US2732302A - Silver halide emulsion containing mo- - Google Patents
Silver halide emulsion containing mo- Download PDFInfo
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- US2732302A US2732302A US2732302DA US2732302A US 2732302 A US2732302 A US 2732302A US 2732302D A US2732302D A US 2732302DA US 2732302 A US2732302 A US 2732302A
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- United States
- Prior art keywords
- silver halide
- emulsion
- fog
- emulsions
- halide emulsion
- Prior art date
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- 239000000839 emulsion Substances 0.000 title claims description 58
- 229910052709 silver Inorganic materials 0.000 title claims description 25
- 239000004332 silver Substances 0.000 title claims description 25
- -1 Silver halide Chemical class 0.000 title claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 16
- 150000001409 amidines Chemical class 0.000 claims description 5
- 229960003671 mercuric iodide Drugs 0.000 description 15
- YFDLHELOZYVNJE-UHFFFAOYSA-L mercury diiodide Chemical compound I[Hg]I YFDLHELOZYVNJE-UHFFFAOYSA-L 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 238000000576 coating method Methods 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 230000035945 sensitivity Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- RAFASWMEVZEDPH-UHFFFAOYSA-N N,N-diphenylmethanimidamide hydroiodide Chemical compound I.C1(=CC=CC=C1)N(C=N)C1=CC=CC=C1 RAFASWMEVZEDPH-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 150000004820 halides Chemical class 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 229940100892 mercury compound Drugs 0.000 description 5
- 150000002731 mercury compounds Chemical class 0.000 description 5
- RURGSYHSEQUYJK-UHFFFAOYSA-N I.C1(=CC=CC=C1)C(C(=N)N)C1=CC=CC=C1 Chemical compound I.C1(=CC=CC=C1)C(C(=N)N)C1=CC=CC=C1 RURGSYHSEQUYJK-UHFFFAOYSA-N 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 4
- 238000011534 incubation Methods 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- QNJJGSUPQRTOEQ-UHFFFAOYSA-N I.C1(=CC=CC=C1)N=C(N(C1=CC=CC=C1)C1=CC=CC=C1)N Chemical compound I.C1(=CC=CC=C1)N=C(N(C1=CC=CC=C1)C1=CC=CC=C1)N QNJJGSUPQRTOEQ-UHFFFAOYSA-N 0.000 description 3
- 230000029087 digestion Effects 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical class [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- RQPALADHFYHEHK-JKMUOGBPSA-N (1s,2r,5r)-5-(6-aminopurin-9-yl)cyclopent-3-ene-1,2-diol Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1C=C[C@@H](O)[C@H]1O RQPALADHFYHEHK-JKMUOGBPSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000909 amidinium group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000000586 desensitisation Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/09—Noble metals or mercury; Salts or compounds thereof; Sulfur, selenium or tellurium, or compounds thereof, e.g. for chemical sensitising
Definitions
- This invention relates to fog-inhibiting agents and stabilizers for photographic emulsions and to photographic emulsions containing them.
- Photographic fog is of two types: local and general. Local fog is formed by exposure of the film or plate at undesired points as by a light leak in the camera. General fog is formed in a number of ways. It may be caused by the conditions of high temperature or humidity or unusually long time of storage. The nature of the emulsion may also produce chemical fog as well as the conditions of development of the emulsion as by development for protracted periods of'time or at temperatures above normal. We are primarily concerned with fog and sensitivity changes in photographic films produced by storage under adverse conditions of temperature and humidity or for prolonged periods of time before exposure and development.
- General fog and loss of sensitivity of the emulsion are especially likely to occur when the sensitive material is stored under conditions other than ideal, that is, under conditions of high temperature and humidity, as in tropical regions.
- a further object is to provide anti-fogging agents which stabilize the initial sensitivity of the emulsion.
- a still further object is to provide anti-fogging agents which improved the keeping of the emulsion in tropical regions.
- the principal purpose of our invention is to provide a means for maintaining the sensitivity and fog of silver halide emulsions at or close to initial optimum values under keeping conditions of high temperature and humidity.
- the fog inhibitors which we propose to use are added to the emulsion at any stage during the process of manufacture prior to coating the emulsion to avoid loss of sensitivity and to inhibit the growth of incubation or keeping fog with passage of time under non-ideal conditions of storage.
- the mercury fog inhibitor may be added to the emulsion in solution in any convenient solvent not injurious to the emulsion such as water, lower alcohols and ketones.
- a solution of the mercuric compound which we employ when added in suitable concentration before coating to unsensitized or optically sensitized silver halide emulsions does not appreciably affect the sensitometric values for sensitivity and fog when measurements are made soon after coating.
