WO1991012361A1 - A method of tyre cord sheet construction - Google Patents
A method of tyre cord sheet construction Download PDFInfo
- Publication number
- WO1991012361A1 WO1991012361A1 PCT/GB1991/000218 GB9100218W WO9112361A1 WO 1991012361 A1 WO1991012361 A1 WO 1991012361A1 GB 9100218 W GB9100218 W GB 9100218W WO 9112361 A1 WO9112361 A1 WO 9112361A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- yarn
- stiff
- core
- tabby
- tyre cord
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/48—Tyre cords
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/0042—Reinforcements made of synthetic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/18—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers
- B60C9/20—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel
- B60C9/2003—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel characterised by the materials of the belt cords
- B60C9/2009—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel characterised by the materials of the belt cords comprising plies of different materials
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/593—Stiff materials, e.g. cane or slat
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/02—Inorganic fibres based on oxides or oxide ceramics, e.g. silicates
- D10B2101/06—Glass
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S57/00—Textiles: spinning, twisting, and twining
- Y10S57/902—Reinforcing or tyre cords
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10495—Pneumatic tire or inner tube
- Y10T152/10765—Characterized by belt or breaker structure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10495—Pneumatic tire or inner tube
- Y10T152/10855—Characterized by the carcass, carcass material, or physical arrangement of the carcass materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3065—Including strand which is of specific structural definition
- Y10T442/3073—Strand material is core-spun [not sheath-core bicomponent strand]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
- Y10T442/322—Warp differs from weft
- Y10T442/3228—Materials differ
- Y10T442/326—Including synthetic polymeric strand material
- Y10T442/3268—Including natural strand material
Definitions
- This invention relates to methods of stiffening and improving resistance ⁇ ,o lateral distortion, applicable to flexible webs used as tyre cord tabbies.
- a typical cord sheet or ply stock comprises a long (typically up to 3000m) strip of fabric made up of a warp of closely spaced cords, e.g. twisted synthetic filament yarns or wire, with relatively weak and widely spaced cotton weft strands serving to maintain the warp cords in a parallel even array.
- Each end of a cord sheet of this type comprises a 'tabby' - a short length which is reinforced with densly woven weft strands, conventionally of cotton yarn.
- the term 'tabby' is used herein to denote the end portion of a length of tyre cord sheet, otherwise known as a splicing header, splicing head-end or bordure which is used to handle the cord sheet and, in particular to join sheets together into a long web for further processing.
- the further processing involves applying longitudinal tension and dipping in an aqueous latex bath and rapid hot-air drying and heat setting in an ascending column drier, thus subjecting the cotton to shrinkage caused by heat and wet.
- the cord sheet passes over banana rollers and the like which both extend and narrow the width of the sheet, causing non-resilient weft threads to break, leading to splitting or distortion of the sheet.
- the latexed sheet is then subsequently coated with rubber between calender rolls and split to provide the reinforecement ply material used in tyre manufacture.
- a web such as a tabby can be substantially stabilised by incorporating therein weft strands of a highly resilient, stiff yarn, especially a composite yarn, such as a composite yarn having a stiff core, for example a filament or wire which has been mantled with fibres, e.g. by a core spinning, e.g. a friction spinning, technique.
- a composite yarn such as a composite yarn having a stiff core
- a filament or wire which has been mantled with fibres, e.g. by a core spinning, e.g. a friction spinning, technique.
- fine steel wire is a suitable core material for such a composite yarn
- a particularly preferred embodiment of this invention comprises a core of glass filaments, either untwisted or with a small degree of twist, mantled with fibres of, for example, polyamide, polyester or cellulose ester, or with natural fibres or with mixtures thereof.
- the mantle fibres preferably comprise about 10% to 70% of the composite by weight.
- the glass filament core is preferably of around 800 to 4800 dtex, e.g. about 1360 to 4080.
- the size of the core will depend on the nature of the tyre cord sheet and its intended use. Within certain limits, the tabbies of sheets for lighter tyres need stiffer weft strands than those of sheets for heavier tyres. A light tyre cord sheet tends to have wider gaps between the warps than a heavy tyre cord sheet, where the warps lie adjacent one another.
