/materials in the amount dissolved. 15 200936172 Solubility of sunscreen in additive mixture A (%) Solubility in Finsolv TN (%) Solubility in Finester EH-25 (%) Solubility in Finsolv BOD (%) Benzophenone-3 17 15 11 10 Parsol 1789 18 13 10 9 The high solubility of the additive mixture A for solid crystalline organic sunscreens has a beneficial effect in formulating sunscreen products for the skin care market. - 5 Thus, in addition to the foregoing as a cosmetic emollient, the ester mixture is an excellent solvent for the aforementioned organic sunscreen agents. A further advantage of the additive mixture A is to provide a water-repellent effect. This utility is very attractive for formulating long-acting sunscreen products that allow sunscreens to remain on the skin for extended periods of time. 10 Example 2 Solubility and Compatibility of Additive Mixture A The solubility characteristics of Additive Mixture A are listed below. The ester mixture is soluble in most of the solvents, emollients and carriers commonly used in cosmetic product formulations. θ 15 16 200936172

Water - Ethanol + Isopropanol + Mineral Oil - Glycerol - Propylene Glycol - Dioxanol Copolyol (Silwet 7604 & 7230) + Dow Corning Fluid 244 - Dow Corning Fluid 200 - Isopropyl myristate + isopropyl hexadeta vinegar + Finsolv SLB101 + Finsolv SLN 201 + Finsolv PL 62 + Finsolv PL 355 + Finsolv BCO 115 + Finsolv BCR 111 + Finsolv BOHS 111 + Finsolv TN + Finsolv TPP + Finsolv EMG 20 + Finsolv BOD + Finsolv SB + Finsolv PG22 + Finester EH 25 + Finester DOM-R + Symbol: + indicates that the temperature is soluble at ambient temperature: - indicates that the temperature is insoluble at ambient temperature 5 Example 3 Soap The evaluation of the use of additive mixture A and Finsolv TN in the fertility evaluation is carried out as described later in 17 200936172. The results show that the properties of the soap are improved when the additive mixture A is included. Prepare soap containing synthetic detergent base 96.143-1 (Syndet base 96.143-1), and prepare a complex functional soap (25% synthetic detergent base 96 and 5 75% Bradford soap base 80/20), each containing 1% Finsolv TN. The basic processing, i.e., the formulation, is added to the mixer, the perfume is incorporated and the soap is colored and refined as usual. This soap has the following characteristics during processing and after washing with the soap: Good in the extruder. 10 has a uniform body. The average subject organization. When using soap to wash hands with water, it has a mild cream to the beads, which are small but not dense bubbles. After drying, a soft feeling of no viscous, shiny or shiny can be observed. 15 Corresponding soap is prepared by replacing 1% with 1% additive mixture a

Finsolv TN. It was found that the soap containing the additive mixture A was preferably carried out in an extruder, having a uniform body better than the control soap containing Finsolv TN, having a transparent or jewel effect and a preferred host structure. The soap containing the additive mixture A 20 produces a dense bubble when the water is washed, and a smooth feel is observed when the soap is wet. After drying, there is no stickiness on the skin. A pleasant satin-like touch with a shiny and lustrous color is observed and the skin feels very moist. Example 4 Transparent Complex Soap 18 200936172 A transparent complex soap was prepared in the amounts indicated in the table using the following ingredients in weight percent: AB Glycerin 21.18 21.18 Sorbitol 70% 23.58 23.58 Triethanolamine 163 163 Finsolv TN 12 - Additive Mixture A - 12 Surfine AZI-A 15 15 edta-na 1.2 1.2 Vaporized sodium 3 3 Water 46.92 46.92 Coco fatty acid 25.5 25.5 Stearic acid 25.5 25.5 Sodium stearate 9 9 Soap base 80/20 239.92 239.92 Tauranol I 78 C 30.1 30.1

The procedure is to sequentially add the glycerin to water components of the table and heat to 60 ° C with mixing. Then add the coconut fatty acid and stearic acid and mix. Heat to 7 ° C and allow the components to dissolve. Sodium stearate and soap base are then added and mixed. When it becomes clear, add Tauranol I 7 8. Mix and freeze the whole week to get a clear liquid. It is poured out from the mixing device and formed into a rod shape. The resulting clear composite soap containing the additive mixture A provides better clarity and fenestration than the soap containing no additive mixture A but containing Finsolv TN. Example 5 ...Annoles and body lotions are formulated with the following ingredients in the amounts indicated in the table. 19 200936172 ABCD I. Water 75.75 75.75 75.75 75.75 Carbomer 0.15 0.15 0.15 0.15 Sorbitol 70% 2 2 2 2 Four nano EDTA 0.2 0.2 0.2 0.2 II. Isopropyl myristate 6.5 isopropyl hexadecane ester - 6.5 - - Additive mixture A 6.5 - - - Finsolv TN - - - 6.5 Whale wax Alcohol 0.7 0.7 0.7 0.7 Stearic acid 1.5 1.5 1.5 1.5 Glyceryl stearate SE 0.8 0.8 0.8 0.8 Cetearyl alcohol and stearyl ether-20 (Ceteareth - 20) 1 1 1 1 Octylmethoxy cassia Octyl metoxy cinnamate 7 7 7 7 Octyl salicylate 3 3 3 3 Dibenzophenone-3 3 3 3 3 III. Triethanolamine 99% 0.9 0.9 0.9 0.9 Glydant 0.2 0.2 0.2 0.2

