US3843424A

US3843424A - Normal grain growth(110)(001)textured iron-cobalt alloys

Info

Publication number: US3843424A
Application number: US00228071A
Authority: US
Inventors: D Thornburg; K Foster
Original assignee: Westinghouse Electric Corp
Current assignee: Westinghouse Electric Corp
Priority date: 1972-02-22
Filing date: 1972-02-22
Publication date: 1974-10-22
Anticipated expiration: 1991-10-22
Also published as: BE795762A; FR2173187A1; JPS4897722A; DE2307929A1; IT976647B; FR2173187B1; CA988752A; GB1420371A

Abstract

1. AN ALLOY MEMBER WHICH EXHIBITS IMPROVED PERMEABILITIIES AT LOW FIELD STRENGTHS RESULTING FROM CRYSTALLOGRAPHIC ORIENTATION COMPARED TO UNORIENTED MAGNETIC MATERIAL OF THE SAME COMPOSITION CONSISTING ESSENTIALLY OF FROM ABOUT 5% TO ABOUT 35% COBALT, UP TO 2% CHROMIUM, UP TO 1% MANGANESE, UP TO 3% SILICON, LESS THAN 0.005% SULFUR AND THE BALANCE ESSENTIALLY IRON WITH INCIDENTAL IMPURITIES, THE ALLOY HAVING A PRIMARY RECRYSTALLIZED GRAIN STRUCTURE IN WHICH A MAJOR PROPORTION OF THE GRAINS EXHIBIT A (110) TEXTURE AND IN WHICH A MAJOR PROPORTION OF THE ORIENTED GRAINS HAVE CUBE EDGES OF THEIR CRYSTAL LATTICES ALIGNED WITHIN 10* OF THE ROLLING DIRECTION.

Description

Oct. 22, 1974 Filed Feb. 22, 1972 ToRouE,ERss/ :M

D. R. THORNBURG HAL NORMAL GRAIN GROWTH (110) [001] TEXTURED IRON-COBALT ALLOYS I 4 Sheets-Sheet 1 M849 AND M853-ANNEALED I35 3%Si-Fe 48 HOURS AT 900C ORIENTED I THICKNESS PEAK SAMPLE (IN) RATIO 3/os| Fe 9o I ORIENTED M8 0342 1 M853 -o.0I2I 0.370

I M849, 0.0l 0.548 I 45 |8O I I I l 0 90 I35 I ANGLE BETWEEN FIELD AND ROLLINGIDIRECTION (DEGREES) IFIGI NORMAL GRAIN GROWTH (110) [001] TEXTUREDIRON-GOBALTALLOYS Filed Feb. 22, 1972 1974 D. R. THORNBURG 4 Sheets-Sheet 2 FIG Oct. 22, 1974 THQRNBURG EI'AL 3,843,424

NORMAL GRAIN GROWTH (110) [001] TEXTURED IRON-COBALT ALLOYS Filed Feb. 22, 1972 4 Sheets-Sheet 3 FIG.4

Oct. 22, 1974 R- THORNBURG ETAL 3,843,424

NORMAL GRAIN GROWTH (110) [001] TEXTURED IRON-COBALT ALLOYS Filed Feb. 22, 1972 4 Sheets-Sheet 4 United States Patent O1 fice 3,843,424 Patented Oct. 22, 1974 3,843,424 NORMAL GRAIN GROWTH (110) [001] TEXTURED IRON-COBALT ALLOYS Donald R. Thornburg and Karl Foster, Pittsburgh, Pa.,

assignors to Westinghouse Electric Corporation, Pittsburgh, Pa.

Filed Feb. 22, 1972, Ser. No. 228,071 Int. Cl. H01f 1/00 US. Cl. 148-120 6 Claims ABSTRACT OF THE DISCLOSURE An alloy and a method for producing the same are described in which the alloy is characterized by a primarily recrystallized microstructure having a (110) [001] orientation. The alloy contains from to 35% cobalt, up to 2% chromium, up to 3% silicon, less than 0.005% sulfur and a balance essentially iron with incidental impurities. The method includes a schedule of hot and cold working the latter in limited amounts together with corresponding heat treatments producing the desired improved magnetic characteristics.

CROSS REFERENCE TO RELATED APPLICATIONS The present application is closely related to application Ser. No. 228,319, filed Feb. 22, 1972 and application Ser. No. 228,070, filed Feb. 22, 1972 each of which application is presently pending.

