WO1995001400A3 - Folie oder formkörper aus einem mehrphasigen kunststoff sowie dessen verwendung zur herstellung von verbundfolien - Google Patents

Folie oder formkörper aus einem mehrphasigen kunststoff sowie dessen verwendung zur herstellung von verbundfolien Download PDF

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Publication number
WO1995001400A3
WO1995001400A3 PCT/EP1994/002157 EP9402157W WO9501400A3 WO 1995001400 A3 WO1995001400 A3 WO 1995001400A3 EP 9402157 W EP9402157 W EP 9402157W WO 9501400 A3 WO9501400 A3 WO 9501400A3
Authority
WO
WIPO (PCT)
Prior art keywords
asa
sheeting
modified
elastomer
softener
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1994/002157
Other languages
English (en)
French (fr)
Other versions
WO1995001400A2 (de
Inventor
Dirk Leiss
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Benecke Kaliko AG
Original Assignee
Benecke Kaliko AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6491861&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1995001400(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Benecke Kaliko AG filed Critical Benecke Kaliko AG
Priority to US08/392,838 priority Critical patent/US5683815A/en
Priority to EP94923709A priority patent/EP0658178B1/de
Publication of WO1995001400A2 publication Critical patent/WO1995001400A2/de
Publication of WO1995001400A3 publication Critical patent/WO1995001400A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
    • Y10T428/31576—Ester monomer type [polyvinylacetate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
    • Y10T428/31583—Nitrile monomer type [polyacrylonitrile, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
    • Y10T428/31587—Hydrocarbon polymer [polyethylene, polybutadiene, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Laminated Bodies (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)

Abstract

Die Erfindung betrifft eine Folie oder einen Formkörper aus einem mehrphasigen thermoplastischen Kunststoff, der einen elastomermodifizierten Thermoplasten, einen Modifikator und andere übliche Zusatzstoffe enthält, wobei der elastomermodifizierte Thermoplast ein Acrylnitril-Styrol-Acrylester-Copolymer (ASA) eines Acrylesteranteils von etwa 25 bis 80 Gew.-% ist und die gewünschte Härte bzw. Weichheit des ASA durch Einverleibung eines Modifikators gesteuert ist, wobei dem ASA-Copolymer 1) zur Weichmachung eines härteren ASA-Copolymers ein äußerer Weichmacher in Form a) eines monomeren oder oligomeren Weichmachers, der zur Weichmachung von PVC üblich ist, und/oder b) eines amorphen oder teilkristallinen polymeren Weichmachers eines Kristallinitätsgrades von höchstens etwa 25 % einverleibt ist, wobei das Mischungsverhältnis (Gewicht/Gewicht) von hartem elastomermodifiziertem Acrylnitril-Styrol-Acrylester-Copolymer (ASA) zu dem äußeren Weichmacher etwa 9:1 bis 1:1 beträgt, und 2) zur Anhebung der Härte eines weichen ASA-Copolymers ein Polymer hinreichender Verträglichkeit mit dem ASA-Copolymer und eines E-Moduls von » 2000 N/mm2, einverleibt ist, wobei das Mischungsverhältnis von weichem ASA-Copolymer zu härtendem Copolymer etwa 20:1 bis 1:1 beträgt. Diese Folie eignet sich insbesondere zur Verwendung in Form einer Verbundfolie zur Innenverkleidung von Fahrzeugen.
PCT/EP1994/002157 1993-07-02 1994-07-01 Folie oder formkörper aus einem mehrphasigen kunststoff sowie dessen verwendung zur herstellung von verbundfolien Ceased WO1995001400A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US08/392,838 US5683815A (en) 1993-07-02 1994-07-01 Sheeting and molding made of multi-phase plastic and its use in the manufacture of composite sheeting
EP94923709A EP0658178B1 (de) 1993-07-02 1994-07-01 Folie oder formkörper aus einem mehrphasigen kunststoff sowie dessen verwendung zur herstellung von verbundfolien

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4322145.9 1993-07-02
DE4322145A DE4322145C2 (de) 1993-07-02 1993-07-02 Folie oder Formkörper aus einem mehrphasigen Kunststoff sowie dessen Verwendung zur Herstellung von Verbundfolien

Publications (2)

Publication Number Publication Date
WO1995001400A2 WO1995001400A2 (de) 1995-01-12
WO1995001400A3 true WO1995001400A3 (de) 1995-02-16

Family

ID=6491861

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1994/002157 Ceased WO1995001400A2 (de) 1993-07-02 1994-07-01 Folie oder formkörper aus einem mehrphasigen kunststoff sowie dessen verwendung zur herstellung von verbundfolien

Country Status (6)

