WO1993000470A1 - Ozone bleaching process - Google Patents
Ozone bleaching process Download PDFInfo
- Publication number
- WO1993000470A1 WO1993000470A1 PCT/FI1992/000198 FI9200198W WO9300470A1 WO 1993000470 A1 WO1993000470 A1 WO 1993000470A1 FI 9200198 W FI9200198 W FI 9200198W WO 9300470 A1 WO9300470 A1 WO 9300470A1
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- Prior art keywords
- fiber suspension
- vessel
- ozone
- reaction vessel
- pressure
- Prior art date
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
- D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
Definitions
- the present invention relates to ozone bleaching of a medium consistency suspension of cellulosic fibers such as paper pulp and, particularly, to a method of sequentially bleaching pulp by ozone and a second bleaching agent, preferably, an alkali agent to obtain a ZE bleaching sequence.
- medium consistency pulp i.e. a cellulosic fiber suspension having a consistency of from about 5 - 20 % is bleached with ozone by (a) feeding said fiber suspension and an ozone containing carrier gas under pressure preferably at about 3 to about 25 bar, more preferably at about 5 - 14 bar, to a mixer effecting high sheer mixing for intimately and homogeneously intermixing the ozone with the medium consistency fiber suspension.
- a carrier gas oxygen air and nitrogen may be used, with oxygen being presently preferred as it contains the greatest amount of ozone, namely, about 3 - 16 % at the most.
- an ozone carrier gas mixture may contain for instance about 10 kg ozone and 90 kg oxygen.
- the water/gas ratio is preferably between about 1:10 and 2:1 depending on the pressure which varies between 3 to about 25 bar.
- the high shear mixer which is preferably a commercially available MC R mixer, the ozone in carrier gas and the paper pulp are thoroughly mixed so that an adequate transfer and contact between the ozone and the fibers is achieved resulting in high bleaching efficiency,
- the intimate and uniform paper pulp/ozone mixture is passed into a first reaction vessel for allowing the bleaching process .to proceed until a major part of the ozone is consumed.
- the residence time of the mixture in the fluidizing mixer is less than 1 second and the residence time of the mixture of paper pulp and ozone in carrier gas in the first reaction vessel is about 0. 1 to 5. 0 minutes. This permits about 99 % of the ozone to be consumed and the bleaching process to be substantially completed.
- a second chemical agent preferably a known bleaching agent such as sodium hydroxide, hydrogen peroxide or chlorine dioxide is added to the mixture in liquid form and also intimately mixed therewith.
- the top of the reaction vessel is provided with a known fluidizing device which fluidizes the contents of the reaction vessel for discharging the mixture into a second vessel for permitting the excess ozone, the carrier gas and a minor amount of possible additional reaction gases to separate from the mixture and also to permit the second bleaching reaction to proceed.
- this preferably alkaline mixture of paper pulp may reside in the second vessel, which has preferably a considerably larger cross-section than the first reaction vessel, for up to about 1 - 3 hours.
- the paper pulp which has now been subjected to a ZE bleaching sequence is then discharged from the bottom of the second vessel either to a washer or to another treatment stage including another bleaching stage in a bleaching sequence.
- the pressure in the first reaction vessel is maintained at a predetermined level by a suitable valve and control loop.
- the pressure in the second vessel is also controlled with known means, albeit at a lower level relative to the pressure in the first vessel.
- a suitable known control device is provided to maintain the level of the paper pulp within the second vessel at least within a predetermined range.
- Excess gas may be vented at various locations, such as, for example, from the first reaction vessel through the fluidizing device at the top of the reaction vessel.
- a constant pressure should be maintained in the first reaction vessel to achieve maximum ozone bleaching effect.
- the injection under pressure of the liquid bleaching agent is performed at or in close proximity to the fluidizing operation to intimately and uniformly mix the preferably alkaline bleaching agent with the pulp.
- both the first and second vessels are preferably upright reactors, whereby the pulp is passed through the first vessel in an upward direction of flow while the pulp passes through the second vessel in a downward flow.
- FIG. 1 is a schematic illustration of a first embodiment of the present invention.
- FIG. 2 is a schematic illustration of a second embodiment of the present invention.
- pulp is transferred from a storage unit 10 by a pump 12 which is preferably a degassing medium consistency pump through a line or conduit
- Mixer 14 is preferably a high-shear, medium consistency mixer commercially available from Kamyr Inc. of Glens Falls, N.Y.
- the mixer has an inlet for the medium consistency pulp suspensions connected to line 16, and an inlet port 18, for the pressurized feed of ozone containing carrier gas such as air, nitrogen and preferably oxygen.
- ozone containing carrier gas such as air, nitrogen and preferably oxygen.
- the pulp suspension is intimately and uniformly mixed with the ozone containing carrier gas and discharged through a mixture outlet into a conduit 20 and passed within about 2 - 3 seconds into the bottom 23 of a first upright reaction vessel 22. After a residence time of about 0.5 to 5 min.