BACKGROUND OF THE INVENTION [Field of The Invention The present invention relates to iron-cobalt alloys having improved magnetic characteristics and a method for producing said alloys. The alloys are characterized by having a high grain volume of (110) ][001] orientation texture, the same having been derived by means of primary recrystallization and normal grain growth.

Description of The Prior Art The operating inductions of large portions of todays transformers are limited by the saturation value of oriented silicon steel, that is, a steel containing about 3% silicon and which has a high degree of (110) [001] orientation. This saturation value is generally taken to be about 20,300 gauss. Both from an economic and a technological standpoint this is the highest quality transformer material presently available commercially. v

Cobalt functions in iron to significantly increase the saturation value of the iron, and saturation inductions on the order of 24,000 gauss are observed in cobalt-iron alloys containing 25 to 50% cobalt. The alloys containing from about 35 to 50% cobalt have a low magnetocrystalline anisotropy and the lowest values occur in the range of about 50% cobalt. Consequently, high inductions are obtained at low field strengths. It is noted however that when the cobalt content in the alloy is increased to a value ranging from more than about 35% and up to about 80% by weight, with a corresponding decrease in the iron content, the alloy undergoes atomic ordering. Consequently, high cobalt-iron alloys such as the 50% cobaltiron alloy are quite brittle and can only be cold worked after a drastic quench resulting in high production costs.

While considerable ductility is observed in alloys containing less than 35 cobalt which alloys do not undergo atomic ordering, the high induction values for low field strength have never been observed in this alloy most likely because of their high positive anisotropy values. However, the improved ductility makes the alloys containing between about 5% and about 35% cobalt quite attractive from an economic manufacturing point of view.

Heretofore, there have been commercially available alloys containing about 27% cobalt in an iron base. However, these alloys, while showing some improvement in the overall saturation induction value, nonetheless were deficient from the standpoint of having low inductions at low field strengths. Consequently, such material only found limited use where it was designed for operation at near the saturation value. While the presence of between about 5% and about 35% cobalt in an iron matrix will provide improved saturation values, by the present invention it has been found that proper processing makes it pos- .sible to develop grain orientation such that high inductions are obtained at low field strengths without adversely affecting the coercive force or of the saturation induction values. The method as applied to the alloy of the present invention is effective for producing such results which are manifest in the observed magnetic characteristics.

Summary of The Invention The present invention relates to an alloy which contains in weight percent between about 5% and about 35% cobalt, up to about 2% chromium, up to about 1% manganese, up to about 3% silicon and the balance iron with incidental impurities. A critical aspect of the invention is recognizing and controlling the sulfur content thereof to a value of less than about 0.005% and preferably less than about 0.002%.

The method for obtaining the improved magnetic characteristics in these alloy compositions includes an initial step of hot working of the metal at a temperature of between about 1000 C. and about 1100 C. to a desired intermediate gauge and thereafter a critical cold working the alloy in one or more steps to the desired final gauge and a final critical primary recrystallization anneal. While any hot working will suffice since it is not a critical point in the process, hot rolling is preferred. It has been found that in order to develop the desired magnetic characteristics, at least the last cold working operation to final gauge must effect a reduction in the cross sectional area ranging between about 40% and about and the alloy is preferably heated rapidly to the recrystallization temperature and finally subjected to a high temperature heat treatment which results in the development of a primarily recrystalliZed microstructure having a majority of the grains displaying an orientation described as [001] in Miller Indices, and the majority or a high proportion of the grains have the cube edges of their crystal lattices parallel within 10 to the direction of rolling of the sheet or strip of the alloy. The final high temperature heat treatment to which the alloy is subjected usually takes place at a temperature between about 800 C. and the A temperature of the alloy undergoing the final heat treatment. Preferabbly the final heat treatment is conducted in a protective atmosphere, such as an atmosphere of substantially pure hydrogen having a dew point of less than about 40 F.

DESCRIPTION OF THE DRAWINGS magnification of magnification of magnification of magnification of magnification of DESCRIPTION OF THE PREFERRED v EMBODIMENT Generally speaking, the present invention relates to an alloy having improved magnetic characteristics, and which has a composition containing from about to about 35% cobalt, at least one element which is effective for raising the volume resistivity such as up to about 2% chromium, and up to about 3% silicon, less than about 0.005% sulfur, up to about 1% manganese, and the balance essentially iron with incidental impurities. The alloy in its fabricated form is characterized by having a primarily recrystallized-grain structure in which a majority of the grains possess a (110) [00 1] texture.