- sensitometric measure- 2,732,302 Patented Jan. 24, 1956 ments are made after appreciable intervals of time under tropical or dry conditions of storage at elevated temperatures, these compounds do stabilize photographic speed and maintain fog at a low level.
- CH C N :v-(Diphenylacetamidine hydriodide) mercuric iodide
- the preparation of silver halide emulsions involves three separate operations: (1) the emulsification and digestion or ripening of the silver halide, (2) the freeing of the emulsion from aqueous soluble salts usually by washing, (3) the second digestion or after-ripening to obtain increased sensitivity (Mees, The Theory of the Photographic Process, 1942, page 3).
- the fog inhibiting agents may be added at any stage, e. g., after the final digestion.
- the mercury compounds are useful generally in photographic silver halide developing out emulsions. They may be used in emulsions chemically sensitized with sulfur'compounds, reducing agents such as stannous salts or polyarnines, or noble metals such as gold, palladium or platinum or by various combinations of these.
- the most useful concentration of fog inhibitor is from about 0.05 to 2.0 mg. of fog inhibitor per mole of silver halide in the emulsion. Although higher amounts may be used, it is generally undesirable to use more than five times this upper limit since desensitization of the emulsion may result.
- the antifoggant and stabilizing action was determined by incubation of the emulsions for one Week at F.-
- Example A fast negative gelatino-silver halide emulsion was used for incorporation of the mercury compounds, in each case the mercury compound being incorporated in the emulsion in the amount in milligrams per mole of silver halide in the emulsion as indicated in the following table.
- Samples of the emulsion with and without the mercury compound were exposed for ,4 second in an intensity scale sensitometcr and developed for 5 minutes in a developer of the following composition:
- Samples of each of the coatings were stored for 7 days in an atmosphere of 42% relative humidity at 120 F. and were then exposed and developed in the same way.
- the fog-inhibitors of our invention may be incorporated in a colloid layer such as a gelatin layer on one or both sides of the support or they may be incorporated in a processing bath such as a developer or pre-bath.
- the fog-inhibiting agents which we have described may be used in various kinds of photographic emulsions. In addition to being useful in ordinary non-sensitized emulsions they may also be used in orthochromatic, panchromatic and X-ray emulsions. If used with sensitizing dyes, they may be added to the emulsion before or after the dyes are added.
- Various silver salts may be used as the sensitive salt, such as silver bromide, silver iodide, silver chloride and mixtures of these.
- the mercury compounds may be used in emulsions intended for color photography, for example, emulsions containing color-forming couplers, or emulsions to be developed by solutions containing couplers.
- the dispersing agents may be gelatin or other colloid such as collodion, albumen, cellulose derivatives or synthetic resins.
- a light-sensitive silver halide emulsion containing a small amount of a molecular addition compound of a mercuric halide with an amidine hydrohalide 1.
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- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
United States Patent SILVER HALIDE EMULSION CONTAINING MO- LECULAR COMPOUNDS OF MERCURY SALTS WITH AMIDINES Edward B. Knott and John Morgan, Harrow, England, assignors to Eastman Kodak Company, Rochester, N. Y., a corporation of New Jersey No Drawing. Application November 8, 1952, Serial No. 319,600
11 Claims. (Cl. 95-7) This invention relates to fog-inhibiting agents and stabilizers for photographic emulsions and to photographic emulsions containing them.
It is known that photographic emulsions, particularly ultra-sensitive emulsions or those containing optical sensitizers exhibit a tendency to form a deposit of silver in the emulsion upon development. This deposit extends more or less uniformly over the entire emulsion and is known as fog. Photographic fog is of two types: local and general. Local fog is formed by exposure of the film or plate at undesired points as by a light leak in the camera. General fog is formed in a number of ways. It may be caused by the conditions of high temperature or humidity or unusually long time of storage. The nature of the emulsion may also produce chemical fog as well as the conditions of development of the emulsion as by development for protracted periods of'time or at temperatures above normal. We are primarily concerned with fog and sensitivity changes in photographic films produced by storage under adverse conditions of temperature and humidity or for prolonged periods of time before exposure and development.
General fog and loss of sensitivity of the emulsion are especially likely to occur when the sensitive material is stored under conditions other than ideal, that is, under conditions of high temperature and humidity, as in tropical regions.
It is an object of the invention to provide novel antifogging or fog-inhibiting compounds for emulsions. A further object is to provide anti-fogging agents which stabilize the initial sensitivity of the emulsion. A still further object is to provide anti-fogging agents which improved the keeping of the emulsion in tropical regions. Other objects will appear from the following description of our invention.
These objects are accomplished by incorporating in a silver halide emulsion a molecular compound of a mercury saltwith an amidine or amidinium salt.