- the mixture of pulp, carrier gas and ozone which has not yet been entirely consumed during the bleaching reaction, arrives at the top 25 of the reaction vessel 22.
- an additional bleaching chemical for example, sodium hydroxide, hydrogen peroxide, sodium peroxide, chlorine dioxide, or the like, preferably in liquid form and if necessary with a carrier, under pressure.
- the bleaching chemical is intimately mixed with the paper pulp to effect the alkaline bleaching step.
- vessel 22 is provided at the top portion 25 thereof with a known fluidizing device or fluidizing discharger 26 which preferably has an integral injection port for the bleaching chemical at or near the fluidizing rotor or fluidizing device or discharger 26 so as to effect the proper mixing of the bleaching chemical with the fluidized paper pulp.
- the fluidizing discharger 26 is preferably provided with means 28 for discharging preferably pressurized gas from the reactor to be used, for example, in another pressurized bleaching stage.
- the pressure in the first reaction vessel 22 should be maintained at a constant level which is achieved with a pressure regulating valve 27, preferably located closely adjacent fluidizing discharger 26, and control loop 31 in known manner.
- the bleached pulp which now contains excess ozone, carrier gas and bleaching chemical, for example, sodium hydroxide, is now discharged from first vessel 22, preferably into the enlarged inlet portion 33 of a second upright vessel 32 to assist in the separation of the gasses from the pulp mixture. Separated gas is then removed from the second vessel 32 through a gas discharge line 34.
- the pressure in the second vessel 32 is also maintained steady, albeit at a relatively substantially lower level than in the first vessel, generally only at slight overpressure, by a separate pressure regulating valve 36 and a control loop 37 in a known manner.
- the pulp is now collected in the second vessel 32 at or near a predetermined level, through known level control means 38, line 41, pump 44, and pressure regulating valve 47 for up to 1 to 3 hours to complete the alkaline (E) bleaching stage and thereafter is discharged at the bottom 42 of vessel 32 by a pump 44, which is preferably also a degassing medium consistency pump, through a valve 47 into a conduit 46 leading to a washer or other suitable treatment stage.
- a pump 44 which is preferably also a degassing medium consistency pump
- second vessel 132 is provided at its bottom 142 with an outlet 152 which is dimensioned to permit the bleached paper pulp to be fed, due to the pressure head thereof, into a suitable washer 150, preferably a drum diffusion washer as sold by assignee A. Ahlstrom Corporation, with pressurized inlet or diffuser available from Kamyr Inc. of Glens Falls, N.Y.
- a suitable washer 150 preferably a drum diffusion washer as sold by assignee A. Ahlstrom Corporation, with pressurized inlet or diffuser available from Kamyr Inc. of Glens Falls, N.Y.
- a level control mechanism 138 cooperates through line 148 with an rp regulator of washer 150 in known manner to maintain the paper pulp level in the second vessel 132 at a predetermined level.
- the washed pulp is discharged from washer 150 by a pump 144, preferably a degassing medium consistency pump through a conduit 146 for further treatment.
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- Wood Science & Technology (AREA)
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Abstract
Method and apparatus for ozone bleaching a medium consistency cellulosic fiber suspension include feeding the fiber suspension and an ozone in carrier gas stream under pressure into a fluidizing mixer (14); intimately and uniformly mixing the fiber suspension with the ozone to achieve a bleaching reaction; passing the mixture into a first reaction vessel (22) to permit the bleaching reaction to proceed and to consume a major part of the ozone; adding a second bleaching chemical to the mixture; separating the excess ozone and carrier gas from the mixture in a second considerably larger vessel (32) and removing the fiber suspension from the second vessel after the effective second bleaching reaction.
Description
OZONE BLEACHING PROCESS
Field of the invention The present invention relates to ozone bleaching of a medium consistency suspension of cellulosic fibers such as paper pulp and, particularly, to a method of sequentially bleaching pulp by ozone and a second bleaching agent, preferably, an alkali agent to obtain a ZE bleaching sequence.
Background of the invention
Bleaching of medium consistency paper pulp with ozone has only recently become possible and is described in more detail in pending U.S. applications SN 693,287 filed April 30, 1991 and SN 498,2.05 filed March 23, 1990, the entire content of both of which applications is incorporated herein by reference. Previous draw backs, e.g. the high cost of ozone, the known disadvantages associated with operating at either low consistency (less than about 5 %) or at very high consistency (above about 25 %) and the fact that ozone readily attacks the carbohydrates of the pulp, have now been overcome. Due to the present invention the efficiency of an ozone bleaching operation of medium consistency pulp, i.e. a cellulosic fiber suspension having a consistency of from about 5 to about 20 percent, is further increased by incorporation of an additional chemical feeding step into the ozone bleaching stage.