Country Link
US (1) US5683815A (de)
EP (1) EP0658178B1 (de)
AT (1) ATE161869T1 (de)
DE (1) DE4322145C2 (de)
ES (1) ES2112554T3 (de)
WO (1) WO1995001400A2 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4437501A1 (de) * 1994-10-20 1996-04-25 Basf Ag Thermoplastische Formmassen
FR2736978B1 (fr) 1995-07-21 1998-12-24 Moulinex Sa Charniere pour couvercle de boitier d'appareil de cuisson et son procede de montage
US5814702A (en) * 1996-02-20 1998-09-29 General Electric Company Elastomer composition and thermoplastic resin composition modified therewith
EP0910058B1 (de) * 1997-10-14 2002-02-06 Minnesota Mining And Manufacturing Company Recyclierbares Etikett
EP0963837A1 (de) * 1998-06-09 1999-12-15 The Procter & Gamble Company Wasserdampfdurchlässige Verbundstruktur und deren Verwendung in Saugkörper
US7271209B2 (en) 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
US7998579B2 (en) 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
US7622523B2 (en) 2002-08-12 2009-11-24 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
CN100345896C (zh) 2002-08-12 2007-10-31 埃克森美孚化学专利公司 增塑聚烯烃组合物
US7531594B2 (en) 2002-08-12 2009-05-12 Exxonmobil Chemical Patents Inc. Articles from plasticized polyolefin compositions
US8003725B2 (en) 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
KR100509868B1 (ko) * 2003-06-09 2005-08-22 주식회사 엘지화학 내후성 및 외관특성이 우수한 열가소성 수지 조성물
US8192813B2 (en) 2003-08-12 2012-06-05 Exxonmobil Chemical Patents, Inc. Crosslinked polyethylene articles and processes to produce same
US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
WO2007011530A2 (en) 2005-07-15 2007-01-25 Exxonmobil Chemical Patents, Inc. Elastomeric compositions
US7740951B2 (en) * 2007-04-11 2010-06-22 Lyondellbasell Advanced Polyolefins Usa Inc. Multilayered polymeric structure and methods
DE202007016189U1 (de) * 2007-11-19 2009-04-02 Rehau Ag + Co Verarbeitungshilfe
US20110024939A1 (en) * 2009-07-28 2011-02-03 Nilton Pereira Alves Thermoplastic polyacrylonitrile production process
DE102011014989A1 (de) * 2011-03-24 2012-09-27 Webasto Ag Kunststoffbauelement eines Dachöffnungssystems
US10329393B2 (en) 2012-12-12 2019-06-25 Eastman Chemical Company Copolysters plasticized with polymeric plasticizer for shrink film applications
CN112677588A (zh) * 2020-11-17 2021-04-20 苏州洛瑞卡新材料科技有限公司 一种asa双层复合覆膜
US11480008B1 (en) * 2022-03-28 2022-10-25 Trim-Fast, LLC Window trim for replacement windows

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4211415A1 (de) * 1992-04-04 1993-10-07 Benecke Ag J H Folie oder Formkörper aus einem mehrphasigen Kunststoff

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3312542A1 (de) * 1983-04-07 1984-10-11 Bayer Ag, 5090 Leverkusen Weiche polymerlegierungen
DE3429523A1 (de) * 1984-08-10 1986-02-20 Alkor GmbH Kunststoffe, 8000 München Schaumlaminatfolie oder -bahn
US4731414A (en) * 1986-06-20 1988-03-15 General Electric Company Blends of an ASA terpolymer, an acrylic polymer and an acrylate based impact modifier
DE3722472A1 (de) * 1987-07-08 1989-01-19 Alkor Gmbh Folie und verfahren zu deren herstellung
DE3900064A1 (de) * 1987-07-08 1990-07-05 Alkor Gmbh Folie, insbesondere tiefziehfaehige folie, fuer kraftfahrzeuginnenraeume
DE3811899A1 (de) * 1988-04-09 1989-10-19 Bayer Ag Polymerisatmischung fuer flexible folien
DE3834607C2 (de) * 1988-10-11 1997-12-11 Alkor Gmbh Verfahren zur Herstellung von Gegenständen aus thermoverformbaren Kunststoffolien
DE4019799A1 (de) * 1990-06-21 1992-01-02 Bayer Ag Thermoplastische zusammensetzungen aus polyurethanen und partiell vernetzten alkylacrylatcopolymeren
FR2666838B1 (fr) * 1990-09-19 1995-06-02 Gerland Revetements a base d'elastomeres thermo-plastiques notamment revetements de sols.
DE4125981A1 (de) * 1991-08-06 1993-02-11 Bayer Ag Ethylenpolymerisate enthaltende polymerlegierungen fuer flexible folien
US5248546A (en) * 1991-08-30 1993-09-28 The B. F. Goodrich Company Vinyl based articles in contact with chloro-fluoro chemicals
US5334450A (en) * 1992-05-20 1994-08-02 The Dow Chemical Company Weatherable styrenic film structures with intermediate tie layer and laminates thereof
US5380785A (en) * 1993-04-05 1995-01-10 The Goodyear Tire & Rubber Company Rubbery polymer

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4211415A1 (de) * 1992-04-04 1993-10-07 Benecke Ag J H Folie oder Formkörper aus einem mehrphasigen Kunststoff

Also Published As

Publication number Publication date
ATE161869T1 (de) 1998-01-15
US5683815A (en) 1997-11-04
DE4322145C1 (de) 1994-11-03
WO1995001400A2 (de) 1995-01-12
DE4322145C2 (de) 2002-07-18
EP0658178B1 (de) 1998-01-07
EP0658178A1 (de) 1995-06-21
ES2112554T3 (es) 1998-04-01

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