The procedure for blending hands and body lotions is as follows: Disperse carbomer in water. Heat to 70 ° C, add sorbitol and EDTA. Add all Part II ingredients together and heat to 70 °C. Add part of the 5 II ingredients to the well-mixed I ingredients. Triethanolamine was added and mixing continued. Glydant was added and mixing continued while allowing to cool to room temperature. Pour out and collect. Evaluate each product. The amount of sample used was 0.5 cc with a syringe. Each product evaluates the following traits and ranks on a scale of 1 to 5, with 1 being the best and 10 5 being the worst. Each product is timed from the time of application to the final tactile sensation, and it is determined that it will absorb the time of 200936172. This product is applied to the forearm and into the skin with four fingers on the other hand. The previous arm was washed with warm water and wiped dry before evaluating other samples. This step and the method of evaluation are also used in other embodiments of the present specification relating to sunscreens, skin creams and the like. 5 The results are as follows. A B C D Skin touch 1 3 4 2 Nourishment 2 4 3 2 Smoothness 1 5 4 2 Viscosity 1 4 3 3 Moisturizing effect 1 4 5 2

Example 6 Waterproof sunscreen lotion Waterproof sunscreen lotion 10 was prepared from the ingredients listed in the table below and the amounts indicated in the table. ABCD I. Deionized water 72.75 72.75 72.75 72.75 Hydroxypropyl cellulose (1% solution) 10 10 10 10 Quaternium 15 0.15 0.15 0.15 0.15 disodium EDTA 0.05 0.05 0.05 0.05 II. Octylmethoxycinnamate 7 7 7 7 Octyl salicylic acid vinegar 3 3 3 3 Benzene _ (Oxybenzone) 2 2 2 2 Additive mixture A 4 - - - Isopropyl myristate - 4 - isopropyl hexadecanoic acid S - 4 - Finsolv TN - - - 4 Carbopo 1954 0.25 0.25 0.25 0.25 Pamulen TR-1 0.2 0.2 0.2 0.2 p-benzoic acid methyl ester 0.05 0.05 0.05 0.05 p-propyl benzoate 0.15 0.15 0.15 0.15 III. triethanolamine 99% 0.4 0.4 0.4 0.4 21 200936172 The procedure for preparing this emulsion is as follows: 1. Prepare the secondary-mixture I by mixing until homogeneous. 2. Mix the four components before the second-mixture II in a separate container and stir until the hydroxybenzone is dissolved. 5 3. Add the remaining ingredients of the secondary-mixture II with mixing. 4. Add the secondary-mixture II to the secondary-mixture I with vigorous stirring and continue mixing for 40 minutes until smooth. 5. Add component III and stir vigorously until smooth. 6. Pour out and recycle. 10 Prepare Formula A-D to test skin feel, emollient, smoothness, viscosity, water wash resistance and moisturizing effect. The results are as follows. A B C D Skin touch 2 4 4 3 Emolliency 2 5 4 3 Smoothness 2 4 3 4 Viscosity 2 4 5 3 Wash resistance 2 4 3 3 Moisturizing effect 1 3 4 2

Example 7 15 High SPF sunscreen lotion (cold process) High S PF sunscreen lotion (cold process) was prepared from the following ingredients in the amounts indicated in the table: 22 200936172 ABCD I. Abil WE_09 5 5 5 5 Cyclodecyl ester 3 3 3 3 Additive A 8 - - - Isopropyl myristate - 8 - isopropyl hexadecanoic acid S - 8 - Finsolv TN - - - 8 Abil Wax W9801 1 1 1 1 Octyloxy cinnamic acid Ester 3 3 3 3 Octyl salicylate 3 3 3 3 Dibenzophenone-3 2 2 2 2 II. Water 68.4 68.4 68.4 68.4 Hydroxyethylcellulose (Natrosoll 250 HHR CS) 0.8 0.8 0.8 0.8 Sodium gasification 0.8 0.8 0.8 0.8 Natlfine TP-T 5 5 5 5

A high SPF sunscreen lotion was prepared from the following ingredients and indicated amounts. 1. Combine the ingredients of the second-mixture I. Mixed enough. 5 2. Dissolve hydroxyethylcellulose in the vortex of the vigorously stirred aqueous phase. The cellulose is allowed to completely hydrolyze before the addition of the gasified sodium. Add Natrlfine TP-T. Mix until uniform.