- the weft reinforcement has to maintain the spacing of the warp cords and thus needs to be stiffer; while in the very heavy type cord sheet there is, very little gap to maintain and little space for the wefts, so the core can be as low as 800-1600 dtex.
- the overall bulk of the composite yarn is not dependent on the stiffness or strength of the core, since the amouont of mantling fibre can be adjusted to provide different composite yarns all of the same size but with differing cores.
- the other function of the mantle fibre is to cushion the yarn and provide weave stability by allowing the warps to grip at the intersections without slipping.
- the yarn comprising mantled glass filament is a preferred embodiment
- other stiff yarns are possible provided that they are capable of forming a stable weave, for example monofil yarn which has been surface-roughened, e.g. by a roller treatment; mantled yarn in which the mantle fibres themselves are relatively stiff and the core less so; and co-spun or twist yarns in which a stiff fibre or filament is combined with non-stiff fibres or filaments.
- the stiffness of the yarn used in the present invention is typically 30 to 110 seconds, preferably 38 to 91 seconds, e.g. about 65 seconds, as measured by the stiffness/bendability test developed by Kordarna a.s. (Czechoslovakia).
- the apparatus for this test is shown in Figures 4a and 4b.
- the pendulum 23 of the apparatus is raised through an angle of 150° to the vertical and then released.
- the yarn to be tested is held by a clamp 24, 10 mm of the yarn being allowed to protrude vertically from the claim.
- the time is measured between release of the pendulum and when the pendulum finally comes to rest.
- the stiffer the yarn the greater the retardation of the motion of the pendulum and hence the shorter the time before the pendulum comes to rest.
- Fig. 1 represents a schematic view of a composite yarn used according to the invention
- Fig. 2 represents a diagrammatic plan view of part of a tyre cord sheet with tabby
- Fig. 3 represents sections through two tabby constructions.
- Fig. 4 represents front and side views of the stiffness/bendability apparatus developed by Kordarn a.s. (C ⁇ echoslovakia) .
- the composite yarn shown in Fig. 1 comprises a core 1 of glass filaments 2. Each filament has a typical diameter of 10 microns. There are about 150 filaments in all, giving a total gauge of about 3,000 dtex. The core 1 filaments have no twist. The core 1 is surrounded by a mantle 3 of short random fibres 4 of a mixture of 45% cotton, 45% polyester and 10% acrylic. The mantle 3, which comprises about 32.5% by weight of the total composite yarn is applied to the core 1 by a friction spinning technique. The overall diameter of the composite yarn is about 1.5 mm. The breaking strength for the above described composite yarn is about 15-20 Kg at an elongation of about 2.5%. The strength and especially the stiffness can be selected by the appropriate combination of core and mantle sizes. A composite yarn of this type is extremely suitable for use as the weft in a tabby as described above and described in more detail below.
- Fig. 2 shows a detail of one corner of a tyre cord sheet comprising closely spaced warped strands 11, each comprising a drawn, twisted synthetic resin tyre cord, such as a polyamide filament yarn of single, two-, three- or multi-ply, depending on the nature of the tyre for which it is intended.
- the warp strands 11 are interwoven with fine weft strands 12, typically spaced about 1 cm apart. These weft strands are typically formed from 16, 20 or 30 singles cotton yarn.
- the weft strands 12 are replaced by about 16 to 20 rows of reinforcing strands 13 formed from a composite yarn as described with reference to Fig. 1.
- the reinforcing strands are more closely spaced than the weft strands 12 (typically about 28-64 wefts per decimeter) and, together with the warp strands 11, form a solid tough textile band which serves as the tabby.
- a conventional tabby is represented in section in (a) and a tabby according to the invention in (b) .
- the reinforcing strands 13 ensure that the the tabby remains substantially the full width of the tyre cord sheet throughout the dipping, drying and heat setting process.
- the handling techniques can cause the straight reinforcing weft strands 13 to become displaced in the plane of the sheet for example into wavy, buckled lines rather than straight configurations, thus leading, to a slight narrowing of the piece.