The principal purpose of our invention is to provide a means for maintaining the sensitivity and fog of silver halide emulsions at or close to initial optimum values under keeping conditions of high temperature and humidity. The fog inhibitors which we propose to use are added to the emulsion at any stage during the process of manufacture prior to coating the emulsion to avoid loss of sensitivity and to inhibit the growth of incubation or keeping fog with passage of time under non-ideal conditions of storage. The mercury fog inhibitor may be added to the emulsion in solution in any convenient solvent not injurious to the emulsion such as water, lower alcohols and ketones.
A solution of the mercuric compound which we employ when added in suitable concentration before coating to unsensitized or optically sensitized silver halide emulsions does not appreciably affect the sensitometric values for sensitivity and fog when measurements are made soon after coating. However, when sensitometric measure- 2,732,302 Patented Jan. 24, 1956 ments are made after appreciable intervals of time under tropical or dry conditions of storage at elevated temperatures, these compounds do stabilize photographic speed and maintain fog at a low level.
The following compounds may be used according to our invention:
ON=O\ -HI -HgIn a: :e-(Triphenylguanidlne hydriodide) mercuric iodide m- (Diphenylformamidine hydriodide) mercuric iodide 3.
CH C=N :v-(Diphenylacetamidine hydriodide) mercuric iodide The preparation of silver halide emulsions involves three separate operations: (1) the emulsification and digestion or ripening of the silver halide, (2) the freeing of the emulsion from aqueous soluble salts usually by washing, (3) the second digestion or after-ripening to obtain increased sensitivity (Mees, The Theory of the Photographic Process, 1942, page 3). The fog inhibiting agents may be added at any stage, e. g., after the final digestion.
The mercury compounds are useful generally in photographic silver halide developing out emulsions. They may be used in emulsions chemically sensitized with sulfur'compounds, reducing agents such as stannous salts or polyarnines, or noble metals such as gold, palladium or platinum or by various combinations of these.
The most useful concentration of fog inhibitor is from about 0.05 to 2.0 mg. of fog inhibitor per mole of silver halide in the emulsion. Although higher amounts may be used, it is generally undesirable to use more than five times this upper limit since desensitization of the emulsion may result.
The antifoggant and stabilizing action was determined by incubation of the emulsions for one Week at F.-
and 42% relative humidity. The results of aging tests are tabulated in the following example and compare fog of the emulsions initially and after incubation, for emulsions with and without the stabilizing compound.
Example A fast negative gelatino-silver halide emulsion was used for incorporation of the mercury compounds, in each case the mercury compound being incorporated in the emulsion in the amount in milligrams per mole of silver halide in the emulsion as indicated in the following table. Samples of the emulsion with and without the mercury compound were exposed for ,4 second in an intensity scale sensitometcr and developed for 5 minutes in a developer of the following composition:
Grams N-methyl p-aminophenol sulfate 2.2 Sodium sulfite, desiccated 72 Hydroquinone 8.8 Sodium carbonate, desiccated 48 Potassium bromide 4 Water to 1 liter.
Samples of each of the coatings were stored for 7 days in an atmosphere of 42% relative humidity at 120 F. and were then exposed and developed in the same way.
Fog
Compound mg./mole After Initial Incubation OHCA: (DMD The compounds which we used were prepared as follows:
Instead of incorporation in the silver halide emulsion, the fog-inhibitors of our invention may be incorporated in a colloid layer such as a gelatin layer on one or both sides of the support or they may be incorporated in a processing bath such as a developer or pre-bath.
The fog-inhibiting agents which we have described may be used in various kinds of photographic emulsions. In addition to being useful in ordinary non-sensitized emulsions they may also be used in orthochromatic, panchromatic and X-ray emulsions. If used with sensitizing dyes, they may be added to the emulsion before or after the dyes are added. Various silver salts may be used as the sensitive salt, such as silver bromide, silver iodide, silver chloride and mixtures of these. The mercury compounds may be used in emulsions intended for color photography, for example, emulsions containing color-forming couplers, or emulsions to be developed by solutions containing couplers.
The dispersing agents may be gelatin or other colloid such as collodion, albumen, cellulose derivatives or synthetic resins.
(s-Triphenylguanidine hydriodide) mercuric iodide s-Triphenylguanidine (2.85 g.), ethanol (25 cc.) and hydriodic acid S. G. 1.97 (4 cc.) were mixed to give a clear solution. Mercuric iodide (4.5 g.) was added and the whole boiled until a clear solution was obtained. This was chilled overnight and the hard aggregates (4.7 g.) collected. A further crop of (2.8 g.) was obtained on diluting the filtrate with water. From ethanol (100 cc.) it formed chrome yellow aggregates, M. P. 227-228".
