WO1987005985A1

WO1987005985A1 - Fire resistant plastic pipe

Info

Publication number: WO1987005985A1
Application number: PCT/EP1987/000171
Authority: WO
Inventors: Paul Robert Marks; Michael Harry Collins
Original assignee: Shell Internationale Research Maatschappij BV
Current assignee: Shell Internationale Research Maatschappij BV
Priority date: 1986-04-02
Filing date: 1987-03-23
Publication date: 1987-10-08
Anticipated expiration: 1988-10-02
Also published as: US4788090A; KR880701350A; NO169742C; EP0262203B1; NO874631L; NO874631D0; EP0240072A1; JPS63503005A; JPH0794877B2; KR960004554B1; NO169742B; GB8608055D0; CA1281662C; DE3775870D1; ES2030446T3; EP0262203A1; GR3003831T3; ATE71446T1

Abstract

A plastic pipe (1, 2) is coated at the outer surface thereof with a thermal insulating layer comprising phenolic foam (4, 6). This layer is enclosed in an integrity retaining layer comprising fibres (7), such as glassfibres, which fuse together upon exposure to fire, thereby providing mechanical strength to the foam if the pipe is exposed to fire.

Description

FIRE RESISTANT PLASTIC PIPE

The invention relates to a fire resistant plastic pipe. The present restrictions on the use of plastic materials in flowline circuits in hazardous areas e.g. on board ships or on offshore platforms are imposed mainly because of the poor fire resistance of these materials relative to metallic materials.

Numerous attempts have already been made to improve the fire resistance of plastic flowlines such as by covering the wall thereof with various types of coatings. During the course of experiments it has been found that many coatings provide a temporary protection to the pipe wall in case of fire but that the coatings tend to fall after exposure to fire during an extended period of time.

Object of the invention is to provide a plastic pipe of which the wall is protected against fire even if the pipe is exposed to fire during an extended period of time.

In accordance with the invention this object is accomplished by a plastic pipe which is coated at the outer surface thereof with a thermal insulating layer comprising phenolic foam which layer is enclosed in an integrity retaining layer comprising fibres which fuse together upon exposure to fire thereby providing mechanical strength to the foam if the pipe is exposed to fire.

The invention will now be explained in more detail, by way of example, with reference to the accompanying drawing illustrating a fire resistant plastic pipe according to the invention. The pipe shown in the drawing comprises two plastic pipe sections 1 and 2 joined by a socket and spigot joint 3. A major portion of the outer surface of each pipe section is coated with a continuous insulating layer 4 of phenolic foam. This layer 4 is overwrapped with an integrity retaining layer 5 of glassfibre reinforced epoxy. In the region of the joint 3 the pipe wall is surrounded by a series of phenolic foam blocks 6 which have been cut to shape to a series of complementary elements 6 to fill-up the gap between the adjacent continuous foam layers 4. The elements 6 are held in place by an overlay 7 of glassfibre reinforced epoxy, which overlay 7, together with the integrity retaining layers 5, forms a continuous layer of glassfibre reinforced epoxy surrounding the entire body of phenolic foam.

Phenolic foam is generally regarded as a suitable thermal insulation for room temperature. Although phenolic foams do burn, they are inherently difficult to ignite and tend to carbonize slowly under the influence of direct flame, while emitting only very low levels of smoke.

During the course of experiments with plastic pipes of which the outer wall was insulated by a phenolic foam coating it became apparent that although the foam charred only very slowly under the influence of direct flame, it became very weak mechanically and that the updraft of the fire caused much of the insulation to be blown away. Detailed examination of the damaged insulation revealed that under the influence of flames a phenolic foam coating has the tendency to crack and that the cause of the cracking is the contraction of the char layer over the undamaged foam. Due to the relatively low toughness of the phenolic foam the cracks produced in this way tend to penetrate to the pipe surface and cause an increase in heat flux thus reducing the effectiveness of the protection. The present invention is at least partly based on the insight that if the tendency of phenolic foam to crack under the influence of flames can be suppressed, the foam is able to maintain its insulating properties in case of fire so that it can perform as a fire protective material. It was found that overwrapping the phenolic foam insulation layer with a glassfibre reinforced mastic enhanced the fire resistant properties of the foam to an unexpected large degree. Experiments revealed that after exposure to fire the glassfibre overwrapping had fused together to form a tough protective layer to the foam, which though charred, had retained a large proportion of its thermal and mechanical properties. The presence of an overwrap comprising fibres which fuse together upon exposure to fire is essential to retain the mechanical and thermal properties of the phenolic foam if the pipe is exposed to fire. It will be appreciated that in addition to, or instead of, glassfibres the fibrous overwrap may contain other fibrous materials provided that upon exposure to fire at least some of the fibres fuse together and to the phenolic foam. Impregnating the fibrous overwrap with a mastic, such as an epoxy or phenolic resin, has the advantage that during normal operation of the pipe the foam is protected against occasional impacts. In case of fire the mastic will however rapidly burn away and it is the effect of the fusing fibres that provides mechanical strength to the foam.

Furthermore chopped glassfibres may be added to the phenolic foam to further suppress propagation of cracks through the foam upon exposure to fire. The plastic pipe itself may be made of any suitable synthetic material, such as an epoxy or polyester resin. The pipe wall may be reinforced by one or more layers of glassfibres. The fire resistant pipe thus fabricated is suitable for use in all tubular constructions where fire resistance is needed, such as in glassfibre reinforced plastic pipes having rectangular or circular shape or in large diameter pressure or storage vessels. Besides use of the pipe in ships or on offshore platforms, the pipe may also find application in onshore flowline circuits where fire resistance is required.

Claims

C L A I M S

1. A plastic pipe coated at the outer surface thereof with a thermal Insulating layer comprising phenolic foam which layer is enclosed in an integrity retaining layer comprising fibres which fuse together upon exposure to fire thereby providing mechanical strength to the foam if the pipe is exposed to fire.

2. The pipe of claim 1, wherein the integrity retaining layer consists of an epoxy or phenolic impregnated woven glassfibre mat.

3. The pipe of claim 1, wherein the insulating layer consists of phenolic foam.

4. The pipe of claim 1, wherein the insulating layer consists of phenolic foam and chopped glassfibres.

5. The pipe of claim 1, wherein the pipe is made of a glassfibre reinforced resin.

6. The pipe of claim 1, wherein the pipe consists of a plurality of interconnected pipe sections, a major part of the wall of each section of the pipe being covered by a continuous layer of thermal insulating material comprising phenolic foam, the region of each joint interconnecting a pair of adjacent pipe sections being covered by a series of complementary elements of thermal insulating material, comprising phenolic foam, the outer surface of said elements and said continuous layer being covered by a continuous fibrous integrity retaining layer comprising fibres which fuse together upon exposure to fire.