US1591369A - Photomechanical printing surface and process - Google Patents
Photomechanical printing surface and process Download PDFInfo
- Publication number
- US1591369A US1591369A US20251A US2025125A US1591369A US 1591369 A US1591369 A US 1591369A US 20251 A US20251 A US 20251A US 2025125 A US2025125 A US 2025125A US 1591369 A US1591369 A US 1591369A
- Authority
- US
- United States
- Prior art keywords
- coating
- solution
- printing
- acid
- plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007639 printing Methods 0.000 title description 10
- 238000000034 method Methods 0.000 title description 7
- 239000011248 coating agent Substances 0.000 description 22
- 238000000576 coating method Methods 0.000 description 22
- 239000002253 acid Substances 0.000 description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 230000007935 neutral effect Effects 0.000 description 6
- 238000007645 offset printing Methods 0.000 description 6
- 108010068370 Glutens Proteins 0.000 description 5
- 239000005018 casein Substances 0.000 description 5
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 5
- 235000021240 caseins Nutrition 0.000 description 5
- 235000021312 gluten Nutrition 0.000 description 5
- 210000004276 hyalin Anatomy 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 102000009123 Fibrin Human genes 0.000 description 4
- 108010073385 Fibrin Proteins 0.000 description 4
- BWGVNKXGVNDBDI-UHFFFAOYSA-N Fibrin monomer Chemical compound CNC(=O)CNC(=O)CN BWGVNKXGVNDBDI-UHFFFAOYSA-N 0.000 description 4
- 101710094902 Legumin Proteins 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- NEKNNCABDXGBEN-UHFFFAOYSA-L disodium;4-(4-chloro-2-methylphenoxy)butanoate;4-(2,4-dichlorophenoxy)butanoate Chemical compound [Na+].[Na+].CC1=CC(Cl)=CC=C1OCCCC([O-])=O.[O-]C(=O)CCCOC1=CC=C(Cl)C=C1Cl NEKNNCABDXGBEN-UHFFFAOYSA-L 0.000 description 4
- 229950003499 fibrin Drugs 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 235000018102 proteins Nutrition 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108010076119 Caseins Proteins 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920002160 Celluloid Polymers 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 241001237728 Precis Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- -1 glyceryl alcohol Chemical compound 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007775 late Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/04—Chromates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/908—Impression retention layer, e.g. print matrix, sound record
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
- Y10T428/31685—Natural source polyamide [e.g., casein, gelatin, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31768—Natural source-type polyamide [e.g., casein, gelatin, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31826—Of natural rubber
Definitions
- he principal object of the invention is to remedy the defects above described and to make photo-mechanical off-set printing a success, so that it may be possible to print satisfactorily without half-tone blocks, electros and stereos.
- the object of this invention is achieved by the present improvements which are the result of research, in-. vestigation and experiment in connection with the problem above stated. Others have failed to achieve this object for the reason that they have not paid attention or have paid insufiicient'attention, to the chemical, physical or electro-chemical action above described. It was well-known in practice that aluminium sheets had the drawback that the metal became bare. when in use on the off-set machine, the lines or dots appearing to become brittle and breaking away so that the shadows opened up unduly.
- lactic casein, legumin, gluten or fibrin obtained as a highly purified precipitate which is dissolved in a suitable acid or acid solution, the product being a hyaline gelatinous neutral solution which is made use of in the production of printing surfaces, as hereinafter explained.
- the chemical physical and electro-chemical actions of the rubber sheet are prevented by a coating of a thin solution of prepared casein, legumin, gluten or fibrin with an addition of ingredients or reagents the said coating resulting in a stratum which is leather-like and permeable to liquids.
- the said solution is employed also in the preparation of the plates, as will appear from the following practical examples.
- the first example is that of the preparation of a printing plate by coating a sufliciently grained sheet of copper, zinc, aluminium, celluloid or other suitable material.