3. Slowly add the secondary-mixture 11 to the secondary-mixture I in slow agitation. 10 4. Mix until homogeneous. Formula A-D was prepared in accordance with this to test skin feel, emollient, smoothness, viscosity, water wash resistance and moisturizing effect. The results are as follows. 23 200936172 ABCD Skin Touch 1 3 4 2 Emolliency 2 4 3 3 Smoothness 1 3 3 2 Wash Resistance 1 3 3 2 Moisturizing Effect 2 4 4 3 Example 8 High SPF Sunscreen Lotion 5 From the following ingredients in the table Formulated high SPF sunscreen lotion (cold)

ABCD I. Abil WE 09 (polyglycerol-4-isostearate cetylpyrene copolyol hexyl hexate) 5 5 5 5 cyclomethacrylate 3 3 3 3 additive mixture A 8 - - - isopropyl Tetradecane-8 - isopropyl hexadecanate - 8 - Finsolv TN - - - 8 Abil Wax W9801 (Cetylmethyst) 1 1 1 1 Octyloxy cinnamate 3 3 3 3 Octyl salicylate 3 3 3 3 benzophenone-3 2 2 2 2 II. Water 68.4 68.4 68.4 68.4 Hydroxyethyl cellulose (Natrosol 250 HHR CS) 0.8 0.8 0.8 0.8 Gasification nano 0.8 0.8 0.8 0.8 Natrlfine 137 T 5 5 5 5

A high SPF sunscreen lotion was prepared from the above ingredients in the following sections. 1. Combine the ingredients of the second-mixture I. Mixed enough. 10 2· Dissolve hydroxyethylcellulose in the vortex of the vigorously stirred aqueous phase. The cellulose is allowed to completely hydrolyze before the addition of the gasified sodium. Add Natrlfine 24 200936172 137-T. Mix until uniform. 3. Slowly add the secondary mixture II to the secondary-mixture I with slow agitation. 4. Mix until homogeneous. Formula A-D was prepared in accordance with this to test skin feel, emollient, smoothness, viscosity, water wash resistance and moisturizing effect. The results are as follows. ABCD Skin Touch 1 3 4 2 Emolliency 1 4 3 2 Smoothness 1 3 3 2 Wash Resistance 1 3 3 2 Moisturizing Effect 2 4 4 3 ❹ Example 9 10 Sunscreen Cream is indicated by the following ingredients in the table below Amount of high sunscreen lotion: ABCD I. Water 67.7 67.7 67.7 67.7 Magnesium silicate S-1.5 1.5 1.5 1.5 Propylene glycol 3 3 3 3 Diethanolamine 0.6 0.6 0.6 0.6 11. -- Benzophenone-3 5 5 5 5 Change: Additive Mixture A 7.5 . Isopropyl myristate S _ 7.5 _ liter of propyl hexadecanoate F F? · Γ--------- 7.5 _ Finsolv TN 7.5 Mineral oil 4 4 4 4 爹脂酸 2.2 2.2 2.2 2.2 Glyceryl stearate ~ 0.5 0.5 0.5 0.5 Whale oxalate - 0.5 0.5 0.5 0.5 g decyl cinnamate ~~~ 7.5 7.5 7.5 7.5 25 200936172 By the following steps from the above ingredients Prepare a sunscreen lotion. 1. Heat the water to 80 °C. Magnesium aluminum citrate was slowly added with stirring and mixed until smooth. 2. Add the remaining ingredients to the secondary-mixture I and mix until smooth, while maintaining the temperature. 3. Heat the secondary-mixture II to 75 ° C and add to the secondary-mixture I. · 4. Mix until cooled to 45 ° C, pour out and collect. Formula A-D was prepared in accordance with this to test skin feel, emollient, smoothness, viscosity, water wash resistance and moisturizing effect. The results are as follows. Ο A B C D Skin touch 2 4 5 3 Emolliency 1 3 4 2 Smoothness 1 3 4 2 Viscosity 1 3 3 2 Moisturizing effect 1 3 2 2 Wash resistance 1 3 4 2