. Within the broad chemical analysis set forth hereinbefore a preferred embodiment contains between about 8% and about 20% cobalt, from about 0.5% to about 2.0% silicon, a sulfur content of less than about 0.005% and the balance iron with incidental impurities. Another preferred composition contains cobalt within the range between about 20% and about 30%, chromium within the range between about 0.25% and about 1%, less than about 0.005% sulfur and the balance essentially iron with the normal impurities. Outstanding results have been obtained where the cobalt content is maintained within the range between about 26.5% and about 28%, from about 0.25% to about 0.75% chromium, less than about 0.002% sulfur and the balance iron with incidental impurities. This latter compositional range has improved magnetic characteristics including a high saturation value, as well as high inductions at low field strengths thereby resulting in an outstanding combination of magnetic characteristics. Excellent magnetic materials have also been obtained where the cobalt content is maintained within the range betwe n about 10% and about 18% cobalt, from about 0.5% and about 2.0% silicon, less than about 0.0025% sulfur with the balance being essentially iron with incidental impurities. While ttu's latter alloy will have greater resistivity from the standpoint of the inclusion of the silicon content and slightly lower saturation induction values, nonetheless thedegree of orientation is outstanding so as to given exceedingly high B value which is a measure indicative not only of the degree of orientation but also is indicative of the attainment of high inductions at low field strengths. Consequently, the various combina tions of magnetic characteristic obtainable in each of the ranges set forth. hereinbefore together with the simplified processing for obtaining these desirable results makes the same quite economically attractive compared with commercially available oriented 3% silicon-iron.

It is noted that the alloy of the present invention must be critically controlled with respect to the sulfur content. In this respect. it has been noted that the majority of the grains will developthe required degree of orientation provided the initial sulfur content within the melt is limited to about 0.005% maximum. As will be set forth more fully hereinafter no special desulfurizing heat treatments are performed during the manufacture of the alloy to its desired finished gauge product. Accordingly, it becomes exceedingly important and in fact critical to maintain the sulfur content at less than about .005 and preferably less than about 0.0025 Exceedingly good results have been obtained where the sulfur content has been limited to a value notin excess of about 0.002%

It will be noted that where silicon is not added as a deliberate alloying element, as for example, where the cobalt content is maintained within the range between about 20%. and about 35%., it is desirable to have the silicon content at a value of less than about 0.25%. While silicon is noted for its effect of improving volume resistivity it has been found that other elements such as chromium, vanadium, aluminum, titanium and molybdenum are more effective where the cobalt content is within the range between 20 and 35%. Consequently, the alloying silicon addition is preferred only where the cobalt is less than about 20%. Any element which is soluble and does not form a'second phase will improve volume resistivity; however care must be exercised so that the other properties are not detrimentally afiected. By the same token, it has also been found that it is preferred, although not critically necessary, to have the manganese content at a value of less than about 0.50%. Where, however, silicon is added as an alloying component, for example, in an alloy with a cobalt content of between 8% and 20% for improved resistivity, the manganese may be quite lownominally about 0.05%.

While during normal processing of the alloys into finished gauge material the alloy may be subjected to a decarburizing anneal, nonetheless it is preferred to maintain the carbon content at less than about 0.030% with a correspondingly low content of oxygen and the balance of the other incidental impurities. Typical levels of these elements may include about 0.003% oxygen, about 0.05% manganese, about 0.1% silicon and the balance essentially of iron. Such levels of incidental impurities are ob tained by vacuum induction melting; however other melting methods may be employed with equal success.

The alloy having the desired composition is subjected to a hot working operation and one or more cold working operations in order to reduce the alloy to the desired final gauge thicknessl'n this respect it has been found that good success has been obtained where the alloy in ingot form is hot worked as by rolling from a temperature within the range between about 1000 C. and about 1100" C. The material is hot worked at this temperature range to any desired'intermediate gaugethickness such as a hot rolled band gauge of between about 0.075 and about 0.150 inches. It will be appreciated that while the intermediate gauge has been set forth, deviations therefrom may be made depending on the finish gauge thickness. Thus the intermediate gauge thickness is selected with respect to the subsequent cold reductions and finish gauge thickness.