Summary of the invention
In accordance with the present invention medium consistency pulp, i.e. a cellulosic fiber suspension having a consistency of from about 5 - 20 % is bleached with ozone by (a) feeding said fiber suspension and an ozone containing carrier gas under pressure preferably at about 3 to about 25 bar, more preferably at about 5 - 14 bar, to a mixer effecting high sheer mixing for intimately and homogeneously intermixing the ozone with the medium consistency fiber
suspension. As a carrier gas oxygen, air and nitrogen may be used, with oxygen being presently preferred as it contains the greatest amount of ozone, namely, about 3 - 16 % at the most. Thus, for example, an ozone carrier gas mixture may contain for instance about 10 kg ozone and 90 kg oxygen. At a pulp suspension consistency of 10 %, the water/gas ratio is preferably between about 1:10 and 2:1 depending on the pressure which varies between 3 to about 25 bar. (b) In the high shear mixer, which is preferably a commercially available MCR mixer, the ozone in carrier gas and the paper pulp are thoroughly mixed so that an adequate transfer and contact between the ozone and the fibers is achieved resulting in high bleaching efficiency, (c) From the mixers, the intimate and uniform paper pulp/ozone mixture is passed into a first reaction vessel for allowing the bleaching process .to proceed until a major part of the ozone is consumed. The residence time of the mixture in the fluidizing mixer is less than 1 second and the residence time of the mixture of paper pulp and ozone in carrier gas in the first reaction vessel is about 0. 1 to 5. 0 minutes. This permits about 99 % of the ozone to be consumed and the bleaching process to be substantially completed. A second chemical agent, preferably a known bleaching agent such as sodium hydroxide, hydrogen peroxide or chlorine dioxide is added to the mixture in liquid form and also intimately mixed therewith. Preferably, the top of the reaction vessel is provided with a known fluidizing device which fluidizes the contents of the reaction vessel for discharging the mixture into a second vessel for permitting the excess ozone, the carrier gas and a minor amount of possible additional reaction gases to separate from the mixture and also to permit the second bleaching reaction to proceed. To this end, this preferably alkaline mixture of paper pulp may reside in the second vessel, which has preferably a considerably larger cross-section than the first reaction vessel, for up to about 1 - 3 hours. The paper pulp which has now been subjected to a ZE bleaching sequence is then discharged from the bottom of the second
vessel either to a washer or to another treatment stage including another bleaching stage in a bleaching sequence. Preferably, the pressure in the first reaction vessel is maintained at a predetermined level by a suitable valve and control loop. The pressure in the second vessel is also controlled with known means, albeit at a lower level relative to the pressure in the first vessel. In addition, a suitable known control device is provided to maintain the level of the paper pulp within the second vessel at least within a predetermined range.
Excess gas may be vented at various locations, such as, for example, from the first reaction vessel through the fluidizing device at the top of the reaction vessel. In this connection it should be kept in mind that a constant pressure should be maintained in the first reaction vessel to achieve maximum ozone bleaching effect. Also, the injection under pressure of the liquid bleaching agent is performed at or in close proximity to the fluidizing operation to intimately and uniformly mix the preferably alkaline bleaching agent with the pulp. Finally, both the first and second vessels are preferably upright reactors, whereby the pulp is passed through the first vessel in an upward direction of flow while the pulp passes through the second vessel in a downward flow.
Other objects and features of the present invention will become apparent from the following detailed description considered in conjunction with the accompanying drawings. It is to be understood, however, that the drawings are designed solely for the purposes of illustration and not as a definition of the lir -s of the invention, for which reference should be made t«. the appended claims.
Brief description of the drawings
The present invention is further described in detail below with reference to the accompanying drawings in which:
FIG. 1 is a schematic illustration of a first embodiment of the present invention; and
FIG. 2 is a schematic illustration of a second embodiment of the present invention.
Detailed description of the presently preferred embodiments
In the figures the same elements are given the same numerals with the exception that all numbers in Fig. 2 are preceded by the numeral 1.
Referring now to Fig. 1 in detail, pulp is transferred from a storage unit 10 by a pump 12 which is preferably a degassing medium consistency pump through a line or conduit
16 to a fluidizing mixer 14. Mixer 14 is preferably a high-shear, medium consistency mixer commercially available from Kamyr Inc. of Glens Falls, N.Y. The mixer has an inlet for the medium consistency pulp suspensions connected to line 16, and an inlet port 18, for the pressurized feed of ozone containing carrier gas such as air, nitrogen and preferably oxygen. The pulp suspension is intimately and uniformly mixed with the ozone containing carrier gas and discharged through a mixture outlet into a conduit 20 and passed within about 2 - 3 seconds into the bottom 23 of a first upright reaction vessel 22. After a residence time of about 0.5 to 5 min. the mixture of pulp, carrier gas and ozone, which has not yet been entirely consumed during the bleaching reaction, arrives at the top 25 of the reaction vessel 22. Into the reaction mixture is how fed through a conduit or line 24, at the top 25 of the reaction vessel 22 an additional bleaching chemical, for example, sodium hydroxide, hydrogen peroxide, sodium peroxide, chlorine dioxide, or the like, preferably in liquid form and if necessary with a carrier, under pressure. Preferably, the bleaching chemical is intimately mixed with the paper pulp to effect the alkaline bleaching step.