EXAMPLE 10 Moisturizing Cleansing Lotion A moisturizing cleansing lotion is prepared from the following ingredients in the amounts indicated in the table: 26 200936172 AB c D I. Water 80.4 80.4 80.4 80.4 Fizul MD 318 C (oily amine MIPA-sulfosuccinic acid II Sodium) 1 1 1 1 Glycerol 3 3 3 3 Carbopol ETD 2001 Resin 0.2 0.2 0.2 0.2 Tetra-Delta EDTA 0.1 0.1 0.1 0.1 II. Additive Mixture A 6.5 Isopropyl myristate - 6.5 - - Isopropyl hexadelate - - 6.5 - Finsolv TN - - - 6.5 Caprylic/capric triglyceride 1 1 1 1 Stearic acid 3 3 3 3 Glyceryl stearate SE 2 2 2 2 III. Water 1 1 1 1 Triolamine 99% 0.8 0.8 0.8 0.8 IV. Germaben 1 1 1 1 Prepare a moisturizing cleansing lotion from the above ingredients via the following procedure: Disperse the carbomer in water. The remainder of the sub-mixture I component was added 5 and heated to 75 °C. The sub-mixture II ingredients were mixed together and heated to 〇 75 °C. The secondary-mixture II is added to the secondary-mixture I with mixing. The sub-mixture III component is mixed, then added to the sub-mixture I/II and cooling begins. At 40 ° C, the ingredients were added and cooled to 30 ° C. Formula A-D was prepared in accordance with this to test skin feel, smoothness, and emollient properties. The result is as follows. ABCD Skin Touch 1 4 3 2 Smoothness 1 3 3 2 Emolliency 2 4 4 3 27 200936172 Example 11 Hand and Body Lotion Hand and body lotions are prepared from the following ingredients in the amounts indicated in the table: ABCD I. Water 85.75 85.75 85.75 85.75 UltrizlO 0.15 0.15 0.15 0.15 Sorbitol 75% 2 2 2 2 Tetrasodium EDTA 0.2 0.2 0.2 0.2 II. Additive Mixture A 6.5 Isopropyl myristate - 6.5 - - Isopropyl ten Hexaic acid S - - - - Finsolv TN - - - 6.5 cetyl alcohol 0.7 0.7 0.7 0.7 stearic acid 1.5 1.5 1.5 1.5 glyceryl stearate SE 0.8 0.8 0.8 0.8 cetyl alcohol & stearyl ether 20 1 1 1 1 III. Triethanolamine 99% 0.9 0.9 0.9 0.9 Germaben II 0.3 0.3 0.3 0.3 5 A hand and body lotion was prepared from the aforementioned ingredients by the following procedure: The carbomer was dispersed in water. Heat to 70 ° C. Add sorbitol and tetrasodium EDTA. The sub-mixture II ingredients were weighed together and heated to 75 °C. The secondary-mixture II is added to the secondary-mixture I with mixing. Triethanolamine was added and mixing continued until the temperature dropped to 45 °C. Add preservatives. 10 Formulation A-D was prepared in accordance with this to test skin feel, smoothness and emollient properties. ABCD Skin Touch 1 4 4 2 Smoothness 1 4 3 2 Emolliency 1 3 3 2 28 200936172 Example 12 Light body lotion A light body lotion is prepared from the following ingredients in the amounts indicated in the table: ABCD I. Additive Mixture A 5 _ _ _ Isopropyl myristate - 5 - isopropyl hexadecanoic acid S - - 5 - Finsolv TN - - - 5 Sesame oil 4.4 4.4 4.4 4.4 Mineral oil 4 4 4 4 Glycerol monostearate 1 1 1 1 Stearic acid 2.4 2.4 2.4 2.4 Fourteen brewed lactic acid S 1 1 1 1 propyl p-benzoate 0.2 0.2 0.2 0.2 II. Water 74.95 74.95 74.95 74.95 Glycerol 4.5 4.5 4.5 4.5 Triethanolamine 99% 1.1 1.1 1.1 1.1 mercapto-p-benzoate 0.15 0.15 0.15 0.15

