WO1994007944A1 - Compositions, articles and methods for scavenging oxygen which have improved physical properties - Google Patents

Compositions, articles and methods for scavenging oxygen which have improved physical properties Download PDF

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Publication number
WO1994007944A1
WO1994007944A1 PCT/US1993/009126 US9309126W WO9407944A1 WO 1994007944 A1 WO1994007944 A1 WO 1994007944A1 US 9309126 W US9309126 W US 9309126W WO 9407944 A1 WO9407944 A1 WO 9407944A1
Authority
WO
WIPO (PCT)
Prior art keywords
articles
compositions
methods
physical properties
improved physical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1993/009126
Other languages
French (fr)
Inventor
Drew Ve Speer
William Peyton Roberts
Charles Robert Morgan
Ram Kumar Ramesh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co Conn
WR Grace and Co
Original Assignee
WR Grace and Co Conn
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to AU51403/93A priority Critical patent/AU673011B2/en
Priority to FI951538A priority patent/FI951538A7/en
Priority to CA002146133A priority patent/CA2146133C/en
Priority to DK93922392T priority patent/DK0662986T3/en
Priority to KR1019950701294A priority patent/KR950703601A/en
Priority to BR9307156A priority patent/BR9307156A/en
Application filed by WR Grace and Co Conn, WR Grace and Co filed Critical WR Grace and Co Conn
Priority to EP93922392A priority patent/EP0662986B1/en
Priority to JP6509204A priority patent/JP3064420B2/en
Priority to DE69323319T priority patent/DE69323319T2/en
Publication of WO1994007944A1 publication Critical patent/WO1994007944A1/en
Anticipated expiration legal-status Critical
Priority to GR990401050T priority patent/GR3029971T3/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/10—Metal compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/012—Additives improving oxygen scavenging properties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)
  • Packages (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Wrappers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Gas Separation By Absorption (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Bag Frames (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

A composition for scavenging oxygen is disclosed. The composition comprises an ethylenically unsaturated hydrocarbon polymer which has 0.01-1.0 equivalents of carbon-carbon double bonds per 100 g of polymer and a transition metal catalyst and can be incorporated into various types of layers. The composition has an elongation-at-break of at least 20 % and retains at least 50 % of its original tensile strength after oxygen scavenging has occurred.
PCT/US1993/009126 1992-10-01 1993-09-24 Compositions, articles and methods for scavenging oxygen which have improved physical properties Ceased WO1994007944A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
EP93922392A EP0662986B1 (en) 1992-10-01 1993-09-24 Packaging material for scavenging oxygen which has improved physical properties
FI951538A FI951538A7 (en) 1992-10-01 1993-09-24 Compositions, articles and methods for removing oxygen with improved physical properties
CA002146133A CA2146133C (en) 1992-10-01 1993-09-24 Compositions, articles and methods for scavenging oxygen which have improved physical properties
DK93922392T DK0662986T3 (en) 1992-10-01 1993-09-24 Packaging material with improved physical properties for oxygen binding
KR1019950701294A KR950703601A (en) 1992-10-01 1993-09-24 Compositions, articles, and methods for oxygen removal with improved physical properties
AU51403/93A AU673011B2 (en) 1992-10-01 1993-09-24 Compositions, articles and methods for scavenging oxygen which have improved physical properties
DE69323319T DE69323319T2 (en) 1992-10-01 1993-09-24 PACKAGING MATERIAL WITH IMPROVED PHYSICAL PROPERTIES FOR THE REMOVAL OF OXYGEN
BR9307156A BR9307156A (en) 1992-10-01 1993-09-24 Compositions articles and processes for absorbing oxygen from oxygen that have improved physical properties
JP6509204A JP3064420B2 (en) 1992-10-01 1993-09-24 Oxygen scavenging compositions, articles and methods with improved physical properties
GR990401050T GR3029971T3 (en) 1992-10-01 1999-04-16 Compositions, articles and methods for scavenging oxygen which have improved physical properties.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/955,547 US5399289A (en) 1992-10-01 1992-10-01 Compositions, articles and methods for scavenging oxygen which have improved physical properties
US07/955,547 1992-10-01

Publications (1)

Publication Number Publication Date
WO1994007944A1 true WO1994007944A1 (en) 1994-04-14

Family

ID=25496968

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/009126 Ceased WO1994007944A1 (en) 1992-10-01 1993-09-24 Compositions, articles and methods for scavenging oxygen which have improved physical properties

Country Status (16)