Following hot working at a temperautre within the range between l000 C. and 1100 C. the alloy is heat treated for a time period of about 10 minutes to about 60 minutes at a temuperature within the range between about 600 and 900 C. During such heat treatment it is convenient to introduce a hydrogen atmosphere such hydrogen atmosphere having a dew point of greater than about -40 F. in order to decarburize the material. It is desired in some cases to decarburize at the intermediate g auge thickness and typical annealing times of about 15 minutes at about 700 C. in a hydrogen atmosphere at approximately a +60 F. dew point is effective for removing about half of the carbon content remaining in the sample following hot working. However, it is also contemplated that such decarburizing heat treatment can be delayed to just prior to final heat treatment or cut any other step therebetween. After .the decarburizing anneal, the material is pickled in preparation for cold working.

Cold working is accomplished in one or more operations. Preferably, the cold working is accomplished in two steps. However, it has been found that it is necessary that at least the last cold working of the material to finish gauge must effect a reduction in the cross sectional area ranging between about 40% and about 75%. In this respect it has been noted that where the final cold reduction is less than about 40% a sharply defined [001] texture is not obtained as where the material has been subjected to at least a 40% reduction in cross sectional area. While reductions in excess of 75% will not adversely affect the final texture to any marked degree, nonetheless some deterioration has been noted and the degree of recrystallization may be some-what affected thereby. Consequently it has been found desirable to limit the cold reduction to finish gauge to avalue between about 40% and about 75% and outstanding results have been obtained where the final cold reduction has been effected in an amount ranging between about 50% and about 60%.

- In this respectit should be noted that the initial cold reduction, if more than onecold rdeuction stage ,is contemplated, may be effected by means of a hot-cold working. That is, the material may be heated to a temperature above ambient temperature but at a temperature below the temperature at which spontaneous recrystallization takes place during working. Thus while the material will be warmed well above room temperature it will nonetheless be a cold working and hence has been termed hotcold working. In this respect it has been found that where the intermediate gauge following 'hot working is for example about 0.100 inches in thickness, warm rolling may be effected at a temperature within the range between about 200 C. and about 300 C. to reduce the material to a thickness of about 0.040 inches, following which the material is permitted to cool to ambient temperature where it is then further cold rolled to about 0.025 inch. Thus the total reduction from hot rolled band thickness in the first cold rolling stage is effective for reducing the cross sectional area about 75%.

In all cases where more than one cold working operation is performed on the material, an intermediate anneal is preferably employed, said intermediate anneal being conducted for -a time period of up to about two hours at a temperature in excess of about 800 C. Preferbaly, such intermediate anneal is performed in an atmosphere of pure dry hydrogen, that is, a hydrogen content having a dew point of less than about 40 F.

Following such intermediate annealing the material is cold worked to finish gauge, such finish gauge cold working typically effecting a 40 to 75% reduction in cross sectional area and outstanding results have been obtained Where the cold reduction has been limited to a range between about 50% and 60% reduction in cross sectional area. Thus the overall processing is not only effective for removing about one-half of the original carbon content but thematerial has been reduced to finish gauge and thereafter fhwmaterial may be given the final high temperature heat treatment in order to develop the desired degree of oriented grain texture. In this respect it has been found that annealing the material at a temperature within the range betwene about 800 C. and the A temperature for a time period between about 12 hours and about 72 hours in an atmosphere of hydrogen having a dew point of less than -40 F. followed by furnace cooling has been effective for producing an outstanding degree of grain orientation the same having been accomplishedby means of a primary recrystallized grain structure which has undergone normal grain growth. It has been found that orientation textures have been more pronounced where the finish gauge material has been rapidly heated to a temperature of about 800 C'. Consequently, the preferred mode of processing includes a strip anneal for five minutes at 800 C. followed by a final box annealing-at a temperature within the range between 800 C. and the A temperature.

In order to more clearly demonstrate the alloy and the method of the present'invention reference may be had to the following Table I which includes the chemical composition of a number of heats which were made and tested in accordance with the present invention together with a commercially available material containing an iron base with about 27% cobalt being present and which was processed employing present commercial practices.