To assist the removal of the paper pulp from the first reaction vessel, vessel 22 is provided at the top portion
25 thereof with a known fluidizing device or fluidizing discharger 26 which preferably has an integral injection port for the bleaching chemical at or near the fluidizing rotor or fluidizing device or discharger 26 so as to effect the proper mixing of the bleaching chemical with the fluidized paper pulp. The fluidizing discharger 26 is preferably provided with means 28 for discharging preferably pressurized gas from the reactor to be used, for example, in another pressurized bleaching stage. To achieve good bleaching results and stable conditions the pressure in the first reaction vessel 22 should be maintained at a constant level which is achieved with a pressure regulating valve 27, preferably located closely adjacent fluidizing discharger 26, and control loop 31 in known manner.
The bleached pulp, which now contains excess ozone, carrier gas and bleaching chemical, for example, sodium hydroxide, is now discharged from first vessel 22, preferably into the enlarged inlet portion 33 of a second upright vessel 32 to assist in the separation of the gasses from the pulp mixture. Separated gas is then removed from the second vessel 32 through a gas discharge line 34. The pressure in the second vessel 32 is also maintained steady, albeit at a relatively substantially lower level than in the first vessel, generally only at slight overpressure, by a separate pressure regulating valve 36 and a control loop 37 in a known manner. The pulp is now collected in the second vessel 32 at or near a predetermined level, through known level control means 38, line 41, pump 44, and pressure regulating valve 47 for up to 1 to 3 hours to complete the alkaline (E) bleaching stage and thereafter is discharged at the bottom 42 of vessel 32 by a pump 44, which is preferably also a degassing medium consistency pump, through a valve 47 into a conduit 46 leading to a washer or other suitable treatment stage.
The elements, structure and operation of the embodiment illustrated in Fig. 2 are substantially the same as the embodiment described above in connection with Fig. 1, except that second vessel 132 is provided at its bottom 142 with an outlet 152 which is dimensioned to permit the bleached paper pulp to be fed, due to the pressure head thereof, into a suitable washer 150, preferably a drum diffusion washer as sold by assignee A. Ahlstrom Corporation, with pressurized inlet or diffuser available from Kamyr Inc. of Glens Falls, N.Y.
A level control mechanism 138 cooperates through line 148 with an rp regulator of washer 150 in known manner to maintain the paper pulp level in the second vessel 132 at a predetermined level. Finally, the washed pulp is discharged from washer 150 by a pump 144, preferably a degassing medium consistency pump through a conduit 146 for further treatment.
It is understood that additions and modifications can be made to the described embodiments which are within the scope of the present invention. The description is thus not to be construed as limiting but only as exemplary, the scope of the invention being properly delineated only in the appended claim.
Thus, while there have been shown and described and pointed out fundamental novel features of the invention as applied to preferred embodiments thereof, it will be understood that various omissions and substitutions and changes in the form and details of the disclosed invention may be made by those skilled in the art without departing from the spirit of the invention. It is the intention, however, therefore, to be limited only as indicated by the scope of the claims appended hereto.
Claims
1 . A method of ozone bleaching a medium consistency fiber suspension characterized by the steps of: a) pressure feeding said fiber suspension and an ozone containing carrier gas to a mixer; b) intimately and uniformly mixing said fiber suspension and said ozone in said mixer; c) passing said intimate and uniform mixture of fiber suspension and ozone into a first reaction vessel; d) separating said gas from said fiber suspension by moving said fiber suspension into a second, relatively larger reaction vessel; and e) adding a bleaching chemical to said fiber suspension during at least one of said steps (c) and (d); and f) removing said fiber suspension from said second reaction vessel.
2. The method of claim 1, characterized by steps of maintaining in said first reaction vessel a first pressure and maintaining in said second reaction vessel a relatively lower pressure.
3. The method of claim 2, characterized in that said pressure in said first reaction vessel is between about 3 and about 25 bar.
4. The method of claim 1, characterized in that said ozone in carrier gas is fed to said fiber suspension at a pressure of from about 3 to about 25 bar.
5. The method of claim 1, characterized in that said mixture containing ozone and fiber suspension is moved through said first reaction vessel in an upward flow direction, and said mixture is moved through said second vessel in a downflow direction.
6. The method of claim 1, characterized in that step b) is performed b -mixing with a fluidizing mixer.
7. The method of claim 1, characterized in that said added chemical is a liquid and is added in said first reaction vessel.
8. The method of claim 7, characterized in that said liquid is selected from the group consisting of sodium hydroxide, hydrogen peroxide and chlorine dioxide.
9. An apparatus for ozone bleaching a medium consistency fiber suspension characterized by a) a fluidizing mixer comprising a pulp inlet, an ozone in carrier gas inlet and an outlet for a mixture containing pulp; b) a pressurized first upflow reaction vessel having a bottom portion connected to said mixture outlet of said fluidizing mixer and a top portion; c) a second downflow vessel comprising a top portion, an inlet at said top portion connected to said top portion of said first reaction vessel, and a bottom portion; and d) means for feeding a chemical to said fiber suspension at a locus somewhere between said top portion of said first reaction vessel and said second vessel.