5 A light body lotion was prepared from the aforementioned ingredients by the following procedure: The ingredients of the sub-mixture I were mixed and heated to 65 °C. Mix the sub-mixture ® II ingredients and heat to 70 °C. The sub-mixture I was added to the secondary-mixture II with mixing and the temperature was maintained at 70 °C. Mix for 15 minutes. Cool to 25 ° C with mixing. 10 Formulation A-D was prepared in accordance with this to test skin feel, smoothness and emollient properties. The results are as follows. ABCD Skin Touch 1 4 4 2 Smoothness 1 5 3 2 Emolliency 1 3 4 3 29 200936172 Example 13 Non-Whitening Antiperspirant Cream Non-whitening antiperspirant cream is prepared from the following ingredients in the amounts indicated in the table: ABCD I Cyclodecyl ester 39 39 39 39 Stearyl alcohol 18 18 18 18 Hydrogenated castor oil 5 5 5 - Additive mixture A 5 - - - Isopropyl myristate - 5 - - Isopropyl hexadelate - 5 - Finsolv TN - - - 5 Finsolv 116 10 10 10 10 II. Tetrahydrate hydroxyaluminum zirconium-glycine 20 20 20 20 Talc 2 2 2 2 Cerium oxide 1 1 1 1 5 Prepare non-prepared from the above ingredients via the following procedure Whitening antiperspirant cream. 1. Combine the ingredients of the second-mixture I and heat to 75 ° C with mixing. 2. Add the secondary-mixture II powder. Mix for 15 minutes or until completely dispersed. Maintained at 75 ° C. 3. Cool to 55 ° C and mold into a paste. 10 Each product was evaluated by applying an antiperspirant cream to the arm at a constant application pressure to ensure uniform application. After the evaluation, the tested product was washed by the arm and the arm was patted dry. Do not perform the next test until the arm is completely dry. Using a rating of 1 to 5, 1 is the best and 5 is the worst. This procedure and method of evaluation are also used in the examples of other antiperspirant creams and body balms in this specification, unless otherwise specified. Formula A-D was prepared to test skin feel, smoothness, emollient, and paste 30 200936172 structure and viscosity. The results are as follows. ABCD Skin touch 1 4 3 2 i Slip 1 4 3 2 Ridge structure 1 3 3 2 Emolliency 2 5 4 3 Hysteresis 2\ 4 5 3 Implement your 丨 w 艘 5 bottles of balm from the following ingredients in the table Labeled balm: ABCD Propylene glycol 71 71 71 71 Water 14 14 14 14 Additive mixture A 3 - - - Isopropyl myristate - 3 - Isopropyl palmitate - 3 - Pinsolv TN - - - 3 Sodium stearate 5 5 5 5 Digas sand 0.2 0.2 0.2 0.2 Pentadecylphenol polyether-200 6.6 6.5 6.5 6.5 Diethanolamine 99% 0.3 0.3 0.3 0.3 The procedure is as follows. Feed all ingredients in a suitable container. Heat to 8 ° C and mix to allow all ingredients to dissolve. Cooling mirror. c and mold in a rod-like 10 mold. Formulation A_D was prepared for skin feel, smoothness, cream structure, emollient and viscous testing. The results are as follows. 31 200936172 ABCD Sense 1 4 3 2 Smooth jT*·' —----- 1 1 3 3 2 Paste structure 1 3 3 2 2 5 4 3 Viscosity 2 ——*' 4 5 3 iSiL_is Spray body fragrance Dance j The spray fragrance is prepared from the following ingredients in the amounts indicated in the table: __________ ABCD % S stone 36.5 36.5 36.5 36.5 SD alcohol 35.2 35.2 35.2 35.2 Water 2.7 2.7 2.7 2.7 Three gas sand 0.2 0.2 0.2 0.2 Additive mixture A 9 - - - Isopropyl myristate - 9 - - Isopropyl palmitate - 9 - Finsolv TN - - _ 9 1,3-butanediol 1 1 1 1 PPG-3 tetradecanoate Ether 15.5 15.5 15.5 15.5 A spray deodorant is prepared from the above ingredients via the following procedure: Combination of alcohol, water and digass. Mixed enough. Add the remaining ingredients while mixing. Formulations A-D were prepared for skin feel, smoothness, dryness, emollient and viscous testing. 32 200936172 A B C D Skin touch 1 4 3 2 Smoothness 2 3 4 3 Dryness 1 3 3 2 Emolliency 2 4 4 3 Viscosity 1 3 4 2 Example 16 Antiperspirant cream

The antiperspirant cream is prepared from the following ingredients in the amounts indicated in the table: ABCD I. Stearic acid glycerin 6 6 6 6 Propylene glycol 1 1 1 1 Additive mixture A 4 - - - Isopropyl myristate - 4 - - Propyl hexadecanate - 4 - Finsolv TN - - - 4 II. Magnesium citrate 1 1 1 1 Aluminum hydride 50% solution 40 40 40 40 Water 48 48 48 48 Antiperspirant is prepared from the aforementioned ingredients via the following procedure Cream: 1. Disperse sodium magnesium citrate in water and heat to 70 °C. 2. Blend and heat the oil phase to 70 °C. 3. Add the secondary-mixture I to the secondary-mixture II by mixing. 4. Cool the cream to 50 ° C and add aluminum hydride. 5. Mix for 30 minutes and pack. Formulations A-D were prepared for skin feel, smoothness, dryness, emollient and viscous testing as previously described for cream preparation. The results are as follows. 33 10 200936172 ABCD Skin touch 1 4 4 2 Smoothness 1 3 3 2 Dryness 1 3 4 2 Emolliency 1 4 3 2 Viscosity 2 4 4 3 Example 17 2 in 1 moisturizing lotion (opaque Cream type)