The foregoing processing removed about half of the original carbon but the other additions including sulfur did not change significantly. The finish gauge material was cut into Epstein strips in the rolling direction. In addition a 1 inch'diameter torque disc of each of the alloys was annealed for 48 hours at 900 C. in dry hydrogen and thereafter furnace cooled.

Reference is directed to Table II which includes the DC magnetic characteristics exhibited by each of the alloys.

TABLE IL-MAGNETIC CHARACTERISTICS Peak torque (ergs/ Torque I I B10 Brno crnfi) ratio (0a.) (G) (G) 64, 700 0.53 1. 03 18, 400 22,700 53. 400 0.61 1.36 17. 300 22, 000 44, 0. 42 1. 59 17, 200 22, 100 131, 0. 45 0. 60 19, 300 23, 100 3 138, 000 0. 37 0. 57 19, 600 22, 900 Commercial 27% C Fe (unoriented) l. 70 16, 100 21, 100 Commercial 3% Si-Fe (oriented) 167, 000 0. 34 0. l1 18, 300 19, 800

In order to complete the comparison, data is also included on a typical commercial heat of a singly oriented 3% silicon steel and a 27% cobalt-iron alloy (unoriented) for comparative purposes. In interpreting the data set forth in Table II it should benoted that the peak torque values in the Table represent the average of the absolute values of the large peaks in the curve. The torque ratio represents a ratio of the absolute values of the small peaks to the large peaks for a given curve. Since the commercially processed 27% cobalt material did not have measurable torque peaks and had a B value of only 16,100 gauss such values clearly indicate that the grain texture in the commercially processed material is essentially random.

From the data set forth in Table II it can be seen from the torque values as well as the induction at 10 oersted, substantially higher values for B have been obtained with each of the compositions. However, the compositions with the lowest sulfur content, that is, heats M 852 and M 853 had outstandingly high B values together with peak torque values which closely approach the value for:the 3% silicon iron which has a high degree of [001] orientation for commercially available material.

This is more clearly demonstrated by reference to FIG. 1 which superimposes the plots of the torque value versus the angle between the field and the rolling direction in degrees for a highly oriented 3% silicon iron as well as for alloys M 853 and M 849. Thus from the value of M 853 it can be seen that by decreasingthe sulfur content to a critically low level and by processing the material as set forth hereinbefore torque curves approaching those of. the commercially available 3% silicon iron are closely approximated. However, by comparing the saturation values in Table II, that is, the induction values where the field strength is 100 oersted it is clearly seen that much higher saturation induction values are obtained from the cobalt-iron alloys with overall improved magnetic characteristics resulting from the orientation of the material.

Reference is now directed to FIGS. 2 through 6 inclusive which are photomacrographs of alloys identified therein and whose composition is set forth in Table I. These photomacrographs are at a magnification of 20X after annealing the cobalt iron alloy sheets for 48 hours at 900 C., and show a strong correlation between the sulfur content and the final grain size. From FIGS. 2 through 6 it isv apparent that the low sulfur levels result in a large grain size by normal grain growth, that is, from a primarily recrystallized microstructure and not as a result of secondary recrystallization and grain growth. These results as well as the shorter annealing times on M 852 and M 853 indicate that the degree of (110) [001] texture is increased by primary grain growth in alloys containing low sulfur. This in direct contrast to the development of a similar oriented texture in 3% silicon iron where controlled high sulfur levels are required for texture development by secondary grain growth. Thus alloys M 852 and M 853 reflect the additional beneficial aspect that the cobalt iron alloys with low sulfur values have low coercive force values. Moreover it appears that the addition of chromium to these cobalt iron alloys appear to improve the textureiorma tion to some degree while increasing volume resistivity.

Another heat of cobalt iron alloy was melted to substantially the same composition as heat M 853. This heat was identified as heat M 903 and was processed employing substantially the same conditions as heat M 853 with the following exception. After annealing for one hour at 900 C. at an intermediate gauge of 0.025 inch, the material was cold rolled to final thicknesses of 0.0095 and 0.012 inch.

Reference is directed to Table III which contains the magnetic characteristics of the heat M 903.

TABLE III.-MA GNE'IIC CHARACTERISTICS Domain pattern texture analysis were performed on samples of material from heats M 852 and M 903, the latter. having a finish gauge thickness of about 0.0095 inch. It was found that 85% by volume of the grains had the (110) and 7% by volume displayed (100) texture, of which such (110) grains had crystal lattices whose cube edges aligned within 10 of the [001] driection in 80% of the grains. When the deviation from the [001} or rolling direction was measured within it was found that the edges of the crystal lattices of 88% of the (110) grains were within this limitation.