10. The apparatus of claim 9, characterized by means at said top portion of said first reaction vessel for fluidizing said mixture to assist the feeding of said mixture into said inlet of said second vessel.
11. The apparatus of claim 10, characterized in that said means for feeding said chemical feeds said chemical into said first vessel and is a part of said fluidizing means.
12. The apparatus of claim 9, characterized by
e) means connected to said bottom portion of said second vessel for removing said fiber suspension therefrom; f) means operatively connected to said fluidizing mixer for feeding said ozone in carrier gas under pressure to said mixer; and g) means operatively connected to said first and second vessels for controlling and maintaining the pressure therein at different levels.
13. The apparatus of claim 9, characterized in that said first and second vessels are pressurized.
14. The apparatus of claim 13, characterized in that said pressure in said first vessel is between about 3 and 25 bar.
15. The apparatus of claim 14, characterized in that said pressure is from about 5 to 14 bar.
16. The apparatus of claim 9, characterized in that said chemical feeding means comprises means for feeding a liquid chemical to said first vessel.
17. The apparatus of claim 16, characterized in that said liquid chemical is selected from the group consisting of sodium hydroxide, hydrogen peroxide, chlorine dioxide.
18. The apparatus of claim 12, characterized in that the pressure in said first vessel is controlled and maintained at a higher level than the pressure in said second vessel.
19. The method of claim 1, characterized by the additional steps of separating and removing pressurized gas from said mixture in said first vessel.
20. The method of claim 19, characterized in that said pressurized gas contains oxygen and is utilized in another pressurized bleaching stage.
21. The apparatus of claim 9, characterized by means- operatively connected to said first reaction vessel for separating and removing gas from said first reaction vessel.
22. The apparatus of claim 9, characterized by means operatively connected to said second vessel for separating and removing gas therefrom.
23. The method of claim 1, characterized in that said bleaching chemical is added to said fiber suspension while the fiber suspension is being fluidized.
24. The method of claims 1, characterized by the step of washing said bleached .fiber suspension.
25. A method of ozone bleaching a medium consistency fiber suspension, characterized by a) pressure feeding said fiber suspension and an ozone containing carrier gas to a mixer; b) intimately and uniformly mixing said fiber suspension and said ozone into a first reaction vessel; c) passing said intimate and uniform mixture of fiber suspension and ozone into a first reaction vessel; d) separating said gas from said fiber suspension and discharging said fiber suspension from said first reaction vessel by fluidizing said fiber suspension; e) adding a bleaching chemical under pressure to said fiber suspension immediately after said ozone mixing step b) during step d); and f) washing said bleached fiber suspension.
AMENDED CLAIMS
[received by the International Bureau on 27 November 1992
(27.11.92); original claims 1-25 replaced by amended claims 1-20 (4 pages)]
1 . A method of ozone bleaching of a fiber suspension having a consistency between 5 and 20 % in the following process steps: a) pressure feeding said fiber suspension and an ozone containing carrier gas to a mixer; b) intimately and uniformly mixing said fiber suspension and said ozone in said mixer; c) passing said intimate and uniform mixture of fiber suspension and ozone into a first reaction ves¬ sel; d) separating said gas from said fiber suspen- - sion by moving said fiber suspension into a second, rela- tively larger reaction vessel; and e) removing said fiber suspension from said second reaction vessel, charac erized in adding a bleaching chemical to said fiber suspension during at least one of said steps (c) and (d).
2. The method of claim 1, characterized in maintaining in said first reaction vessel a first pressure and maintain¬ ing in said second reaction vessel a relatively lower pressure, said first pressure being between about 3 and about 25 bar.
3. The method of claim 1, characterized in that said mixture containing ozone and fiber suspension is moved through said first reaction vessel in an upward flow direction, and said mixture is moved through said second vessel in a downflow direction.
4. The method of claim 1, characterized in that said added chemical is a liquid and is added in said first reaction vessel.
5. The method of claim 4, characterized in that said
liquid is selected from the group consisting of sodium hydroxide, hydrogen peroxide and chlorine dioxide.
6. The method of claim 1, characterized by the additional steps of separating and removing pressurized gas from said mixture in said first vessel.
7. The method of claim 6, character!zed in that said pressurized gas contains oxygen and is utilized in another pressurized bleaching stage.
8. The method of claim 1, characterized in that said bleaching chemical is added to said fiber suspension while the fiber suspension is being fluidized.
9. A method of ozone bleaching a medium consistency fiber suspension, said method comprising the steps of a) pressure feeding said fiber suspension and an ozone containing carrier gas to a mixer; b) intimately and uniformly mixing said fiber suspension and said ozone containing carrier gas in said mixer; c) passing said intimate and uniform mixture of fiber suspension and ozone into a first reaction vessel; characterized in d) separating said gas from said fiber suspen¬ sion and discharging said fiber suspension from said first reaction vessel by fluidizing said fiber suspension; e) adding a bleaching chemical under pressure to said fiber suspension immediately after said ozone mixing step b) during step d); and f) washing said bleached fiber suspension.