- this can in part be caused by narrowing of the sheet thus enabling the tabby to stay the same width as the sheet. If desired, this can also be overcome by lateral pulling to straighten the strands 13.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
- Tires In General (AREA)
- Tyre Moulding (AREA)
- Ropes Or Cables (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/916,828 US5342678A (en) | 1990-02-14 | 1991-02-13 | Method of tyre cord sheet construction |
| EP19910903393 EP0516645B1 (en) | 1990-02-14 | 1991-02-13 | A method of tyre cord sheet construction |
| DE69115261T DE69115261D1 (en) | 1990-02-14 | 1991-02-13 | METHOD FOR PRODUCING A TIRE CORD. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9003329A GB2240998B (en) | 1990-02-14 | 1990-02-14 | Stiffened webs and composite yarns |
| GB9003329.1 | 1990-02-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1991012361A1 true WO1991012361A1 (en) | 1991-08-22 |
Family
ID=10670970
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/GB1991/000218 Ceased WO1991012361A1 (en) | 1990-02-14 | 1991-02-13 | A method of tyre cord sheet construction |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5342678A (en) |
| EP (1) | EP0516645B1 (en) |
| JP (1) | JPH05504175A (en) |
| AT (1) | ATE131226T1 (en) |
| AU (1) | AU7218291A (en) |
| CS (1) | CS38691A2 (en) |
| DE (1) | DE69115261D1 (en) |
| GB (1) | GB2240998B (en) |
| IN (1) | IN179590B (en) |
| WO (1) | WO1991012361A1 (en) |
| YU (1) | YU47683B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013076617A1 (en) * | 2011-11-22 | 2013-05-30 | Kordsa Global Endustriyel Iplik Ve Kord Bezi̇ Sanayi̇ Ve Ticaret Anonim Sirketi | A tire cord fabric with tabby |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3342759B2 (en) * | 1993-11-30 | 2002-11-11 | 住友ゴム工業株式会社 | Method for manufacturing rubber-reinforced blind fabric, tire reinforcing ply, and rubber-reinforced blind fabric |
| US5609701A (en) * | 1995-08-04 | 1997-03-11 | Milliken Research Corporation | Radial tire with bias cut woven nylon chafer fabric |
| FR2824296A1 (en) * | 2001-05-03 | 2002-11-08 | Michelin Soc Tech | REINFORCEMENT TAPE FOR TIRES |
| DE102006030699B4 (en) * | 2006-06-30 | 2014-10-02 | Daimler Ag | Cast steel piston for internal combustion engines |
| US20090071587A1 (en) * | 2007-09-14 | 2009-03-19 | Kenneth Dean Conger | Tire cord fabric |
| WO2010032082A1 (en) * | 2008-09-16 | 2010-03-25 | Kordsa Global Endustriyel Iplik Ve Kord Bezi Sanayi Ve Ticaret A.S | A tire cord fabric tabby |
| US20100108218A1 (en) * | 2008-10-30 | 2010-05-06 | E. I. Du Pont De Nemours And Company | Extensible non-load bearing cut resistant tire side-wall component cotaining elastomeric filament, tire containing said component, and processes for making same |
| US20100108231A1 (en) * | 2008-10-30 | 2010-05-06 | E. I. Du Pont De Nemours And Company | Non-load bearing cut resistant tire side- wall component and tire containing said component, and processes for making same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2238783A1 (en) * | 1973-07-28 | 1975-02-21 | Dunlop Ltd | |
| US3938313A (en) * | 1967-08-29 | 1976-02-17 | Owens-Corning Fiberglas Corporation | Reinforcement for tires and method of making same |
| US4024895A (en) * | 1976-03-24 | 1977-05-24 | E. I. Du Pont De Nemours And Company | Product reinforcing fabric and two-component weft yarn useful therein |