Heat M 852 was given a final cold reduction of just 50%, consequently, it did not develop as high a texture as heat M 903 rolled to 0.0095 inch thickness. Actual measurements of heat M 852 indicated 61% by volume of the grains had the (110) texture while 16% exhibited the (100) texture. Further, 58% of the cube edges of crystal lattices of the grains deviated less than 10 from the [001] direction and 68% of the grains were within 15 of the [001] direction.

In each of the forgeoing, the texture developed by means of primary recrystallizationv and normal grain growth. In each instance the presence of the (100) [001] texture does not detract from the magnetic characteristics exhibited by the alloy containing the preponderating texure (110) [001].

These data appear to indicate that a slightly higher degree of final cold reduction results in an improvement in the texture and that extremely high induction values are obtained. If the B values as well as the peak torque values for the heat M 903 at the 9.5 mil stage are compared with the commercial oriented 3% silicon steel as set-forth in Table II it becomes clear that a higher degree of (110) [001] texture was obtained in heat M 903' than that in the commercial 3% silicon steel. Thus the peak torque values are higher, the B values are higher and clearly, as would be expected, the saturation values are near the theoretical maximum. T r

Another series of heats were made in. which the sulfur content'was controlled to very low limits that is, a sulfur content of lessthan 001% by weight. Reference is directed to Table which includes the chemical composition of three heats which were made and tested.

TAB LE IV.CHEMICAL COMPOSITION [Percent by weight] Percent Co Cr Mn Si O S 0 Both disc samples for torque measurements as well as Epstein samples were cut from the material which samples were annealed for 48 hours at 900 C. in dry hydrogen.

Reference is directed to Table V which lists the magnetic characteristics of the alloys.

TABLE V.MAGNETIC CHARACTERISTICS Peak torque Torque II B10 Brno Alloy (ergs/cma) ratio (oe.( (G) (G) From the test results set forth in Table V it is noted that high B 'values were obtained indicating a high degree of (100) [001] orientation. To substantially the same elfect the saturation values were quite acceptable for the alloys although the peak torque values were somewhat lower than obtained with the better materials previously set forth herein. It is believed that the thicker hot rolled band material resulting in substantially higher intermediate cold reductions resulted in the somewhat lower peak torque values. Accordingly, it is desired to limit the cold reduction elfected in each step to a value within the range between about 40% and about 75% in cross sectional area.

From the foregoing it may be noted that each of the alloys which were made and tested contained a cobalt content near the upper limit. Having thus found a high degree of orientation being eifected by means of the process of the present invention, other cobalt contents were investigated in order to determine the relative level of cobalt which would be effective for obtaining improved induction values commensurate with obtaining the required degree of (100) [001] orientation in a primarily recrystallized microstructure. -Reference is directed to Table VI which contains the nominal composition of two alloys which were made and tested in accordance with the teachings of the present invention it being noted that the alloys set forth in Table VI contain 18% cobalt and 10% cobalt with a corresponding amount of silicon of 1% and 2% being added to obtain improved volume resistivity. In these heats, the sulfur content was controlled so as to The alloys were processed in accordance with the following schedule:

hot roll at 1050" C. to 0.080 inch;

pickle; anneal 5 hours at 850 C. in dry hydrogen; cold roll to 0.025 inch;

anneal 5 hours at 850 C. in dry hydrogen.

cold roll to 0.011 inch finish gauge thickness.

TABLE VII.MAGNETIC CHARACTERISTICS Peak torque (ergs/ Torque He B B Sample cmfi) ratio (e.) (G) M 833 106, 700 O. 44 0. 368 18, 500 21, 700 M 887 121, 300 0. 45 O. 275 18, 000 20, 900

The torque values indicate a high degree of (110) [001] texture. Although the 10% cobalt sample appears to be a little more highly textured, the 18% cobalt alloy has a higher induction value because of its higher saturation value. These samples exhibited only primary recrystallization and normal grain growth. In other tests, much lower torque values were obtained in similarly processed alloy compositions having sulfur additions of 0.01%. Also samples slowly heated to final annealing temperature, that is, appear to give poorer results.