10. An apparatus for ozone bleaching a medium consistency fiber suspension, said apparatus comprising a fluidizing mixer comprising a pulp inlet, an ozone in carrier gas inlet and an outlet for a mixture containing pulp, ozone and carrier gas;
a pressurized first upflow reaction vessel having a bottom portion connected to said mixture outlet of said fluidi¬ zing mixer and a top portion; and a second downflow vessel comprising a top portion, an inlet at said top portion connected to said top portion of said first reaction vessel, and a bottom portion, charac¬ terized in means for feeding a chemical to said fiber suspension at a locus somewhere between said top portion of said first reaction vessel and said second vessel.
11. The apparatus of claim 10, characterized in means at said top portion of said first reaction vessel for fluidi¬ zing said mixture to assist the feeding of said mixture into said inlet of said second vessel.
12. The apparatus of claim 11, characterized in that said means for feeding said chemical feeds said chemical into said first vessel and is a part of said fluidizing means.
13. The apparatus of claim 10, characterized in e) means connected to said bottom portion of said second vessel for removing said fiber suspension therefrom; f) means operatively connected to said fluidi¬ zing mixer for feeding said ozone in carrier gas under pressure to said mixer; and g) means operatively connected to said . first and second vessels for controlling and maintaining the pressure therein at different levels.
14. The apparatus of claim 10, characterized in that said first and second vessels are pressurized.
15. The apparatus of claim 14, characterized in that said pressure in said first vessel is between about 3 and 25 bar, preferably from about 5 to 14 bar.
16. The apparatus of claim 10, characterized in that said chemical feeding means comprises means for feeding a liquid chemical to said first vessel.
17. The apparatus of claim 13, character!zed in that the pressure in said first vessel is controlled and maintained at a higher level than the pressure in said second vessel.
19. The apparatus of claim 10, characterized by means operatively connected to said first reaction vessel for separating and removing gas from said first reaction vessel.
20. The apparatus of claim 10, characterized by means operatively connected to said second vessel for separating and removing gas therefrom.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4511066A JPH0781239B2 (en) | 1991-06-27 | 1992-06-25 | Ozone bleaching process |
| EP92911890A EP0591264B1 (en) | 1991-06-27 | 1992-06-25 | Ozone bleaching process |
| DE69204461T DE69204461T2 (en) | 1991-06-27 | 1992-06-25 | BLEACHING METHOD BY OZONE. |
| CA002102899A CA2102899C (en) | 1991-06-27 | 1992-06-25 | Ozone bleaching process |
| FI935784A FI114719B (en) | 1991-06-27 | 1993-12-22 | Method and apparatus for ozone bleaching of pulp |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72195891A | 1991-06-27 | 1991-06-27 | |
| US721,958 | 1991-06-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1993000470A1 true WO1993000470A1 (en) | 1993-01-07 |
Family
ID=24899960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/FI1992/000198 Ceased WO1993000470A1 (en) | 1991-06-27 | 1992-06-25 | Ozone bleaching process |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5607545A (en) |
| EP (2) | EP0577157B1 (en) |
| JP (1) | JPH0781239B2 (en) |
| AU (1) | AU1973692A (en) |
| CA (1) | CA2102899C (en) |
| DE (2) | DE69204461T2 (en) |
| FI (1) | FI114719B (en) |
| MX (1) | MX9203303A (en) |
| WO (1) | WO1993000470A1 (en) |
| ZA (1) | ZA924351B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0588704A3 (en) * | 1992-09-15 | 1995-12-06 | Liquid Air Canada | Recovery of oxygen-rich gas from ozone bleaching processes |
| EP0677124B1 (en) * | 1993-06-08 | 1996-03-27 | Kvaerner Pulping Technologies AB | Process in association with pulp bleaching |
| WO1996023929A1 (en) * | 1995-01-31 | 1996-08-08 | A. Ahlstrom Corporation | Bleaching pulp with peroxide at superatmospheric pressure and in multiple stages |
| WO1997036042A1 (en) * | 1996-03-26 | 1997-10-02 | Sunds Defibrator Industries Ab | Oxygen delignification of pulp in two stages |