(Diphenylformamidine hydriodide) mercuric iodide Diphenylformamidine (1.95 g.), ethanol cc.), hydriodic acid S. G. 1.97 (2.0 cc.) and mercuric iodide (4.5 g.) were heated together on a steam bath. A crystalline mass separated rapidly. It (5.5 g.) formed white needles, M. P. 192-195 from ethanol.
(Diphenylacetamidine hydriodide) mercuric iodide Diphenylacetamidine (2.1 g.), ethanol (10 cc.), hy-
driodic acid S. G. 1.97 (2.0 cc.) and mercuric iodide (4.5 g.) were heated on a steam bath to dissolve. On chilling overnight heavy aggregates (4.5 g.) separated. After an ethanol wash they had M. P. 123-126.
It will be understood that we contemplate as included within our invention all modifications and equivalents falling within the scope of the appended claims.
We claim;
1. A light-sensitive silver halide emulsion containing a small amount of a molecular addition compound of a mercuric halide with an amidine hydrohalide.
2. A light-sensitive silver halide emulsion containing a small amount of a molecular addition compound of a mercuric halide with triphenylguanidine hydriodide.
3. A light-sensitive silver halide emulsion containing a small amount of a molecular addition compound of a mercuric halide with diphenylformamidine hydriodide.
4. A light-sensitive silver halide emulsion containing a small amount of a molecular addition compound of a mercuric halide with diphenylacetamidine hydriodide.
5. A light-sensitive silver halide emulsion containing a small amount of triphenylguanidine hydriodide mercuric iodide.
6. A light-sensitive silver halide emulsion containing a small amount of diphenylformamidine hydriodide mercuric iodide.
7. A light-sensitive silver halide emulsion containing a small amount of diphenylacetamidine hydriodide mercuric iodide.
8. The method of reducing fog and loss of speed upon storage of a silver halide emulsion, which comprises incorporating in said emulsion at any stage prior to coating, a molecular addition compound of a mercuric halide with an amidine hydrohalide.
9. The method of reducing fog and loss of speed upon storage of a silver halide emulsion, which comprises incorporating in said emulsion at any stage prior to coating, triphenylguanidine hydriodide mercuric iodide.
10. The method of reducing fog and loss of speed upon storage of a silver halide emulsion, which comprises incorporating in said emulsion at any stage prior to coating, diphenylformamidine hydriodide mercuric iodide.
11. The method of reducing fog and loss of speed upon storage of a silver halide emulsion, which comprises incorporating in said emulsion at any stage prior to coating, diphenylacetamidine hydriodide mercuric iodide.
References Cited in the file of this patent UNITED STATES PATENTS 1,738,530 Frankenburger et al. Dec. 10, 1929 2,059,642 Kankelwitz Nov. 3, 1936 2,263,012 Schinzel Nov. 18, 1941 2,353,754 Peterson July 18, 1944 2,540,086 Baldsiefen et al. Feb. 6, 1951
Claims (1)
1. A LIGHT-SENSITIVE SILVER HALIDE EMULSION CONTAINING A SMALL AMOUNT OF A MOLECULAR ADDITION COMPOUND OF A MERCURIC WITH AN AMIDINE HYDROHALIDE.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2732302A true US2732302A (en) | 1956-01-24 |
Family
ID=3442015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US2732302D Expired - Lifetime US2732302A (en) | Silver halide emulsion containing mo- |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2732302A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1738530A (en) * | 1927-08-19 | 1929-12-10 | Agfa Ansco Corp | Preparation of photosensitive photographic emulsions |
| US2059642A (en) * | 1934-03-10 | 1936-11-03 | Kankelwitz Bruno | Process for manufacturing photographic silver halide developing emulsions durably free from grey and yellow fogging and of durable quality |
| US2263012A (en) * | 1937-12-23 | 1941-11-18 | Eastman Kodak Co | Process for making natural color photographs |
| US2353754A (en) * | 1942-11-07 | 1944-07-18 | Eastman Kodak Co | Color photography using metallic salt coupler compounds |
| US2540086A (en) * | 1948-06-17 | 1951-02-06 | Silver halibe emulsions |
-
0
- US US2732302D patent/US2732302A/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1738530A (en) * | 1927-08-19 | 1929-12-10 | Agfa Ansco Corp | Preparation of photosensitive photographic emulsions |
| US2059642A (en) * | 1934-03-10 | 1936-11-03 | Kankelwitz Bruno | Process for manufacturing photographic silver halide developing emulsions durably free from grey and yellow fogging and of durable quality |
| US2263012A (en) * | 1937-12-23 | 1941-11-18 | Eastman Kodak Co | Process for making natural color photographs |
| US2353754A (en) * | 1942-11-07 | 1944-07-18 | Eastman Kodak Co | Color photography using metallic salt coupler compounds |
| US2540086A (en) * | 1948-06-17 | 1951-02-06 | Silver halibe emulsions |
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