5 Prepare 2 in 1 moisturizing lotion (opaque cream type) from the following ingredients in the amounts indicated in the table:

AB c D I. Water 53.4 53.4 53.4 53.4 Propylene glycol 1.5 1.5 1.5 1.5 Magnesium citrate 0.25 0.25 0.25 0.25 Yellow gum 0.25 0.25 0.25 0.25 II. Ammonium laurate (28%) 22 22 22 22 Ammonium sulphate (25) 10 10 10 10 Shul WLL (Surfine WLL) 2 2 2 2 Gasification Na 0.5 0.5 0.5 0.5 Tetra-Deta EDTA 0.2 0.2 0.2 0.2 Cetyltrimethylammonium hydride (30%) 0.8 0.8 0.8 0.8 III. Amine Merlot HCA (Aminol HCA) 4 4 4 4 Additive Mixture A 2 - - - Isopropyl myristate - 2 - isopropyl hexadecanate - 2 - Finsolv TN - - - 2 Cetyl alcohol 0.5 0.5 0.5 0.5 Stearic acid alcohol 0.5 0.5 0.5 0.5 Stearic acid ethylene glycol 2 2 2 2 IV. DMDM Hydante 0.1 0.1 0.1 0.1 34 200936172 The shampoo is prepared from the above ingredients by the following procedure: 1. Mixing the gum with propylene glycol Wet. 2. Add the tree and propylene glycol to the water and mix well to disperse. The mixture was heated to 65 ° C when dispersed. 3. Add the sub-mixture π component at 65 ° C and mix before mixing the next one. 4. Add the sub-mixture III components together, heat to 65 ° C, and mix until all melted. 5. Add the rest of the formula and mix well to achieve uniformity. Continue mixing 10 while cooling. 6. Add ingredient W at 45 °C. Cool to 35. (:, pour out and collect. Table A compares the properties of shampoos of Formulations A-D. Table B compares the foamy scars of Formulation AD shampoos in Standard Foam Test 4. Table c compares formulations a 'B, C And the shampoo effect of D. Table A (The nature of shampoo A, BC and D) Shampoo preparation appearance PH Viscosity (cPs at 25 ° C) A Creamy flowable liquid 6.1 3200 B Creamy Flowable liquid 6.1 2800 C Creamy flowable liquid 6.1 2650 D Creamy flowable liquid 6.1 3000 35 200936172

Table B Formulations of Formulations A, B, C, and D for 2 in 1 Run Shampoo. Shampoo Preparation Foam initial volume (ml) Volume after 5 minutes Volume (ml) Foam characteristics A 350 330 Thick and dense foam. There is no air in the bubble. Soft touch. B 300 270 Thin, loose, dispersed, light foam. Not dense. No soft touch. C 300 260 Thin, loose, dispersed, lightly colored beads. Not dense. No soft touch. D 320 300 Thin dense foam. There is little air in the bubble. Slightly sticky touch. Procedure: 5 1% of the product was dissolved in 200 ml of water and vibrated 10 times in a graduated cylinder.

Table C compares the effect of Formulations A, B, C, and D of 2 in 1 Run Shamp on Hair Hair 10 . A B C D Dry comb 2 5 4 3 Wet comb 2 4 4 3 Knot 2 3 4 3 Brightness/gloss 3 4 4 4 Soft touch/handling 2 4 5 3

All measurements are on a scale of 1 to 10, with 1 being the best and 10 being the worst. Step: Moist hair hair under the faucet for 15 seconds. Moist hair 15 Hair is treated with shampoo. Shampoo for 5 minutes. Move the hair and rinse with faucet water 36 200936172 for 15 seconds. The air is dry. Wet and dry comb tests were performed and the knotted quality was evaluated. Evaluate shine/gloss and dry touch/handling. Example 18 Clearing Shampoo 5 A clear conditioner shampoo was prepared from the following ingredients in the amounts indicated in the table: ABCD Water 51.2 51.2 51.2 51.2 Sodium lauryl ether 25% 28.0 28.0 28.0 28.0 Tauranol WS (cone) 15.0 15.0 15.0 15.0 Amiele HCA 4.0 4.0 4.0 4.0 Additive Mixture A 1.0 - - - Isopropyl myristate S - 1.0 - - Isopropyl palmitate - - - 1.0 - Finsolv TN - - - 1.0 Crothix 0.3 0.3 0.3 0.3 DMDM intramethylene urea 0.2 0.2 0.2 0.2

A clear conditioner shampoo was prepared from the above ingredients via the following procedure: Water was added and heated to 75 °C. All ingredients were added in sequence except DMDM 乙 carbendazim. Mix well. Cool to 45 ° C and add DMDM carbendazim. 10 Cool to room temperature. Table A compares the properties of shampoos prepared in Formulations A, B, C, and D.