| EP0672209B1 (en) * | 1992-12-07 | 1998-01-21 | Ahlstrom Machinery Oy | Method and apparatus for bleaching pulp |
| WO2000020678A1 (en) * | 1998-10-08 | 2000-04-13 | Valmet Fibertech Aktiebolag | Oxygen gas bleaching of pulp |
| US6547923B1 (en) | 1989-05-10 | 2003-04-15 | Andritz Oy | Process for bleaching medium consistency pulp with ozone using a pressurized fluidizing mixer |
| EP3712323A4 (en) * | 2017-12-20 | 2020-11-11 | Unicharm Corporation | METHOD FOR MANUFACTURING RECYCLED PULP FIBERS |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6010594A (en) * | 1993-03-03 | 2000-01-04 | Ahlstrom Machinery Corporation | Method of bleaching pulp with chlorine-free chemicals wherein a complexing agent is added immediately after an ozone bleach stage |
| FR2719854B1 (en) * | 1994-05-11 | 1996-06-21 | Atochem Elf Sa | Process for the preparation of delignified and bleached chemical paper pulps. |
| SE9402542D0 (en) * | 1994-07-20 | 1994-07-20 | Kvaerner Pulping Tech | Method and apparatus for bleaching with pressurized peroxide |
| FI103818B (en) * | 1995-02-21 | 1999-09-30 | Ahlstrom Machinery Oy | Pulp Bleaching Process |
| DE19622421A1 (en) * | 1996-06-04 | 1997-12-11 | Fraunhofer Ges Forschung | Process for processing waste wood |
| US5851407A (en) * | 1996-12-04 | 1998-12-22 | Applied Process Technolgy, Inc. | Process and apparatus for oxidation of contaminants in water |
| US6024882A (en) * | 1997-08-08 | 2000-02-15 | Applied Process Technology, Inc. | Process and apparatus for water decontamination |
| AU8692998A (en) * | 1997-08-08 | 1999-03-01 | Applied Process Technology, Inc. | Process and apparatus for water decontamination |
| US20050173082A1 (en) * | 1998-08-24 | 2005-08-11 | Arbozon Oy Ltd. | Bleaching of medium consistency pulp with ozone without high shear mixing |
| SE522593C2 (en) * | 1999-07-06 | 2004-02-24 | Kvaerner Pulping Tech | Oxygen gas delignification system and method of pulp of lignocellulosic material |
| JP2002069879A (en) * | 2000-09-04 | 2002-03-08 | Nippon Paper Industries Co Ltd | Method for bleaching pulp of cellulosic fiber material |
| SE532470C2 (en) * | 2008-05-13 | 2010-02-02 | Metso Paper Inc | Final bleaching of oxygen delignified pulp with ozone, chlorine dioxide and peroxide |
| SE538752C2 (en) * | 2014-11-21 | 2016-11-08 | Innventia Ab | Process for the production of a treated pulp, treated pulp, and textile fibres produced from the treated pulp |
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| US4450044A (en) * | 1978-04-04 | 1984-05-22 | Myrens Verksted A/S | Method for bleaching oxygen delignified cellulose-containing pulp with ozone and peroxide |
| EP0397308A2 (en) * | 1989-05-10 | 1990-11-14 | A. Ahlstrom Corporation | Method of bleaching cellulose pulp with ozone |
| EP0426652A1 (en) * | 1989-10-30 | 1991-05-08 | Lenzing Aktiengesellschaft | Process for the chlorine-free bleaching of pulp |
| EP0434662A1 (en) * | 1989-12-22 | 1991-06-26 | SCHMIDDING-WERKE Wilhelm Schmidding GmbH & Co. | Process for bleaching cellulosic materials and plant for carrying out the process |
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| FI67413C (en) * | 1977-04-27 | 1985-03-11 | Myrens Verksted As | FOERFARANDE FOER BEHANDLING AV FINFOERDELAD FIBERHALTIG ELLER CELLULOSAHALTIG MASS SAMT ANORDNING FOER UTFOERANDE AV FOERFARANDET |
| DE3207157C1 (en) * | 1982-02-27 | 1983-06-09 | Degussa Ag, 6000 Frankfurt | Process for the production of semi-bleached cellulose |
| AT380496B (en) * | 1984-06-27 | 1986-05-26 | Steyrermuehl Papier | METHOD AND REACTOR FOR DELIGNIFYING CELLULAR WITH OXYGEN |
| FI79361B (en) * | 1988-01-05 | 1989-08-31 | Ahlstroem Oy | FOERFARANDE OCH APPARATUR FOER UNDERLAETTANDE AV UTTOEMNING AV FALLROER ELLER LIKNANDE OCH BEHANDLING AV MASSA I SAGDA UTRYMME. |
| US4902381A (en) * | 1988-12-09 | 1990-02-20 | Kamyr, Inc. | Method of bleaching pulp with ozone-chlorine mixtures |
| US5034095A (en) * | 1989-06-01 | 1991-07-23 | Oji Paper Co., Ltd. | Apparatus and process for the delignification of cellulose pulp |
| US5141563A (en) * | 1989-12-19 | 1992-08-25 | Eltech Systems Corporation | Molten salt stripping of electrode coatings |
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- 1992-06-15 ZA ZA924351A patent/ZA924351B/en unknown