| EP0120175A2 (en) * | 1983-03-28 | 1984-10-03 | The Goodyear Tire & Rubber Company | Woven wire fabric |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1780085A1 (en) * | 1968-07-31 | 1971-10-21 | Olbo Textilwerke Gmbh | Radial tires |
| US3628995A (en) * | 1968-10-03 | 1971-12-21 | Carborundum Co | Flame resistant cloth |
| US3863683A (en) * | 1968-11-19 | 1975-02-04 | Textiles Artificiels Et Synthe | Tire cord for pneumatic tires and pneumatic tires containing the same |
| US3572397A (en) * | 1968-12-27 | 1971-03-23 | Uniroyal Inc | Noncombustion-supporting fabric |
| GB1292055A (en) * | 1969-03-11 | 1972-10-11 | Courtaulds Ltd | Novelty textile yarns |
| IL36371A (en) * | 1970-03-17 | 1975-06-25 | Chiarotto N | Flameproof composite yarns |
| US3837982A (en) * | 1970-09-03 | 1974-09-24 | Goodyear Tire & Rubber | Wire woven fabric for pneumatic tires |
| JPS5526215B1 (en) * | 1971-07-12 | 1980-07-11 | ||
| DE3023936A1 (en) * | 1979-07-27 | 1981-02-19 | Ernst Dr Fehrer | DEVICE FOR PRODUCING A YARN |
| FR2497239A1 (en) * | 1980-12-31 | 1982-07-02 | Valeo | YARNS AND OTHER GLASS FIBER PRODUCTS AND METHOD FOR THE PRODUCTION THEREOF |
| AT367104B (en) * | 1981-02-09 | 1982-06-11 | Fehrer Ernst | DEVICE FOR PRODUCING A YARN |
| DE3330417A1 (en) * | 1983-08-23 | 1985-03-14 | Karl-Josef Dipl.-Ing. 4156 Willich Brockmanns | FRICTION SPIDER DEVICE |
-
1990
- 1990-02-14 GB GB9003329A patent/GB2240998B/en not_active Expired - Fee Related
-
1991
- 1991-02-13 YU YU54991A patent/YU47683B/en unknown
- 1991-02-13 AT AT91903393T patent/ATE131226T1/en not_active IP Right Cessation
- 1991-02-13 US US07/916,828 patent/US5342678A/en not_active Expired - Fee Related
- 1991-02-13 AU AU72182/91A patent/AU7218291A/en not_active Abandoned
- 1991-02-13 WO PCT/GB1991/000218 patent/WO1991012361A1/en not_active Ceased
- 1991-02-13 EP EP19910903393 patent/EP0516645B1/en not_active Revoked
- 1991-02-13 DE DE69115261T patent/DE69115261D1/en not_active Expired - Lifetime
- 1991-02-13 JP JP3503813A patent/JPH05504175A/en active Pending
- 1991-02-14 IN IN126MA1991 patent/IN179590B/en unknown
- 1991-02-14 CS CS91386A patent/CS38691A2/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3938313A (en) * | 1967-08-29 | 1976-02-17 | Owens-Corning Fiberglas Corporation | Reinforcement for tires and method of making same |
| FR2238783A1 (en) * | 1973-07-28 | 1975-02-21 | Dunlop Ltd | |
| US4024895A (en) * | 1976-03-24 | 1977-05-24 | E. I. Du Pont De Nemours And Company | Product reinforcing fabric and two-component weft yarn useful therein |
| EP0120175A2 (en) * | 1983-03-28 | 1984-10-03 | The Goodyear Tire & Rubber Company | Woven wire fabric |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013076617A1 (en) * | 2011-11-22 | 2013-05-30 | Kordsa Global Endustriyel Iplik Ve Kord Bezi̇ Sanayi̇ Ve Ticaret Anonim Sirketi | A tire cord fabric with tabby |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05504175A (en) | 1993-07-01 |
| AU7218291A (en) | 1991-09-03 |
| ATE131226T1 (en) | 1995-12-15 |
| YU54991A (en) | 1994-01-20 |
| DE69115261D1 (en) | 1996-01-18 |
| EP0516645A1 (en) | 1992-12-09 |
| EP0516645B1 (en) | 1995-12-06 |
| GB2240998B (en) | 1994-05-18 |
| CS38691A2 (en) | 1991-09-15 |
| IN179590B (en) | 1997-10-25 |
| GB2240998A (en) | 1991-08-21 |
| GB9003329D0 (en) | 1990-04-11 |
| YU47683B (en) | 1996-01-08 |
| US5342678A (en) | 1994-08-30 |
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