Table A Table A Formulations A, B, C and D have clear hair shampoo properties. Shampoo Properties Appearance Clearness Viscosity (cPs, 250C) A Clear Gel Clear 12000 B Clear Gel Clear 9000 C Clear Gel Clear 8500 D Clear Gel Clear 10000 37 200936172

Table B Foam results for clear hair shampoos prepared in Formulations A, B, C and D (using the method of Example 17). Shampoo Formula Foam Initial Volume (ml) After 5 minutes Volume (ml) Foam Characteristics A 350 300 Thick and stable foam dense body. There is no gap between the bubbles. B 300 200 Thin, loose foam, dispersed. Disappeared quickly. There is a gap between the bubbles. C 300 210 Thin, loose foam, dispersed. Disappeared quickly. There is a gap between the bubbles. D 340 310 Thin, loose, dispersed, light foam. There is a gap between the bubbles. ❹ 5 The effect of shampoos of Formulations A, B, C and D on hair hair was compared (using the method described in Example 17).

Table C Table C compares the effects of clear hair shampoos of Formulations A, B, C and D ABCD Dry Comb 3 5 5 4 Wet Comb 3 6 4 4 Knot 2 5 3 4 Shine / Gloss 2 4 3 4 Soft Touch / Handling 3 3 3 4

10 EXAMPLE 19 Shower and Shower Gel The shower and shower gel were prepared from the following ingredients in the amounts indicated on the table: 38 200936172

ABCD I. Water 48.0 48.0 48.0 48.0 1,3 Butanediol 4.0 4.0 4.0 4.0 Four EDTA 0.1 0.1 0.1 0.1 DL Panthenol 0.5 0.5 0.5 0.5 Sodium lauryl ether 20.0 20.0 20.0 20.0 Amino MCA 5.0 5.0 5.0 5.0 Fizul MD 318C 4.0 4.0 4.0 4.0 Surfine AZI-A 2.0 2.0 2.0 2.0 Additive Mixture A 2.0 - - - Isopropyl myristate - 2.0 - - Isopropyl hexaderate - 2.0 - Finsolv TN - - - 2.0 II. Crothix 1.0 1.0 1.0 1.0 Sucrose-cocoate 1.0 1.0 1.0 1.0 III. DMDM carbendazim 55% 0.4 0.4 0.4 0.4 citric acid 25% to pH 6.2 QS QS QS QS

The shower and shower gel were prepared from the aforementioned ingredients via the following procedure. The water was heated to 50 ° C and all of the sub-mixtures I mentioned were added in 5 portions, and mixed well with each other. The temperature was raised to 70 ° C and the sub-mixture 11 ingredients were added to allow each to mix well. Cool to 45 ° C and add DMDM carbendazim. Cool to below 35 ° C and adjust the pH with citric acid. Pour out when warm. Table A compares the properties of the shower and shower gels prepared in Formulations A, B, C and D. 39 200936172

Table A Properties of Showers and Shower Gels for Formulations A, B, C and D Shower and Bath Gel Appearance Clearness Viscosity (cPs at 25°C) A Clear Gel Clear 7500 B Clear Lean Gel Clear 5200 C Clear Clear gel 5080

Table B5 Shower and bathing foam results prepared by Formulations A, B, C and D (using the method of Example 17). Shower and shower gel formula Initial foam volume (ml) 5 minutes After volume (ml) Foam characteristics A 360 300 Thick and stable foam Compact body. There is no gap between the bubbles. B 300 210 Thin bubble. Disperse the foam. There is a gap between the bubbles. C 300 200 Thin bubble. Disperse bubble swimming. There is a gap between the bubbles. D 340 270 Thin bubble. Disperse bubble swimming. There is a gap between the bubbles. Example 20 10 Foaming Cleansing Cream A foaming cleansing cream was prepared from the following ingredients in the amounts indicated in the table: 40 200936172 ABCD I. Tauranol I-78(C) 20 20 20 20 Additive Mixture A 2 - - - Isopropyl 14 Acid ester - 2 - isopropyl hexadecanoic acid - 2 - Finsolv TN - . - - 2 1,3 butanediol 1 1 1 1 Water 70 70 70 70 II. Tetraic acid 3 3 3 3 Whale wax Alcohol 2 2 2 2 Glyceryl stearate 2 2 2 2 ❹ Prepare a foaming cleansing cream from the above ingredients in the stated amounts by the following procedure: -5 ❹ 10 Combinations - Mixture I components and heat to 75 ° C With gentle agitation until a homogeneous system is formed. Avoid aeration, mix the components of the secondary-mixture II separately and heat to 60 °C with mixing. The secondary-mixture II was added slowly to the vortex of the second-mixture I until it was below 40 °C. The resulting product achieves viscosity and pearl luster within hours. Table A compares the properties of the cleansing creams of Formulations A, B, C and D. Foam Cleansing Cream Appearance Viscosity (cPs at 25°C) A Cream 6000 B Cream 4800 C Cream 4500 D Cream 5400