- 1992-06-25 EP EP93114758A patent/EP0577157B1/en not_active Expired - Lifetime
- 1992-06-25 DE DE69204461T patent/DE69204461T2/en not_active Expired - Fee Related
- 1992-06-25 DE DE69230034T patent/DE69230034T2/en not_active Expired - Fee Related
- 1992-06-25 MX MX9203303A patent/MX9203303A/en unknown
- 1992-06-25 WO PCT/FI1992/000198 patent/WO1993000470A1/en not_active Ceased
- 1992-06-25 EP EP92911890A patent/EP0591264B1/en not_active Expired - Lifetime
- 1992-06-25 JP JP4511066A patent/JPH0781239B2/en not_active Expired - Fee Related
- 1992-06-25 CA CA002102899A patent/CA2102899C/en not_active Expired - Fee Related
- 1992-06-25 AU AU19736/92A patent/AU1973692A/en not_active Abandoned
- 1992-08-27 US US07/935,334 patent/US5607545A/en not_active Expired - Lifetime
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- 1993-12-22 FI FI935784A patent/FI114719B/en active IP Right Review Request
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| US4450044A (en) * | 1978-04-04 | 1984-05-22 | Myrens Verksted A/S | Method for bleaching oxygen delignified cellulose-containing pulp with ozone and peroxide |
| EP0397308A2 (en) * | 1989-05-10 | 1990-11-14 | A. Ahlstrom Corporation | Method of bleaching cellulose pulp with ozone |
| EP0426652A1 (en) * | 1989-10-30 | 1991-05-08 | Lenzing Aktiengesellschaft | Process for the chlorine-free bleaching of pulp |
| EP0434662A1 (en) * | 1989-12-22 | 1991-06-26 | SCHMIDDING-WERKE Wilhelm Schmidding GmbH & Co. | Process for bleaching cellulosic materials and plant for carrying out the process |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6547923B1 (en) | 1989-05-10 | 2003-04-15 | Andritz Oy | Process for bleaching medium consistency pulp with ozone using a pressurized fluidizing mixer |
| US5688367A (en) * | 1992-09-15 | 1997-11-18 | Canadian Liquid Air/Air Liquide Canada Ltee | Method of monitoring and recovering oxygen-rich gas from ozone bleaching |
| EP0971066A1 (en) * | 1992-09-15 | 2000-01-12 | Air Liquide Canada Inc. | Recovery of oxygen-rich gas from ozone bleaching processes |
| EP0588704A3 (en) * | 1992-09-15 | 1995-12-06 | Liquid Air Canada | Recovery of oxygen-rich gas from ozone bleaching processes |
| EP0672209B1 (en) * | 1992-12-07 | 1998-01-21 | Ahlstrom Machinery Oy | Method and apparatus for bleaching pulp |
| US5571377A (en) * | 1993-06-08 | 1996-11-05 | Kvaerner Pulping Technologies Ab | Process for peroxide bleaching of chemical pulp in a pressurized bleach vessel |
| EP0677124B1 (en) * | 1993-06-08 | 1996-03-27 | Kvaerner Pulping Technologies AB | Process in association with pulp bleaching |
| WO1996023929A1 (en) * | 1995-01-31 | 1996-08-08 | A. Ahlstrom Corporation | Bleaching pulp with peroxide at superatmospheric pressure and in multiple stages |
| WO1997036042A1 (en) * | 1996-03-26 | 1997-10-02 | Sunds Defibrator Industries Ab | Oxygen delignification of pulp in two stages |
| US6221207B1 (en) | 1996-03-26 | 2001-04-24 | Valmet Fibertech Aktiebolag | Oxygen delignification of pulp in two stages with low pressure steam heating between stages |
| WO2000020678A1 (en) * | 1998-10-08 | 2000-04-13 | Valmet Fibertech Aktiebolag | Oxygen gas bleaching of pulp |
| EP3712323A4 (en) * | 2017-12-20 | 2020-11-11 | Unicharm Corporation | METHOD FOR MANUFACTURING RECYCLED PULP FIBERS |
| US11131061B2 (en) | 2017-12-20 | 2021-09-28 | Unicharm Corporation | Method for manufacturing recycled pulp fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0781239B2 (en) | 1995-08-30 |
| ZA924351B (en) | 1993-03-31 |
| EP0577157A3 (en) | 1995-04-12 |
| JPH06502229A (en) | 1994-03-10 |
| MX9203303A (en) | 1992-12-01 |
| FI935784A0 (en) | 1993-12-22 |
| DE69230034T2 (en) | 2000-02-03 |
| EP0591264A1 (en) | 1994-04-13 |
| FI114719B (en) | 2004-12-15 |
| AU1973692A (en) | 1993-01-25 |
| CA2102899C (en) | 2007-05-01 |
| CA2102899A1 (en) | 1992-12-28 |
| EP0577157B1 (en) | 1999-09-22 |
| FI935784L (en) | 1993-12-22 |
| US5607545A (en) | 1997-03-04 |
| DE69204461D1 (en) | 1995-10-05 |
| DE69230034D1 (en) | 1999-10-28 |
| EP0591264B1 (en) | 1995-08-30 |
| EP0577157A2 (en) | 1994-01-05 |
| DE69204461T2 (en) | 1996-03-07 |
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