- lactic casein, legumin, gluten or fibrin is treated and purified of fat and albumen and finally recipitated by oxyglutaric acid (C H,(OHO).
- C H,(OHO) oxyglutaric acid
- Any one of these pure precipitates is then dissolved at a low temperature in aaminoglutaric acid OO,H.GH NIL) CH,CH,GO,H)
- the fine etching can then be carried out as in the half tone process and to such a depth as is comparable with that of the ordinary relief process block.
- the etched plate is now cleaned and gummed up on the margins and other nonprinting parts, and rolled up with ink and the gum washed off, and the plate is ready for use.
- the second example is that of the coating of plate of polished copper, zinc, or aluminium.
- the coating is performed with the solution described in the first example and the etching is performed in the same manner.
- the plate After cleaning, the plate is grained on the margin and non-printing parts. The margin and non-printing parts are now gummed up, and the whole plate is rolled up with suitable ink, leaving the plate ready for use on press or machine.
- the plates roduced according to the foregoing examp es are suitable-for three colour work in the off-set process and are adapted for giving great depth of colour and sharp definition in printing.
- the third examp e is that of coating a rubber off-set sheet.
- the casein or like solution, prepared as described in the first example is mixed in the proportion of 5 to 1 with a 20% solution of liquefied gluten or serecin, a 10% solution of formaldehyde being added in the proportion of 1 to 10,-and propenyl alcohol being added in the proportion of 1 to 50.
- the stratum rinting object is fixed,
- a surface coating for use in off-set printing said coating being obtained by the application to the surface of a hyalinegelatinous neutral solution of a protein.
- a surface coating for use in off-set printing said coating eing obtained by the application to the surface of a hyaline gelatinous neutral solution of a protein, the latter being employed in the form of a highly pure preci itate which is dissolved in the presence 0 an acid.
- a surface coating for use in off-set printing said coating being obtained by the application to the surface of a hyaline gelatinous neutral solution of a protein, the latter being employed in the form of a highl pure roduct obtained by precipitation wit oxy utaric acid which productis dissolved in t e presence of an acid.
- a surface coating for use in ofi-set printing said coating being obtained by the app ication to the surface of a hyaline elatinous neutral solution of a rotein, the atter being employed in the orm of a highly pure pro not obtained by precipitation which product is dissolved at a low temperature in a-aminoglutaric acid and dilute ammonia.
- a surface coating for use in off-set printing said coating being obtained by the application to the surface of a mixture of a 20% solution of serecin and a hyaline gelatinous neutral solution of a protein, the latter being employed in the form of a highly pure product obtained by precipitation which product is dissolved in the presence of an acid.
- a surface coating for use in off-set printing said coating being obtained by the resulting from this coating is leatherlike' application to the surface of a mixture of a of an acid.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Peptides Or Proteins (AREA)
- Printing Plates And Materials Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8561/24A GB236621A (en) | 1924-04-04 | 1924-04-04 | Improvements in or relating to photo-mechanical printing surfaces and processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1591369A true US1591369A (en) | 1926-07-06 |
Family
ID=9854827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US20251A Expired - Lifetime US1591369A (en) | 1924-04-04 | 1925-04-02 | Photomechanical printing surface and process |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US1591369A (fr) |
| FR (1) | FR596238A (fr) |
| GB (1) | GB236621A (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2532866A (en) * | 1944-10-21 | 1950-12-05 | Toland William Craig | Method and plate for lithographic printing |
-
1924
- 1924-04-04 GB GB8561/24A patent/GB236621A/en not_active Expired
-
1925
- 1925-04-02 US US20251A patent/US1591369A/en not_active Expired - Lifetime
- 1925-04-03 FR FR596238D patent/FR596238A/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2532866A (en) * | 1944-10-21 | 1950-12-05 | Toland William Craig | Method and plate for lithographic printing |
Also Published As
| Publication number | Publication date |
|---|---|
| GB236621A (en) | 1925-07-06 |
| FR596238A (fr) | 1925-10-19 |
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