WO1993017065A3 - PROCESS FOR PRODUCING A CROSSLINKED POLYMER USING A β-DICARBONYL COMPOUND - Google Patents

PROCESS FOR PRODUCING A CROSSLINKED POLYMER USING A β-DICARBONYL COMPOUND Download PDF

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Publication number
WO1993017065A3
WO1993017065A3 PCT/US1993/002662 US9302662W WO9317065A3 WO 1993017065 A3 WO1993017065 A3 WO 1993017065A3 US 9302662 W US9302662 W US 9302662W WO 9317065 A3 WO9317065 A3 WO 9317065A3
Authority
WO
WIPO (PCT)
Prior art keywords
formaldehyde
released
crosslinking
crosslinked polymer
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1993/002662
Other languages
French (fr)
Other versions
WO1993017065A2 (en
Inventor
Christopher J Bradford
Adriana Ticu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Corp
Original Assignee
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Corp filed Critical BASF Corp
Priority to CA002115658A priority Critical patent/CA2115658C/en
Priority to JP51129793A priority patent/JP3247112B2/en
Priority to ES93913772T priority patent/ES2164664T3/en
Priority to BR9206765A priority patent/BR9206765A/en
Priority to EP93913772A priority patent/EP0598886B1/en
Priority to DE69232071T priority patent/DE69232071T2/en
Publication of WO1993017065A2 publication Critical patent/WO1993017065A2/en
Publication of WO1993017065A3 publication Critical patent/WO1993017065A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paints Or Removers (AREA)

Abstract

In a process for crosslinking a polymer, a β-dicarbonyl functionality is present as a reactive diluent and/or as a reactive solvent and/or on a crosslinking entity. The β-difunctional compound reacts with formaldehyde which is either released during the crosslinking reaction (or otherwise present) whereby less formaldehyde is released than would otherwise be released. The formaldehyde which reacts with the β-dicarbonyl compound is either incorporated into the crosslinked polymer network or released in the form of a reaction product which is not as harmful to the environment as the unreacted formaldehyde. The process enables the reduction of formaldehyde release during crosslinking to levels otherwise unobtainable. Furthermore, the process enables a reduction in the amount of organic solvent utilized.
PCT/US1993/002662 1991-08-15 1992-07-29 PROCESS FOR PRODUCING A CROSSLINKED POLYMER USING A β-DICARBONYL COMPOUND Ceased WO1993017065A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA002115658A CA2115658C (en) 1991-08-15 1992-07-29 Process for producing a crosslinked polymer using a .beta.-dicarbonyl compound
JP51129793A JP3247112B2 (en) 1991-08-15 1992-07-29 Method for producing crosslinked polymer using β-dicarbonyl compound
ES93913772T ES2164664T3 (en) 1991-08-15 1992-07-29 PROCEDURE FOR THE PRODUCTION OF A RETICULATED POLYMER THROUGH THE USE OF A BETA-DICARBONILIC COMPOUND.
BR9206765A BR9206765A (en) 1991-08-15 1992-07-29 Process for the production of a cross-linked polymer using a beta-dicarbonyl compound
EP93913772A EP0598886B1 (en) 1991-08-15 1992-07-29 Process for producing a crosslinked polymer using a beta-dicarbonyl compound
DE69232071T DE69232071T2 (en) 1991-08-15 1992-07-29 METHOD FOR PRODUCING A POLYMER CROSSLINKED WITH A BETA-DICARBONYL COMPOUND

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US74540791A 1991-08-15 1991-08-15
US07/745,407 1991-08-15

Publications (2)

Publication Number Publication Date
WO1993017065A2 WO1993017065A2 (en) 1993-09-02
WO1993017065A3 true WO1993017065A3 (en) 1993-10-28

Family

ID=24996562

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/002662 Ceased WO1993017065A2 (en) 1991-08-15 1992-07-29 PROCESS FOR PRODUCING A CROSSLINKED POLYMER USING A β-DICARBONYL COMPOUND

Country Status (9)

Country Link
US (1) US5552488A (en)
EP (1) EP0598886B1 (en)
JP (1) JP3247112B2 (en)
BR (1) BR9206765A (en)
CA (1) CA2115658C (en)
DE (1) DE69232071T2 (en)
ES (1) ES2164664T3 (en)
MX (1) MX9204705A (en)
WO (1) WO1993017065A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4406858A1 (en) * 1994-03-02 1995-09-07 Thera Ges Fuer Patente Prepolymers and free-radically polymerizable preparations made therefrom and processes for their preparation
DE19620351A1 (en) * 1996-05-21 1997-11-27 Buna Sow Leuna Olefinverb Gmbh Binder combination for thick-layer lacquers etc.
US6232368B1 (en) 1999-10-12 2001-05-15 Borden Chemical, Inc. Ester cured binders
US7381347B2 (en) * 2003-03-31 2008-06-03 Cytec Technology Corp. Crosslinking composition
US7442325B2 (en) 2004-09-29 2008-10-28 Cytec Technology Corp. Stabilized crosslinking composition
AU2008207325A1 (en) * 2007-01-19 2008-07-24 Dynea Oy Phenol-formaldehyde resins, method for the production thereof and use thereof as binders
CA2752572C (en) 2009-02-17 2014-09-16 Shaobing Wu Solvent-borne coating composition containing acetoacyl-functional polymers
WO2016069572A1 (en) * 2014-10-27 2016-05-06 Eastman Chemical Company Resole phenolic resins curable with functional polyesters
EA037245B1 (en) * 2015-04-14 2021-02-25 Хюттенес-Альбертус Хемише Верке Гезелльшафт Мит Бешренктер Хафтунг Phenolic resin composition for use in the polyurethane cold-box and/or no-bake process and corresponding two-component binder system, use and process
DE102018133239A1 (en) * 2018-12-20 2020-06-25 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung Isocyanate composition and binder system containing this isocyanate composition

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4172822A (en) * 1977-06-06 1979-10-30 Herberts Gesellschaft Mit Beschrankter Haftung Aqueous coating compositions containing polyester containing carboxyl groups
US4987186A (en) * 1987-12-29 1991-01-22 Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha Pressure sensitive adhesive composition

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3892903A (en) * 1971-03-04 1975-07-01 Ppg Industries Inc Method of coating surfaces with high solids thermosetting beta-keto ester coating compositions and the resulting coated article
US4689373A (en) * 1985-10-24 1987-08-25 Celanese Corporation Use of amino resins to improve properties of oxymethylene polymer molding compositions
US5194674A (en) * 1986-09-02 1993-03-16 West Point Pepperell Water-soluble active methylene as formaldehyde scavenger
US5268502A (en) * 1986-09-02 1993-12-07 West Point Pepperell Water-soluble active methylenes as formaldehyde scavengers
AU1939388A (en) * 1987-05-20 1988-12-21 West Point-Pepperell Inc. Water-soluble active methylenes as formaldehyde scavengers
US4935149A (en) * 1989-01-12 1990-06-19 Calgon Corporation Low free formaldehyde melamine-formaldehyde detackifier and method of using
US5160503A (en) * 1989-11-13 1992-11-03 West Point Pepperell Water-soluble blends of active methylene compounds and polyhydric alcohols as formaldehyde scavengers
GB9006902D0 (en) * 1990-03-28 1990-05-23 Alcan Int Ltd Polyester amino resin paint systems
JPH06505738A (en) 1991-02-14 1994-06-30 イーストマン ケミカル カンパニー thermosetting coating composition
US5276130A (en) * 1991-10-30 1994-01-04 Basf Corporation Aminoplast resin or aminoplast resin precursor
US5288820A (en) * 1993-03-01 1994-02-22 Eastman Kodak Company Thermosetting coating compositions

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4172822A (en) * 1977-06-06 1979-10-30 Herberts Gesellschaft Mit Beschrankter Haftung Aqueous coating compositions containing polyester containing carboxyl groups
US4987186A (en) * 1987-12-29 1991-01-22 Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha Pressure sensitive adhesive composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0598886A4 *

Also Published As

Publication number Publication date
CA2115658C (en) 2000-05-09
WO1993017065A2 (en) 1993-09-02
DE69232071D1 (en) 2001-10-25
JPH06510328A (en) 1994-11-17
MX9204705A (en) 1993-07-01
BR9206765A (en) 1995-10-24
ES2164664T3 (en) 2002-03-01
EP0598886A4 (en) 1994-11-17
US5552488A (en) 1996-09-03
EP0598886B1 (en) 2001-09-19
JP3247112B2 (en) 2002-01-15
CA2115658A1 (en) 1993-02-16
EP0598886A1 (en) 1994-06-01
DE69232071T2 (en) 2002-05-16

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