Country Link
US (1) US5399289A (en)
EP (2) EP0854166B1 (en)
JP (1) JP3064420B2 (en)
KR (1) KR950703601A (en)
AT (2) ATE176263T1 (en)
AU (1) AU673011B2 (en)
BR (1) BR9307156A (en)
CA (1) CA2146133C (en)
DE (2) DE69333159T2 (en)
DK (1) DK0662986T3 (en)
ES (1) ES2128439T3 (en)
FI (1) FI951538A7 (en)
GR (1) GR3029971T3 (en)
IL (1) IL107136A (en)
NZ (1) NZ256614A (en)
WO (1) WO1994007944A1 (en)

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US5552556A (en) * 1994-08-31 1996-09-03 The Procter & Gamble Company Perhydrolysis-selective bleach activators
US5578136A (en) * 1994-08-31 1996-11-26 The Procter & Gamble Company Automatic dishwashing compositions comprising quaternary substituted bleach activators
US5686015A (en) * 1994-08-31 1997-11-11 The Procter & Gamble Company Quaternary substituted bleach activators
WO1998005555A3 (en) * 1996-08-02 1998-08-06 Grace W R & Co Method, apparatus, and system for triggering oxygen scavenging films
WO1999015433A1 (en) * 1996-09-23 1999-04-01 Bp Amoco Corporation Active oxygen scavenger compositions and their use in packaging articles
WO2000011972A1 (en) * 1998-08-27 2000-03-09 Chevron Phillips Chemical Company Lp Oxygen scavenging packaging
WO2001003521A1 (en) * 1999-07-09 2001-01-18 Cryovac, Inc. Oxygen scavenging composition
EP0685523B1 (en) * 1994-06-01 2003-05-14 Cryovac, Inc. Method for packing a food product
RU2204512C2 (en) * 1998-03-17 2003-05-20 Бп Корпорейшн Норт Америка Инк. Active oxygen absorbing composite materials and their use in packing containers
US7427436B2 (en) 2004-11-24 2008-09-23 Toyo Seikan Kaisha, Ltd. Oxygen-absorbing resin compositions
EP2065443A4 (en) * 2006-09-12 2010-12-08 Kuraray Co RESIN COMPOSITION ABSORBING OXYGEN
EP3118228A1 (en) 2015-07-14 2017-01-18 Evonik Degussa GmbH Method for the preparation of polyalkenamers for packaging applications
DE102015215387A1 (en) 2015-08-12 2017-02-16 Evonik Degussa Gmbh Process for the preparation of polyalkenamers for packaging applications
EP3153227A1 (en) 2015-10-07 2017-04-12 Evonik Degussa GmbH Method for the preparation of polyalkenamers for packaging applications
EP3360904A1 (en) 2017-02-10 2018-08-15 Evonik Degussa GmbH Process for preparing polyalkenamers for packaging applications

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US5627239A (en) * 1993-07-13 1997-05-06 Chevron Chemical Company Compositions having ethylenic backbone and benzylic, allylic, or ether-containing side-chains, oxygen scavenging compositions containing same, and process for making these compositions by esterification or transesterification of a polymer melt
US5698250A (en) 1996-04-03 1997-12-16 Tenneco Packaging Inc. Modifield atmosphere package for cut of raw meat
US5830545A (en) * 1996-04-29 1998-11-03 Tetra Laval Holdings & Finance, S.A. Multilayer, high barrier laminate
DK0915930T3 (en) 1996-08-02 2003-03-10 Cryovac Inc Method for activating pulsed light oxygen scavenging composition
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US6926846B1 (en) 1996-08-08 2005-08-09 Pactiv Corporation Methods of using an oxygen scavenger
US5928560A (en) 1996-08-08 1999-07-27 Tenneco Packaging Inc. Oxygen scavenger accelerator
US6395195B1 (en) 1996-08-08 2002-05-28 Pactiv Corporation Oxygen scavenger accelerator
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US5804236A (en) * 1996-09-26 1998-09-08 Frisk; Peter Oxygen scavenging container
US6254802B1 (en) 1997-05-16 2001-07-03 Cryovac, Inc. Low migratory photoinitiators for oxygen-scavenging compositions
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IL107136A0 (en) 1993-12-28
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ATE176263T1 (en) 1999-02-15
US5399289A (en) 1995-03-21
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DE69333159T2 (en) 2004-06-09
AU673011B2 (en) 1996-10-24
KR950703601A (en) 1995-09-20
JP3064420B2 (en) 2000-07-12
FI951538A0 (en) 1995-03-31
AU5140393A (en) 1994-04-26
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EP0662986A1 (en) 1995-07-19

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