From the foregoing examples it can be seen that a high degree of 110) [001] texture can be obtained by primary recrystallization and normal grain growth in cobalt iron alloys over a wide range of cobalt, manganese, silicon and chromium contents. The processing schedule is clearly important and should be noted that the final anneal must be kept below the alpha to gamma transformation temperature which is approximately 950 C. or, in more precise terms, at a maximum temperature below the A temperature. By thus keeping the sulfur content to less than 0.005%, highly (110) [001] textured alloys are obtained through primary recrystallization and grain growth. Accordingly, transformers and rotating magnetic core devices such as motors and generators employing this material can be made with decreased size and weight resulting in significant economic advantages in the production of both the alloy and the apparatus.

We claim:

1. An alloy member which exhibits improved permeabilities at low field strengths resulting from crystallographic orientation compared to unoriented magnetic material of the same composition consisting essentially of from about to about 35% cobalt, up to 2% chromium, up to 1% manganese, up to 3% silicon, less than 0.005% sulfur and the balance essentially iron with incidental impurities, the alloy having a primary recrystallized grain structure in which a major proportion of the grains exhibit a (110) texture and in which a major proportion of the oriented grains have cube edges of their crystal lattices aligned within of the rolling direction.

2. The alloy member of claim 1 in which the cobalt is present in an amount between about 8% and about 20% and the silicon is present within the range between about 0.5% and about 2.0%

3. The alloy member of claim 1 in which the cobalt is present within the range between about 20% and about 30% and the chromium is present within the range between about 0.25% and about 1.0%.

4. An alloy member which exhibits improved permeabilities at low field strengths resulting from crystallographic orientation compared to unoriented magnetic material of the same composition consisting essentially of from about 26.5% to about 28% cobalt, from about 0.25 to about 0.75% chromium, less than about 0.002% sulfur and the balance iron with incidental impurities, the alloy being characterized by a primary recrystallized microstructure having a major proportion of the grains exhibiting a orientation and a major proportion of the oriented grains having cube edges of their crystal lattices aligned within 10 of the rolling direction.

5. An alloy member which exhibits improved permeabilities at low field strengths resulting from crystallographic orientation compared to unoriented magnetic material of the same composition consisting essentially of from about 10% to about 18% cobalt, from about 0.5 to about 2.0% silicon, less than about 0.0025 sulfur and the balance essentially iron with incidental impurities, the alloy being characterized by a primary recrystallized grain structure with a major proportion of the grains exhibiting a (110) orientation and a major proportion of the oriented grains have cube edges of their crystal lattices aligned within 10 of the rolling direction.

6. An alloy member which exhibits improved permeabilities at low field strengths resulting from crystallographic orientation compared to unoriented magnetic material of the same composition consisting essentially of from about 5% to about 35% cobalt, up to 3% of at least one element for improving the volume resistivity without detrimentally affecting the chemical, physical and mechanical properties of the alloy and selected from the group consisting of silicon, chromium, vanadium, aluminum, titanium and molybdenum, less than about 0.005% sulfur, up to 1% manganese and the balance es sentially iron with incidental impurities, the alloy having a primary recrystallized grain structure with a major proportion of the grains exhibiting a (110) orientation and a major proportion of the oriented grains having the cube edges of their crystal lattices aligned within 10 of the rolling direction.

References Cited UNITED STATES PATENTS 1,247,206 11/1917 Becket 75-123 K 2,442,219 5/1948 Stanley 75123 K 3,164,496 1/1965 Hibbard et al. 148120 1,678,001 7/1928 Brace 75--123 K 2,717,223 9/1955 Binstock et al 148122 2,292,191 8/1942 Brandt et al. 148122 3,695,944 10/1972 Stroble 148-31.55 2,112,084 3/1938 Frey et al 14831.55 3,418,710 12/1968 Seidl et al. 148122 3,124,491 3/1964 Foster 148--31.55 3,166,408 1/1965 Chen 14831.55 3,347,718 10/1967 Carpenter et al 148-111 3,597,286 2/1968 Thornburg 148-121 FOREIGN PATENTS 424,327 1935 Great Britain 148-3155 1,180,954 1964 Germany 148100 OTHER REFERENCES Bozorth, R. M.: F erromagnetism, New York, 1951, pp.

WALTER R. SATTERFIELD, Primary Examiner US. Cl. X.R.