Table B Foam results for Foaming Cleansing Cream (tested as described above in Example 17). Preparation of Formulations A, B, C and D. 41 200936172 Formulation Initial volume of beads (10)) Volume after 5 minutes (ml) Foam characteristics A 250 200 Thick and stable foam dense body. There is no gap between the bubbles. B 220 180 Thin, loose, and scattered. Disappeared quickly. There is a gap between the bubbles. C 220 170 Thin, loose, and dispersed. Disappeared quickly. There is a gap between the bubbles. D 230 190 Thin, loose foam, dispersed. Disappeared quickly. There is a gap between the bubbles. General Notes for the full text In this specification, included in the examples, the percentage values presented are based on the total weight (wt/wt) of the composition unless otherwise specified. 5 [Illustration of Simple Jade] (None) [Explanation of main component symbols] (none)

42

Claims (1)

200936172 VII. Patent application scope: 1. An additive composition capable of promoting a cosmetic composition comprising (8) an optionally substituted aromatic acid and a C12 primary alcohol vinegar 5 10 15 Ο 20 and (8) selectable A substitution of a substituted aromatic acid and a C14 primary alcohol vinegar wherein the compounds (8) and (8) together provide at least 60% by weight of the additive composition. 2- The composition of claim i, wherein the alternative acid in the vinegar (8) and in the (b) b) is a phenyl substituted benzoic acid. • For example, please refer to the vinegar of the first or second patent, in which the aromatic acid in the _) and in the vinegar (b) is unsubstituted. 4. The additive composition of any of the preceding claims, wherein the weight ratio of the vinegar $(4) to the _) is between 5:1 and ι:ι. For example, apply for the additive composition of item 4, where the ratio is between 15:1 and 3:1.如. The additive composition of any of the preceding claims, wherein _ (8) and (b) together constitute at least (10) hunger % of the ageing product. The additive composition of claim 6 wherein the composition is substantially composed of esters (a) and (b). A flank of personal care ribs comprising (8) optionally aromatic aromatic and -C12-series (d) and (b) optionally substituted aromatic acids and C14 primary alcohols. 7 The composition of the special item, in which the substance and the aromatic which can be optionally substituted in the day (b) _ optionally substituted benzene 43 200936172 acid bismuth). As claimed in the scope of the 8th or 9th a composition in which the weight ratio of the vinegar (4) to the vinegar (8) in the cosmetic composition is between 5: i and 丄:! Between the scope. 11. The composition of claim 8, wherein the combined weight of the vinegar (8) and (b) is between 5% and the range of the total weight of the composition.如. The composition of the first application of the scope of the patent application comprises a carrier or diluent or agent; and/or a cosmetic active ingredient, for example selected from the group consisting of sunscreens, deodorants, antiperspirants and individuals detergent. The composition of any one of claims 8 to 12 wherein the vinegar (8) and (b) function as an emollient and is the only emollient in the composition. Agent. 15 20 Φ The composition according to any one of claims 8 to 13, wherein the vinegars (4) and (9) constitute a Cl2_Ci5 fatty alcohol in the contact; at least 4% by weight of the aromatic acid, more preferably At least 5, more preferably at least 20,000 wt%, most preferably at least 9 wt%, and preferably all. 15. The composition of any of the items 8 to 14 of the patent application, wherein the 16 (a) and (b) constitute at least 40 wt% of the fatty alcohol and the acid in the composition, preferably It is at least 5 Torr, more preferably ≤ wt%, most preferably at least 9 〇 wt%, and preferably all. 11. The composition of any of the items 8 to 15 of the patent application, wherein ^(a) and (b) are supplied in the form of a composition of the first to seventh embodiments of the patent application. 44 200936172 ^ 17. A method of preparing a cosmetic composition according to any one of claims 8 to 16, which is a blend of the compounds (a) and (b) with other ingredients. A method of treating personal skin or hair using (a) an ester of a 5th generation aromatic acid with a C12-alcohol and (b) an ester of an optionally substituted aromatic 'aromatic acid and a C14 primary alcohol 19. An (8) ester of an optionally substituted aromatic acid with a C12-alcohol and (b) an optionally substituted aromatic acid and an ester of a C14 primary alcohol, which is used to provide improved sun protection, One of 10 or more improved moisturizing properties and improved emollient properties. 45 200936172 IV. Designated representative map: (1) The representative representative of the case is: ( ). (None) (2) A brief description of the symbol of the representative figure: 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: