WO1994000609A1 - Material de friccion destinado a ser utilizado en un sistema tribologico lubricado - Google Patents
Material de friccion destinado a ser utilizado en un sistema tribologico lubricado Download PDFInfo
- Publication number
- WO1994000609A1 WO1994000609A1 PCT/ES1993/000052 ES9300052W WO9400609A1 WO 1994000609 A1 WO1994000609 A1 WO 1994000609A1 ES 9300052 W ES9300052 W ES 9300052W WO 9400609 A1 WO9400609 A1 WO 9400609A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- particles
- material according
- matrix
- friction
- chosen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
- F16D69/02—Composition of linings ; Methods of manufacturing
- F16D69/027—Compositions based on metals or inorganic oxides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
Definitions
- This invention concerns friction materials for lubricated tribological systems and in particular, but not exclusively, for the manufacture of synchronizer rings used in manual gearboxes.
- the aim of the invention is to provide a friction material that allows a high coefficient of friction to be obtained and which allows to obtain pieces of complex geometry at less cost.
- the invention provides It is a friction material for lubricated systems, consisting of a metal matrix with inclusions of high hardness particles. This material has the peculiarity that the particles are between 50 and 300 meters in size.
- the material of the particles is chosen from those having a hardness greater than 600 HVO.1.
- the particle material is chosen from those that maintain its hardness and have a "passivable" surface by reaction with the lubricated system.
- a "passivable” surface means a surface that when immersed in the medium considered, creates a continuous reaction surface that constitutes a barrier between the material and the environment.
- this matrix is bronze.
- the matrix is made of steel.
- the particles constitute 5% to 40% of the total weight.
- the desired effect is obtained to an insufficient degree.
- the manufacture of the material by sintering or other means is of increasing difficulty.
- Tables I and II show the results of 23 tests that allow comparing specimens according to the invention and different reference specimens. These tests consist of the test of cylindrical specimens of 3 mm in diameter on a tribometer.
- the tribometer is of the bolt and disc type and is equipped to ensure the lubrication of the contact and allow adjustment of the temperature, the contact pressure and the speed of rotation of the disk.
- the friction coefficients shown in Table II have been obtained from friction forces measured in the tribometer.
- the sliding speeds have been varied between 0.34 m / ⁇ , which corresponds to the current technology to the limit lubrication (coefficient of friction greater than 0.1), or mixed (coefficient of friction between 0.1 and 0.03 ) and 1.7 m / s corresponding, according to current technology, to the hydrodynamic lubrication regime (friction coefficient less than 0.03).
- Tests 1 to 3 have been done with test pieces machined on a brass bar rich in silicon. This composition is generally used for the manufacture of synchronizer rings used in manual gearboxes. In test 3 the specimens were machined with grooves 0.5 mm deep and crest width, as well as a valley bottom width of 0.2 mm.
- Test specimens 4 were obtained by spraying molybdenum at high temperature on a brass substrate.
- Test specimens 5 and 7 consist of a bronze matrix with graphite and iron particles. This metallurgy is frequently used in sintered friction materials.
- test specimens 8 and 12 are manufactured to check the friction properties of the molten metal in the form of inclusion in a ductile matrix.
- Test specimens 9 and 23 have been manufactured to test the properties of the matrix without additives.
- Test specimens 10, 11, 19 and 21 have inclusions rich in chromium, but of a hardness less than that required in the invention. These specimens serve as a reference for test 18.
- Test specimens 13, 14, 16 and 18 correspond to the invention with inclusions percentages of 5%, 15% and 20%. They have been manufactured by the classical procedures of powder metallurgy (compaction and sintering of a powder mixture).
- test specimens 15 are identical to those in test 14, except that slots of depth 0.3 mm and crest width have been machined, as well as a valley bottom width of 0.2 mm.
- Test specimens 20 also correspond to the invention, but contain inclusions of a different alloy and therefore of different hardness.
- Test specimens 22 have the same composition as in test 18, but the particle size is smaller than that required by the invention. It has been proven by examining the friction surface, especially in test 14, that inclusions appear without being affected by the lubricating oil, in contrast to the bronze matrix that undergoes strong color changes. The comparison of tests 14 and 15 indicates that the presence of grooves adds a small improvement, but that they can be suppressed without major inconvenience.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Operated Clutches (AREA)
- Lubricants (AREA)
- Powder Metallurgy (AREA)
Abstract
Description
Claims
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/199,125 US5540750A (en) | 1992-06-22 | 1993-06-22 | Friction material for lubircated tribological systems |
| EP93913031A EP0721018B1 (fr) | 1992-06-22 | 1993-06-22 | Materiau de friction pour systemes tribologiques lubrifies |
| BR9305571A BR9305571A (pt) | 1992-06-22 | 1993-06-22 | Material de fricção para ser utilizado em sistemas tribológicos lubrificados |
| JP6502066A JPH07508799A (ja) | 1992-06-22 | 1993-06-22 | 潤滑化された摩擦系で使用され得る軋轢物質 |
| DE69327258T DE69327258T2 (de) | 1992-06-22 | 1993-06-22 | Reibungsmaterial zur verwendung in geschmierten tribologischen systemen |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9207564A FR2692506B1 (fr) | 1992-06-22 | 1992-06-22 | Materiau de friction destine a etre utilise dans un systeme tribologique lubrifie |
| FR92/07564 | 1992-06-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1994000609A1 true WO1994000609A1 (es) | 1994-01-06 |
Family
ID=9430997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/ES1993/000052 Ceased WO1994000609A1 (es) | 1992-06-22 | 1993-06-22 | Material de friccion destinado a ser utilizado en un sistema tribologico lubricado |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5540750A (es) |
| EP (1) | EP0721018B1 (es) |
| JP (1) | JPH07508799A (es) |
| BR (1) | BR9305571A (es) |
| DE (1) | DE69327258T2 (es) |
| ES (1) | ES2142872T3 (es) |
| FR (1) | FR2692506B1 (es) |
| WO (1) | WO1994000609A1 (es) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6844085B2 (en) | 2001-07-12 | 2005-01-18 | Komatsu Ltd | Copper based sintered contact material and double-layered sintered contact member |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4445898A1 (de) * | 1994-12-22 | 1996-06-27 | Schaeffler Waelzlager Kg | Reibpaarung für eine Synchronisiereinrichtung in Zahnräderwechselgetrieben |
| US6191204B1 (en) | 1998-06-25 | 2001-02-20 | Caterpillar Inc. | Tribological performance of thermoplastic composite via thermally conductive material and other fillers and a process for making the composite and molded articles of the same |
| FR2834999B1 (fr) * | 2002-01-21 | 2004-06-18 | Delachaux Sa | Procede de fabrication d'elements metalliques de purete elevee |
| US20030209103A1 (en) * | 2002-05-10 | 2003-11-13 | Komatsu Ltd. | Cooper-based sintering sliding material and multi-layered sintered sliding member |
| DE10239093B4 (de) * | 2002-08-26 | 2005-11-03 | Diehl Metall Stiftung & Co.Kg | In einem Medium laufende Reibschicht |
| US7211323B2 (en) * | 2003-01-06 | 2007-05-01 | U Chicago Argonne Llc | Hard and low friction nitride coatings and methods for forming the same |
| US7251893B2 (en) * | 2003-06-03 | 2007-08-07 | Massachusetts Institute Of Technology | Tribological applications of polyelectrolyte multilayers |
| US7094474B2 (en) * | 2004-06-17 | 2006-08-22 | Caterpillar, Inc. | Composite powder and gall-resistant coating |
| ES2399377T3 (es) * | 2009-09-24 | 2013-04-01 | Otto Fuchs Kg | Paquete de anillos de sincronización |
| CN103298967B (zh) | 2010-12-08 | 2016-07-06 | 盖伦国际公司 | 硬且低摩擦的氮化物涂层 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2207193A1 (es) * | 1972-11-17 | 1974-06-14 | Union Carbide Corp | |
| DE2354826A1 (de) * | 1973-11-02 | 1975-05-07 | Porsche Ag | Gleichlaufeinrichtung, insbesondere fuer geschwindigkeitswechselgetriebe fuer kraftfahrzeuge |
| DE3808460A1 (de) * | 1987-03-13 | 1988-09-22 | Mitsubishi Metal Corp | Verschleissfeste sinterlegierung auf eisen-basis und aus dieser legierung bestehender synchronring fuer einen geschwindigkeitsregler |
| EP0407596A1 (en) * | 1988-10-26 | 1991-01-16 | Mitsubishi Materials Corporation | Copper-based sintered alloy |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB823675A (en) * | 1956-07-30 | 1959-11-18 | Bendix Aviat Corp | Friction article and method of producing same |
| DE3122522A1 (de) * | 1981-06-05 | 1982-12-23 | Hermann Dipl.-Ing. 8033 Planegg Pflaum | Synchronisiereinrichtung fuer formschluessige schaltkupplungen sowie verfahren zur herstellung einer solchen synchronisiereinrichtung |
| US5326384A (en) * | 1990-07-31 | 1994-07-05 | Taiho Kogyo Co., Ltd. | Sliding material |
| US5290507A (en) * | 1991-02-19 | 1994-03-01 | Runkle Joseph C | Method for making tool steel with high thermal fatigue resistance |
-
1992
- 1992-06-22 FR FR9207564A patent/FR2692506B1/fr not_active Expired - Lifetime
-
1993
- 1993-06-22 EP EP93913031A patent/EP0721018B1/fr not_active Expired - Lifetime
- 1993-06-22 US US08/199,125 patent/US5540750A/en not_active Expired - Fee Related
- 1993-06-22 ES ES93913031T patent/ES2142872T3/es not_active Expired - Lifetime
- 1993-06-22 WO PCT/ES1993/000052 patent/WO1994000609A1/es not_active Ceased
- 1993-06-22 BR BR9305571A patent/BR9305571A/pt not_active Application Discontinuation
- 1993-06-22 DE DE69327258T patent/DE69327258T2/de not_active Expired - Fee Related
- 1993-06-22 JP JP6502066A patent/JPH07508799A/ja active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2207193A1 (es) * | 1972-11-17 | 1974-06-14 | Union Carbide Corp | |
| DE2354826A1 (de) * | 1973-11-02 | 1975-05-07 | Porsche Ag | Gleichlaufeinrichtung, insbesondere fuer geschwindigkeitswechselgetriebe fuer kraftfahrzeuge |
| DE3808460A1 (de) * | 1987-03-13 | 1988-09-22 | Mitsubishi Metal Corp | Verschleissfeste sinterlegierung auf eisen-basis und aus dieser legierung bestehender synchronring fuer einen geschwindigkeitsregler |
| EP0407596A1 (en) * | 1988-10-26 | 1991-01-16 | Mitsubishi Materials Corporation | Copper-based sintered alloy |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6844085B2 (en) | 2001-07-12 | 2005-01-18 | Komatsu Ltd | Copper based sintered contact material and double-layered sintered contact member |
| US7056598B2 (en) | 2001-07-12 | 2006-06-06 | Komatsu, Ltd. | Copper based sintered contact material and double-layered sintered contact member |
| US7087318B2 (en) | 2001-07-12 | 2006-08-08 | Komatsu Ltd. | Copper based sintered contact material and double-layered sintered contact member |
| US7261951B2 (en) | 2001-07-12 | 2007-08-28 | Komatsu Ltd | Copper based sintered contact material and double-layered sintered contact member |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69327258D1 (de) | 2000-01-13 |
| FR2692506B1 (fr) | 1997-02-14 |
| JPH07508799A (ja) | 1995-09-28 |
| ES2142872T3 (es) | 2000-05-01 |
| BR9305571A (pt) | 1996-01-09 |
| DE69327258T2 (de) | 2000-03-30 |
| EP0721018A1 (fr) | 1996-07-10 |
| FR2692506A1 (fr) | 1993-12-24 |
| US5540750A (en) | 1996-07-30 |
| EP0721018B1 (fr) | 1999-12-08 |
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